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6621results about "Hydrocarbon oils refining" patented technology

Composite molecular sieve and hydrodesulfurization catalyst prepared with composite molecular sieve as carrier

The invention provides a composite molecular sieve and a hydrodesulfurization catalyst prepared with the composite molecular sieve as a carrier. According to the composite molecular sieve and the hydrodesulfurization catalyst, the Beta-FDU-12 composite molecular sieve is of a bimodal porous structure, namely a Beta micropore and an FDU-12 mesoporous, the superficial area of the composite molecular sieve is 800-1000m<2>.g<-1>, the pore diameter is 14-25 nm, and the pore volume is 0.4-0.9 cm<3>.g<-1>.The hydrodesulfurization catalyst prepared with the Beta-FDU-12 composite molecular sieve as the carrier is outstanding in performance, the yield of FCC diesel oil can be higher than 99%, the denitrification percent can be higher than 98%, and the sulphur content is lower than 10 ppm.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Production of diesel fuel from vegetable and animal oils

A process for producing a fuel composition from vegetable and / or animal oil comprises hydrodeoxygenating and hydroisomerizing the oil in a single step. The fuel composition has acceptable lubricity and comprises a mixture of C14 to C18 paraffins having a ratio of iso to normal paraffins of 2 to 8 and less than 5 ppm sulfur.
Owner:BEN GURION UNIVERSITY OF THE NEGEV

Process for manufacturing lubricating base oil with high monocycloparaffins and low multicycloparaffins

A process for manufacturing a lubricating base oil by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an is dimerized oil; and d) hydrofinishing said isomerized oil to produce a lubricating base oil having specific desired properties.
Owner:CHEVROU USA INC

Method for gas-solid contacting in a bubbling fluidized bed reactor

The present invention relates to a method for gas-solid contacting in a bubbling fluidized bed reactor by:(a) introducing into a reactor with bed length to bed diameter ratio below about 5.0, a primary gas consisting essentially of reactant(s) of the reaction to be carried out in the bed of solid particles through a primary gas distributor located at the reactor bottom at a superficial gas velocity Up, which is very close or equivalent to the minimum fluidization velocity Umf, required for achieving the incipient fluidization of the solid particles in the bed to obtain an emulsion phase consisting essentially of the solid particles and the primary gas with little or no formation of gas bubbles to achieve incipient fluidization or liquid-like behavior of fluidizable solid particles;(b) forming gas bubbles in the incipiently fluidized bed by introducing through a secondary gas distributor located immediately above the primary gas distributor a secondary gas, selected from one of the reactants which is used in excess of that required for the reaction stoichiometry, steam, an inert or a mixture of two or more thereof at a superficial gas velocity, Us, which is related to the superficial velocity of the primary gas such that a ratio of the superficial velocity of the secondary gas to the superficial velocity of the primary gas Us / Up, is in the range from about 0.5 to about 10.0, preferably from about 1 to about 5.
Owner:COUNCIL OF SCI & IND RES

Olefin production utilizing whole crude oil and mild catalytic cracking

A method for utilizing whole crude oil as a feedstock for the pyrolysis furnace of an olefin production plant wherein the feedstock after preheating is subjected to mild catalytic cracking conditions until substantially vaporized, the vapors from the mild catalytic cracking being subjected to severe cracking in the radiant section of the furnace.
Owner:EQUSR CHEM LP

Process for Co-Producing Jet Fuel and LPG from Renewable Sources

The present invention generally relates to a method for producing an isoparaffinic product useful as jet fuel from a renewable feedstock. The method may also include co-producing a jet fuel and a liquefied petroleum gas (LPG) fraction from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins and hydroisomerizing the hydrotreating unit heavy fraction to produce a hydroizomerizing unit heavy fraction that includes isoparaffins. The method also includes recycling the hydroisomerizing unit heavy fraction through the hydroisomerization unit to produce an isoparaffinic product that may be fractionated into a jet fuel and an LPG fraction. The present invention also relates to a jet fuel produced from a renewable feedstock having improved cold flow properties.
Owner:REG SYNTHETIC FUELS LLC

Catalyst and process of paraffin hydrocarbon conversion

A catalyst composition and process for the conversion of linear and / or branched paraffin hydrocarbons based on the use of an ionic liquid catalyst in combination with a Brønsted Acid, which provides a catalytic composition with an increased activity compared with said ionic liquid. Under suitable reaction conditions this conversion is leading to paraffin hydrocarbon fraction with higher octane number.
Owner:HALDOR TOPSOE AS

Process for the manufacture of diesel range hydro-carbons

The invention relates to chemical industry and is directed to the production of middle distillate from vegetable oils. In the first step of the production method, the fatty acids or triglycerides of said vegetable oils are hydrogenated to give n-paraffins, and in the second step, the n-paraffins are catalytically converted to paraffins with branched chains. Using this process having two steps, a high-quality middle distillate useful as a component of diesel fuels without any particular specifications may be produced.
Owner:NESTE OIL OY

