232 results about "Sodium Bentonite" patented technology

The invention discloses a preparation method of an ultra-thin high-density fiberboard with ultra-low formaldehyde emission, which is characterized by comprising the following steps: peeling wood by using a peeling machine, chipping to obtain wood chips, washing the wood chips with water, cooking in a cooking cylinder, feeding into a defibrator, and adding molten paraffin for treatment to obtain fibers; meanwhile, formaldehyde is taken to be mixed with sodium bentonite, triethylene diamine and polyvinyl alcohol, then urea is added in five times, melamine is added in two times, a reaction is conducted, and melamine modified urea-formaldehyde resin is prepared; taking fibers, applying an adhesive formed by mixing melamine modified urea-formaldehyde resin, nano titanium dioxide and an ammonium chloride curing agent, drying and dehydrating the fibers uniformly mixed with the adhesive, sorting to remove micelles, fiber agglomerates and fiber bundles, and paving and forming to obtain a plate blank; and the plate blank is taken to be subjected to the hot pressing procedure to obtain a plate, and after the plate is cooled, the ultra-thin high-density fiberboard with the advantages of being high in strength, low in formaldehyde emission and the like is obtained after sanding.

The invention relates to the field of civil engineering waterproof materials, in particular to a nano bentonite-polymer composite material with high salt tolerance and a preparation method thereof, and the nano bentonite-polymer composite material is especially suitable for a sodium-based bentonite waterproof blanket in a saline soil area or a marine environment, and the preparation method comprises the following steps: (1) preparing nano bentonite lamellar colloidal dispersion liquid; (2) introducing and mixing an electrostatic screening agent and a polymerizable monomer; (3) carrying out in-situ free radical polymerization reaction; and (4) post-treatment and finished product preparation. By constructing a three-dimensional interpenetrating hierarchical structure composed of a covalent grafted polymer network, a physically anchored electrostatic screening agent and a stripped bentonite nanosheet layer, effective protection of a bentonite core anti-seepage unit is realized, so that the adaptability and long-term stability of the material under a complex water quality condition are remarkably improved.

The invention relates to the technical field of land treatment, in particular to an organic fertilizer for improving the soil fertility of a sand land. Comprising the following raw materials in parts by weight: 3-12 parts of a microbial agent, 20-50 parts of volcanic rock, 5-12 parts of an additive, 32-45 parts of sodium bentonite, 12-18 parts of a functional agent, 5-25 parts of a modifier and 15-32 parts of a water retention material. By increasing organic matters in the soil, the viscosity of the soil is improved, the air permeability, water retention and permeability of the soil are improved, the formation of a soil aggregate structure is promoted, and the water and fertilizer retention capability of the sand soil is improved.

The invention relates to the technical field of lubricating oil, in particular to high-temperature-corrosion-resistant lubricating oil and a preparation method thereof. The high-temperature-corrosion-resistant lubricating oil is prepared from the following raw materials in parts by mass: 130 to 190 parts of base oil, 1 to 5 parts of an anti-wear reagent at extreme pressure, 1 to 5 parts of amino modified graphene, 0.1 to 1 part of an anti-rust agent, 1 to 3 parts of an antioxidant, 0.1 to 1 part of a de-foaming agent, 5 to 15 parts of trioctyl trimellitate, 1 to 5 parts of sodium lignin sulfonate and 1 to 5 parts of sodium bentonite. The high temperature resistance and the viscosity-temperature performance of the lubricating oil can meet the use requirements of a bearing under the working conditions of high speed, high temperature and large load, the wear resistance and the friction reduction of the lubricating oil at high temperature are effectively improved, and meanwhile the preparation method is simple and suitable for large-scale popularization and application.

