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13998results about How to "Increase added value" patented technology

Method for preparing aromatic hydrocarbons and propylene simultaneously employing methanol/dimethyl ether

The invention discloses a method for preparing aromatic hydrocarbons and propylene simultaneously employing methanol / dimethyl ether, comprising the following steps: 1) placing raw materials containing methanol or / and dimethyl ether, metals and molecular sieve based catalyst which is modified through silanizing in a first fixed bed reactor to perform catalytic reaction; 2) separating the products obtained in step 1) to obtain propylene, then placing propylene in a second fixed bed reactor with molecular sieve based catalyst which is modified by using metals to react, then performing aromatization on the obtained product in step 1) and obtaining aromatic hydrocarbons; then separating to obtain toluene and sending toluene back to the outlet of the first fixed bed reactor as a raw material. In the method, methanol is converted and prepared to aromatic hydrocarbons while propylene is produced at the same time and the content of paraxylene in aromatic hydrocarbons is high. In the products prepared by the method, the content of propylene can reach above 20%, the content of aromatic hydrocarbons can reach above 58wt% and the content of paraxylene in aromatic hydrocarbons is more than 35wt%.
Owner:CHINA NAT OFFSHORE OIL CORP +2

Hydrogenation method for coal tar suspension bed of heterogeneous catalyst

The invention relates to a hydrogenation method for a coal tar suspension bed of a heterogeneous catalyst. The method comprises processes of coal tar raw material pretreatment and distillatory separation, coal tar heavy fraction suspension bed hydrogenation cracking and conventional light fraction oil extraction, wherein the suspension bed hydrogenation reaction temperature is between 320 and 480DEG C, the reaction pressure is 8 to 19MPa, the volume air speed is 0.3 to 3.0h<-1>, the hydrogen oil volume ratio is 500 to 2,000, the catalyst is a powdery granular coal tar suspension bed hydrogenation catalyst of a single metal active ingredient containing molybdenum, nickel, cobalt, tungsten or iron or a composite multi-metal active ingredient, the adding amount of the catalyst is based on the ratio of the metal quantity of the active ingredient to the weight of the coal tar raw materials of 0.1: 100-4: 100, most of tail oil containing the catalyst after lightweight oil is separated froma hydrogenation reaction product is directly circulated to a hydrogenation bed reactor, a small part of tail oil is subjected to catalyst removal treatment and then circulated to the hydrogenation bed reactor to be subjected to further lightweight treatment, and the heavy oil is totally or furthest circulated. The method fulfills the purposes of maximum production of the lightweight oil in the coal tar and cyclic utilization of the catalyst, and greatly improves the utilization efficiency of the raw materials and the catalyst.
Owner:CCTEG CHINA COAL RES INST

Method of decomposing hydrogen sulfide for preparation of hydrogen and elemental sulfur

The invention discloses a method of decomposing hydrogen sulfide for preparation of hydrogen and elemental sulfur, which belongs to the technical field of hydrogen production and gas purification. The invention is characterized in that: hydrogen sulfide or gas containing hydrogen sulfide is subjected to ionization through blockage of discharge by using a medium so as to form uniformly distributednon-equilibrium plasma, and hydrogen sulfide spontaneously decomposes into hydrogen and elemental sulfur in the plasma; when there is a photocatalyst in the plasma, energy in the photons of the photocatalyst can be utilized to promote decomposition of hydrogen sulfide, and complete conversion can be realized under proper conditions. All the frequently used solid photocatalysts can be used in the above mentioned process, e.g., titanium oxide, cerium oxide, zirconia, zinc oxide, cadmium oxide, copper oxide, molybdena, tungsten oxide, zinc sulfide, cadmium sulfide, copper sulfide, molybdenum sulfide, tungsten sulfide and a mixture composed of two or more selected from the above-mentioned photocatalysts; the photocatalysts can also be loaded on a porous material to prepare load type catalysts. The method provided in the invention is especially applicable to treatment of gas containing hydrogen sulfide in the industries of natural gas, petroleum and coal chemistry and is also applicable topreparation of hydrogen and elemental sulfur through dissociation of gas containing hydrogen sulfide in the fields of metallurgy, sea and the like. The method has no special requirements for or restriction on the source and composition of gas; thus, the method has universality to preparation of hydrogen through decomposition of hydrogen sulfide.
Owner:DALIAN UNIV OF TECH

Production of solvent oil, lubricant base oil and heavy wax by fischer-tropsch synthetic wax

The invention provides a method of producing prime city naphtha, lube base oil and pyroparaffine from Fischer-Tropsch processed wax. The invention includes: a) contacting the Fischer-Tropsch processed wax with the hydrogenated refined catalyst in a hydrogenation refining reaction zone 1, separating the product in the zone, and obtaining a distillate the final distilling point of which is lower than 380 DEG C to 550 DEG C and a distillate the initial distilling point of which is higher than 380 DEG C to 550 DEG C; b) contacting the distillate the final distilling point of which is lower than 380-550 DEG C to 550 DEG C with a hydrogenated isomerization catalyst in a wax hydrogenation conversion reaction zone, and preparing a wax conversion produced oil the pour point of which is lowered; c) contacting the wax conversion produced oil with the hydrogenated refined catalyst in a hydrogenation refining reaction zone II, and separating the product in a distillation zone 2, obtaining at least one kind of solvent oil and at least one kind of lube base oil; d) contacting the distillate the initial distilling point of which is higher than 380 DEG C to 550 DEG C with a hydrogenated refined catalyst in a hydrogenation refining reaction zone 3, thereby obtaining a wax which is hydrogenated and discolored.
Owner:CHINA PETROLEUM & CHEM CORP +1

