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202 results about "Transesterification" patented technology

In organic chemistry, transesterification is the process of exchanging the organic group R″ of an ester with the organic group R′ of an alcohol. These reactions are often catalyzed by the addition of an acid or base catalyst. The reaction can also be accomplished with the help of enzymes (biocatalysts) particularly lipases (E.C.3.1.1.3).

Isosorbide-based copolyester as well as preparation method and application thereof

PendingCN121537618APolymer scienceEnd-group
The invention provides isosorbide-based copolyester as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. According to the preparation method, a step-by-step esterification method is adopted, firstly, isosorbide, excessive aromatic dicarboxylic acid and an acylating agent are subjected to a first esterification reaction, so that the acylating agent can efficiently and specifically activate secondary hydroxyl of isosorbide, and the initial esterification rate of isosorbide is greatly increased. Meanwhile, the excessive aromatic dicarboxylic acid ensures that the generated isosorbide prepolymer takes carboxyl as a terminal group, so that isosorbide molecules are'locked 'in the middle of a polymer chain segment. Due to the fact that the isosorbide is embedded in the middle of the chain segment in advance, the problem that the isosorbide falls off in the ester exchange reaction due to the fact that the isosorbide is located at the chain end and low in reaction activity in the subsequent polycondensation stage is effectively solved, and therefore the retention rate of the isosorbide in the final polymer is greatly increased, and the glass-transition temperature of the isosorbide is greatly increased.
Owner:CHINA RESOURCES PACKAGING MATERIALS CO LTD

Molecular sieve catalyst for synthesizing methyl ethyl carbonate by transesterification method and regeneration method of molecular sieve catalyst

The invention discloses a molecular sieve catalyst for synthesizing methyl ethyl carbonate by a transesterification method and a regeneration method, and relates to the technical field of molecular sieve catalysts, the molecular sieve catalyst comprises a microporous double-active-center inner core and an amphoteric mesoporous shell; the microporous double-active-center core takes the X-type zeolite as a carrier to load potassium, cesium, lanthanum and barium; the amphoteric mesoporous shell is an MCM-41 and SBA-15 composite mesoporous silica layer coating the outer part of the inner core and has a double-mesoporous structure, amino propyl triethoxy silane and carboxyethyl triethoxy silane are grafted on the surface of the amphoteric mesoporous shell, and zirconium and titanium are co-doped. According to the invention, collaborative optimization of active centers and mass transfer channels is realized through a core-shell structure of a microporous double-active-center core and an amphoteric mesoporous shell. The activity and selectivity of catalytic transesterification are remarkably improved by the microporous core; due to the double-mesoporous structure and surface functional modification of the amphoteric mesoporous shell, the mass transfer efficiency of reactants and products is improved, and the adaptability of the catalyst to a reaction system is enhanced.
Owner:RENQIU NORTH CHINA PETROLEUM CLEAN ENVIROMENTAL PROTECTION CO LTD

Dispersing agent based on modified benzyl resin micelle and preparation method thereof

The preparation method comprises the following steps: S1, hydrophilic-hydrophobic bi-component modification reaction: dissolving a styrene-maleic anhydride copolymer, hydrophilic polyethylene glycol monomethyl ether and hydrophobic long-chain alkyl alcohol in butanone according to a ratio, adding a catalyst, stirring, reacting, filtering, washing, and drying to obtain the dispersing agent for the lithium battery diaphragm based on the modified benzyl resin micelle. Performing ester exchange reaction on anhydride bonds of the styrene-maleic anhydride copolymer and polyether hydroxyl and alkyl alcohol hydroxyl respectively to obtain a modified intermediate; s2, neutralization reaction: dropwise adding organic alkali into the modified intermediate, and adjusting the pH value to obtain a modified SMA solution containing carboxylate groups; s3, preparing nano-micelles: dropwise adding the modified SMA solution into deionized water, and stirring to enable the modified SMA solution to be self-assembled to form the nano-micelles, so as to obtain nano-micelle dispersion liquid; and S4, dispersing agent forming: stirring the nano-micelle dispersion liquid to remove butanone so as to obtain the water-based dispersing agent.
Owner:SHANGHAI FUJUYUAN NEW MATERIALS CO LTD

