1323 results about "Chain segment" patented technology

The invention provides a comb-shaped polymer binder, a pole piece and a battery, the comb-shaped polymer binder comprises an acrylate main chain, a flexible soft segment, a polar hard segment and a functional chain segment, the flexible soft segment, the polar hard segment and the functional chain segment are respectively grafted on the acrylate main chain, the flexible soft segment comprises an ether chain segment and / or an ester chain segment, the polar hard segment comprises a polar group and / or a first heteroaromatic ring group, and the functional chain segment comprises a functional group and a second heteroaromatic ring group. The functional chain segment comprises an aromatic ring group containing a pi-conjugated structure and / or a second heteroaromatic ring group containing a pi-conjugated structure. The comb-shaped binder adopts a structural design of'hard section anchoring + soft section buffering + functional side chain ', is helpful for enabling the binder to have high peel strength, stress buffering and electron conduction capabilities at the same time, is compatible with an existing wet coating-rolling process, is helpful for improving the peel strength and prolonging the cycle life of an electrode plate when being used for preparing the electrode plate, and is beneficial for improving the service life of the electrode plate. And the rate capability of the battery is improved.

The invention relates to the field of polyester materials, and particularly discloses modified polyester with low yellowness value and high glass transition temperature characteristics and a preparation method thereof, and the modified polyester is prepared by taking terephthalic acid, diphenyldicarboxylic acid and fluorenyl aromatic dicarboxylic acid as carboxylic acid monomers, respectively esterifying with ethylene glycol, and carrying out co-polycondensation on corresponding esterification products. According to the present invention, the biphenyldicarboxylic acid with the conjugated aromatic ring structure and the fluorenyl aromatic dicarboxylic acid monomer are selectively introduced to modify the PET, such that the regularity of the polyester chain segment is broken so as to ensure the optical performance of the polyester; the movement of a polyester chain segment is limited so as to improve the Tg value of polyester; and by matching with a novel preparation method, the yellowness value of the polyester material is reduced.

The invention discloses an adhesive containing epoxy-terminated polyurethane epoxy resin as well as a preparation method and application of the adhesive. The adhesive comprises the following components in parts by weight: 10-15 parts of epoxy resin, 70-75 parts of epoxy-terminated polyurethane epoxy resin, 19-21 parts of an amine curing agent and 8-15 parts of heat-conducting filler, wherein the epoxy-terminated polyurethane epoxy resin is obtained by reacting a polyurethane prepolymer and epoxy resin, NCO of the polyurethane prepolymer and hydroxyl of the epoxy resin are subjected to an addition reaction, and after the reaction is finished, NCO of a system is eliminated by adopting a small-molecule epoxy compound; the polyurethane prepolymer is obtained by reaction of isocyanate and polyether polyol with flexible chain segments. According to the adhesive, the curing heat release peak value is reduced, the toughness is improved, meanwhile, the high strength is kept, the foaming problem is avoided, the defects that a traditional epoxy adhesive is high in heat release and poor in toughness are overcome, and the adhesive is suitable for the fields such as aerospace and electronic and electric appliances which have strict performance requirements.

The invention provides a preparation method of a self-repairing resin-based composite material based on dynamic bonds. The self-repairing epoxy resin comprises one covalent dynamic bond of a Diels-Alder bond, a disulfide bond or a borate bond, and the preparation method of the self-repairing epoxy resin comprises the following steps: heating epoxy resin to a molten state, adding a curing agent component while stirring, and carrying out a prepolymerization reaction to obtain a prepolymer; the curing agent comprises a rigid diamine curing agent, a dynamic diamine monomer and a flexible chain segment regulator, and the dynamic diamine monomer contains a dynamic covalent bond; and carrying out curing molding on the prepolymer to obtain the self-repairing epoxy resin. And impregnating reinforced fibers or fabrics thereof with the prepared prepolymer, and heating and curing to obtain the self-repairing resin-based composite material. The invention provides a chemical molecule design, dynamic reversible chemical bonds are introduced into a resin matrix, and by constructing the dynamic bonds, the composite material has high performance of a traditional composite material and also has life-like self-healing ability.