Preparation method of high length-diameter ratio anhydrous calcium sulfate whisker

A preparation method of high length-diameter ratio anhydrous calcium sulfate whisker belongs to the technical field of inorganic chemical material preparation. The method takes inorganic calcium saltand inorganic precipitant as raw materials and surfactant as dispersant, and includes the following steps: first preparing superfine calcium sulphate dihydrate precursor with good dispersion at the temperature of 10-90 DEG C; then adding the precursor into water solution containing shape control agent to conduct hydrothermal reaction for 0.5-10h at the temperature of 100-250 DEG C, and obtaining calcium sulfate hemihydrate whisker; mixing the calcium sulfate hemihydrate whisker with inorganic solvent; and roasting the mixture for 0.5-6h at the temperature 200-800 DEG C to obtain anhydrous calcium sulfate whisker with the length of 20-2000mum, the diameter of 0.5-20mum, the length-diameter ratio of 40-1000 and the main content greater than 95wt% after washing and drying. The technology is simple, the cost is low and the added value of the product is high. The prepared calcium sulfate whisker has large length-diameter ratio and regular shape and can be used as reinforcing material to beapplied in industries such as plastics, rubber, ceramics, cement, papermaking and the like.
Owner:TSINGHUA UNIV

Method for preparing methyl alcohol synthesis gas and compressed natural gas from coke oven gas and coal

The invention discloses a method for producing methanol synthesis gas and compressed natural gas by taking coke oven gas and coal as raw materials, and the main steps comprise that purification treatment, transformation treatment, desulfurizing decarburization, pressure swing absorption separation of methane and hydrogen and methane-rich gas compression are carried out to the coke oven gas to prepare the compressed natural gas; and coal gasification reaction, purification treatment, mixing with the hydrogen and fine desulfurization treatment are carried out to the coal to obtain the methanol synthesis gas. The method is based on the characteristics of more hydrogen and less carbon in the coke oven gas and more carbon and less hydrogen in the coal-made methanol feed gas, transforms CO to H2 and CO2 by the transformation treatment after the effective pretreatment to the coke oven gas, and then the H2 and CH4 are separated effectively by a PSA technology so as to be used as the raw materials with higher values, and therefore the method achieves the purpose of comprehensively utilizing the coke oven gas and the coal as the raw materials for producing the methanol synthesis gas and the compressed natural gas, adopts the effective energy in the coke oven gas and the coal to maximum, saves energy, reduces emission and improves the economic benefits.
Owner:SOUTHWEST RES & DESIGN INST OF CHEM IND

Integrated equipment for omnibearing treatment of kitchen garbage and production method of products

The invention discloses integrated equipment for omnibearing treatment of kitchen garbage and a production method of products. The equipment comprises a central intelligent automatic control system, an air treatment system, a straw biochemical system, an advanced oxidization artificial forced inactivation system, a combined screening and impurity removal system, a compound biochemical system, an automatic drying system, a combined conveying system, a waste plastic reversion engineering system, a sludge treatment system, a sewage treatment system, an oil treatment system and a hot smoke combined treatment system. Produced finished products comprise high-nutrition microbial protein feed, mineral state III diesel, biodiesel, emulsification diesel, low-sulfur clean fire coal, hybrid charge adsorbents and industrial recycle water. A recycling rate of the kitchen garbage reaches above 95%; basically no waste water is discharged, no sludge is transferred, no room temperature discharge exists, no peculiar smell or smoke is discharged and no residue is transferred during production; and the environment-friendly, safe and reliable highly-integrated production equipment and the production method are provided for the treatment of the kitchen garbage.
Owner:SOUTH CHINA REBORN RESOURCES ZHONGSHAN

Technological process of ramie bast fiber

The invention relates to a technological process of a ramie bast fiber, which comprises a basic degummed ramie production route: raw ramie skin-sorting and derooting-mechanical ungluing-cage loading-biological ungluing-high-temperature rinsing-cage unloading-sub-fiber washing-soft rinsing-radio frequency drying- degummed ramie. Long ramie can be growth through the mechanical hemp oiling- infiltration and health care-stretch breaking and carding-pre-gilling-combing and sorting-final gilling of the degummed ramie. Short ramie can be produced through the combing and the sorting of combed noil. Oakum can be produced through biological ungluing-high-temperature stewing and ungluing-high-temperature rinsing-cage unloading-sub-fiber washing-soft rinsing-dehydration and drying-radio frequency drying-mechanical hemp oiling- infiltration and health care-opening and edulcoration- combing and sorting. Improving methods are adopted for the mechanical ungluing, biological ungluing, high-temperature rinsing, sub-fiber washing, stretch breaking and carding, combing and sorting and the like. The preparation process has the advantages of short process, high production efficiency, high mechanical automation degree, stable product quality, excellent fiber quality and strong operability of fiber length and fineness, and can be used in the production processes of various bast fiber raw material, gramineae fiber raw material, leaf fiber raw material and other fibers.
Owner:THE QUARTERMASTER RES INST OF THE GENERAL LOGISTICS DEPT OF THE CPLA +2
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