The utility model provides an ecological reservoir for water conservancy and hydropower engineering, which comprises a reservoir body, and the reservoir body comprises a dry stone protection slope, a coarse sand layer, a natural sodium bentonite waterproof blanket and a plain soil layer which are sequentially arranged from top to bottom; a plurality of parallel water permeable pipes are laid below the bottom wall of the reservoir at intervals, each water permeable pipe is provided with a check valve at intervals, and the lower surface of each water permeable pipe is coated with non-woven geotechnical cloth. The stress on the bottom of the reservoir body is reduced by arranging the water permeable pipe below the reservoir body, and the crack resistance of the reservoir is comprehensively improved by combining with the arrangement of the expansion joints; the ecological reservoir takes the natural footstone as a slope protection, the bentonite waterproof blanket is waterproof, the construction method is simple, the anti-seepage effect is good, and the ecological reservoir is economical, practical, ecological and environment-friendly.

The invention provides a composition and application thereof in plant growth promotion, and the composition is granular and is prepared from corn glume, polyvinyl alcohol, sodium bentonite and water. The composition can be directly applied through a fertilizer throwing machine or applied together with a chemical fertilizer and an organic fertilizer, after application, the plant yield and quality can be improved, the lodging resistance of plants can be improved, the composition especially has a remarkable effect on increasing the yield of crops in arid regions, materials are easy to obtain, the price is low, pollution is avoided, and the composition has important significance on development of the planting industry in China.

The invention relates to bacteriostatic bentonite cat litter and a preparation method thereof, and belongs to the technical field of pet supplies. The bacteriostatic bentonite cat litter sequentially comprises a sodium bentonite matrix embedded with a bacteriostatic agent, a metal oxide layer and a biological membrane layer from inside to outside, the sodium bentonite matrix is obtained by mixing and aging bentonite and a sodium modifying agent in a solvent. When the biological membrane is in contact with excrement, the outer-layer biological membrane preferentially blocks liquid permeation, the middle-layer nano ZnO still generates active oxygen in a weak light environment, and the inner-layer Ag < + >-loaded zeolite slowly releases and inhibits bacteria, so that the antibacterial persistence can be improved. The bacteriostatic bentonite cat litter disclosed by the invention is remarkable in deodorization and antibacterial effects, does not stick to hands when being used, does not generate dust, and has relatively strong caking performance.

The invention relates to the technical field of bentonite preparation, in particular to organic modified bentonite and a preparation method thereof.The preparation method comprises the following steps that (a) natural bentonite is subjected to acidification whitening pretreatment through sulfuric acid; (b) sodium carbonate is subjected to sodium modification and transformation to obtain sodium bentonite; (c) dispersing sodium bentonite in absolute ethyl alcohol, adding 3-aminopropyltriethoxysilane (APTES) and polyethylene glycol diacrylate (PEGDA), and performing reflux reaction under the condition that the pH is 4.0 to realize silanization intercalation; (d) adding 5% of a template agent, and carrying out hydrothermal construction at 120 DEG C to form a mesoporous-macroporous hierarchical pore channel; and (e) eluting the template agent by using an ethanol / water mixed solvent, drying and crushing to obtain a finished product. According to the method, the defects that traditional bentonite is low in mass transfer efficiency and insufficient in macromolecule adsorption capacity are overcome, the adsorption capacity of organic pollutants can be improved by 40% or above, and meanwhile the structural stability in the high-temperature and acid environment is enhanced.

The invention provides a composition and application thereof in ecological restoration, and the composition is granular and is prepared from glume of corncob, polyvinyl alcohol, sodium bentonite and water. The composition can keep soil moisture and improve the soil structure, the raw materials are biomass materials, water retention is achieved, food sources can be provided for microorganisms and soil animals in soil, microcirculation of moisture and soil organisms is formed around the composition, the soil organisms can further increase nutrients in the soil, and the soil quality is improved. Soil carbon-solid continuous increase of soil organic matters and aggregates is realized, and the method has great significance on ecological restoration.

The application relates to the technical field of building materials, and discloses a permeable crystalline self-healing waterproof material for concrete self-waterproofing, which is prepared from the following raw materials in parts by weight: 20-30 parts of sodium-based bentonite, 20-50 parts of sodium methyl silicate, 4-6 parts of a penetrating agent, 8-12 parts of a sulphoaluminate cement, 15-18 parts of a silicone zirconium, and 2-5 parts of a complexing agent; the complexing agent is composed of 2-[3-(4-pentylphenyl)prop-2-enylamino]benzoic acid and sodium ethylenediaminetetraacetate. The above technical scheme solves the problem of low mechanical performance and waterproofness of concrete in the prior art.

