2246 results about "Fixed bed" patented technology

A bed sheet holder includes a bracket and sleeving members. The bracket includes a bottom plate, supporting members arranged on the bottom plate, and first sliding blocks arranged on the supporting members. A first sliding slot is defined in the sleeving member. At least one end of the first sliding slot is a first opening. The first sliding block is arranged inside the first sliding slot. When the bracket is used in conjunction with a bed sheet, the bottom plate is pressed under a mattress, the supporting member is attached to an outer side wall of the mattress, the first sliding block is exposed on an outer side of the mattress, and the sleeving member is sleeved on the first sliding block through the first sliding slot, thereby pressing one part of the bed sheet between the sleeving member and the first sliding block to fix the bed sheet.

The invention relates to a preparation method of phenylmethylamine. The technical scheme adopted by the invention for mainly solving the problems of high catalyst loss, low production efficiency and high intermittent operation labor intensity is as follows: the preparation method of the phenylmethylamine comprises the following steps: mixing the raw material of cyanobenzene with a solvent material or at least one of one part of product materials in a mixing unit, introducing the mixture into a fixed bed hydrogenation reactor to be in contact with hydrogen and a catalyst and carry out multi-phase continuous hydrogenation reaction to obtain a product material containing phenylmethylamine, separating the product material to obtain a phenylmethylamine product, wherein the catalyst is a metal loaded catalyst; and the metal is selected from at least one of Pd, Pt, Cu, Ni, Mo and Fe. The preparation method can be used for preparing phenylmethylamine.

Methods and systems for converting a renewable fuel intermediate composition to finished transportation fuel are provided herein. In some examples, a renewable fuel intermediate composition is flowed over a first catalyst in a first reaction zone to generate a saturated, hydrodeoxygenated product. A liquid portion of the renewable fuel intermediate composition may be characterized as having more than about 70 wt % of the oxygen being within ketone groups. The saturated, hydrodeoxygenated product may be flowed over a second fixed-bed catalyst in a second reaction zone to generate a product including the finished transportation fuel.

The invention relates to the technical field of biomass energy conversion, in particular to a gradient catalytic biomass tar cracking reactor and a control method thereof.The gradient catalytic biomass tar cracking reactor comprises a multilevel component characterization module, a functional group reaction activity evaluation module, a multi-scale reaction network coupling module, an oxygen content gradient regulation module, a self-adaptive product directional regulation module and the like; the system is used for finely representing tar components, improving complicated composition understanding and processing capability, calculating a functional group reaction activity index, constructing a three-level reaction network, optimizing reaction path selectivity, and generating an oxygen content gradient index and a catalyst distribution scheme, so that gradient reduction of oxygen content and oriented conversion of products in a reactor are realized; the multi-section fixed bed reactor is designed, different catalysts are filled in each reaction area, the reaction requirements are met, the system intelligently regulates and controls reaction operation parameters, the biomass tar cracking efficiency and the product directionality are remarkably improved, and innovation and breakthrough are brought to the technical field of biomass energy conversion.

The invention discloses a method and a system for designing a fluid flow channel of a calcium-based thermochemical heat storage fixed bed reactor based on topological optimization and a storage medium. The method comprises the following steps: S1, constructing a geometric model of a design domain of the reactor; s2, constructing an objective function and establishing a two-dimensional topological optimization mathematical model based on a control equation of conjugate heat transfer and fluid flow; s3, solving the mathematical model to obtain an optimal fluid flow channel two-dimensional topological structure; s4, performing geometric reconstruction on the two-dimensional topological structure obtained in the step S3, converting the two-dimensional topological structure into a Bezier curve, and integrating the Bezier curve into a geometric model corresponding to the original design domain; s5, establishing a finite element model of the reactor; s6, temperature field and pressure field distribution is calculated based on CFD simulation, whether the heat storage performance target is met or not is judged, and if not, corresponding control parameters are adjusted to return to the step S3 until the heat storage performance target is met; the device can optimize the heat transfer and mass transfer performance of the reactor at the same time, and the optimization design efficiency is high.