The invention discloses intrinsic copolymerized low-temperature toughened polyamide resin which comprises a polyamide component and a flexible chain segment component, and the molar ratio of the polyamide component to the flexible chain segment component is 98.5: 1.5-85: 15; the invention also discloses a preparation method of the intrinsic copolymerized low-temperature toughened polyamide resin, which comprises the following steps: mixing a polyamide component and a flexible chain segment component, and carrying out polymerization reaction in a sectional or continuous manner, and comprises a pre-polymerization process and a post-polymerization process; the intrinsic copolymerized low-temperature toughened polyamide resin obtained by the preparation method disclosed by the invention keeps excellent mechanical strength and modulus while improving low-temperature resistance of the intrinsic copolymerized low-temperature toughened polyamide resin.

The invention relates to a long-life room-temperature phosphorescent material and a preparation method and application thereof.According to the phosphorescent material, epoxy resin is doped with an epoxy prepolymer containing a fluorine-containing chain segment to serve as a host matrix, F-pi and pi-pi non-covalent synergistic interaction is formed between the host matrix and aromatic fluorescent guest molecules, the energy level difference of the excited state is adjusted, and the phosphorescent material is obtained. Intersystem crossing (ISC) and radiative transition rates are optimized, so that the phosphorescence lifetime and environmental adaptability are improved; a fluorine-containing chain segment introduced into a polymer system can be enriched on the surface of a material to form a needle-shaped structure, so that the surface energy of the material is remarkably reduced, the antifouling property is excellent, and additional functions of lyophobicity, transparency, chemical stability and the like are also realized while ultra-long room-temperature phosphorescence is realized; and cooperative enhancement and multifunctional integration of optical performance and surface performance are realized.

The invention provides a damping liquid silicone rubber material which is obtained by curing a damping liquid silicone rubber raw material composition, and also provides damping liquid silicone rubber and a preparation method thereof. The hardness and strength of the liquid silicone rubber material are improved through filling of the MQ silicon resin and the high-white carbon black, meanwhile, a large number of interface areas are formed by the nano-particles and a matrix, microcosmic slippage of the interfaces is generated under the action of dynamic stress, mechanical energy is converted into heat energy through friction and viscous effects between the interfaces and molecular chains, and damping is improved; according to the invention, by introducing methyl-terminated vinyl silicone oil, a silicone rubber chain forms a large number of suspension chain structures, energy dissipation is enhanced, hydrogen-containing chain extension is carried out at a use end, a main polymer has a longer free molecular chain segment to generate a friction effect, and the damping performance of the liquid silicone rubber material is further improved. Experimental results show that the liquid silicone rubber provided by the invention has excellent damping, mechanical and other properties under high hardness.

This invention discloses a PETG co-extruded composite sheet and its preparation method. The method involves adding extruder and APET masterbatch to an extruder, then layering and combining the extruder melt and APET masterbatch melt to form a composite melt with an upper and lower layer of extruder and a middle layer of APET masterbatch. This is then shaped by roller pressing to obtain the PETG co-extruded composite sheet. During the blending process of modified polyester and modified filler, the epoxy group structure in the modified polyester molecule can react with the secondary amine in the modified filler, resulting in mild cross-linking and increasing the strength of the polyester material. The modified polyester molecular chain contains polysiloxane segments, and also has polysiloxane segments branched onto its side links. When impacted, the flexible polysiloxane segments absorb and dissipate a large amount of energy through violent movement, rotation, and entanglement. Furthermore, the nano-reinforcing points formed by the cage-like silsesquioxane structure within the molecule contribute to the excellent scratch resistance of the prepared composite sheet.

