215 results about "Aromatization" patented technology

To provide a compound useful as a material for an organic device such as an organic electroluminescent element.SOLUTION: Polycyclic aromatic compounds having a structure consisting of one or two or more structural unit (s) represented by the formula (1); (Ra1 to Ra3, Rb1 to Rb4, Rc1 to Rc4 are independently H or substituents; provided that at least one of Rc1 to Rc4 is a group represented by the formula (1-1); Y1 is B; and are independently> N-RNX; RNX is substituted / unsubstituted aryl; at least one of the aryl ring and the heteroaryl ring in the above structure may be fused with at least one cycloalkane, and H in the above structure may be replaced by D. X1 X2. ) SELECTED DRAWING: None

The invention is directed to a process for the preparation of an aromatic acid or a phenolic compound, said process comprising reacting a dienophile and a furanic compound comprising an acetal moiety in a Diels-Alders reaction to obtain an aromatic compound comprising said acetal moiety, followed by hydrolysis and oxidation of said acetal moiety into a hydroxide or carboxylate moiety to form the aromatic acid or phenolic compound, wherein said dienophile is selected from the group consisting of alkylenes, acetylenes, acrylates, maleates, fumarates, maleimides, propiolates, acetylene dicarboxylates, and benzynes and wherein said acetal moiety is bound directly to the 2-position of the furanic compound.

This application proposes methods for synthesizing aromatic compounds using ionizing radiation based on N₂O, and methods for synthesizing aromatic compounds using industrial waste gas. The method includes: placing benzene and a combined gas containing N₂O in a sealed container, and adjusting the volume of the combined gas to bring the benzene in the sealed container to its saturated vapor pressure; irradiating the sealed container with radiation to cause the benzene to react and yield the aromatic compounds, wherein the radiation includes X-rays, gamma rays, or electron beams, the energy range of which is 0.0110 MeV, and the absorbed dose rate is 0.1 Gy / min to 1000 kGy / min. This method can synthesize aromatic compounds such as phenol in one step using ionizing radiation based on N₂O without the use of a catalyst, achieving precise and high-value utilization of N₂O.

This invention discloses a yam oxylipoic acid compound with aromatase inhibitory activity, its application, and analytical identification methods, belonging to the field of medicinal chemistry. The yam oxylipoic acid compound is (Z)-9-ethoxy-6,10-dihydroxyoctadec-7-enoic acid, a novel compound. This compound can significantly inhibit aromatase activity and possesses the ability to inhibit excessive estrogen production, thus showing promising application prospects and value in diseases related to estrogen imbalance regulation.

A fluidized bed device for coupling naphtha and methanol to prepare aromatics and co-produce olefins and its application method are provided. By using the device, under the action of a catalyst, naphtha reacts with methanol to generate product gas containing aromatics and light olefins as main components. The method can efficiently and selectively convert linear and branched aliphatic hydrocarbons into aromatics, while also increasing p-xylene production through aromatic methylation reactions, with the p-xylene content in the xylene mixture exceeding 75 wt %. The fluidized bed reactor achieves increased p-xylene production by controlling the progression of cascade reactions (naphtha→benzene / toluene→p-xylene). Additionally, it utilizes the methylation reaction of benzene / toluene with methanol to provide in-situ heat for the coupled naphtha-methanol aromatization process, thereby achieving autothermal balance.

This invention relates to a method for ultra-high sensitivity and specific naked-eye detection of trace aromatic compounds. The method utilizes the long afterglow induced by the specific interaction between the analyte and a matrix as the output signal to achieve naked-eye detection of the analyte. The aromatic compounds are aromatic pollutants and aromatic organic metabolites. This invention utilizes the organic long afterglow induced by mixing the analyte G with the host molecule H through methods such as heating and melting, solvent evaporation and crystallization, matrix adsorption, and paper chromatography as a monitoring signal to achieve ultra-high sensitivity and specific naked-eye detection of trace aromatic compounds. The afterglow induced by the analyte G is highly dependent on the type and content of the analyte and matrix, which gives this detection method extremely high sensitivity and selectivity. The method is simple to operate, rapid, visible to the naked eye, requires inexpensive and readily available materials, and provides stable results.

The present invention relates to oct-5-en-2-yl acetate, to the use thereof as an aroma chemical, to the use thereof to impart an aroma to a composition, and to a method for imparting an aroma to a composition. The present invention further relates to a mixture comprising oct-5-en-2-yl acetate and 2-octyl acetate, to the use of said mixture as an aroma chemical, to the use of said mixture to impart an aroma to a composition, and to a method for imparting an aroma to a composition. The present invention is also directed to the use of oct-5-en-2-yl acetate for boosting or modifying the aroma of 2-octyl acetate. The present invention is further directed to a composition comprising oct-5-en-2-yl acetate or the mixture of oct-5-en-2-yl acetate and 2-octyl acetate.