The invention discloses a method for joint production of cyclohexylamine and dicyclohexylamine, which comprises the following steps: 1) feeding aniline tail gas of a nitrobenzene catalytic hydrogenation production device into a gas-liquid separator for gas-liquid separation to obtain aniline tail hydrogen and aniline condensate; 2) mixing aniline tail hydrogen and new hydrogen as a raw material A, and mixing defective aniline and fresh aniline in proportion as a raw material B; (3) feeding the vaporized raw material B and the vaporized raw material A into a fixed bed reactor according to a certain hydrogen-oil ratio, and carrying out hydrogenation reaction; a hydrogenation reaction product is subjected to heat exchange condensation and then enters a gas-liquid separator for gas-liquid separation, a gas phase serves as recycle hydrogen to be mixed with the raw material A, and a liquid phase is fed into a distillation device; and 4) carrying out primary distillation and rectification purification in sequence to obtain cyclohexylamine and dicyclohexylamine. According to the method, aniline tail gas resources and defective aniline are fully utilized, the three-waste treatment cost is reduced, product benefits can be improved, pollution to the environment can be reduced, and economic benefits and social benefits are remarkable.

The invention discloses a synthesis method of bromo-triazine, which belongs to the technical field of organic synthesis, and comprises the following steps: preparing an alumina-loaded N, N-dimethylaminopyridine catalyst, filling the alumina-loaded N, N-dimethylaminopyridine catalyst in a fixed bed reactor, introducing tribromophenol and metal oxide mixed slurry and cyanuric chloride slurry, carrying out a reaction for 2-4 hours, and carrying out a reaction for 2-4 hours to obtain the bromo-triazine. Raising the temperature for reaction to obtain a crude product solution; and performing post-treatment to obtain a bromo-triazine product. According to the invention, the aluminum oxide loaded N, N-dimethylaminopyridine catalyst is synthesized, and the N, N-dimethylaminopyridine enables the reaction speed to be higher and the yield to be higher; nano aluminum oxide is adopted for loading, so that on one hand, dealkalization synthesis of bromotriazine is realized, and on the other hand, the reaction efficiency is accelerated; the continuous process realizes non-aqueous medium and low-temperature short-time reaction, so that hydrolysis is further avoided; the aluminum oxide loaded N, N-dimethylaminopyridine catalyst is high in activity and stability, the synthesis method is simplified, and the aluminum oxide loaded N, N-dimethylaminopyridine catalyst is suitable for industrial large-scale production.

The application provides a method for grading diesel deep hydrodesulfurization catalysts, which comprises the following steps: loading catalysts containing AlPO4-5 phosphorus aluminum molecular sieves and catalysts containing ETS-10 titanium silicon molecular sieves in the upper and lower parts of a fixed bed hydrogenation reactor respectively according to a loading mass ratio of 1:3-3:1, so that diesel is subjected to hydrodesulfurization reaction through catalysts containing AlPO4-5 phosphorus aluminum molecular sieves first and then through catalysts containing ETS-10 titanium silicon molecular sieves; the carrier of the catalysts containing AlPO4-5 phosphorus aluminum molecular sieves comprises AlPO4-5 phosphorus aluminum molecular sieves and aluminum oxide powder, the carrier of the catalysts containing ETS-10 titanium silicon molecular sieves comprises ETS-10 titanium silicon molecular sieves and aluminum oxide powder, and the active components of the two kinds of catalysts respectively comprise a combination of two or three of nickel oxide, molybdenum oxide and cobalt oxide. The sulfur content of the hydrogenated diesel obtained through the method can be as low as 10 μg / g or below.

The invention provides a system and method for improving the ability of activated carbon to adsorb medium and low temperature VOCs waste gas, and the system comprises: a heat exchanger for introducing steam heat of the medium and low temperature VOCs waste gas to perform waste heat recovery to generate high temperature circulating water; the refrigerating system is used for receiving the high-temperature circulating water through a pipeline and recovering heat of the high-temperature circulating water to enable the refrigerating system to generate a refrigerant, and the refrigerant enters the heat exchanger to exchange heat with the medium-low-temperature VOCs waste gas; the activated carbon fixed bed adsorption device is used for receiving the medium and low temperature VOCs waste gas after heat exchange and adsorbing organic gas in the waste gas; the steam thermal desorption device is used for introducing steam into the activated carbon fixed bed adsorption device for desorption after the activated carbon fixed bed adsorption device is saturated in adsorption, and the steam takes away the organic gas adsorbed by the activated carbon fixed bed adsorption device and enters a downstream phase change heat exchanger; and the phase change heat exchanger is used for recycling steam heat after analysis by using circulating water to generate high-temperature circulating water, and after heat is recycled, waste gas is condensed, so that organic gas is dissolved in water to form an organic solvent to be recycled.