The invention discloses a UV curing adhesive for coating a low-refractive-index optical fiber and a processing method thereof, belongs to the technical field of adhesive preparation, and is used for solving the technical problem that the refractive index and the damp-heat resistance of the UV curing adhesive for coating the optical fiber in the prior art need to be further improved. The preparation method comprises the following steps: introducing a low-refractive-index hybrid siloxane prepolymer, a multi-component interface bonding prepolymer and a modified branched polyester prepolymer into a system together, and constructing a compact and uniform organic-inorganic three-dimensional network in a curing process by utilizing silica condensation, interface chemical bonding and a flexible chain segment cross-linking reaction, the low-refractive-index hybrid siloxane prepolymer endows a film layer with a stable refractive index, the multi-component interface bonding prepolymer enhances the binding force of a base material, the modified branched polyester prepolymer improves stress buffering and toughness, and the obtained cured film is low in refractive index, firm in interface bonding and small in mass change in a humid and hot environment and shows excellent optical stability and long-term reliability.

The invention relates to a PVB (Polyvinyl Butyral) film for PDLC (Polymer Dispersed Liquid Crystal) dimming glass, a preparation method and the PDLC dimming glass, and belongs to the technical field of dimming glass. The PVB film for the PDLC dimming glass comprises PVB resin and a plasticizer, at least one end group of the plasticizer is a benzoate group, and the plasticizer belongs to benzoate. Through molecular structure design, the main chain of the plasticizer can be a polyether type [-CH2-CHY-O-] n chain segment or a polyol skeleton, and meanwhile, benzoate groups or specific end group structures (such as branched chain alkyl, aromatic hydrocarbon and the like) are introduced, so that the interaction (such as hydrogen bond damage, dipole interaction, pi-pi accumulation and the like) between the plasticizer and PVB resin is enhanced, and the plasticizer can be used for preparing PVB resin. By introducing structures such as branched chains and aromatic rings, the steric hindrance and rigidity of molecules are greatly improved, and migration and precipitation phenomena of the plasticizer in the PVB film are effectively inhibited.

The invention provides polyester and a preparation method and application thereof, the polyester comprises a structural unit derived from the following monomer components: at least one monomer component I selected from hydroxybenzoic acid or hydroxynaphthoic acid; and at least one monomer component II, wherein the monomer component II is selected from p-hydroxybenzoic acid containing a substituent group. A small amount of the monomer component II is introduced into the polyester material, interaction points are provided for chain segments of the polymer, the chain segments are promoted to form a branched structure, and therefore the melt strength of the polymer is well improved.

The invention discloses a high-barrier material based on a PET aminolysis monomer and a preparation method of the high-barrier material, and belongs to the technical field of high polymer materials. The preparation method comprises the following steps: carrying out aminolysis reaction on polyethylene glycol terephthalate (PET) to prepare a dihydric alcohol monomer containing an amido bond, and carrying out polymerization reaction on the dihydric alcohol monomer and aliphatic dibasic acid to prepare a polyesteramide (PEA) material. The prepared PEA material has excellent oxygen barrier property and toughness, the oxygen barrier property of the PEA material is obviously superior to that of a PET material, and the barrier property and mechanical property of the PEA material can be regulated and controlled by changing the length of a methylene chain segment of the aliphatic dibasic acid monomer. The aliphatic dibasic acid monomer can be derived from biomass resources, the reaction condition is mild, the process is simple, and the method is suitable for industrial large-scale production.

The invention relates to a flame-retardant high-temperature-resistant fiber woven fabric and a preparation process thereof, and belongs to the technical field of textiles. The preparation method comprises the following steps: grafting and crosslinking a self-made grafting monomer and polyvinyl chloride, and then weaving to obtain the modified polyvinyl chloride fiber fabric; a phosphate group in the monomer can promote surface carbonization to form a protective carbon layer, silicate generated by decomposition of a siloxy group at a high temperature is combined with the carbon layer to improve the strength and melt viscosity of the carbon layer, and the phosphate group and the siloxy group synergistically enhance the flame retardance and the molten drop resistance of the fabric; a cyclic phosphate group and a pyridine ring are connected to form a rigid structure with relatively high thermal stability, chain segment movement is limited, a plurality of siloxy groups in a monomer are crosslinked to form a crosslinked network, molecular chain segments are difficult to move, and the combination of the rigid group and the crosslinked network improves the high temperature resistance of the fabric and effectively improves the mechanical properties of the fabric; in addition, the positively charged quaternary ammonium salt structure in the monomer improves the antistatic performance of the fabric, and cooperates with trifluoromethyl to destroy the structural integrity of bacterial cells, so that the fabric achieves efficient bacteriostasis.