The invention belongs to the technical field of oil field gas channeling plugging agents, and discloses a high-molecular pre-crosslinked gel particle plugging agent suitable for a carbon dioxide drive oil reservoir and a preparation method of the high-molecular pre-crosslinked gel particle plugging agent. The raw materials comprise an acrylamide monomer, sodium bentonite, an acrylic monomer, an acid-resistant functional monomer, a temperature-resistant and salt-resistant functional monomer, a first cross-linking agent, a second cross-linking agent, an initiator, an inorganic reinforcing agent, an antioxidant and water. The prepared acid-resistant gel particle is good in temperature resistance, salt resistance and acid resistance and long in effective period of action, the viscosity of a system is increased after the particle swells for a certain time, the plugging capacity is enhanced, and the acid-resistant gel particle can be used as an excellent CO2 drive reservoir gas channeling plugging agent and is used for plugging a heterogeneous formation with developed micro-cracks.

The invention discloses a caking composition, composite cat litter as well as a preparation method and application of the composite cat litter. The caking composition is prepared from the following components in parts by weight: 74 to 76 parts of desert sand, 18 to 22 parts of sodium bentonite, 2 to 3 parts of pregelatinized starch, 1 to 3 parts of polyacrylamide and 0.5 to 1.5 parts of solvent; the gelatinization degree of the pregelatinized starch is 73-86%, and the mass content of amylopectin in the pregelatinized starch is 75-84%; the molecular weight of the polyacrylamide is 1400 million to 20 million. The caking composition provided by the invention has relatively good caking strength, is less prone to a bottom sticking phenomenon, has excellent water absorption speed, and can rapidly agglomerate. The use of bean fiber and starch is reduced, and the consumption of non-renewable resources such as bentonite ore is reduced.

The invention relates to the technical field of oily sewage treatment, and discloses a flocculant as well as a preparation method and application thereof. The flocculant contains a component A, a component B, a component C and a component D, the component A contains etherified starch and nano magnetic iron oxide, the component B contains sodium bentonite and nano magnetic iron oxide, the component C contains tannin modified chitosan and nano magnetic iron oxide, and the component D contains carbonate, citric acid and auxiliary materials. The flocculant is easy to store, does not need to be compounded on site, flocculates quickly in water, only needs 60-120 seconds in flocculation time, and has an excellent flocculation effect; the emergency requirement of an accident site can be met, and the good popularization value is achieved; the method is suitable for an oil-containing sewage system with coexistence of anions and cations, can also adapt to a wide pH range, is good in salt resistance and has a good dehydration and filtration aiding effect.

The invention discloses a green and environment-friendly superfine bentonite anticorrosive coating and a preparation process thereof. The anticorrosive paint is prepared from 40 to 70 parts of water-based film forming matter, 0.3 to 3.0 parts of composite bentonite, 1.0 to 8.0 parts of a green corrosion inhibition system, 2.0 to 12.0 parts of an auxiliary agent, 0.30 to 0.40 part of a surface modifier, 10 to 30 parts of deionized water and 0.5 to 5 parts of a cosolvent. The composite bentonite is prepared by compounding sodium bentonite, nano titanium dioxide and a natural antibacterial extract according to the mass ratio of 100: (3-5): (0.3-2.0); the green corrosion inhibition system is formed by compounding molybdate, an organic corrosion inhibitor and a silane co-condensation compound. The preparation process comprises four key steps of preparation of a composite bentonite suspension, surface functionalization treatment, gradient shearing dispersion and coating blending. The salt spray resistance of the anticorrosive paint can reach 1150 hours, the VOC content is as low as 35 g / L, the antibacterial rate of the natural antibacterial extract is 97.2%, and the anticorrosive paint has excellent anticorrosive performance and green and environment-friendly characteristics.