The invention discloses a method for preparing 12-mercaptan through solid organic acid catalysis, belongs to the technical field of 12-mercaptan preparation, and aims to solve the problems of low catalyst activity, harsh reaction conditions, serious pollution, high cost and dependence on import in the prior art. N-dodecanol and hydrogen sulfide are used as raw materials and are mixed according to the molar ratio of 1: 1.2-1: 1.3; the method comprises the following steps: gasifying n-dodecanol, mixing with purified hydrogen sulfide, preheating to 210-240 DEG C, introducing into a fixed bed reactor filled with a solid organic acid catalyst, and reacting at-0.08-3.0 MPa for 3.5-4 hours; and cooling and condensing the reaction product, carrying out gas-liquid separation, rectifying and purifying the liquid product to obtain 12-mercaptan with the purity of more than or equal to 99.5%, and recycling unreacted hydrogen sulfide. The solid organic acid can be a catalyst of p-toluenesulfonic acid and the like or mesoporous silica loaded nickel, cobalt and molybdenum metal oxides. The method has the advantages of high catalytic activity, mild reaction conditions, high product yield (the conversion rate of n-dodecanol is greater than or equal to 94.5%), environmental protection and low cost, can realize the domestic mass production of 12-mercaptan, and meets the market demand.

The present invention refers to a SiC and Chlorosilane production system 2540, comprising at least one CVD SiC production reactor 850, in particular SiC fluidized bed reactor 850a, in particular according to claim 9, and a Chlorosilane production unit 2550, wherein the Chlorosilane production unit 2550 comprises at least a bed reactor 2416, in particular a fixed bed reactor or a fluidized bed reactor, for generating Chlorosilanes by reacting at least one fraction of the vent gas mixture provided via the vent gas outlet 216 of the CVD SiC production reactor 850 and Si, wherein further fractions of the vent gas mixture at least comprise H2 and a C-bearing molecule, in particular methane, and wherein Si is provided as solid 2398 inside the bed reactor 2416.

The invention provides a fixed bed reactor for preparing aromatic hydrocarbon through hydrogenation of carbon dioxide. The fixed bed reactor comprises a reaction cavity and a temperature control system, the reaction cavity comprises a rapid reaction section and a slow reaction section which are sequentially arranged in the material flow direction; the rapid reaction section is provided with a first heat exchange assembly, and the slow reaction section is provided with a second heat exchange assembly; the temperature control system comprises a first temperature adjusting unit and a second temperature adjusting unit, the first temperature adjusting unit is connected with the first heat exchange assembly, the second temperature adjusting unit is connected with the second heat exchange assembly, and the first temperature adjusting unit and the second temperature adjusting unit are independently connected with the central processing unit. The reactor provided by the invention adopts a multi-section design and global temperature linkage control, is suitable for a strong heat release rapid reaction process, and can effectively inhibit hot spots and improve aromatic hydrocarbon selectivity and catalyst stability.

The invention belongs to the technical field of alkane processing, and particularly relates to a process for preparing isopentene by dehydrogenation of isopentane, a catalyst and a tert-amyl alcohol preparation process. The process for preparing isopentene by dehydrogenation of isopentane comprises an isopentane dehydrogenation device and an isopentene separation device, in the isopentane dehydrogenation device, a dehydrogenation reactor is a fixed bed adiabatic reactor and is filled with a Pt-Sn-K / alumina type alkane dehydrogenation catalyst, the catalyst has hydromethanation performance under the CO2-containing dehydrogenation reaction condition, and the arrangement and operation of a dehydrogenation reactor group comprise a mode A, a mode B or a mode C; the isopentene separation device comprises a cooling separation system, a pressure swing adsorption separation system and an optional rectification system. The tert-amyl alcohol is further prepared from isoamylene under the conditions of a fixed bed hydration reactor, ethylene glycol monobutyl ether and other solvents, and the tert-amyl alcohol product is obtained through separation. The process is superior to the prior art on the whole, and has certain application prospects.