A method for preparing high-quality bio-based 1,9-nonanediol

This invention discloses a method for preparing high-quality bio-based 1,9-nonanediol, comprising the following steps: transesterification, precipitation, fatty acid methyl ester refining, ozone oxidation pyrolysis, solvent recovery, esterification, dimethyl azelaate refining, and hydrogenation to obtain high-quality bio-based 1,9-nonanediol. This invention achieves gradient and full-component utilization of vegetable oil raw materials: the oil-based portion of triglycerides is used to produce high-quality bio-based 1,9-nonanediol, while simultaneously producing byproducts such as methyl palmitate, methyl stearate, propionic acid, hexanoic acid, and nonanoic acid; the glycerol-based portion of triglycerides is used as a byproduct of glycerol production. This invention utilizes esterification to reconstruct the products of ozone oxidation pyrolysis, converting the high-boiling-point monomethyl azelaate into the low-boiling-point dimethyl azelaate, achieving efficient separation from saturated fatty acid methyl esters. The dimethyl azelaate, as a raw material, is then hydrogenated to obtain high-quality nonanediol, significantly reducing production costs.
Owner:ZHEJIANG UNIV OF TECH

A catalytic system for ester exchange reaction of swill-cooked oil

The present application provides a kind of waste oil transesterification reaction catalytic system, belong to biomass refining field.The preparation steps of catalyst include: in the solution containing Ni (NO3) 2 And Fe (NO3) 3 Carboxymethyl cellulose is added, then urea is added, reaction is carried out, and nano-porous NiFe2O4 is obtained, MgCl2 / ZnCl2 Solution and KOH / K2CO3 Solution are added to NiFe2O4 water dispersion, reaction is carried out, solid product is collected, calcination is carried out, and catalyst is obtained.Catalyst is added to waste oil to carry out catalytic reaction.The present application adopts carboxymethyl cellulose to regulate the crystal form, grain size and dispersity of catalyst carrier, and the obtained solid magnetic catalyst can improve the production efficiency of waste oil for preparing biodiesel.The catalyst has high active site, fast reaction rate, mild reaction condition, can reduce reaction energy consumption and production cost.The catalyst also has good magnetic property, is convenient for recovery.The catalyst has good stability, improves the controllability and stability of reaction.
Owner:QILU UNIVERSITY OF TECHNOLOGY (SHANDONG ACADEMY OF SCIENCES)

Bismuth-containing catalyst with heteroatoms-bearing dicarboxylate ligand

UndeterminedAE202602173APolymer sciencePtru catalyst
The present invention relates to a bismuth-containing catalyst of formula (R1)2-(R2)-(Bi)3+ (I), wherein (R1)2- is a dianion of formula (II*), wherein A is unsubstituted or at least monosubstituted linear C3-30-alkylene, wherein at least two not adjacent CH2 groups of C3-30-alkylene are replaced by a heteroatom independently selected from the group consisting of O, S, 5 NH, N-C1-30-alkyl, N-C6-14-aryl and N-C7-30-aralkyl, wherein alkyl and aryl fragments of N-C1-30-alkyl, N-C6-14-aryl, N-C7-30-aralkyl may at least be monosubstituted by hydroxyl, halogen, -CF3, NH2, -NH-C1-6-alkyl, -NH- phenyl, -N(C1-6-alkyl)2, -N(phenyl)2, -SH, -S-C1-6-alkyl, -S-phenyl, -O-C1-6-alkyl or -O-phenyl, to process for the preparation of the bismuth containing catalyst, to a process for the preparation of a compound, oligomer or polymer comprising at least one urethane group using the bismuth-containing catalyst, to a composition comprising (i) at least one monoalcohol (B1) or polyol (B2), (ii) at least one polyisocyanate (A) and (iii) the bismuth-containing catalyst, to a coating or adhesive layer formed from the composition on a substrate, to a foam formed from the composition, and to the use of the bismuth-containing catalyst in for preparing compounds, oligomers or polymers comprising a urethane group, as esterification and transesterification catalyst and as catalyst for ring-opening polymerizations of lactones and epoxides.
Owner:BASF SE