The invention discloses a method for preparing industrial hexane with ultralow benzene content through pre-hydrogenation. The method comprises the following steps: light naphtha, hydrogen and a hydrogenation catalyst are subjected to a hydrogenation reaction in a hydrogenation reactor for desulfurization and dearomatization, and a first mixture is obtained; feeding the first mixture into a gas-liquid separator to respectively obtain a liquid-phase product and a hydrogen-containing gas-phase product, and separating hydrogen from the gas-phase product through a circulating hydrogen compressor for recycling; and sequentially carrying out second rectification and third rectification on the liquid-phase product to obtain a heavy component substance, and adsorbing the heavy component substance through a molecular sieve. According to the method, by means of front hydrogenation reaction and rear molecular sieve adsorption, on one hand, the reaction load of molecular sieve adsorption is greatly reduced while the reaction activity of the hydrogenation reaction is improved; on the other hand, an extracting agent does not need to be added, other gas-phase and liquid-phase components are not introduced except hydrogen, the preparation process is greatly simplified, and the benzene content in the obtained cyclohexane is smaller than 5 ppm.

The present application relates to a kind of from androsta 1, 4-diene-3, 17-dione starting synthesis of estren and the method of a kind of compound thereof.Especially, the present application provides a kind of preparation method of estren shown in formula I, comprising the following steps: in inert solvent, androsta-1, 4-diene-3, 17-dione (II) with reagent R4VX carries out demethylation aromatization reaction step directly to obtain estren (I);Wherein, the definition of reaction substrate, reagent and reaction condition is as claimed in claim or specification.The method is simple in operation, and good in selectivity, and product purity is high, suitable for industrial production.

The application discloses a kind of surface chemical reconfiguration's sodium ion battery hard carbon negative electrode material and preparation method thereof.The method comprises the following steps: constructing organic precursor layer on the surface of carbon source matrix;Using acid dehydrating agent to induce the dehydration, crosslinking or aromatization reaction of precursor layer at 0-300 DEG C, to form stable surface solidification layer;Finally, high-temperature carbonization is obtained hard carbon material.The application utilizes acid-assisted solidification technology, significantly reduces the content of active oxygen-containing functional groups on the surface of hard carbon (XPS shows <5.0%), while maintaining the internal microporous sodium storage capacity, significantly improves the interface stability and the first coulomb efficiency of the material (can reach more than 95%).The process is simple, low in cost, and suitable for large-scale industrial production.

The invention relates to a biomass low-temperature carbonization accelerant as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out water washing pretreatment on powder obtained by crushing a biomass raw material, and then carbonizing in an inert atmosphere to obtain biomass carbon powder; acidizing the biomass carbon powder to obtain carbon-based solid acid; the carbon-based solid acid and a transition metal salt auxiliary agent are mixed and ground, and the biomass low-temperature carbonization accelerant is prepared. The biomass low-temperature carbonization accelerant is a composite catalyst composed of carbon-based solid acid and transition metal salt; wherein the carbon-based solid acid is used as a main catalytic substrate, provides abundant Bronsted acid loci-SO3H, and is mainly used for catalyzing the dehydration reaction of biomass; transition metal ions are used as Lewis acid sites and generate a synergistic effect with the carbon-based solid acid to jointly catalyze depolymerization, dehydrogenation and aromatization reactions, so that deep carbonization can be initiated and completed at a relatively low temperature of 250-400 DEG C, and the carbonization rate is remarkably higher than that of an existing carbonization catalyst.

This invention discloses a compound, octanoic acid 4-methyl-5-thiazole ethyl mercaptan ester, with the specific chemical structure shown below: The aromatic compound is mainly used in food flavorings.

The invention discloses a method for constructing a highly conjugated aromatic ring system from bio-based (Z)-3-hexene-2, 5-diketone, and the method comprises the following steps: preparing a 1, 3-dinitroalkane aromatic compound with high yield from a bio-based aldehyde substance in nitromethane through a nickel-based catalyst, and then carrying out ring opening on the 1, 3-dinitroalkane aromatic compound and electro-catalytic 2, 5-dimethylfuran to prepare the highly conjugated aromatic ring system from the bio-based (Z)-3-hexene-2, 5-diketone and the bio-based (Z)-3-hexene-2, 5-diketone. The high-conjugation biaromatic ring system is constructed through the reaction of 1, 5-diketone; the preparation method has the advantages that the yield is high, the greenization degree is high, and the obtained highly conjugated biaromatic ring system has high bio-based content (gt; 86%), and has a high application value.

