The invention relates to a super-capacitor high-temperature electrolyte. Wherein, its solute is N-trialkyl-N-alkoxy acyl fluoroboric acid or phosphorofluoric acid or Fraude's reagent, or trifluoromethyl sulfonic acid; and the solvent is aprotic solvents; its density in room temperature is 0.8-2.0mol/l; the aprotic solvents are acetonitrile, ethyl cyanide, methacrylonitrile, gamma- butyrolactone, gamma- valerolactone, vinylene carbonate, propylene carbonate, N, N- dimethyl formamide, 1- dimethyl formamide-2- pyrrolidone, methylenedioxy ethane, 2-methoxy ether, tetrahydrofuran, dioxolane, dimethyl carbonate, diethyl carbonate, diethyl carbonate, or dimethyl sulfoxide. And the inventive capacitor has high capacity and high service life at 85Deg. C.