Potassium feldspathoid precursors and dispersions thereof, potassium feldspathoid catalysts and methods of making and use

This invention discloses a potassium nepheline precursor and its dispersion, a potassium nepheline catalyst, its preparation method, and its applications. The potassium nepheline precursor of this invention has an amino-containing silane coupling agent grafted onto its surface. The potassium nepheline precursor dispersion of this invention comprises a potassium nepheline precursor and a dispersion medium, wherein the average diameter of the potassium nepheline precursor in the dispersion is 5–20 nm. The potassium nepheline catalyst prepared using the potassium nepheline precursor dispersion of this invention exhibits high activity and good stability when used in transesterification reactions to produce biodiesel.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Production method of polyaromatic-carbonic acid-aliphatic copolyester

The invention belongs to the technical field of polymer materials, and particularly relates to a polyaromatic-carbonic acid-aliphatic copolyester production method which comprises the following steps: mixing aromatic dibasic acid and aliphatic dihydric alcohol, feeding into a first esterification kettle, and adding an esterification catalyst for esterification reaction to obtain an esterification product; uniformly mixing aliphatic dihydric alcohol, feeding the mixture into a second esterification kettle, adding diester carbonate and a transesterification catalyst into the second esterification kettle, reacting to obtain a transesterification product, and feeding the transesterification product into a demonomerisation kettle to obtain a demonomerisation product; mixing the esterification product and the demonomerisation product with a polycondensation catalyst and a stabilizer, shearing and homogenizing, feeding into a pre-polycondensation kettle for reaction to obtain a pre-polycondensation product, feeding the pre-polycondensation product into a final polycondensation kettle for reaction to obtain a copolymer, and performing water-cooling granulation to obtain a copolyester product. According to the production method provided by the invention, the final polycondensation time can be shortened, and the weight-average molecular weight and the mechanical strength of the prepared copolyester are improved.
Owner:SHANGHAI JUYOU CHEM ENG

Polyester resin composition and resin molded article

PCT designated stageWO2026094466A1Polytetramethylene terephthalateElastomer
This polyester resin composition contains a polybutylene terephthalate resin, a recycled polyethylene terephthalate resin, a transesterification inhibitor, a carbodiimide compound, and an elastomer. The amount of terminal hydroxyl groups in the polybutylene terephthalate resin is 30-70 mmol / kg relative to the total amount of the polybutylene terephthalate resin and the recycled polyethylene terephthalate resin. The amount of the carbodiimide compound is 0.2-1.5 mass% relative to the total amount of the polyester resin composition. The amount of the elastomer is 3-15 mass% relative to the total amount of the polyester resin composition.
Owner:DAICEL CORP

Beta-hydroxy fatty acid ester polymers and process for preparing beta-hydroxy fatty acid ester polymers by polycondensation of transesterification

The present application relates to the field of beta-hydroxy fatty acid ester polymer preparation, further to a kind of beta-hydroxy fatty acid ester polymer and the method for preparing the polymer.The structural formula of the polymer is as shown in formula 1:Wherein, R1 is H or C1-C12 alkyl, R2 is C1-C6 alkyl;The weight average molecular weight of the polymer is 8000-200000;The number average molecular weight of the polymer is 5000-180000;Polydispersity index is 1-2.5.The beta-hydroxy fatty acid ester polymer of the present application has higher molecular weight, narrower molecular weight distribution, has the performance of corresponding biofermentation synthesis beta-hydroxy fatty acid ester polymer, and does not contain the impurity that bio-synthesis beta-hydroxy fatty acid ester polymer is difficult to remove, has higher application value.The preparation method of the present application, reaction condition is relatively mild, process is simple, and has higher process safety.
Owner:CHENGDU ORGANIC CHEM CO LTD CHINESE ACAD OF SCI