The invention provides a construction method of a multi-element solid waste-based cementing material roadbed filler, and relates to the technical field of road engineering, and the construction method comprises the following steps: S1, selecting raw materials: fly ash, slag powder, carbide slag powder, desulfurized gypsum powder, gasified slag powder, coal gangue powder, steel slag powder, tailing powder, coal cinder powder, building solid waste powder and municipal waste powder; s2, raw material pretreatment; s3, preparing a composite exciting agent: preparing sodium sulfate, calcium hydroxide, calcium chloride, calcium sulfate, sodium silicate and sodium hydroxide; s4, preparing a composite exciting agent solution; s5, preparing a multi-element solid waste-based cementing material: uniformly mixing the raw materials pretreated in the step S2 with the composite activator prepared in the step S4 according to a ratio; s6, roadbed laying, wherein a sodium bentonite waterproof blanket is laid on the bottom layer of the roadbed and then laid; s7, geogrids are laid; s8, maintenance is conducted; through fine selection and proportioning of the raw materials, efficient resource utilization of various industrial solid wastes is realized.

The invention relates to the technical field of petrochemical wastewater purification treatment, in particular to a high-selectivity composite adsorption material for petrochemical wastewater treatment and a preparation method thereof, and the preparation method comprises the following steps: dispersing sodium bentonite in deionized water, adding an intercalator, and reacting to obtain pretreated bentonite; dispersing the pretreated bentonite in an ethanol aqueous solution, adding trithiol-s-triazine trisodium salt, and reacting to obtain sulfydryl modified bentonite; the sulfydryl modified bentonite is dispersed in ethyl alcohol, an amino silane coupling agent is dropwise added, and aminated bentonite is obtained through a reaction; the preparation method comprises the following steps: dispersing aminated bentonite into anhydrous tetrahydrofuran, and adding gamma-butyl selenolactone for reaction to obtain the composite adsorption material. According to the prepared composite material, through the synergistic effect of multiple adsorption mechanisms, the adsorption selectivity and bonding strength of metal ions in petrochemical wastewater are remarkably improved, and a technical support is provided for precise purification treatment of the petrochemical wastewater.

The invention provides a wall-fixing leakproof water-based drilling fluid for a myriameter deep well as well as a preparation method and application thereof, and belongs to the technical field of drilling fluids. The water-based drilling fluid is prepared from the following raw materials in parts by mass: 100 parts of water, 1-2 parts of sodium bentonite, 0.5-1 part of a salt response rheological modifier, 5-6 parts of a supramolecular polymer filtrate reducer, 6-8 parts of a cementing plugging agent and 2-4 parts of a cementing wall-fixing agent. The water-based drilling fluid can resist the temperature of 220 DEG C, can resist the salt to be saturated, has good rheology and filtration performance and multiple functions of inhibition, plugging, wall fixation and the like under high-temperature and high-salt conditions, and provides technical guarantee for smooth drilling of myriameter extra-deep wells.

The invention provides an oxidation active zone remediation system and method for underground water organic pollution. The remediation system comprises a plurality of injection wells and monitoring wells which are arranged at the downstream of an underground water pollution plume; the injection wells are distributed in rows at equal intervals in the direction perpendicular to the underground water flow field, the adjacent injection wells in the same row are distributed at equal intervals, and the injection wells in the adjacent rows are distributed in a staggered mode. The monitoring wells are arranged at upstream and downstream positions of an oxidation active zone formed by the injection wells; the injection well is of a double-well structure and comprises an inner well and an outer well. The inner well and the outer well are slotted floral tubes, a repairing agent is injected into the inner well, and the space between the inner well and the outer well is filled with a slow-release repairing material; and the outer side of the outer well is provided with a well wall formed by filling quartz sand filter materials, sodium bentonite particles and anti-seepage cement paste from bottom to top. According to the remediation system, through the reasonable structural design and application of the remediation agent and the slow-release remediation material, an oxidation activity reaction zone can be rapidly established, underground water pollution diffusion is efficiently blocked, and rapid and effective remediation of underground water is achieved.