The invention relates to the technical field of chemical production, in particular to a method for efficiently synthesizing epichlorohydrin. The method provided by the invention comprises the following steps: adding a mixed solution of chloropropene and methanol and part of hydrogen peroxide into a reactor; then injecting residual hydrogen peroxide through a middle-section feeding hole of the reactor; constant-temperature circulating water is adopted to control a front-section temperature control area of the reactor to be at a first temperature, a middle-section temperature control area of the reactor to be at a second temperature and a rear-section temperature control area of the reactor to be at a third temperature, and the third temperature, the first temperature and the second temperature are gradually increased in sequence. The method provided by the invention can effectively solve the problems of side reaction increase, too fast catalyst deactivation and the like caused by local overheating of the fixed bed reactor, and significantly improves product selectivity and production efficiency.

This invention relates to a method for using a low-content ruthenium-based catalyst modified with nitrogen and oxygen ligands in the hydrochlorination of acetylene. The invention utilizes 2-pyridine carboxylate as a ligand, commercial activated carbon as a support, trace amounts of ruthenium as the main active component, and water as a solvent. An improved synthesis procedure yields a low-content ruthenium-based catalyst with ruthenium ions coordinated by a modifier and commercial activated carbon as a support, significantly improving catalyst performance while reducing ruthenium content. This catalyst exhibits high activity and vinyl chloride selectivity in the fixed-bed hydrochlorination of acetylene to vinyl chloride, and its low cost makes it highly valuable for industrial applications. The ruthenium loading is 0.1%, and the reaction gas space velocity is 170 h⁻¹. ‑1 V (C2H2) / V (HCl) With a ratio of 1:1.05 and a reaction temperature of 180℃, the acetylene conversion rate can reach 84.3%, the vinyl chloride selectivity is greater than 99%, and the activity remains basically unchanged within 10 hours.

The invention provides a BVPE preparation method based on solid acid catalysis and continuous flow reaction, and relates to the technical field of disubstituted ethane preparation, and the method comprises the following steps: mixing a compound 1, a polymerization inhibitor, a solid acid catalyst and a solvent to form a reaction liquid; enabling the reaction liquid to pass through a fixed bed continuous flow reactor, and reacting at 20-180 DEG C for 1-45 minutes to obtain a compound 2; post-treating, separating and purifying a product; wherein the solid acid catalyst is an HZSM-5 type molecular sieve or acidic resin, the product purity and yield are high, the HZSM-5 type molecular sieve or acidic resin is adopted as the solid acid catalyst, residual pollution of traditional protonic acid (such as p-toluenesulfonic acid) is avoided, in embodiments 1-3, the product GC purity reaches 98.6%-99.1%, the yield reaches 88.8%-93.8%, and the product GC purity and the yield are remarkably higher than those of a contrast (the purity is 96.1%, and the yield is 74.2%).

The utility model relates to the field of chemical equipment, in particular to a tubular fixed bed reactor which comprises an upper end cover, a lower end cover, a shell pass cylinder, an upper tube plate, a lower tube plate and a plurality of reaction tubes, a tube pass inlet is formed in the upper end cover, a tube pass outlet is formed in the lower end cover, and a shell pass inlet and a shell pass outlet are formed in the shell pass cylinder; the gas distribution assembly is arranged inside the upper end cover; the lower distribution cylinder is positioned in the shell pass cylinder and surrounds the periphery of at least part of the reaction tubes; and a plurality of overflowing through holes are uniformly distributed in the side peripheral wall of the lower distribution cylinder. The gas distribution assembly is arranged, so that the catalyst in each reaction tube can be utilized more uniformly; by arranging the lower distribution cylinder, the shell pass medium at the shell pass inlet can be uniformly distributed, and the situation that part of reaction heat in the reaction tube cannot be taken away in time is avoided. The gas distribution assembly and the lower distribution cylinder are arranged in a combined manner, so that the tubular fixed bed reactor is good in reaction stability and high in product yield.