Preparation method of 3-ethoxy isoamyl propionate

The invention relates to a preparation method of 3-ethoxy isoamyl propionate, and belongs to the technical field of organic solvent synthesis. The preparation method of the 3-ethoxy isoamyl propionate comprises the following steps: S1, adding ethanol, a polymerization inhibitor and a catalyst A into a reaction kettle, heating to 40-55 DEG C, then dropwise adding ethyl acrylate, preserving heat, and carrying out addition reaction for 1-3 hours to obtain a reaction mixture; s2, adding an acidic material for neutralization, and carrying out vacuum rectification to obtain ethyl 3-ethoxypropionate; s3, adding ethyl 3-ethoxypropionate and a catalyst B into a reaction kettle, heating to 100-120 DEG C, introducing isoamyl alcohol, controlling the reaction temperature to 100-115 DEG C, and carrying out transesterification for 2.5-4 hours to obtain a crude product; and S4, cooling to stop the reaction, separating to remove the catalyst B, and carrying out reduced pressure rectification on the obtained crude product to obtain the 3-ethoxypropionic acid isoamyl ester. The method has the effects of mild process, high conversion rate and high product yield.
Owner:EASOURCE NEW MATERIAL CO LTD

Trans-esterification catalysis of un-neutralized polyalkoxylates

A method for producing a (meth)acrylate monomer of a polyalkoxylated alcohol includes providing an unneutralized polyalkoxylated alcohol, wherein the unneutralized polyalkoxylated alcohol is produced by base catalyzed alkoxylation. An alkyl (meth)acrylate is transesterified with the unneutralized polyalkoxylated alcohol to produce the (meth)acrylate monomer of the polyalkoxylated alcohol. No transesterification catalyst is added during the step of transesterifying the alkyl (meth)acrylate with the unneutralized polyalkoxylated alcohol.
Owner:ROHM & HAAS CO +1

Preparation method and application of polyether glycol

The invention relates to a preparation method and application of polyether glycol, the structural formula of the polyether glycol is shown in the specification, the preparation method comprises the following steps: trimethylolpropane and carbonic ester are subjected to transesterification to obtain a ketal compound, then the ketal compound is used as an initiator to polymerize ethylene oxide to obtain nonionic polyether mono-alcohol, and the nonionic polyether mono-alcohol is used as a solvent. And carrying out Williamson reaction on the polyether monoalcohol to obtain methyl-terminated polyether, and carrying out ring-opening reaction on the methyl-terminated polyether under an acidic condition to obtain the nonionic polyether glycol. The preparation process is wide in raw material source, low in cost, mild in condition, efficient in reaction and wide in industrialization prospect.
Owner:WANHUA CHEM GRP CO LTD

Sble mutants with altered activity and sble homologues

PendingCN122459450ABumblebeeHydrolysis
The present invention relates to mutants of the bumblebee Yarrowia SBLE enzyme having modulated transesterification and / or esterification activity compared to the bumblebee Yarrowia SBLE enzyme, and to homologues of the bumblebee Yarrowia SBLE enzyme, such as the C. bogoriensis LE enzyme, the B. batistae LE enzyme and the R. riograndensis LE enzyme, having transesterification and esterification activity on bolaform glycolipids. The present invention also provides genetically modified yeast strains comprising a mutant LE enzyme or a bumblebee Yarrowia SBLE enzyme homologue of the present invention. The present invention further provides the use and methods of the mutant LE enzymes, the bumblebee Yarrowia SBLE enzyme homologues and the modified yeast strains of the present invention for the production of acidic glycolipids, lactone-form glycolipids and / or glycolipid oligomers / polymers / esters. The present invention also provides the three-dimensional structure of the bumblebee Yarrowia SBLE enzyme and its use for the design of mutants having modulated hydrolysis and / or transesterification activity.
Owner:UNIV GENT +2