The Invention relates to a method Method for making a ruthenium catalyst comprising the steps of - Providing an aromatic dithiol substituted on adjacent aromatic carbon atoms with thiol groups, wherein in a first step an aromatic compound substituted with two leaving groups on adjacent aromatic carbon atoms are reacted with alkali trithiocarbonate to obtain an aromatic benzodithiole-thione, which in a subsequent step is reacted / hydrolysed with a base; - providing a zinc dithiolate compound by reacting the aromatic dithiol with a zinc carboxylate in an organic solvent; Reacting the zinc dithiolate compound with a ruthenium compound wherein X1 and X2 are, independently of each other, are anionic ligands and are the same or different; L and L2 are, independently of each other, neutral electron donor ligands and are the same or different; Ar is an aromatic group which may be substituted and that can be bridged with L, if L is an alkoxy group; - Obtaining a ruthenium catalyst of formula 4 or 4a, wherein R1 to R4 are, independently of each other, are selected from hydrogen, halogen, alkyl, aryl, or R.1 with R3, R3 with R4 or R2 with R4 are forming together an aliphatic or aromatic ring.

The invention belongs to the technical field of preparation of organic chemicals, and particularly relates to 2-methyl-5-trifluoromethyl furan and a preparation method thereof. The preparation method comprises the following steps: adding a solvent into trifluoroacetone, adding alkali under an ice bath condition, adding 1-chloro-2-methyl ethylene oxide, reacting at room temperature, adding acid, reacting at 40-60 DEG C to complete a dehydration reaction, then adding alkali for aromatization, continuing to complete an aromatization reaction, adding water to extract a reaction system, taking an organic phase, filtering, washing and drying to obtain the 1-chloro-2-methyl ethylene oxide. And rectifying to obtain the 2-methyl-5-trifluoromethyl furan. According to the 2-methyl-5-trifluoromethyl furan and the preparation method thereof provided by the invention, the reaction conditions are mild, the steps are simple, and the prepared 2-methyl-5-trifluoromethyl furan is high in yield and suitable for industrial production.

A method for processing a hydrocarbon-containing mixture includes the steps of: I) separating the hydrocarbon-containing mixture into a light fraction and a heavy fraction; II) reacting the light fraction from step I) in an aromatization unit and separating the resulting reaction product into a C5− component and a C6+ component; III) reacting the heavy fraction from step I) and optionally the C6+ component from step II) in an aromatics conversion unit and separating the resulting reaction product into a C5− component, a C6-C7 component, a C8 component, and a C9+ component; and IV) optionally, steam cracking or catalytic cracking one or both of the C5− component from step II) and the C5− component from step III). The method can convert low-value hydrocarbon mixtures into C8 aromatic hydrocarbons and cracking raw materials, and improve the product value. A system for practicing this method is also provided.

The application relates to the field of molecular sieves, and discloses an L molecular sieve, a preparation method of the L molecular sieve, an L molecular sieve catalyst, a preparation method of the L molecular sieve catalyst and application. 2 The L molecular sieve has a multistage pore structure of micropores and mesopores, a specific surface area of 310-330 m 2 / g, a total pore volume of 0.162-0.19 mL / g, a micropore volume of 0.137-0.145 mL / g, a crystal grain diameter of 100-800 nm, and a silicon-aluminum molar ratio of 3-10:1. The L molecular sieve has a multistage pore structure of micropores and mesopores and a small crystal grain size, the preparation method is simple, and the prepared L molecular sieve catalyst is suitable for alkane aromatization reaction, and can significantly improve the aromatic hydrocarbon yield of the catalyst and the conversion rate of reactants.

The invention belongs to the field of catalytic processes. In particular, the present invention relates to a thermocatalytic cracking process for the preparation of low molecular weight monocyclic aromatic compounds. According to the present invention there is provided a thermocatalytic cracking process for preparing a low molecular weight monocyclic aromatic compound from a feed stream comprising biomass and / or one or more polymers, the process comprising the steps of: a) subjecting the feed stream comprising biomass and / or one or more polymers to a pyrolysis treatment at a pyrolysis temperature to produce a pyrolysis steam; b) optionally cooling or heating the pyrolysis steam; c) contacting the pyrolysis steam with an aromatization catalyst at an aromatization temperature in a catalytic conversion step to produce a conversion product comprising low molecular weight aromatics, and d) optionally recovering low molecular weight monocyclic aromatics from the conversion product, the catalytic conversion step c) being carried out in a stationary or bubbling fluidized bed reactor.

