Described systems produce high-purity
carbon dioxide from a CO2-rich gas, such as from CO2-rich
tail gas produced as a
waste stream during an upgrading or conditioning stage in a renewable
natural gas (RNG)
biorefinery. An example method comprises H2S
filtration, compression, and cooling of the CO2-rich
tail gas, subsequent
filtration of oil, water, VOCs, and other
sulfur-comprising compounds from the CO2-rich
tail gas, and subsequent
drying and compression of the CO2-rich tail gas. The CO2-rich tail gas is then condensed and a portion of CH4 is separated from the CO2-rich tail gas via flash separation and column
distillation. The CO2-rich tail gas is then communicated into a
reboiler to further separate CH4 from the CO2-rich tail gas. After subsequent further chilling / cooling, if the CO2-rich tail gas has a sufficiently high CO2 concentration, the CO2-rich tail gas is a finished CO2 product, such as food-grade CO2 or beverage-grade CO2.