Method for manufacturing polycarbonate resin

This invention relates to a method for preparing a capped polycarbonate resin, comprising the steps of: a) reacting a dihydroxy compound and a carbonate in a melt, optionally in the presence of an transesterification catalyst, thereby forming a polycarbonate in a molten phase having free hydroxyl terminal groups; and b) reacting the polycarbonate in the molten phase with a capping agent to produce a capped polycarbonate resin, wherein the capping agent comprises an anhydride, and wherein the polycarbonate in the molten phase is subjected to at least partially vacuum after being combined with the capping agent. The invention also relates to capped polycarbonate resins obtained or obtainable by this method. Furthermore, the invention relates to molding articles comprising or composed of such capped polycarbonate resins, and methods for manufacturing such molding articles.
Owner:SABIC GLOBAL TECHNOLOGIES BV

A bio-based polyol, and a method of making and using the same

PendingCN122325331AEpoxyTrans esterification
The application provides a kind of bio-based polyol and its preparation method and application.The preparation method contains the following steps: mixing alcohol with catalyst, adding epoxy soybean oil to react, removing catalyst and VOC after treatment, adding epoxide, natural oil and small molecule polyol reaction and ester exchange.The application adjusts the viscosity, functionality and molecular weight of the product through specific ester exchange reaction, and improves the compatibility of the product by adding epoxide, so that it can meet the needs of various applications.The bio-based polyether polyol synthesized by the method has good performance effect in soft foam, slow rebound and CASE field.
Owner:WANHUA CHEMYANTAI RONGWEI POLYURETHANE CO LTD +1

Preparation method of alcohol-based oxygen-containing fuel additive

The invention belongs to the field of fuel additive preparation, and relates to a preparation method of an alcohol-based oxygen-containing fuel additive. In order to solve the problems that an existing carbonic ester additive is relatively low in boiling point and is not matched with a diesel distillation range, the invention develops a special catalyst and a preparation process for preparing an alcohol-based oxygen-containing fuel additive, the catalyst takes a hierarchical pore molecular sieve as a carrier, and a potassium alcoholate active component and an amphiphilic molecule linking agent are introduced. Then catalyzing the ester exchange reaction of dimethyl carbonate and butanol by using the catalyst to generate a mixture of methyl butyl carbonate, dibutyl carbonate and the like, and fractionating to obtain the alcohol-based oxygen-containing fuel additive which has a proper boiling point and can be used for remarkably improving the oxygen content of the fuel.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Ester-based facaplysin derivative, preparation method and application of ester-based facaplysin derivative in antibacterial products

The invention discloses a method for rapidly and efficiently preparing a series of novel ester group facaplysin derivatives by combining EDCI and HOBT to react with carboxyl facaplysin and directly carrying out ester exchange reaction on an active ester intermediate and alcohol without separation. The invention also discloses application of the derivatives in resisting methicillin-resistant staphylococcus aureus and escherichia coli. The preparation method comprises the following steps that EDCI and HOBT are combined to activate carboxyl facaplysin for reaction, an activated ester intermediate is generated, the activated ester intermediate and alcohol are directly subjected to esterification reaction without separation, and a series of ester-based facaplysin derivatives are obtained. According to the preparation method, ester-based Fascaplysin derivatives with different structures can be rapidly and efficiently constructed, and compared with a traditional method that ester-based carboline derivatives are firstly synthesized and then high-temperature intramolecular cyclization is performed, the time and the raw material cost are greatly saved, the synthesis efficiency is improved, the reaction process is observable and controllable, and the yield is stable. And the synthesized ester group facaplysin derivative has excellent antibacterial activity on methicillin-resistant staphylococcus aureus and escherichia coli.
Owner:NINGBO UNIV

