4461 results about "Polybutadiene" patented technology

A functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I)

A-R¹-Z  (I)

where R¹ is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R¹, and Z are substituents that will not protonate a pseudo-living polymer.

A golf ball includes a hot-molded product of a rubber composition comprising a base rubber composed of (a) 20-100 wt % of a polybutadiene having a high cis-1,4 content, a minimal 1,2 vinyl content, and a viscosity η of up to 600 mPa·s at 25° C. as a 5 wt % toluene solution, and satisfying a certain relationship between Mooney viscosity and polydispersity index Mw/Mn, in combination with (b) 0-80 wt % of another diene rubber, (c) an unsaturated carboxylic acid, (d) an organosulfur compound, (e) an inorganic filler, (f) an organic peroxide, and optionally, (g) an antioxidant. The hot-molded product has a difference in JIS-C hardness between the center and surface thereof of up to 15 units. The composition and hardness characteristics of the hot-molded product provide the golf ball with a solid comfortable feel upon impact and an excellent rebound.

The invention discloses a wet-laying and pre-laying waterproof roll which is made by the following processes: dipping and coating a modified asphalt compound on a blank body, controlling the thickness and sizing, coating a membrane, rolling, and the like, wherein the modified asphalt compound contains modified asphalt, a plasticizer, an antioxidant, a functional auxiliary agent and a filling gent. A preparation method of the waterproof roll comprises the following steps: putting substrate asphalt in a reaction pot, adding a thickening agent, irregular polyethylene and styrene-polybutadiene-styrene segmented copolymer, evenly mixing, heating and stirring for 1.5-2 hours, then reducing the temperature to about 180 DEG C, adding padding, the plasticizer, the antioxidant and the functional auxiliary agent into the reaction pot and stirring for 0.5-1h, evenly mixing and modifying, then conveying into a colloid mill for repeatedly milling to the material, then dipping and coating the modified asphalt on the blank body, controlling the thickness, sizing, coating the membrane and rolling, and finally preparing the waterproof roll which has excellent performance and can carry out chemical bonding and physical crosslinking synergism with the concrete, namely, a CPS waterproof roll for short.

The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, and an inorganic filler. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer is formed by injection molding a single resin blend composed primarily of (A) a thermoplastic polyurethane and (B) a polyisocyanate compound, which resin blend contains a polyisocyanate compound in at least some portion of which all the isocyanate groups on the molecule remain in an unreacted state, and has a thickness of 0.5 to 2.5 mm, a Shore D hardness at the surface of 50 to 70. The golf ball has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of 2.0 to 3.8 mm. The solid golf ball is advantageous overall in competitive use.

The present invention relates to the preparation of rubber compositions for tire tread and tire sidewall component applications. A tire is provided having tread of such composition designed for relatively heavy loads such as, for example, truck tires. A tire having a sidewall of such composition is also provided. Such tire component rubber compositions are of rubber compositions reinforced with precipitated silica and selected carbon black in specified amounts and prepared with a prescribed order of addition to the rubber composition and composed of elastomers as a specific combination of natural or synthetic cis 1,4-polyisoprene rubber together with cis 1,4-polybutadiene rubber or with a combination of cis 1,4-polybutadiene rubber and trans 1,4-polybutadiene rubber.

The present invention relates to a personal care absorbent article comprising at least two substrates each having an internal and external surface, wherein at least one substrate is a fluid permeable bodyside substrate selected from spunbond, meltblown, coform, airlaid, bonded-carded web, spunlace materials and combinations thereof; at least one substrate is an impermeable backsheet; and an absorbent core disposed in between said substrates; wherein at least the external surface of at least one substrate has applied to it a benefit agent selected from an additive composition wherein said additive composition is a polymer dispersion selected from polyolefin dispersions, polyisoprene dispersions, polybutadiene-styrene block copolymer dispersions, latex dispersions, polyvinyl pyrrolidone-styrene copolymer dispersions, polyvinyl alcohol-ethylene copolymer dispersions, and combinations thereof; an enhancement component selected from microparticles, expandable microspheres, fibers, additional polymer dispersions, scents, anti-bacterials, moisturizers, medicaments, soothers and combinations thereof; and combinations thereof.

Golf balls and compositions for use in ball cores, covers and intermediate layers incorporate syndiotactic 1,2-polybutadiene having crystallinity and other specified physical properties. Golf balls incorporating the compositions of the present invention provide flexibility in golf ball design to improve ball performance, such as hit feel and spin rate, without adversely affecting shear-cut resistance of the ball. Also, methods for making golf balls include preparing a composition comprising syndiotactic 1,2-polybutadiene having crystallinity, and then incorporating the composition into a golf ball. The methods can include injection molding only, or injection and compression molding. When the composition being molded incorporates crosslinking agents, co-crosslinking agents, or crosslinking accelerators, preferred methods include inducing partial or total crosslinking of the composition at preferred steps of making the golf balls.

The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, and an antioxidant. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer is formed primarily of a polyurethane material and has a thickness of 0.5 to 2.5 mm, a Shore D hardness at the surface of 50 to 70 and a flexural rigidity of 50 to 300 MPa. The golf ball has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of 2.0 to 3.8 mm. The solid golf ball is advantageous overall in competitive use.

