7668results about "Bio-packaging" patented technology

The present invention discloses a water-based emulsion of PHA, PBAT and PVOH and its application in paper-based barrier coatings. This emulsion is prepared by first melt-blending PHA and PBAT at 150-170 °C and then dispersing them into an aqueous PVOH solution at 80-95 °C. Plasticizers, cross-linking agents and surfactants can be added to improve the performance. After coating on paper and drying at 80-150 °C, a barrier film with a Cobb value of 10-15 g / m² and a Kit ≥ 10 grade is formed. Compared with traditional PE film laminating or fluorine-containing coatings, this system is more environmentally friendly and recyclable; PVOH dissolves in pulping water, PHA and PBAT are easily separated, and fibers can be efficiently recovered; in composting, soil and marine environments, PHA and PBAT have extensive biodegradability and are superior to PLA which is difficult to recycle and requires industrial composting. It is applicable to food, industrial, special packaging and agricultural paper products.

A repulpable insulated container assembly having a container formed of paper such as corrugated cardboard or varying paper materials and defining an interior; and a repulpable insert placed within the interior of the container and formed of a first paper layer; and a paper fiber pad coupled to the first paper layer.

The invention relates to the technical field of film material preparation, and discloses a polylactic acid antibacterial packaging film and a preparation method thereof, the polylactic acid antibacterial packaging film comprises the following raw material components by weight: 60-80 parts of polylactic acid, 10-20 parts of polyvinyl alcohol, 10-20 parts of nano zinc oxide, 0.5-1.5 parts of nano cellulose, 1-3 parts of an antibacterial agent, and 10-15 parts of corn starch; the antibacterial agent is prepared from the following components in parts by weight: 5-10 parts of carboxymethylated chitosan and 0.5-2 parts of a dynamic disulfide bond cross-linking agent, the substitution degree of the carboxymethylated chitosan is greater than or equal to 80%, the antibacterial agent is prepared from tea tree essential oil and eugenol, and the dynamic disulfide bond cross-linking agent is bis (3-aminopropyl) disulfide. By adopting a composite system of carboxymethylated chitosan and a dynamic disulfide bond cross-linking agent, the technical effects of humidity-triggered self-repairing and mechanical property synergistic improvement are achieved, and compared with a packaging film with a single polymer base material in the prior art, the problem of antibacterial failure caused by mechanical damage is solved.

The invention discloses a high-barrier polycrystalline silicon packaging film and a preparation method thereof, and relates to the technical field of packaging materials. The high-barrier polycrystalline silicon packaging film consists of a polyester film carrier and functional slurry, the functional slurry is prepared from the following raw materials in parts by weight: 15 to 25 parts of ethylene-vinyl alcohol copolymer, 10 to 18 parts of polyvinylidene chloride, 5 to 10 parts of modified nano montmorillonite, 8 to 15 parts of modified polylactic acid, 3 to 6 parts of tributyl citrate, 1 to 3 parts of antioxidant 1010, 1 to 3 parts of ultraviolet light absorber UV-531, 0.5 to 1.5 parts of nucleating agent NA-11, 1 to 2 parts of silane coupling agent KH-550 and 3 to 7 parts of modified silicon dioxide aerogel; 2 to 5 parts of vinyl trimethoxy silane, 1 to 3 parts of nano silver and 20 to 30 parts of deionized water. The high-barrier polycrystalline silicon packaging film has excellent barrier performance, and can effectively block oxygen, water vapor and the like. The polycrystalline silicon packaging film is good in mechanical performance, not prone to damage, antibacterial, antioxidant and anti-ultraviolet, the quality guarantee period of polycrystalline silicon can be prolonged, the product quality can be guaranteed, and the polycrystalline silicon packaging film has great application value in the field of polycrystalline silicon packaging.

The invention discloses a large-size green packaging carton and a preparation process thereof, and relates to the field of packaging box preparation. The environment-friendly composite material comprises the following raw materials in parts by weight: 50-80 parts of plant fiber slurry, 10-25 parts of a modified starch-based adhesive, 5-15 parts of a nanoscale inorganic reinforcing filler, 1-5 parts of a degradable water repellent agent, 0.5-3 parts of a cross-linking agent and 2-8 parts of starch and plant fiber composite buffer microspheres. According to the preparation method, full-environment-friendly raw materials such as plant fiber slurry and a modified starch-based adhesive are selected and matched with starch and plant fiber composite buffer microspheres, and optimized processes such as segmented temperature control pressurization molding, adhesive gelatinization treatment, stirring speed reduction and microsphere structure protection are combined; and through coating of the degradable polymer coating and micron-sized hydrophobic texture imprinting, synergistic improvement of high compressive strength, excellent buffering performance, excellent hydrophobic and damp-proof effects and high degradation rate of the carton is achieved.