The invention provides a nylon modified material as well as a preparation method and application thereof, and relates to the technical field of nylon compositing, the nylon modified material comprises the following components: nylon 66, low-viscosity nylon 6, a toughening agent, a compatilizer and a flow crystallization accelerant; wherein the toughening agent comprises a block copolymer containing a polyethylene glycol chain segment and a polydimethylsiloxane chain segment; the compatilizer comprises a compound containing a diglycidyl ether group. According to the nylon modified material provided by the invention, under the condition that the modulus of nylon 66 is slightly reduced, the impact strength is improved, so that the nylon modified material has the characteristics of high flowability, high toughness, self-lubrication and the like, and can meet the requirements of occasions such as automobile parts and industrial production.

The invention is directed to a biodegradable, thermoplastic multiblock copolymer, to a process for preparing a biodegradable, thermoplastic multiblock copolymer, to the use of a biodegradable thermoplastic multiblock copolymer, to a composition for the delivery of at least one pharmacologically active compound to a host, and a medical device comprising a biodegradable, thermoplastic multiblock copolymer. The biodegradable, thermoplastic multiblock copolymers of the invention comprise at least one prepolymer (A) segment and at least one hydrolysable amorphous prepolymer (B) segment, wherein the segments are linked by a multifunctional chain extender, wherein the at least one prepolymer (A) segment comprises: a) one or more hydrolysable linkages, b) a water-soluble polyoxazoline-based polymer, and c) reaction products of one or more cyclic monomers and / or one or more non-cyclic monomers, wherein the water-soluble polyoxazoline-based polymer is a polymer containing a repeating unit of structure −[N(COR1)CH2CH2]n− where R1 is independently selected for each repeating unit from an alkyl group and n is 3-100, and wherein the multiblock copolymer is amorphous.

The invention discloses a super-tough temperature-resistant self-repairing copolymer based on SBS acrylate dynamic synergistic reinforcement and a preparation method thereof, and belongs to the technical field of self-repairing materials in compositions of high-molecular compounds. The copolymer comprises SBS, an acrylate monomer, a dynamic bond functional monomer, an initiator, a cross-linking agent, a nano reinforcing agent and a temperature-resistant modifier, wherein the dynamic bond functional monomer comprises at least one of acryloyloxyethyl disulfide, acrylamide acryloyloxyethyl disulfide or anthracene methyl acrylate. The molecular structure of the dynamic bond functional monomer contains a carbon-carbon double bond and a disulfide bond, in the free radical polymerization reaction initiated by the initiator, the carbon-carbon double bond is opened and is subjected to a copolymerization reaction with an SBS chain segment or an acrylate chain segment, so that the disulfide bond enters the polymer chain segment, the dynamic disulfide bond can be reversibly broken and recombined at high temperature, and the dynamic bond functional monomer is obtained. The high-temperature viscoelasticity is maintained, the material is endowed with self-repairing capability, and the problem that the viscoelasticity of the material in the prior art is sharply reduced at high temperature (gt; 120 DEG C) is solved.

The invention relates to polyethylene wax with a reversible crosslinking characteristic and a preparation method and application thereof, and relates to the field of polymer functional aids and processing and application thereof. The polyethylene wax with the reversible cross-linking characteristic is prepared from three monomers of furyl ethylene, maleimide ethylene and ethylene through double-bond addition copolymerization, and the number-average molecular weight is 1000-100000. The polyethylene wax provided by the invention can be used as a flow modifier during polyethylene material processing and a cross-linking modifier during use. The low molecular weight polyethylene wax can reduce the energy consumption of processing equipment and increase the flatness of the product. And meanwhile, the reversible crosslinking of furan and maleimide groups on the chain segment can endow the resin with thermoset property in use and thermoplastic cycle processability after use.