Method for continuously preparing pure biodiesel from kitchen waste oil based on immobilized enzyme

The invention relates to the technical field of pure biodiesel preparation, and particularly discloses a method for continuously preparing pure biodiesel from kitchen waste oil based on immobilized enzyme. The invention discloses a method for continuously preparing pure biodiesel from kitchen waste oil based on immobilized enzyme. The method comprises the following steps: filtering, dehydrating and degumming the kitchen waste oil to obtain pretreated kitchen waste oil; mixing the pretreated kitchen waste oil with an acyl acceptor to obtain a reaction substrate; and feeding the reaction substrate into an enzyme reactor filled with the immobilized lipase catalyst, carrying out transesterification, collecting reaction effluent, and carrying out separation and purification to obtain pure biodiesel. According to the continuous production technology, separation of the catalyst and the reaction substrate is achieved, the catalyst can be recycled, the immobilized lipase catalyst prepared through the covalent binding method has high stability and activity, and the yield of pure biodiesel can still reach 84% or above after continuous operation exceeds 200 hours.
Owner:SHANGHAI ZHONGQI ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD

Method for producing transesterified oil / fat composition, method for producing oil / fat composition, method for improving absorption properties of c13-c15 fatty acid, method of improving bioavailability of c13-c15 fatty acid, and bioavailability improver

PCT designated stageWO2026075022A1Edible oils/fatsTrans esterificationInteresterified fat
A method for producing a transesterified oil / fat composition (excluding hard butter and oil / fat for puff pastry margarine), said method comprising a step for subjecting a starting material oil / fat that contains a triglyceride, which is composed of a C13-C15 fatty acid, and an oil / fat other than said triglyceride to transesterification to obtain a transesterified oil / fat composition, wherein the C13-C15 fatty acid constitutes at least 3 mass% but less than 100 mass% of the total fatty acids in the transesterified oil / fat composition.
Owner:J OIL MILLS INC

Preparation method of ethylhexyl palmitate

The invention discloses a preparation method of ethylhexyl palmitate, and relates to the technical field of ethylhexyl palmitate. According to the method, firstly, isooctanol is gasified and then introduced into a methyl palmitate solution, ethylhexyl palmitate is prepared through transesterification, gaseous feeding can improve the instantaneous concentration of alcohol in a liquid phase, the reaction is promoted to be carried out in the positive direction, the reaction rate is increased, meanwhile, methanol generated through the transesterification method can be gasified and taken out of a system, and the yield of ethylhexyl palmitate is increased. Forward proceeding of the reaction is further promoted, so that the reaction is more thorough; secondly, chromium salt is used as a metal source precursor and a 2-sulfo-4, 4 '-biphenyldicarboxylic acid ligand to synthesize a catalyst, a biphenyl group in the ligand provides rigid and hydrophobic large pore channels and provides a local high-concentration reaction environment, gaseous isooctanol can be easily diffused into the pore channels of the catalyst and is in contact with enriched methyl palmitate, and the reaction efficiency is improved; and sulfonic acid groups uniformly distributed in the ligand serve as solid superacid, strong acid sites are provided, and the production efficiency is improved.
Owner:HUBEI CHUYI NEW MATERIAL CO LTD

Polycarbonate polyols, methods for making the same, and compositions thereof

A polycarbonate polyol having an ester bond and a urethane bond, and having an acid value of 0.01 mgKOH / g to 5.0 mgKOH / g. Also, a method for producing the polycarbonate polyol described above, which uses a transesterification catalyst, at least one carbonate represented by formula (3), at least one diol represented by formula (4), and a cyclic amide represented by formula (5). Thus, a polycarbonate polyol that is easy to operate and that improves the mechanical properties and solvent resistance of a polyurethane resin obtained from the polycarbonate polyol is provided.
Owner:UBE CORPORATION