The invention discloses a degradable bamboo fiber express packaging bag and a preparation method thereof, and belongs to the technical field of express packaging. The packaging bag is prepared from, by mass, 32-42 parts of pretreated bamboo fibers, 22-28 parts of poly (butylene succinate), 9-14 parts of modified nano calcium carbonate, 12-16 parts of polycaprolactone, 6-11 parts of acetylated chitosan and the like, and the key raw materials are all treated through an exclusive pretreatment or modification process. The preparation method comprises the steps of raw material plasma activation, segmented high-speed mixing, vacuum drying, precise-parameter twin-screw extrusion granulation, secondary drying, precise film blowing, high-precision heat-sealing bag making and the like, and the technological parameters of all the steps are clear. The product disclosed by the invention can be efficiently degraded in a natural environment, has excellent tensile resistance, puncture resistance and impact resistance, is stable and controllable in processing process, and is adaptive to actual requirements of express packaging and industrial batch production.

The invention discloses a bio-based barrier coating for fresh-keeping of paper-based beverages as well as a preparation method and application of the bio-based barrier coating, and belongs to the technical field of paper-based packaging materials for foods and beverages. The coating is a water-based emulsion, and the core solid components of the coating comprise polyhydroxyalkanoate, polyethylene furandicarboxylate, aliphatic polyester, a polyisocyanate cross-linking agent, a nanofiller, a surfactant and a plasticizer. An emulsion is prepared through melt crosslinking and high-shear emulsification, and a dry film is formed through curtain coating and orientation. The film has excellent oxygen and water vapor barrier properties, can be heat-sealed and re-pulpified, and can be biodegraded in industrial compost, household compost and marine environments. According to the preferred embodiment, the bio-based content can be higher than 99%, aluminum foil can be replaced to be used for 60-day fresh-keeping beverage packaging, carbon footprint is reduced, and the recovery value is improved.

The utility model discloses an auger discharging device for feed production, which relates to the technical field of feed production and comprises a feed conveying barrel, symmetrical supports are fixedly connected to two sides of the feed conveying barrel, an auxiliary rod is fixedly connected in the feed conveying barrel, the auxiliary rod is rotatably connected with a sieve plate, and a spring is fixedly connected to the top of one side, far away from the auxiliary rod, of the sieve plate. The side, close to the feeding hopper, of the support is rotationally connected with a movable rod, the side, close to the auxiliary rod, of the movable rod is fixedly connected with a cam, and the cam is located below the spring. The device has the beneficial effects that a movable rod drives a cam to extrude a sieve plate, the sieve plate rotates around an auxiliary rod by a certain angle to drive a spring to be compressed and deformed, the sieve plate is continuously extruded by the cam, one side of the sieve plate vibrates, impurities and chippings in feed are vibrated to fall into a collecting box through vibration, and the feed on the sieve plate moves towards one side of the sieve plate along with vibration; feed can be conveniently screened and collected, and the situation that too many chippings stay in the conveying barrel and are difficult to clean is avoided.

The invention relates to a high-barrier antibacterial polylactic acid packaging material and a preparation method thereof, and belongs to the technical field of biodegradable packaging materials. The technical problems that a traditional polylactic acid material is insufficient in barrier property, poor in antibacterial performance and difficult to meet the packaging requirements of livestock and poultry meat, food and medicine are solved. A graphene oxide lamellar material is subjected to copper ion functionalization treatment and is bridged with tannic acid molecules through copper ions to form a nano filler, and then the filler is blended with a plasticized polylactic acid solution to prepare the membrane. The preparation method comprises the following steps: preparing a copper ion functionalized dispersion liquid from graphene oxide and copper nitrate, self-assembling the copper ion functionalized dispersion liquid and tannic acid under the condition that the pH is 8-10 to generate a nanofiller, uniformly dispersing the nanofiller, mixing the nanofiller with polylactic acid, polyethylene glycol and glycerol according to a specific mass ratio, coating to form a film, and controlling solvent volatilization conditions to obtain the high-performance packaging material. According to the method, the oxygen barrier property and the antibacterial activity of the material are remarkably improved through uniform dispersion of the nanofiller and reinforcement of a coordination network. The obtained material is suitable for packaging foods such as livestock and poultry meat.