Methods and systems for mixing dissimilar hydrocarbon feedstock materials to form hydrocarbon feedstock blends for subsequent processing. The dissimilar hydrocarbon feedstock materials can differ by chemical composition, polarity, solubility, and / or physical state and include one or more of biomass-derived materials, non-petroleum-derived oils or fats, polymers, fabrics or textiles, paper or cardboard, rubber, waste products, pyrolysis products of the foregoing, or petroleum-derived materials. Efficient and thorough mixing of the dissimilar hydrocarbon feedstock materials is performed by static inline mixing to form an intermediate blend, which is further mixed by high shear mixing to form the hydrocarbon feedstock blend. The methods and systems may involve other processing equipment e.g., strainers, filters, pumps, furnaces, heat exchangers, reactors, separators, tanks, and / or distillation columns. The hydrocarbon feedstock blend may be further processed by hydrocracking or hydroconversion e.g., by ebullated bed, fixed bed, or slurry bed reactor), solvent deasphalting, coking, fluid catalytic cracking, hydroprocessing, or hydrotreating.

The invention discloses a biomass gasification product prediction method based on mechanism and data fusion driving, and the method comprises the steps: constructing a biomass gasification product prediction mechanism model, and inputting biomass gasification operation parameters into the model to obtain a prediction result; calculating a residual vector between a prediction result and actual experimental data; establishing a support vector regression model between the biomass gasification operation parameters and the residual vectors; and taking the output of the support vector regression model as an error compensation item of a biomass gasification product prediction mechanism model, constructing a biomass gasification product prediction model based on mechanism and data fusion driving, and predicting a biomass gasification product by using the model. Through fusion of a mechanism model and data driving, the problem of prediction deviation caused by model simplification hypothesis in a traditional method is solved, high-precision prediction of biomass gasification products is achieved, a theoretical basis is provided for real-time optimization of process parameters, and the method is suitable for industrial control of biomass gasification systems such as fluidized beds and fixed beds.

The invention relates to a reaction process model construction method and a reaction safety prediction method. The method comprises the following steps: acquiring catalyst particle parameters and reactor reaction section parameters in the current reaction process; simulating the filling process of the catalyst particles in the fixed bed reactor based on the catalyst particle parameters and the reactor reaction section parameters to obtain a catalyst particle accumulation model; constructing a reaction process model of the current reaction process according to the particle position of the catalyst particle accumulation model; the reaction process model comprises a multiphase flow field model and a chemical reaction model which are coupled with each other. By adopting the method, the comprehensiveness and accuracy of a prediction result can be improved.

The invention relates to a heterogeneous catalysis technology, and aims to provide a method for improving the yield of components of aviation kerosene prepared by ethylene oligomerization through combination of a fixed bed and a slurry bed. Comprising a fixed bed reactor and a slurry bed reactor which are sequentially connected in series, the fixed bed reactor is filled with a metal modified mesoporous zeolite molecular sieve catalyst, and the slurry bed reactor is filled with a mesoporous zeolite molecular sieve catalyst. The method comprises the following steps: firstly, carrying out ethylene oligomerization reaction in a fixed bed reactor to generate a product containing C4-C8 olefin; the reaction product is directly introduced into the fixed bed reactors connected in series for secondary reaction, and the final product comprises C5-C16 + liquid phase olefin as an aviation fuel component. By adopting a fixed bed-slurry bed reactor combined method, the ethylene conversion rate can be greatly improved; secondary oligomerization is carried out by using an acidic mesoporous zeolite molecular sieve catalyst, so that the selectivity of aviation kerosene components is improved; the mesoporous catalyst prepared by an alkali treatment method has a good diffusion effect and keeps high activity for a long time.

The invention belongs to the technical field of industrial waste heat resource utilization, and provides a hydrogen-fused salt energy storage coupled industrial waste heat recovery hydrogen production system and method, a fused salt energy storage subsystem comprises an energy storage module and a waste heat heat exchange module which are connected with each other, and a thermochemical circulation subsystem adopts a reactor; the reactor adopts a horizontal fixed bed reactor, and CaO-Ca (OH) 2 particles are filled in the reactor; a heat absorption stage: the high-temperature molten salt flows through a reactor jacket, a bed layer is heated to a first preset temperature, Ca (OH) 2 is subjected to a decomposition reaction, and nitrogen is introduced in the reaction process; a heat release stage: introducing water vapor into the reactor, carrying out hydration reaction on the water vapor and CaO, heating the fused salt to a second preset temperature by virtue of reaction heat release, and providing a heat source for the electrolytic hydrogen production subsystem; through coupling of a fused salt energy storage system and CaO-Ca (OH) 2 thermochemical circulation, efficient recovery and utilization of low-grade waste heat at the temperature of 300-500 DEG C are achieved, an electrolytic bath is driven to produce hydrogen at low cost, the heat efficiency of the system is improved to 75% or above, and green hydrogen self-supply in the high-energy-consumption industry is promoted.