This invention provides a method for preparing modified bentonite, comprising: step S1, mixing bentonite, an intercalating agent, and water to obtain a mixed slurry, wherein the intercalating agent includes sodium hexafluorosilicate; step S2, freezing the mixed slurry to obtain a frozen mixed slurry; and step S3, thawing and drying the frozen mixed slurry to obtain modified bentonite. This invention uses sodium hexafluorosilicate as one of the intercalating agent components to modify bentonite, and through freezing and thawing steps, it prepares sodium-based bentonite while simultaneously increasing the interlayer spacing and improving its impermeability.

The invention discloses sealing cement for a sliding nozzle and a preparation method of the sealing cement. The formula of the sealing cement for the sliding nozzle is composed of 35-45 parts of blast furnace slag powder, 15-25 parts of calcareous quicklime fine powder, 30-40 parts of graded quartz mortar aggregate, 8-12 parts of a pre-activated composite activator, 5-10 parts of a sodium silicate-based rapid hardening adjusting liquid, 0.5-2 parts of plasticized water-retaining fibers and 0.1-0.3 part of an aluminum powder antioxidant. The pre-activated composite exciting agent is formed by blending sodium bentonite and anhydrous potassium carbonate according to a mass ratio of 7: 3 by a dry method; according to the invention, the pre-activated composite activator is cooperated with the modified slag, the daub forms a compact reaction interface in a plastic stage, and the defect of reaction lag of a traditional slag-lime system is overcome; from initial setting and hardening to high-temperature service, the system always keeps dynamic fit with the sliding nozzle: in the initial setting stage, oligomeric silicate rapidly permeates into a slag interface to generate a rigid gel skeleton, so that rapid structure locking is realized, and the waiting time for nozzle installation is greatly shortened.

The invention relates to a salt core production method, which comprises: stirring industrial salt, sodium bentonite, sodium water glass and absolute ethyl alcohol, taking out, placing into a drying furnace, carrying out thermal insulation, cooling, crushing, and screening with a screen; pouring the mixed salt into a lower mold cavity of the mold, pressing by an upper mold, lifting the upper mold, and ejecting the green body by a lower mold core; the green body is put into a sintering furnace for heat preservation, and then the cooked body is taken out for cooling; turning the cooked blank by using a forming cutter, and drilling after turning is completed; putting the salt core into a sintering furnace for heat preservation and then taking out; and packaging and storing the qualified products in a sealing bag. The method has the beneficial effects of low cost, simple and stable process, high product percent of pass and the like. Compared with a pure salt core, the salt core has the advantages of higher strength, better processability, fewer appearance defects and higher rate of finished products. The raw materials are simple, the product processability is better, and meanwhile the requirements for water solubility and low gas forming amount of aluminum alloy castings are met.

The invention discloses a smelting method for preparing chromium pellets through belt type roasting, which comprises the following steps: primary ingredients are prepared into green pellets through a pelletizer, chromium concentrate green pellets with the particle size of 8-20mm are obtained through screening, the primary ingredients comprise mixed chromium concentrate, fly ash and sodium bentonite, the chromium concentrate green pellets and grate-layer materials are distributed into a belt type roasting machine, and the grate-layer materials are mixed with the mixed chromium concentrate, fly ash and sodium bentonite; the total thickness of a material layer formed by chromium concentrate green pellets and a bedding material is controlled to range from 400 mm to 450 mm, the chromium concentrate green pellets and the bedding material move on a belt type roasting machine and are sequentially subjected to drying, preheating, roasting oxidation and cooling, oxidized pellets are obtained, secondary ingredients are fed into an electric furnace to be smelted, the secondary ingredients comprise the oxidized pellets and auxiliary materials, and the auxiliary materials are fed into the electric furnace to be smelted. The auxiliary materials comprise silica, lime and coke, electrode paste is regularly added in the smelting process, and ferrochrome molten iron and slag obtained after smelting are discharged respectively. According to the invention, the raw material adaptability, efficiency and equipment layout compactness are improved.