The invention relates to the technical field of high-barrier environment-friendly packaging films, and discloses a high-barrier environment-friendly packaging film with an antibacterial function, the high-barrier environment-friendly packaging film comprises a base layer, a nano composite barrier layer, a bio-based functional layer and an outer protective layer from bottom to top in sequence, and the layers are tightly attached through a coated starch-based adhesive. According to the high-barrier environment-friendly packaging film with the antibacterial function, good biodegradability of polyhydroxyalkanoate adopted in the base layer film, polycaprolactone which is adopted in the nano-composite barrier layer film and has a biodegradable function and konjac glucomannan in the biological functional layer film are utilized; the composite packaging film can be decomposed into carbon dioxide and water by microorganisms in various environments, has excellent flexibility and processability, can adapt to different packaging requirements, provides basic flexibility, structural support and green and environment-friendly effects for the whole packaging film, and has a wide application prospect. The procyanidine arranged in the outer protective layer film provides stronger antibacterial property and water solubility for the whole packaging film.

The invention discloses a high-barrier antibacterial packaging material, a preparation method thereof and a packaging bag, and belongs to the technical field of packaging, the packaging material comprises the following raw materials by weight: 75-85 parts of polylactic acid, 15-25 parts of poly (butylene succinate), 2-6 parts of epoxidized urushiol, and 1-3 parts of benzyl quaternary ammonium salt modified montmorillonite; the epoxidized urushiol is prepared by carrying out epoxidation reaction on urushiol and organic peroxy acid; the packaging material further comprises the following raw materials: 2-5 parts of sepiolite fiber loaded magnesium oxide; according to the invention, biodegradable polylactic acid and poly (butylene succinate) are taken as base materials, and epoxidized urushiol is taken as a reactive compatilizer, so that the compatibility between polylactic acid and poly (butylene succinate) is improved, and meanwhile, the binding property between a polymer matrix and benzyl quaternary ammonium salt modified montmorillonite and sepiolite loaded magnesium oxide is enhanced; the packaging material with good mechanical property, barrier property and antibacterial property is obtained.

The invention discloses environment-friendly high-barrier packaging paper and a preparation method thereof, and belongs to the technical field of paper product manufacturing. The method comprises the following steps: dispersing bleached sulfate softwood pulp in an aqueous solution of TEMPO and NaBr, adding a NaClO solution, adjusting the pH value, carrying out a reaction, washing the product obtained by the reaction, and carrying out high-pressure homogenization to obtain TEMPO oxidized nanocellulose (TOCNF); mixing the bleached sulfate softwood chemical pulp, hardwood pulp and viscose fibers, pulping, papermaking and the like to obtain original paper; then, TOCNF and waterborne epoxy modified acrylic emulsion are mixed, and a mixed coating is prepared; and finally, coating the surface of original paper with the coating according to a certain mass ratio, and carrying out hot-pressing curing to obtain the environment-friendly high-barrier packaging paper. The packaging paper is excellent in mechanical property, high in barrier property, good in surface uniformity and printing property, environment-friendly and degradable in raw materials, simple to prepare and low in cost.

A pill dispenser includes a dispenser body, a pill dispensing cover, and a pill outlet cover. The dispenser body is hollow. A fixed cylinder is disposed at a center of the dispenser body. Partition plates are connected between the fixed cylinder and the dispenser body to define pill cavities. The partition plates are disposed in a circumferential array. At least one end of each of the partition plates extends out of the dispenser body. Clamping grooves are defined in the pill dispensing cover. A periphery of each of the partition plates is clamped in a corresponding one of the clamping grooves, so the pill dispensing cover is fixed to the dispenser body. The pill dispensing cover includes pill dispensing openings one-to-one corresponding to the pill cavities. When the pill dispensing cover is fixed to the dispenser body, each of the partition plates abuts against the pill dispensing cover.

The invention relates to the technical field of 3D printing, and discloses an environment-friendly packaging box rapid forming method and system based on biodegradable materials, and the method comprises the steps that a thermal-structure coupling finite element model is established; based on the thermal-structural coupling model, a multi-objective optimization model is constructed, and structural design parameters and initial printing path configuration are obtained; training a printing control strategy by utilizing a strategy optimization algorithm; according to the structural design parameters, the printing path configuration and the printing control strategy, a layer-by-layer printing path and a supporting structure configuration scheme matched with the printing object are generated; and the 3D printing process is executed, and closed-loop adjustment is conducted according to the control strategy. According to the method, the thermal-structural coupling finite element model based on the biodegradable material is constructed, and changes of a temperature field, a stress field and a thermal strain field in the printing process are accurately simulated, so that a printing path and supporting structure configuration are optimized, the printing precision is improved, structural instability caused by thermal deformation and interlayer stress is avoided, and the strength and stability of an object are ensured.