The invention provides a PtIn-coated S-1 hollow H-ZSM-5 composite material, application thereof and a method for preparing aromatic hydrocarbon through propane aromatization, and belongs to the field of catalysts. The invention provides a PtIn (at) S-1 hollow H-ZSM-5 composite material. The PtIn (at) S-1 hollow H-ZSM-5 composite material comprises PtIn (at) S-1 and a hollow acidic H-ZSM-5 molecular sieve, the PtIn (at) S-1 comprises an S-1 molecular sieve and a PtIn alloy loaded on the surface of the S-1 molecular sieve and in pore channels. The PtIn (at) S-1 is mainly used for preparing propylene through propane dehydrogenation, and the hollow acidic H-ZSM-5 molecular sieve is mainly used for catalyzing aromatization of propylene to generate aromatic hydrocarbon. Through the organic combination of the two components, the thermodynamic limitation of propane dehydrogenation is broken, the propane conversion rate is improved, the contact between propane and molecular sieve acid sites is reduced, and the cracking side reaction is inhibited, so that the selectivity and yield of aromatic hydrocarbon are greatly improved.

Catalysts and method of preparing the catalysts are disclosed. One of the catalysts includes a zeolite support, a Group VIII metal on the zeolite support, and at least two halides bound to the zeolite support, to the Group VIII metal, or to both, and can have an average crush strength greater than 11.25 lb based on at least two samples of pellets of the catalyst measured in accordance with ASTM D4179.

Processes for activating a high-chlorine content aromatization catalyst in a reactor system include the steps of contacting the aromatization catalyst with an inert gas stream in the reactor system at a drying temperature of 300-400° C. to form a treated catalyst, and then contacting the treated catalyst with a reducing gas stream in the reactor system to form an activated catalyst. Subsequently, a hydrocarbon feed can be contacted with the activated catalyst under reforming conditions in the reactor system to produce an aromatic product.

This invention provides a method for preparing a wood-based monolithic carbon molecular sieve and its application in nitrogen and oxygen separation. The wood-based monolithic carbon molecular sieve is obtained by primary carbonization, impregnation modification, and secondary carbonization of natural wood. The modifier includes a rigid nitrogen-containing heterocyclic aromatic compound. The process follows a simple route of "primary carbonization to construct the framework – organic molecule impregnation – secondary carbonization deposition to adjust the pore size," requiring no external binder. The carbon deposition generated by the pyrolysis of the modifier at high temperature effectively and controllably reduces the micropore size of the wood-based porous carbon, adjusting it to a size range with ideal kinetic sieving effect for nitrogen and oxygen molecules. The resulting monolithic carbon molecular sieve exhibits a significant difference in diffusion rates for oxygen and nitrogen, demonstrating high oxygen / nitrogen kinetic separation selectivity, making it suitable for efficient pressure swing adsorption (PSA) nitrogen and oxygen separation processes. It offers potential advantages such as low energy consumption, high efficiency, good material strength, and long service life for air separation for nitrogen production or oxygen enrichment.

An agent containing at least one aroma compound selected from the group consisting of E-beta-damascone, S-(2-methyl-3-furyl)ethanethioate, beta-caryophyllene oxide, beta-ionone, 2,5-dihydroxy-1,4-dithiane, methyl anthranilate, S-furfuryl thioformate, 1-isothiocyanate-3-(methylthio)propane, nootkatone, 1,4-dioxacycloheptadecane-5,17-dione, sclareol, and sclareolide is effective for masking an unpleasant smell and for making oral products in which an unpleasant smell is masked.

The invention discloses a synthesis method of an electrically promoted nickel catalyzed 2-aryl pyridine derivative, and belongs to the technical field of chemical synthesis. Aryl bromide and difluoromethyl pyridyl sulfone are used as raw materials, a complex nickel is used as a catalyst, an organic nitrogen-containing aromatic compound is used as a ligand, and the 2-aryl pyridine derivative is synthesized in an organic solvent containing an electrolyte. And carrying out electrolysis at room temperature and normal pressure, and carrying out one-step coupling reaction to prepare the 2-aryl pyridine derivative. The method has the advantages that the cheap catalyst is used, the reaction is driven by electrochemistry, and the use of a metal reducing agent is avoided; starting from aryl halide and pyridyl sulfone, the use of a metal organic reagent is avoided; the reaction does not need high temperature, and the 2-aryl pyridine compound can be obtained at room temperature.