The invention relates to a halogen-free flame-retardant polypropylene composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The halogen-free flame-retardant polypropylene composite material is prepared from the following components in parts by mass: 45 to 60 parts of polypropylene, 15 to 25 parts of a flame retardant, 1 to 3 parts of vinyl trialkoxy silane, 3 to 9 parts of a toughening agent and 0.05 to 1.5 parts of an antioxidant. Vinyl in the vinyl-terminated borosilicate compound and sulfydryl in sulfydryl modified sodium bentonite are subjected to an addition reaction, the borosilicate compound is grafted to the sodium bentonite through C-S chemical bonds, the composite flame retardant is formed, halogen elements are not contained in the flame retardant, and the flame retardant is environmentally friendly and free of toxic and side effects. Meanwhile, the flame retardant contains boron, silicon and sodium bentonite with good heat resistance, and various metal elements and silicon in the sodium bentonite and the boron and silicon in the organic matter generate a synergistic effect, so that the flame retardance of the flame retardant is improved.

This invention belongs to the field of sodium-based bentonite technology, specifically relating to a method for producing sodium-based bentonite from calcium-based bentonite, comprising the following steps: S1. Preliminary mixing: crushing calcium-based bentonite to 90-110 mesh, and then mixing it with a composite sodium-forming agent at a mass ratio of 1:(0.03~0.10); S2. Mechanical shearing: processing the mixture obtained in step S1 in a high-speed shearing machine at a speed of 2000~4000 r / min for 10~40 min; S3. Sodium formation: adding 1~1.5 times its mass of deionized water to the bentonite after mechanical shearing in step S2, and stirring and reacting at a temperature of 60~80℃ for 1~2 h; S4. Drying: centrifuging and dehydrating the sodium-formed bentonite in step S3, drying it at 120~150℃, and pulverizing it to 200~300 mesh to obtain the product. The present invention provides a method for producing sodium-based bentonite from calcium-based bentonite. The preparation method is simple, with high sodiumization efficiency and short reaction time. For the first time, rare earth catalysis, nano-intercalation and bio-based additives are combined, breaking through the traditional sodiumization theoretical framework. The prepared product has good performance, high expansion capacity, and meets the standards of high-end foundry bentonite, making it suitable for high-end application scenarios.

The present invention discloses a method for burning furfural residue, a biomass solid waste. Bentonite is added to the furfural residue, mixed evenly, and then stacked. The residue is passed through a 200-mesh sieve. The oversize material is the low-moisture furfural residue, and the undersize material is the water-absorbed bentonite. The water-absorbed bentonite is dried, recovered, and recycled. Calcium-based bentonite and sodium-based bentonite are added to the furfural residue in a certain proportion, taking advantage of their strong water absorption properties. These materials can absorb moisture from the furfural residue, thereby obtaining low-moisture furfural residue. The moisture content of the furfural residue is reduced to below 30%, and the residue can be directly used as a biomass fuel without drying.

The invention discloses a pectin / titanium pillared bentonite composite adsorption material and a preparation method thereof, and belongs to the technical field of wastewater treatment. According to the method, sodium bentonite is used as a matrix, tetrabutyl titanate is used as a titanium source, titanium pillared bentonite is prepared through a sol-gel method, then the titanium pillared bentonite is compounded with a pectin solution, and the pectin / titanium pillared bentonite composite adsorption material is prepared. The problems that natural bentonite swells when encountering water and solid-liquid separation is difficult are solved through titanium pillared modification, and the specific surface area of the bentonite is increased from 21.22 m < 2 > / g to 116.23 m < 2 > / g; the material is endowed with excellent heavy metal complexation and flocculation performance through pectin compounding, the maximum adsorption capacity of the prepared pectin / titanium pillared bentonite composite adsorption material to Hg (II) reaches 31.40 mg / g, the flocculation settling time is shortened by 90% or above compared with natural bentonite, and the material has photocatalytic reduction performance. The invention has the advantages of wide raw material source, simple preparation process, low cost and no secondary pollution, and has wide application prospect in the field of heavy metal wastewater treatment.