The invention relates to the technical field of food packaging materials, in particular to a cerium dioxide nano-enzyme modified antibacterial coating and application of the cerium dioxide nano-enzyme modified antibacterial coating in food packaging. The biomimetic mineralization layer comprises the following components in percentage by weight: 35-45% of a green base material, 8-12% of dopamine modified yttrium-doped cerium dioxide nano-enzyme, 4-6% of a composite antibacterial agent, 3-4% of a natural cross-linking agent, 2-3% of a degradable plasticizer, 1-2% of a biomimetic mineralization layer precursor and the balance of deionized water, the green base material is a blend of a chitosan-polyethylene glycol graft and polylactic acid; the doping amount of Y3 in the nano enzyme is 3-4at%. The antibacterial agent is excellent and lasting in antibacterial effect, has no migration risk of the antibacterial agent, and can guarantee food safety; a green base material and a degradable plasticizer are adopted, so that natural degradation is realized, and environmental pollution is avoided; the mechanical property is good, the aging resistance is realized, and the oxygen barrier property is strong; the food packaging box is suitable for various foods, effectively prolongs the shelf life, and meets the requirement of green packaging.

The invention relates to the technical field of degradable PE (polyethylene) packaging materials, and discloses a PE film, a preparation process and application in tissue packaging, and the PE film is prepared by the following steps: by taking 7-(diethylamino) coumarin-3-carboxylic acid, 2-naphthyl methanol and epoxy chloropropane as raw materials, carrying out esterification reaction and quaternization reaction to prepare an epoxidized biodegradable organic photosensitizer; based on an epoxy-hydroxyl ring-opening reaction mechanism, hydroxylated titanium dioxide nanoparticles and polyvinyl alcohol resin are respectively modified by using an epoxidized biodegradable organic photosensitizer, and compounding is performed based on a pi-pi accumulation effect between aromatic rings to prepare the ultraviolet light dependent photo-biodegradable component. According to the present invention, the ultraviolet light dependent light-biological degradation component, the compatible component and the composite auxiliary agent are added to the polyethylene matrix, and blow molding is performed to obtain the PE film, and the film product shows excellent light-biological dual degradation performance, has actual use value, and can be used in the tissue packaging field.

The present invention is directed to a capsule (1) for beverage preparation, comprising a cup-shaped body (2) of moulded cellulose pulp and a closing membrane (5) attached to a peripheral rim (4) of said body (2). The capsule further comprises a multilayer polymeric liner (3) attached to the inner surface of the cellulose pulp body (2), said liner comprising: (i) an outermost polymeric layer (7), (ii) a first tie layer (8), (iii) a barrier layer (9), (iv) a second tie layer (10), (v) an innermost polymeric layer (11), In which liner, - the thickness of the outermost layer (7) and the thickness of the innermost layer (11) are comprised between 10 and 100 pm and are preferably identical; - the elongation at break of the outermost layer (7) is higher than the elongation at break of the innermost layer (11); - The melt flow rate (MFR) of the outermost layer (7) measured at 150°C during 10 minutes with a pressure of 2.16 kg, is lower than the melt flow rate (MFR) of the innermost layer (11), measured at 190°C during 10 minutes with a pressure of 2.16 kg; - The melting point temperature of the outermost layer (7) is lower than the melting point temperature of the innermost layer (11), and in which, the outermost layer serves as an adhesive to the cellulose pulp of the capsule body.

The invention relates to the field of coatings, and discloses a biomass-based oil-resistant coating and a preparation method thereof, the coating comprises an additive solution, a paraffin solution and gallic acid; the paraffin solution is obtained by dissolving paraffin in absolute ethyl alcohol; a preparation method of the additive solution comprises the following steps: mixing chitosan powder and an acetic acid aqueous solution to prepare a chitosan solution, ultrasonically dispersing functionalized montmorillonite in deionized water to prepare a suspension, then uniformly mixing the chitosan solution and the suspension, adding modified phytic acid prepared by grafting phytic acid and ethylene glycol diglycidyl ether, and stirring to react; the functional montmorillonite is prepared by modifying modified montmorillonite with titanium dioxide and zinc oxide, then activating the modified montmorillonite with 3-aminopropyltriethoxysilane and succinic anhydride, and then carrying out a ring-opening reaction with glycidyl neodecanoate. The coating prepared by the invention has high water resistance, the Kit oil-proof grade is kept at grade 12, and the oil-proof performance of the coating is greatly improved. Meanwhile, the antibacterial performance, the tensile index and the ultraviolet aging resistance are relatively high.