The invention belongs to the technical field of high-performance polymer materials, and relates to thermal-crosslinkable polyimide, polyimide foam and a preparation method and application thereof. Aiming at the problem that the foaming performance of the existing polyimide foaming material is poor due to the fact that the melt strength and the chain segment activity are difficult to balance, the invention provides a method for regulating and controlling the rheological property by controlling the number-average molecular weight (Mn = 15-45kDa) of a precursor and introducing a thermally-crosslinkable end-capping group. The precursor can form a parison with a specific elastic network structure through hot-pressing cross-linking, and then the polyimide foam which is high in foaming rate, uniform and fine in foam hole, low in density and excellent in heat resistance can be prepared through a two-step method of supercritical fluid saturation pressure relief and high-temperature secondary foaming. The method realizes predictable control from molecular parameters to foaming performance, is suitable for various thermoplastic polyimide systems, and has a wide application prospect in the fields of aerospace heat insulation and the like.

The invention discloses a defoaming agent for industrial automobile paint and a preparation method of the defoaming agent. The defoaming agent is prepared from the following raw materials in parts by mass: 20-40 parts of a star block polyether-siloxane copolymer; 10 to 25 parts of nano hydrophobic silicon dioxide aerogel; 30-70 parts of an alkylbenzene solvent (boiling point gt: 200 DEG C); 3 to 8 parts of epoxy group modified polyether siloxane; and 1 to 3 parts of polyether modified polydimethylsiloxane. The molecular weight range of the star block polyether-siloxane copolymer can effectively balance the defoaming property and compatibility, the siloxane chain segment of the star block polyether-siloxane copolymer destroys the elasticity of a foam film, and the siloxane chain segment cooperates with alkylbenzene to reduce local surface tension and accelerate foam rupture. The polyether chain segment and the siloxane chain segment have a synergistic effect, and the polyether chain segment adjusts hydrophilicity to adapt to different environments.

The invention relates to a preparation, regulation and control method of a thermoplastic elastomer encapsulating material in the technical field of new materials, which comprises the following steps: realizing an in-situ reaction process by controlling the concentration and reaction temperature of reactive functional groups in the encapsulating material according to an interface reaction rate constant and active group distribution density; if the reaction conversion rate reaches a preset value, a chemically bonded interface bonding layer is formed; monitoring the stress distribution state in the rubber coating layer by adopting a stress analysis algorithm, and when detecting that local stress concentration exceeds the yield strength of the material, dispersing a stress concentration area by adjusting the length of a flexible chain segment and the density of a rigid cross-linking point in a cross-linking network; and deformation data and a bonding strength change trend of the interface bonding layer in the temperature cycling process are obtained, if the bonding strength attenuation rate exceeds a preset threshold value, a dynamic cross-linking mechanism is activated, and the dynamic equilibrium state of interface bonding is maintained through fracture and recombination of a reversible covalent bond.

The invention belongs to the field of photovoltaic materials, provides a preparation method and application of reinforced polyurethane resin for a photovoltaic frame, and solves the problem that the existing polyurethane resin for the photovoltaic frame cannot have excellent flame retardant property, water resistance, aging resistance and mechanical property at the same time. Comprising the following steps: carrying out a reaction on polytetrahydrofuran ether glycol and polyisocyanate to obtain a polyurethane prepolymer, and chemically grafting a phosphorus-containing compound onto a polyurethane main chain by using prepared 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, so as to obtain the flame-retardant polyurethane. Hydroxyl-terminated polydimethylsiloxane and polyhydric alcohol are used as part of flexible chain segments to be embedded into a polyurethane main chain, 2-(2-hydroxy-4-acryloyl)-2H-benzotriazole is added to serve as an anti-ultraviolet agent, and final polyurethane resin is obtained through reaction. And injecting the polyurethane resin and the glass fiber into a mold, and preparing the photovoltaic frame profile through a pultrusion process.