The invention relates to the technical field of bentonite materials, and discloses application and a preparation method of diversified agricultural bentonite, and the preparation method comprises the following steps: 1) sodium bentonite; 2) preparing primary bentonite; 3) activating bentonite powder; 4) a mixture; 5) preparing turbid liquid; and 6) dissolving chitosan in an acetic acid solution with the volume percent concentration of 4-6%, fully dissolving the chitosan, adding the turbid liquid into the acetic acid solution, carrying out ultrasonic treatment for 60-90 minutes, carrying out constant-temperature reaction for 1-2 hours, and drying to obtain the diversified agricultural bentonite. The diverse agricultural bentonite prepared by the invention is applicable to a plurality of fields of agriculture, and can be applied to soil conditioners, fertilizer conditioners, fertilizer carriers, fertilizer granulation and microbial agents.

The invention discloses a high-speed railway subsea tunnel corrosion-resistant grouting material and a preparation method thereof, and relates to the field of subsea shield tunnel grouting materials, the grouting material comprises a liquid A and a liquid B. The liquid A comprises, by weight, 30-45 parts of cement, 15-25 parts of superfine mineral powder, 5-10 parts of sodium bentonite and 2-5 parts of nano silicon dioxide; 0.05-0.1 part of a foam stabilizer, 5-12 parts of an inhibitor, 1-3 parts of SAP resin particles and 1-3 parts of polypropylene fibers; the liquid B is prepared from the following components in parts by weight: 40 to 60 parts of water glass, 20 to 30 parts of aluminum sulfate, 1 to 3 parts of early strength agent, 5 to 10 parts of conditioning agent and 10 to 16 parts of acrylate-polyurethane composite emulsion. The anti-permeability grade of the anti-corrosion grouting material is larger than or equal to P12, the strength retention rate in a high-concentration chlorine salt and sulfate seawater environment is larger than or equal to 90%, and the durability is remarkably improved.

The invention relates to the field of biodegradable high polymer materials, and discloses a bio-based packaging material with an anti-oxidation effect and a preparation method of the bio-based packaging material. 40 to 60 parts of polyhydroxyalkanoate; 10-20 parts of a composite antioxidant filler; the composite antioxidant filler is prepared by the following steps: (a) crushing sodium bentonite until the specific surface area is 45-55 m < 2 > / g and the particle size distribution D90 is less than or equal to 10 microns; (b) mixing bentonite powder and water according to the ratio of 1kg: 5L to form dispersion liquid with the solid content of 18%, and adding 0.3% sodium hexametaphosphate dispersing agent; (c) adding cerium nitrate; and (d) heating the product to 1050 DEG C at a speed of 8 DEG C / min, and calcining for 2 hours. Through the intercalation structure of the bentonite-based composite filler, an inorganic antioxidant component is organically combined with a bio-based polymer matrix, so that a breakthrough in long-acting oxidation resistance is realized in a completely biodegradable polylactic acid / polyhydroxyalkanoate system, and the technical bottleneck that traditional bioplastics are easy to oxidize and degrade is solved; and a sustainable solution is provided for green packaging materials.

The invention relates to the technical field of hole filling materials around a shield, and discloses a hole filling material around the shield and a preparation method and application of the hole filling material around the shield. The mass ratio of the sodium bentonite to the calcined kaolin to the organosilicon waterproofing agent to the fly ash to the building retarder to the thickening agent in the component A is (25%-28%): (25%-28%): (2%-4%): (2%-3%): (2%-4%): (0.04%-0.08%), and the balance is water; and the component B comprises a sodium silicate aqueous solution. The material disclosed by the invention can be applied to a soft soil area, and the shield periphery pore filling material has good pumpability, so that the shield periphery pores can be quickly filled; and in addition, the reaction is rapid, the certain viscosity is achieved, and the final supporting performance reduction caused by solid-liquid separation of the shield periphery hole filling material in the reaction process can be avoided.