The invention discloses a water-based PHA (Polyhydroxyalkanoate) coating and PHA extrusion layer compounded paper-based high-barrier material as well as a preparation method and application thereof, and belongs to the technical field of biodegradable high polymer materials and environment-friendly packaging. According to the scheme, a double-component system with a specific melting point difference is innovatively introduced to construct the water-based pre-coating layer, and efficient sealing and strong anchoring of a rough base material can be achieved under the extremely low coating weight by means of the double mechanisms of'microcosmic leveling and interface thermal fusion '. Compared with a traditional thick-layer lamination process, the material achieves more excellent barrier integrity and oil-resistant and moisture-resistant performance through a thinner extrusion surface layer, the moisture-resistant and oxygen-resistant performance is remarkably improved, and meanwhile the requirement for puncture resistance of dry and hard food packaging materials is thoroughly met through the unique double-layer system stress balance design. The material does not contain fluorine additives, is completely biodegradable, and meets the high-standard requirements of food safety and compliance.

The invention discloses a degradable express bag material and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a degradable express bag material. The composite material is prepared from the following raw materials in parts by weight: 40 to 50 parts of poly (butylene adipate-co-terephthalate), 20 to 30 parts of polycaprolactone, 5 to 8 parts of modified bamboo fiber, 2 to 4 parts of modified nano montmorillonite, 3 to 6 parts of tributyl citrate, 0.1 to 0.3 part of antioxidant 1076, 1 to 2 parts of iron dithiocarbamate master batch, 2 to 3 parts of maleic anhydride grafted poly (butylene adipate-co-terephthalate) and 0.3 to 0.6 part of zinc stearate. 0.1 to 0.3 part of baicalein; and 1 to 3 parts of chitosan-sorbitol composite coating liquid. According to the degradable express bag material, poly (butylene adipate-co-terephthalate) and polycaprolactone are used as main degradable raw materials, modified bamboo fibers and modified nano-montmorillonite are matched to enhance the mechanical property, an antioxidant 1076, baicalein and the like are added to guarantee the stability and functionality, temperature is accurately controlled in the preparation process, multi-step modification is adopted for optimizing component combination, and the degradable express bag material is prepared. The performance is improved through the composite coating, degradability is achieved, and good usability is achieved.

The utility model belongs to the technical field of bamboo processing, and particularly relates to a lifting chain type single bamboo chip separating device which structurally comprises a vertical plate for installation and further comprises a chain arranged on the vertical plate for installation and used for conveying bamboo chips upwards and a transverse frame body unit arranged on the chain and used for supporting the bamboo chips. And the protruding plate unit is arranged on the vertical plate for mounting and is used for pushing and dropping an upper-layer bamboo chip of the two stacked bamboo chips and a single conveyed bent bamboo chip with two upwarped ends in a manner of blocking the end positions of the bamboo chips.

The invention relates to the technical field of medicinal material storage, and discloses a white muscardine silkworm storage device which comprises a temperature control assembly and a protective shell, a plurality of storage layers are arranged in the protective shell, two symmetrical moving plates are arranged in each storage layer, trays are arranged on the upper surfaces of the moving plates, each storage layer comprises an upper shell and a lower shell, and the upper shell and the lower shell are arranged in the upper shell. Two symmetrical rotating assemblies used for reciprocating up and down are arranged in the upper shell, a plurality of exhaust pipes are arranged on the bottom face of the lower shell, the exhaust pipes sequentially penetrate through the lower shell and the moving plate, piston sets used for exhausting air are arranged in the exhaust pipes, and a plurality of rotating blades are arranged on the outer surfaces of the rotating assemblies; by changing the positions of the moving plate and the tray, a plurality of exhaust pipes are inserted into the silkworm larva, so that internal heat can be discharged, when the expansion material expands again, the upper shell and the lower shell can be separated, and the first wind shield on the side face is opened, so that ventilation and heat dissipation are further performed, and the silkworm larva is prevented from going bad.