Heavy distillate oil hydrotreating method

The invention relates to a method for hydrotreating heavy oil, in particular to the method for hydrotreating heavy oil, which improves the quality of diesel oil. Heavy distillate oil and animal and vegetable oil are used as raw material oil; under the hydrotreatment condition, the raw material oil and hydrogen gas are mixed and pass through a hydrotreatment reaction region; hydrogen-rich gas which is obtained by separating oil generated by hydrotreatment is circulated and utilized; and liquid obtained by separation is distillated to prepare a diesel oil product and hydrogenated wax oil. Compared with the prior art, the method can effectively improve the material source of a wax oil hydrotreatment device, ensure the quality of the hydrogenated wax oil, substantially increase the quality ofthe hydrotreated diesel oil and improve the storage stability of the animal and vegetable oil as fuel oil.
Owner:CHINA PETROLEUM & CHEM CORP +1

Control of mercury emissions from solid fuel combustion

A system 26 for removing elemental mercury or mercury compounds handles carbonaceous sorbent 28 of a starter batch stored in a silo 30 in an agglomerated state. The sorbent 28 is fed by a feeder 32 to a separation device 34, which comminutes (if necessary) and de-agglomerates the sorbent particles 28 to their primary size distribution. This device 34 may be a particle-particle separator or a jet mill, where compressed air or high-pressure steam is the energy source. The de-agglomerated sorbent 28 of a contact batch created from the starter batch is conveyed by an airsteam for injection at a contact location 66 in a flue gas duct whereat carbonaceous sorbent of the contact batch adsorbs mercury from the flue gas.
Owner:GENERAL ELECTRIC TECH GMBH

Systems and methods for carbon capture and sequestration and compositions derived therefrom

A method of sequestering a greenhouse gas is described, which comprises: (i) providing a solution carrying a first reagent that is capable of reacting with a greenhouse gas; (ii) contacting the solution with a greenhouse gas under conditions that promote a reaction between the at least first reagent and the greenhouse gas to produce at least a first reactant; (iii) providing a porous matrix having interstitial spaces and comprising at least a second reactant; (iv) allowing a solution carrying the at least first reactant to infiltrate at least a substantial portion of the interstitial spaces of the porous matrix under conditions that promote a reaction between the at least first reactant and the at least second reactant to provide at least a first product; and (v) allowing the at least first product to form and fill at least a portion of the interior spaces of the porous matrix, thereby sequestering a greenhouse gas.
Owner:RUTGERS THE STATE UNIV

Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds

A highly dispersed iron-based ionic liquid or liquid-gel catalyst which may be anion-modified and metals-promoted has high catalytic activity, and is useful for hydrocracking / hydrogenation reactions for carbonaceous feed materials. The catalyst is produced by aqueous precipitation from saturated iron salt solutions such as ferric sulfate and ferric alum, and may be modified during preparation with anionic sulfate (SO42-) and promoted with small percentages of at least one active metal such as cobalt, molybdenum, palladium, platinum, nickel, or tungsten or mixtures thereof. The resulting catalyst may be used in a preferred ionic liquid form or in a liquid-gel form, and either fluidic form can be easily mixed and reacted with carbonaceous feed materials such as coal, heavy petroleum fractions, mixed plastic waste, or mixtures thereof. The invention includes methods for making the ionic liquid or liquid-gel catalyst, and processes for using the fluidic catalysts for hydroprocessing the carbonaceous feed materials to produce desirable low-boiling hydrocarbon liquid products.
Owner:HEADWATERS CTL

Process for producing bio-derived fuel with alkyl ester and iso-paraffin components

A process for producing a diesel fuel of biological origin. The process includes a biological component to be trans-esterified into a fatty acid alkyl ester. A fraction of the fatty acid alkyl ester is hydrodeoxygenated and hydroisomerized to produce an iso-paraffinic hydrocarbon. The fatty acid alkyl ester and the iso-paraffin components are combined into a middle distillate product suitable for direct use as diesel or jet fuel.
Owner:REG SYNTHETIC FUELS LLC

Methods and configurations for acid gas enrichment

ActiveUS7635408B2Increase the concentration of hydrogen sulfideSmall sizeGas treatmentCarbon compoundsSolventCarbon dioxide
Hydrogen sulfide is selectively enriched from an acid gas (1) that comprises relatively large quantities of carbon dioxide using a configuration in which a portion of an isolated hydrogen sulfide stream is introduced into an absorber (51) operating as a carbon dioxide rejecter. The resulting concentrated hydrogen sulfide enriched solvent (4) is then further used (directly or indirectly) to absorb hydrogen sulfide from an acid feed gas.
Owner:FLUOR ENTERPRISES

Isoparaffinic base stocks by dewaxing fischer-tropsch wax hydroisomerate over Pt/H-mordenite

A high VI and low pour point lubricant base stock is made by hydroisomerizing a high purity, waxy, paraffinic Fischer-Tropsch synthesized hydrocarbon fraction having an initial boiling point in the range of 650-750° F., followed by catalytically dewaxing the hydroisomerate using a dewaxing catalyst comprising a catalytic platinum component and an H-mordenite component. The hydrocarbon fraction is preferably synthesized by a slurry Fischer-Tropsch using a catalyst containing a catalytic cobalt component. This combination of the process, high purity, waxy paraffinic feed and the Pt / H-mordenite dewaxing catalyst, produce a relatively high yield of premium lubricant base stock.
Owner:EXXON RES & ENG CO