Preparation method of high-barrier degradable material

PendingCN122255695APolymer sciencePtru catalyst
This invention discloses a method for preparing a high-barrier biodegradable material, comprising the following steps: A) Raw material pretreatment: Drying solid raw materials separately in a vacuum drying oven at 60-80℃ for 6-12 hours until the moisture content is below 0.05%; B) Melt blending: Mixing the dried raw materials with the remaining raw materials in a specific ratio until homogeneous. This invention significantly improves the barrier properties of the material through the synergistic effect of benzyl glycidyl ether, transesterification modified monomers, 1,4-succinic acid, nano-montmorillonite, and epoxy-modified graphene oxide. A balanced mechanical property is achieved through the rational ratio of polylactic acid and polybutylene adipate-terephthalate, as well as the effects of catalysts, chain extenders, and compatibilizers. The material achieves a degradation rate of 85.2% within 90 days, exhibiting good biodegradability and meeting environmental protection requirements. Through an optimized melt blending process, the material possesses good processing performance and can be molded using conventional plastic processing equipment, facilitating industrial production.
Owner:DONGGUAN GUANYI NEW MATERIAL TECH CO LTD

Biodegradable anti-aging agent as well as preparation method and application thereof

PendingCN122011356APolymer sciencePhenol
The invention discloses a biodegradable anti-aging agent as well as a preparation method and application thereof, and belongs to the field of biodegradable high polymer materials. Dibasic acid, dihydric alcohol and an acid compound containing a hindered phenol structure or an ester derivative of the acid compound are used as raw materials, esterification and condensation polymerization are performed, and then esterification or ester exchange reaction is performed to prepare the macromolecular anti-aging agent, so that high dispersity and migration resistance are realized; the anti-aging agent and the biodegradable resin are mixed and directly subjected to blow molding, film forming, extrusion casting and other melt forming, the hot working process is simplified, and the loss of material mechanics and aging resistance is reduced; the phenolic hydroxyl group can capture free radicals, so that the aging resistance of the biodegradable material is remarkably improved, and the service life of the material is prolonged. The prepared anti-aging biodegradable material can be applied to thin film products, and is particularly suitable for high-performance degradable mulching films and environment-friendly packaging materials.
Owner:BEIJING TECH & BUSINESS UNIV

Process for the production of diacylglycerol oil by enzymatic method in a solvent-free system

The application discloses a process for producing diacylglycerol oil by an enzyme method in a solvent-free system, and comprises the following steps: taking low-cost lipase as a catalyst, preparing lipase A by immobilization of the enzyme, preparing lipase B by an ester exchange reaction, and then taking the lipase B as a catalyst to catalyze esterification of free fatty acid and monoglyceride in a solvent-free system to prepare diacylglycerol oil.
Owner:JIANGNAN UNIV

An enzymatic process for the production of a diglyceride oil

The application discloses an enzymatic production process of diglyceride, and comprises the following steps: using low-cost lipase as a catalyst, preparing lipase A through immobilization of the enzyme, preparing lipase B through an ester exchange reaction, and then using the lipase B as a catalyst to catalyze esterification of free fatty acid and glycerol to produce diglyceride; the method can realize efficient enzymatic production of diglyceride through a series of methods by using low-cost lipase, and the production cost is reduced. The application provides an economical and efficient method for producing diglyceride by using the enzyme method, greatly reduces the use cost of lipase in the enzymatic esterification reaction, and has certain industrialization application prospect.
Owner:JIANGNAN UNIV