The present invention relates to a method for continuously preparing 5-amino-1-pentanol, 1-amino-2-pentanol, and 1,5-pentanediamine using furfural as a raw material. The method comprises the following steps: After hydrogen and the raw material liquid are preheated to 20-150 °C in a preheater, they are simultaneously introduced into a fixed-bed reactor equipped with two sections of catalysts, and reacted at 30-150 °C and a reaction pressure of 0.1-8 MPa to obtain 5-amino-1-pentanol, 1-amino-2-pentanol, and 1,5-pentanediamine; the first catalyst is a metal catalyst supported on graphitic carbon nitride; the active metal of the second catalyst is one, two, or more of Ru, Pt, Rh, Cu, Co, and Ni; the carrier of the second catalyst is γ-Al2O3, TiO2, SiO2, ZrO2, CeO2, ZSM-5, cerium-zirconium solid solution, or activated carbon. The present invention solves the problem of poor selectivity in the process of generating 1,5-pentanediamine, and the product distribution can be changed by changing the catalyst.

The invention discloses a reminding device for facial state recognition and a using method thereof, and belongs to the technical field of image acquisition assistance. The device comprises an arc-shaped support, movable frames used for adjusting the distance are arranged on the inner sides of the two ends of the arc-shaped support, and clamping frames used for fixing a bed frame are arranged on the outer sides of the movable frames. The moving frame is rotationally connected with the arc-shaped support, a picture collector and a state analysis assembly are arranged on the outer side of the moving frame, an electric connecting device is arranged at the top of the moving frame, and the picture collector is connected with a lens; an adjusting gear matched with a gear groove in the arc-shaped support is arranged in the picture collector, and the adjusting gear is driven by an adjusting motor to drive the moving frame to rotate along the arc-shaped support. The rotary screw rod can be driven to rotate by rotating the rotary knob, finally, the clamping plate can be controlled to move to clamp and fix the bed frame, and flexible adjustment and fixation are facilitated to adapt to different requirements.

The application discloses a kind of synchronous denitrification and phosphorus removal light materials and its preparation and application method, belong to environmental functional materials and sewage treatment technical field.The application is obtained by fully melting and dispersing sulfur and iron-based component, and the iron-based component is a mixture of pyrite and calcium-magnesium carbonate.The molten mixture is foamed to form a synchronous denitrification and phosphorus removal light material.The synchronous denitrification and phosphorus removal light material has high porosity, large specific surface area, light weight and high reactivity.The light material is used as a microbial carrier and an electron donor for biochemical reactions, and is applied to fixed bed, fluidized bed and other reactors for sewage treatment.The light material has good microbial adhesion performance, high denitrification rate and good phosphorus removal effect.

The present invention belongs to the field of adsorption, and discloses a multi-way valve capable of connecting multiple adsorption columns and controlling material switching and its continuous adsorption device. The device mainly consists of an adsorption column, a six-way valve and a feed multi-way valve. By combining multiple adsorption columns with one feed multi-way valve, or combining multiple adsorption columns with multiple six-way valves and two feed multi-way valves, continuous adsorption under different functions is achieved. The number of adsorption columns can be increased or decreased according to specific requirements. Compared with the traditional fixed-bed adsorption system, the number of valves is small and the logic control is simple; compared with the continuous moving-bed adsorption system, the device replaces the rotation of the adsorption column by rotating control of the multi-way valve, simplifies the structure and reduces the operating energy consumption. The device can realize the simultaneous washing and elution, and can also realize the intermittent operation of washing and elution by the combined control of the feed multi-way valve and the six-way valve, thereby reducing the number of adsorption columns and the use of adsorption materials, and finally reducing the system cost.

