This invention discloses a method with a high proportion of supercage Na + This paper describes the application of exchange-site FAU molecular sieves for the adsorption and separation of
fluorine-containing
electron gases. The
molecular sieve possesses the FAU
molecular sieve configuration recognized by the International Zygotes Association (IZA), with a
chemical composition molar ratio of Al₂O₃:mSiO₂:nNa₂O, where the
molar ratio m of the
oxide SiO₂ / Al₂O₃ ranges from 5 to 20. This
molecular sieve is synthesized using an initial gel prepared from an organic template agent, water,
silicon source, and aluminum source. FAU seed crystals are added, and the
charge density of the organic template agent is adjusted. Different cage structures of the FAU molecular
sieve are assembled. Furthermore, through mixing with a
solid salt containing Na and
solid-phase exchange, Na in the supercage is achieved. + Control of the exchange site ratio. Compared with the commercial molecular
sieve USY2.6, this invention has a high proportion of supercage Na. + Exchange-site FAU molecular sieves can be used for the adsorption and separation of
fluorine-containing electronic gases in gas-phase systems, especially pentafluorochloroethane C2F5Cl (R115) and
hexafluoroethane C2F6 (R116), and the separation effect is good.