A sonic actuator including a multi-layer membrane having a non-metallic elastomeric dielectric polymer layer with a first surface and a second surface, a first compliant electrode layer contacting the first surface of the polymer layer, and a second compliant electrode layer contacting the second surface of the polymer layer. The actuator further includes a support structure in contact with the sonic actuator film. Preferably, the non-metallic dielectric polymer is selected from the group consisting essentially of silicone, fluorosilicone, fluoroelastomer, natural rubber, polybutadiene, nitrile rubber, isoprene, and ethylene propylene diene. Also preferably, the compliant electrode layer is made from the group consisting essentially of graphite, carbon, and conductive polymers. The support structure can take the form of grid having a number of circular apertures. When a voltage is applied to the electrodes, portions of the film held at the aperture of the support structure can bulge due to the electrostriction phenomenon. The resultant “bubbles” can be modulated to generate sonic vibrations, or can be used to create a variable surface for airflow control.

The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes from 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, from 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, and an antioxidant. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer has a thickness of from 0.5 to 1.9 mm, and a Shore D hardness at the surface of from 50 to 70. The ball has at least one intermediate layer between the core and the cover, any one of which intermediate layer or layers has a surface hardness in Shore D units of from 40 to 60, the intermediate layer or layers having a total thickness of from 0.9 to 7.0 mm. The golf ball has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 3.8 mm. The solid golf ball is advantageous overall in competitive use.

The present invention relates to an industrially beneficial method of manufacturing golf balls which includes the steps of pre-preparing a masterbatch of an unsaturated carboxylic acid and/or a metal salt thereof by mixing an unsaturated carboxylic acid and/or a metal salt thereof with a rubber material, preparing a rubber composition that contains the rubber material by using the masterbatch, and employing a material obtained by molding the rubber composition under heat as a golf ball component. The masterbatch is composed of:

(A) from 20 to 100 wt % of a modified polybutadiene obtained by a modification reaction wherein a polybutadiene having a vinyl content of from 0 to 2%, a cis-1,4 bond content of at least 80% and an active end is modified at the active end with at least one type of alkoxysilane compound, and

(B) from 80 to 0 wt % of a diene rubber other than Ingredient A.

such that ingredients A and B are included in a combined amount of 100 wt %, and

(C) an unsaturated carboxylic acid and/or a metal salt thereof.

The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes from 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, from 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, and an antioxidant. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer is formed by injection molding a single resin blend composed primarily of (A) a polyurethane material and (B) a polyisocyanate compound, which resin blend includes a polyisocyanate compound in at least some portion of which all the isocyanate groups on a molecule remain in an unreacted state. The cover layer has a thickness of from 0.5 to 2.5 mm and a Shore D hardness at the surface of from 50 to 70. The golf ball has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 3.8 mm. The solid golf ball is advantageous overall in competitive use.

A thermoplastic elastomer composition comprised of (a) a thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) a block copolymer selected from the group consisting of styrene-ethylene butylene-styrene, styrene-ethylene propylene-styrene, hydrogenated polybutadiene, hydrogenated polyisoprene, hydrogenated styrene-isoprene random copolymer, styrene-ethylene propylene block copolymer, styrene-ethylene ethylene propylene-styrene and hydrogenated styrene-butadiene random copolymers, (c) a core-shell polymer comprised of a polymeric core and a polymeric shell with the proviso that the polymeric core and/or the polymeric shell may be crosslinked, and (d) an oil.

A multi-piece solid golf ball has a solid core obtained by molding and vulcanizing a rubber composition which includes (A) a base rubber containing a polybutadiene synthesized using a rare-earth catalyst, (B) an unsaturated carboxylic acid and/or a metal salt thereof, (C) an organic sulfur compound, (D) an inorganic filler and (E) an organic peroxide. The core is enclosed within a mantle of one or more layer which is made primarily of a thermoplastic resin and has a Durometer D hardness of 30 to 70. The mantle is enclosed within a cover which is made primarily of a thermoplastic polyurethane and which has a Durometer D hardness of 40 to 60 that is lower than the Durometer D hardness of the outermost layer of the mantle. This construction provides the golf ball with an outstanding rebound.

Methods for making a crosslinked elastomeric composition and articles made of the same are provided. In at least one specific embodiment, an elastomeric composition comprising at least one propylene-based polymer is blended with at least one component selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, functionalized polybutadiene resins, functionalized cyanurate, and allyl isocyanurate; and blended with at least one component selected from the group consisting of hindered phenols, phosphites, and hindered amines. The propylene-based polymer can include propylene derived units and one or more dienes, and have a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g. The blended composition can then be extruded and crosslinked. The extruded polymer can be crosslinked using electron beam radiation having an e-beam dose of about 100 KGy or less. The crosslinked polymers are particularly useful for making fibers and films.

The present invention relates to one kind of tearproof antiwear conveying belt, and belongs to the field of rubber product technology. The tearproof antiwear conveying belt is produced through pre-pressing and mixing natural rubber, styrene butadiene rubber and cis-butadiene rubber inside a Banbury mixer; adding promoter, activator, leveler and antiaging agent before further mixing; adding reinforcing agent, softening agent and aramid fiber before further mixing to obtain mixed rubber; mixing for the second time and adding cross-linking agent inside a Banbury mixer after being set for some time; discharging batch to obtain mixed rubber; rolling to form rubber sheet; combining rubber sheet with tension element belt blank, rolling up and sulfurizing; and trimming to obtain the product. The tearproof antiwear conveying belt has excellent tearproof performance, excellent antiwear performance and long service life, and is suitable for use in mines.