A fully recyclable container and a method of manufacturing the same is provided. The container includes a cap, a shoulder, a body, a base, and a liner. The cap, the shoulder, and the base are made of biodegradable plastic by injection molding while the body is made of waterproof paper. The cap, the shoulder, and the base are detachably connected to form a housing of the container. The liner is formed inside the housing by blow molding of biodegradable plastic. The respective components of the container are completely made of biodegradable or bio-decomposable material and able to be disassembled for sorting and recycling. Thereby the fully recyclable container completely meets requirements of environmental protection and recycling.

The invention relates to the technical field of plastic bags, in particular to an antibacterial degradable plastic bag and a preparation method thereof. The antibacterial degradable plastic bag is prepared from the following raw materials in parts by weight: 60-80 parts of polyhydroxyalkanoate, 30-40 parts of filler, 2-4 parts of an antioxidant and 0.6-1 part of an active agent. In the preparation process of the antibacterial degradable plastic bag, in a filler system, vesuvianite powder and eggshell powder are used as inorganic reinforcing phases, sericin and mulberry leaf powder are used as bioactive phases, flax and cotton provide a natural fiber structure, and lignin and konjac glucomannan are used as bio-based bonding materials; and the eggshell powder is compact in crystal structure after being subjected to high-temperature calcination treatment, and can be used as a stress transfer medium in a material system, so that the stress concentration when the plastic bag is stressed is reduced, and the strength performance of the plastic bag is improved.

The invention discloses a bacteriostatic and antiviral bamboo pulp paper-based sanitary isolation bag as well as a preparation method and application thereof, and belongs to the field of functional paper-based packaging materials. The isolation bag takes bamboo pulp fiber paper as a base material, and the surface of the isolation bag is coated with a water-based polyhydroxyalkanoate functional coating. According to the preparation method, a special polyphenol derivative-chitosan quaternary ammonium salt-nano zinc oxide organic-inorganic hybrid factor is introduced, and the problem of agglomeration of nano particles is effectively solved by utilizing the special bridging effect of polyphenol, so that high-density cation capture and oxidation inactivation sites are constructed on the surface of the coating. Compared with the prior art, the method has the advantages that the method does not need to depend on organic fluorine compounds, and the excellent waterproof and oil-proof barrier effect and the efficient inactivation of viruses can be achieved only through the extremely low coating amount. In addition, the isolation bag has unique environmental chemical responsiveness, can be efficiently dissociated under the alkaline condition to facilitate repulping recovery, can be completely biodegraded in the natural environment, and perfectly considers the requirements of biological safety protection and green environmental protection.

The invention belongs to the technical field of plastic processing, and particularly relates to a hydrophobic solvent-resistant biodegradable polyester material as well as a preparation method and application thereof in plastic bottles. The preparation method of the hydrophobic solvent-resistant biodegradable polyester material comprises the following steps: reacting polyol glycidyl ether with acrylic acid to prepare polyol glycidyl ether acrylate; the preparation method comprises the following steps: reacting isophthalic dihydrazide with polyol glycidyl ether acrylate to prepare a modifier; pBAT reacts with a modifier and an acrylic acid fluorine monomer to obtain the hydrophobic solvent-resistant biodegradable polyester material. The hydrophobic solvent-resistant biodegradable polyester material adopts PBAT as matrix resin, has biodegradability, has good hydrophobicity and solvent resistance through modification treatment of the modifier and the acrylic acid fluorine monomer, and can be applied to manufacturing of plastic bottles.

The present disclosure relates to a biodegradable multilayer film comprising stacked on each other in the following order: a) a first outer layer comprising a first polymer selected from the group consisting of poly (butylene adipate-co-terephthalate) (PBAT), poly (butylene succinate) (PBS), poly (butylene succinate-co-adipate) (PBSA), and mixtures thereof; b) a core layer comprising a blend of thermoplastic starch (TPS) and polybutylene adipate terephthalate (PBAT); c) a second outer layer comprising a second polymer selected from the group consisting of poly (butylene adipate-co-terephthalate) (PBAT), poly (butylene succinate) (PBS), poly (butylene succinate-co-adipate) (PBSA), and mixtures thereof. The present disclosure also relates to a disposable bag, a bioreactor and a container suitable for mixing, packaging, storing or transporting biopharmaceutical substances, wherein the disposable bag, bioreactor and container comprise the biodegradable multilayer film.