The invention discloses a preparation method and application of an acid-base bifunctional magnesium-aluminum bimetallic oxide catalyst, and relates to the technical field of biomass catalytic conversion and heterogeneous catalytic materials.The preparation method comprises the steps that firstly, magnesium nitrate hexahydrate and aluminum nitrate nonahydrate are dissolved into a metal salt mixed solution; dropwise adding a sodium hydroxide aqueous solution into the metal salt mixed solution to obtain a turbid solution; heating and crystallizing in a water bath, transferring into a reaction kettle, and putting into a drying oven for hydrothermal crystallization. The method comprises the following steps: synthesizing a hydrotalcite-like precursor through a coprecipitation-hydrothermal coupling method, and carrying out high-temperature roasting to obtain the acid-base bifunctional composite metal oxide. The acid-base bifunctional composite metal oxide has the beneficial effects that the acid-base bifunctional composite metal oxide has a layered structure and a high specific surface area and is suitable for a biomass pyrolysis-catalytic reforming process, an alkaline site of the acid-base bifunctional composite metal oxide promotes a deoxidation reaction, an acidic site of the acid-base bifunctional composite metal oxide promotes an aromatization reaction, and the acid-base bifunctional composite metal oxide can effectively regulate and control the composition of biomass pyrolysis volatile components; the content of oxygen-containing compounds is obviously reduced, and the selectivity of monocyclic aromatic hydrocarbon is improved.

The invention discloses a method for preparing light aromatic hydrocarbon by catalytic pyrolysis of waste polypropylene plastics, which comprises the following steps: by taking a hollow ZSM-5 molecular sieve as a carrier, loading metal Ga by an ion exchange method, introducing Zr by an impregnation method to obtain a zirconium-gallium modified hollow ZSM-5 molecular sieve catalyst, and carrying out two-stage ex-situ reaction process, firstly, deeply depolymerizing the polypropylene plastics to obtain the light aromatic hydrocarbon. Macromolecular long-chain hydrocarbon is converted into micromolecular short-chain hydrocarbon, so that a more suitable reactant is provided for subsequent aromatization; then short-chain hydrocarbon is fully diffused in pore channels of the zirconium-gallium modified hollow ZSM-5 molecular sieve, and is subjected to hydrogen transfer and aromatization reaction under the synergistic effect of acidic sites of the molecular sieve. Meanwhile, the introduction of nitrogen or carbon dioxide atmosphere inhibits the generation of alkane by-products caused by hydrogen transfer to a certain extent, and further improves the selectivity of aromatic hydrocarbon.

The present invention relates to a process for the selective dehydrocyclization and aromatization of linear or branched hydrocarbons in the SAF range to aromatics in the SAF range.

This invention relates to the field of new energy and liquid carbon fuel technology, specifically to a high-cleanliness methanol alternative fuel for vehicles and its preparation method. The method includes raw material mixing and vaporization, atmospheric pressure gas-phase catalysis, and multi-stage condensation and separation steps. The method combines base methanol with hydrocarbon additives and introduces them into a composite mixed-bed molecular sieve catalyst containing aromatic cascade, etherification, and alkylation active units, as well as an anti-coking flow carrier. Its core principle is to enhance the octane number by following the atmospheric pressure gas-phase aromatization and cascade mechanism, generate ethers in situ as phase stabilizers and hydrogen bonding agents, and utilize a mesoporous carrier to reduce steric hindrance and promote macromolecular desorption. This invention differs from the high-pressure reaction conditions of traditional methanol-to-gasoline processes by overcoming the defects of methanol fuel phase separation upon contact with water and catalyst coking through a one-step atmospheric pressure gas-phase conversion. It eliminates the need for physical co-solvents and significantly extends the catalyst regeneration cycle.

To provide a platinum group metal recovery agent with a novel structure different from conventional platinum group metal recovery agents, and to provide a method for recovering platinum group metals by a mechanism different from conventional methods. [Solution] A platinum group metal recovery agent comprising a nitrogen-containing heterocyclic aromatic compound having an electron-donating group in the heterocyclic side chain. The platinum group metal recovery agent wherein the nitrogen-containing heterocyclic aromatic compound is a 6-membered ring. According to the present invention, it is possible to provide a platinum group metal recovery agent with a novel structure, and a platinum group metal recovery method that precipitates and / or adsorbs platinum group metals by a novel mechanism.

The utility model discloses a kind of aromatization production devices for improving aromatic quality, the production device is connected by external diesel pipeline, and is interlocked with diesel flow controller by heavy tower bottom temperature transmitter, realizes according to operating condition change control diesel pipe feed quantity, solves the problem of unqualified quality of heavy aromatic hydrocarbon caused by aromatization due to aromatic raw material change.