The invention discloses an optical monomer and a preparation method thereof, a composition, a resin material and a preparation method thereof. The optical monomer provided by the invention comprises a quaternary carbon structure and a side chain connected with the quaternary carbon structure through an ester bond. The side chain comprises a thioether chain segment connected with an ester bond, an aromatic group connected with the thioether chain segment and an epoxy group connected with the thioether chain segment. The optical monomer provided by the embodiment of the invention takes a quaternary carbon structure as a core skeleton, and a side chain sequentially comprises an aromatic group, a thioether chain segment and a terminal epoxy group. A thioether structure with high polarizability and an aromatic group are introduced into the molecular design of the optical monomer, so that the refractive index and the optical transparency of a resin material are remarkably improved. And the rigidity of the epoxy aromatic ring is beneficial to improving the thermal stability and mechanical strength of the resin material. The epoxy group at the tail end can react with conventional epoxy resin to form a compact network structure, so that the stability of the resin material is improved, and the yellowing tendency is reduced.

The invention belongs to the technical field of water-based ink, and provides high-temperature-resistant water-based ink for laminated iron and a preparation method thereof.According to the high-temperature-resistant water-based ink for laminated iron and the preparation method of the high-temperature-resistant water-based ink for laminated iron, the design of a double-resin system formed by compounding waterborne polyurethane resin and flexible segment copolymer modified ternary vinyl chloride-vinyl acetate resin is adopted, and the synergistic effect of surface modified nanometer aluminum oxide reinforcing filler and an elastomer modifier is combined; the interface compatibility is improved through a siloxane coupling agent surface treatment technology, a composite coating structure with balanced flexibility and heat resistance is formed, the high temperature resistance can reach 200 DEG C or above, continuous use is free of failure, the flexibility is free of cracking through a T-bend test, the adhesion of a coating film reaches the 0-level standard, the drying time is shortened to be within 30 minutes, and the service life of the coating film is prolonged. The comprehensive performance index that the storage stable period is prolonged to 12 months or above is achieved, the technical problems that an existing laminated iron coating is insufficient in flexibility and poor in thermal stability in a high-temperature environment are solved, and the high-temperature-resistant laminated iron coating has wide food packaging and industrial protection application value.

The invention belongs to the field of RAFT (reversible addition-fragmentation chain transfer) polymerization reaction, and particularly discloses a macromolecular RAFT polymer, a preparation method and application of the macromolecular RAFT polymer in RAFT reaction. The macromolecular RAFT polymer at least comprises a block Z-[A] x-b-[B] y; wherein Z is a small molecule RAFT group; the block [A] x is formed by double-bond addition polymerization of hydrophilic monomers, and the hydrophilic monomers are C7-C20 quaternary ammonium salt monomers and / or sulfonate monomers; the block [B] y is formed by double-bond addition polymerization of a hydrophobic monomer, and the hydrophobic monomer is a C10-C22 methacrylate or acrylate monomer. The hydrophilic monomer with the quaternary ammonium salt monomer and / or the sulfonate monomer is selected to construct the hydrophilic chain segment, and meanwhile, the C10-C22 acrylate monomer / methacrylate monomer with strong hydrophobicity is introduced, so that the emulsifying property of the macromolecular RAFT reagent is improved.

The invention provides an olefin polymer composition and application thereof, and relates to the technical field of composite materials. The olefin polymer composition is prepared from the following raw material components in parts by weight: 100 parts of an olefin polymer, 0.5 to 5 parts of an anthraquinone compound and 1 to 5 parts of aspartic ester resin, the structure of the aspartic ester resin contains C8-C24 alkylene and a polyethylene glycol chain segment. The olefin polymer composition has good hydrophilicity, and the treatment effect of the olefin polymer composition on nitrogen-containing sewage can be improved.

The invention relates to the technical field of polymer microspheres, in particular to a thermal expansion microsphere and a preparation method and application thereof. The thermal expansion microsphere comprises a polymer shell and an inner core coated in the shell, the inner core comprises a foaming agent, and the thermal expansion microsphere is characterized in that the polymer shell is formed by polymerization reaction of a monofunctional monomer and a cross-linking agent under the initiation of an initiator; wherein the difference value between the 10-hour half-life period temperature of the initiator and the peak exothermic temperature of the cross-linking agent is 60-81 DEG C. By controlling the decomposition activity of the initiator and the reaction activity of the cross-linking agent to be matched in a specific temperature difference range, construction of a uniform cross-linked network between shell polymer chain segments is achieved, and the obtained thermal expansion microspheres have a wide expansion temperature range, good heat resistance, stable expansion behavior and high expansion rate.