Cooling crystallization system of DMT

The utility model discloses a DMT cooling crystallization system, which comprises an ester exchange reaction kettle, a DMT crystallization tank and a DMT slurry storage tank, an outlet is arranged at the bottom of the ester exchange reaction kettle, an outlet pipeline at the bottom of the ester exchange reaction kettle is connected to the DMT crystallization tank, a material circulation line is arranged on the side surface of the DMT crystallization tank, a vacuum treatment line is connected to the top of the DMT crystallization tank, and an outlet is arranged at the bottom of the DMT crystallization tank. The DMT crystallization device is reasonable in structural layout, a series of process steps such as output of mixed liquid containing DMT components, vacuum cooling crystallization and output and storage of suspended slurry can be completed in sequence, a material circulation line is designed to replace a stirring mechanism in an existing DMT crystallization tank, and the DMT crystallization device is simple in structure, convenient to operate and high in practicability. Key equipment of the system is optimized, and the system has the advantages of simplifying the equipment structure and reducing the equipment failure rate.
Owner:ZHEJIANG JIANXIN JIAREN NEW MATERIALS CO LTD

A process for the preparation of a catalyst for the carbonate-based synthesis of oxygenate fuel components additives

Carbonate compounds are excellent additives of oxygen-containing fuel, and play an important role in improving the oxygen content of fuel. The present application mainly relates to a preparation method of a catalyst for synthesizing carbonate additives. The catalyst is used for catalyzing the preparation of a mixture of methyl ethyl carbonate and diethyl carbonate by means of an ester exchange reaction with dimethyl carbonate and ethanol as raw materials. The mixture obtained after the reaction is used as an oxygen-containing fuel additive. The catalyst is characterized in that the catalyst is a high-efficiency ester exchange catalyst with a multistage-pore ZSM-5 molecular sieve as a carrier, a double-molecule as a connecting agent and an alcohol salt as an active component. In the preparation process of the catalyst, the connecting agent is added. The connecting agent has the advantages of increasing the stability of the sodium alcoholate active component and increasing the loading capacity by using a molecular connecting agent with multiple active groups. The performance of the catalyst is evaluated by using a tank reactor, and the stability of the prepared catalyst in the ester exchange reaction is investigated. The performance evaluation shows that the catalyst prepared by using the connecting agent has higher product yield and more excellent product yield. This has important significance for improving the combustion performance of the oxygen-containing fuel and reducing the fuel cost.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Supported solid base catalyst and application thereof

The invention discloses a supported solid base catalyst and application thereof, micron-scale or nano-scale lanthanum oxide is used as a carrier, calcium oxide active sites are dispersed and supported on the surface of the lanthanum oxide, the molar ratio of calcium element to lanthanum element in the catalyst is 0.016-0.83: 1, the calcium-based solid base catalyst with excellent activity and stability is obtained, the addition amount of the catalyst is small, the reaction time is short, and the reaction time is short. The method is simple in operation, short in reaction time and capable of being widely applied to preparation of biodiesel from various biolipid and other types of ester exchange reactions, and the problems of lipid resource waste and diesel product quality reduction caused by saponification reaction caused by homogeneous alkali in the existing biodiesel preparation process are effectively solved.
Owner:GUANGZHOU INST OF ENERGY CONVERSION CHINESE ACAD OF SCI

Bio-based haplotype dispersant as well as preparation method and application thereof

PendingCN121592011APolymer scienceHigh activity
The invention provides a bio-based haplotype dispersant as well as a preparation method and application thereof, and the method comprises the following steps: carrying out transesterification on a compound A as shown in a formula 1 and a polyhydroxy compound to generate a compound B as shown in a formula 2; and carrying out addition reaction on the compound B as shown in the formula 2 and allyl glycidyl ether to generate the bio-based haplotype dispersant as shown in a formula 3. The invention provides a dispersant with high activity, low viscosity, high dispersion efficiency and flexibly controllable reaction activity by taking renewable resources as raw materials.
Owner:SHANGHAI CHLOR ALKALI CHEM +2