The invention relates to technical fields of materials, chemical engineering and electronics, in particular to a cable material with a polymer substrate and CTR effect and a preparation method thereof. The temperature sensing cable material with CRT characteristics consists of thermoplastic polymer, a filling agent, a plasticizer, functional additives, a stabilizing agent, a flame retardant, a lubricant, an antioxidant and a processing agent, has the use temperature range between -30 and 150 DEG C, and can be applied on occasions such as recoverable line-type temperature sensing cables, fire prewarning and alarm devices, temperature measurement, overheating alarm and protection and the like. The temperature sensing cable material with the CRT characteristics takes a polymer material as a substrate, and is added with multiple organic and inorganic compounds with special CTR characteristics taken as the functional additives, and has the characteristics of flexibility, and capacities of being continuously processed and being used like a common cable material.