The invention relates to a toughened modified epoxy resin material and a preparation method thereof, and belongs to the technical field of high polymer materials. The toughened modified epoxy resin material comprises the following components in parts by weight: 90-120 parts of epoxy resin, 8-25 parts of a curing agent, 1-3 parts of a diluent, 0.5-5 parts of a curing accelerator, 4-18 parts of graphite, 5-15 parts of a modified toughening agent and 1-5 parts of a modified flame retardant, in the modified flexibilizer, a benzene ring and carbonyl of a polyimide structure endow the material with excellent heat resistance, intertwining between chains is avoided, embrittlement is avoided, the material and polyurethane are synergistically toughened, and a flexible-Si-O-Si-chain segment relieves thermal stress generated in the resin and improves the tensile strength; benzoxazine in the modified flame retardant contains a nitrogen element, releases non-combustible gas during combustion, forms a carbon layer at high temperature and covers the surface of the material, so that the flame retardance is improved; the toughened and modified epoxy resin material prepared by the invention not only has good toughening and heat-resisting effects, but also has an excellent flame-retardant effect.

According to the dispersing agent for the positive electrode slurry, the positive electrode slurry, the positive plate and the electrochemical device, the dispersing agent comprises a solvation chain segment, the solvation chain segment is a hyperbranched polymer, and a terminal unit of the hyperbranched polymer is an electronegative group. According to the dispersing agent for the positive electrode slurry, provided by the invention, the hyperbranched polymer with an electronegative terminal group is used as a solvation chain segment, and a high-density terminal functional group is provided through a hyperbranched structure, so that the anchoring capability and the space stabilization effect on a positive electrode active material are remarkably enhanced; meanwhile, by utilizing the electrostatic repulsion effect of electronegative groups and the surface of the positive electrode material, the dispersion stability of the slurry is effectively improved, and sedimentation and agglomeration are inhibited.

The application discloses a high-flexibility drag chain cable and a preparation method thereof, and belongs to the technical field of cable processing, and is used for solving the technical problem that the flame-retardant property and wear resistance of the drag chain cable in the prior art need to be further improved, and specifically comprises an electric core, a wrapping layer and a sheath layer which are sequentially arranged from inside to outside. The modified polyorganosiloxane and phosphorus-based substances are prepared into a modified flame retardant through amine aldehyde condensation, the modified flame retardant is introduced into a polyurethane segment through block reaction, the modified polyurethane with a three-dimensional network structure is obtained through chain extension reaction, the modified polyurethane, a filler and auxiliary additives are melt-extruded and coated outside the wrapping layer to obtain the drag chain cable, so that the flame-retardant property and wear resistance of the drag chain cable are improved, and the twist resistance of the drag chain cable is also improved.

The invention belongs to the technical field of high polymer material preparation, and provides a low-melting-point toughened copolyester chip and a preparation method thereof. The preparation method comprises the following steps: firstly, preparing hyperbranched polyester of which the surface is rich in carboxyl-terminated functional groups through core growth of polybasic acid alcohol and end group functionalization reaction of anhydride; the other chain extender is a linear chain extender which has a long flexible chain segment and two tail ends of which are also functionalized by carboxyl groups, and is obtained by carrying out end group esterification reaction on polyether glycol; then, in the synthesis process of the main polyester, carrying out multi-stage melt polycondensation on an aromatic dibasic acid component and a polyol component under the action of a composite catalyst system, introducing the hyperbranched polyester and a chain extender into a reaction system in the form of slurry, and covalently bonding a functional additive to a copolyester main chain through a polycondensation process, so as to obtain the hyperbranched polyester. An integrated network reinforced structure is formed, so that the copolyester chip has the characteristics of low melting point and excellent toughness.