The invention discloses a U-shaped wall tubular reactor and an application method thereof. The reactor comprises a shell, the top of the shell is provided with a synthesis gas inlet, the bottom of the shell is provided with a synthesis gas outlet, the shell is internally provided with a gas distributor, a central gas collection cylinder and a water-cooling bundling pipe, and the outer side of the shell is provided with an upper annular cavity and a lower annular cavity; the gas distributor is arranged in the synthesis gas inlet, the central gas collection cylinder is arranged at the central part of the shell, and the water-cooling bundling pipe is arranged on the outer side of the central gas collection cylinder and consists of a plurality of U-shaped heat exchange pipes; the upper ends of all the U-shaped heat exchange tubes penetrate through the upper tube plate to be communicated with the upper annular cavity, the lower ends of all the U-shaped heat exchange tubes penetrate through the lower tube plate to be communicated with the lower annular cavity, and the upper tube plate and the lower tube plate are both arranged on the side wall of the shell. The welding seam of the heat exchange tube is not in contact with process gas, so that the corrosion problem is thoroughly solved; no internal part structure is arranged in the shell, so that the uniform distribution of reaction gas in a catalyst bed layer is improved, and the ammonia synthesis efficiency is improved. The reactor can be used for fixed bed ammonia synthesis reaction or water gas shift reaction.

The invention discloses a catalytic method for converting alpha-olefin in an alkane-olefin mixture into internal olefin and application, raw materials and a solid acid catalyst are carried out in a fixed bed or a reaction kettle, the reaction temperature is 50-150 DEG C, the reaction pressure is 15-400 psi, and the reaction environment is an inert gas atmosphere; when the reaction is carried out on the fixed bed, the mass space velocity of the solid acid catalyst is 1h <-1 >-20h <-1 >; when the reaction is carried out in the reaction kettle, the conversion frequency of the raw materials is 5000 mol substrate mol acid site density <-1 > h <-1 > to 50000 mol substrate mol acid site density <-1 > h <-1 >; wherein the raw material is an alkane-alkene mixture; the solid acid catalyst comprises an active component and a carrier, wherein the carrier contains at least one inorganic oxide; the active component has a structure as shown in a formula (1) and / or a formula (2), in the formula (1) and the formula (2), R is alkyl or phenyl, and n is greater than or equal to 1. According to the catalysis method provided by the invention, the conversion rate of alpha-olefin can be increased, and the proportion of skeleton isomerization products and oligomers in internal olefin products can be reduced.

The invention discloses a method for preparing 1, 3-butadiene, and the method comprises the following steps: enabling a raw material containing gamma-valerolactone to be in contact and react with a catalyst to obtain the 1, 3-butadiene, the catalyst is a hydrogen type molecular sieve with a ten-membered ring topological structure, and the typical topological structure types of the catalyst comprise FER, TON, MTT, EUO, * MRE, MEL and MWW. In a fixed bed reactor, gamma-valerolactone is taken as a raw material and passes through the reactor from top to bottom. The target product 1, 3-butadiene can be efficiently prepared under the condition of 300-450 DEG C by using the catalyst.

The application belongs to the technical field of photo-thermal catalysts, and particularly relates to a molecular sieve photo-thermal catalyst for methane oxidation to prepare methanol and a preparation method thereof, the catalyst has a structural formula of Cu / M-ZSM-5, and the preparation method comprises the following steps: S1: uniformly mixing a silicon source, an aluminum source, a metal source, a template agent and water to form a starting gel; S2: performing hydrothermal crystallization, centrifugal separation, washing until neutral, and drying to obtain a molecular sieve raw powder; S3: performing calcination to obtain M-ZSM-5 molecular sieve; and S4: under ultrasonic wave conditions, ion exchanging M-ZSM-5 with a copper salt solution, and performing rotary evaporation and drying to obtain the Cu / M-ZSM-5 photo-thermal catalyst. The catalyst is filled into a fixed bed reactor, helium is introduced, the temperature is raised to an activation temperature, the catalyst is activated, and a mixed gas of methane, oxygen and water is introduced; when the doped metal is Zn, the methanol yield of the Cu / Zn-ZSM-5 photo-thermal catalytic methane is 100.05 micromoles g cat ‑1 h ‑1 , which is increased by 91% compared to the methanol yield of Cu / ZSM-5. The catalyst exhibits excellent catalytic performance and stability in the reaction of preparing methanol by photo-thermal catalysis of methane.