Process for converting triglycerides to hydrocarbons

Processes for the conversion of hydrocarbons boiling in the temperature range of from about 80° F. to about 1000° F. to diesel boiling range hydrocarbons, and processes for increasing the cetane number and amount of n-C17 hydrocarbon products in such processes. Diesel boiling range hydrocarbons may be produced by contacting a hydrocarbon boiling in the above-mentioned boiling range with a triglyceride-containing compound to form a mixture, and then contacting the mixture with a hydrotreating catalyst under suitable reaction conditions.
Owner:PHILLIPS 66 CO

Methods for producing a total product in the presence of sulfur

Methods of producing a total product are described. A method includes continuously contacting a feed with a hydrogen source in the presence of one or more inorganic salt catalysts and steam to produce a total product, wherein the feed has at least 0.02 grams of sulfur, per gram of feed; and producing a total product that includes coke and the crude product. The crude product has a sulfur content of at most 90% of the sulfur content of the feed.
Owner:SHELL OIL CO

Systems and methods of producing a crude product

InactiveUS20050133405A1ProductsHydrogenGramChemistry
Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. At least a portion of the crude product may be produced as a vapor. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.
Owner:SHELL OIL CO

Wide-cut synthetic isoparaffinic lubricating oils

A wide-cut lubricant base stock is made by hydroisomerizing and then catalytically dewaxing a waxy Fischer-Tropsch synthesized hydrocarbon fraction feed and comprises the entire dewaxate having an initial boiling point in the 650-75O° F.+ range. Formulated lubricating oils made by admixing the base stock with a commercial automotive additive package meet all specifications, including low temperature properties, for multigrade internal combustion engine crankcase oils. The waxy feed has an initial boiling point in the 650-750° F. range and continuously boils to an end point of at least 1050° F.+. Lower boiling hydrocarbons produced by the process are separated from the base stock by simple flash distillation. The base stock comprises the entire dewaxate having an initial boiling point in the 650-750° F. range.
Owner:EXXON RES & ENG CO

Effective integration of solvent deasphalting and ebullated-bed processing

This invention relates to a novel method for economically processing vacuum residue from heavy crude oils by selectively processing the difficult and easy components in reactors whose design and operating conditions are optimized for the specific feed. The process utilizes an integrated solvent deasphalting (SDA) / ebullated-bed design wherein the heavy vacuum residue feedstock is initially sent to an SDA unit operated with C4 / C5 solvent to achieve a high deasphalted oil (DAO) yield. The resulting SDA products, namely asphaltenes and DAO are separately treated in ebullated-bed reactor(s) systems whose design and operating conditions are optimized for a particular feedstock. The resulting net conversion, associated distillate yield and product qualities are greatly improved relative to treatment of the entire residue feedstock in a common ebullated-bed reactor system.
Owner:INST FR DU PETROLE

Polyalphaolefin & fischer-tropsch derived lubricant base oil lubricant blends

Blended lubricant base oils and blended finished lubricants comprising ≧70 weight percent Fischer-Tropsch derived lubricant base oils comprising ≧6 weight % molecules with monocycloparaffinic functionality and less than 0.05 weight % molecules with aromatic functionality; at least one polyalphaolefin lubricant base oil with a kinematic viscosity at 100° C. greater than about 30 cSt and less than 150 cSt are provided. These blended lubricant base oils and blended finished lubricants exhibit superior friction and wear properties, in addition to other highly desired properties. Also provided are processes for making these blended lubricant base oils and blended finished lubricants.
Owner:CHEVROU USA INC

Process to produce biofuels from biomass

Biofuels can be produced by: (i) providing a biomass containing celluloses, hemicelluloses, lignin, nitrogen compounds and sulfur compounds; (ii) removing sulfur compounds and nitrogen compounds from the biomass by contacting the biomass with a digestive solvent to form a pretreated biomass containing carbohydrates and having less than 35% of the sulfur content and less than 35% of the nitrogen content of untreated biomass on a dry mass basis; (iii) contacting the pretreated biomass directly with hydrogen in the presence of a hydrogenolysis catalyst to form a plurality of oxygenated intermediates, and (vi) processing at least a portion of the oxygenated intermediates to form a liquid fuel.
Owner:SHELL OIL CO

Functionalized ionic liquids, and methods of use thereof

One aspect of the present invention relates to ionic liquids comprising a pendant Bronsted-acidic group, e.g., a sulfonic acid group. Another aspect of the present invention relates to the use of an ionic liquid comprising a pendant Bronsted-acidic group to catalyze a Bronsted-acid-catalyzed chemical reaction. A third aspect of the present invention relates to ionic liquids comprising a pendant nucleophilic group, e.g., an amine. Still another aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to catalyze a nucleophile-assisted chemical reaction. A fifth aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to remove a gaseous impurity, e.g., carbon dioxide, from a gas, e.g., sour natural gas.
Owner:UNIV OF SOUTH ALABAMA
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