1599results about "Hydrocarbon oils refining" patented technology

A process for upgrading plastic derived oil includes contacting the plastic derived oil with a mixed catalyst in a first reactor, where the mixed catalyst includes a decontamination catalyst and a cracking catalyst different from the decontamination catalyst. The first reactor reduces concentrations of halogen-containing compounds in the plastic derived oil. The process includes passing the first reactor effluent to a second reactor and contacting the first reactor effluent with the cracking catalyst to produce a second effluent comprising light olefins and naphtha range hydrocarbons. The process includes separating used mixed catalyst from the first reactor to produce a used decontamination catalyst and a second used cracking catalyst, and regenerating the decontamination catalyst and cracking catalyst in separate regenerators to reduce exposure of the cracking catalyst to halogen-containing compounds produced during regeneration of the used decontamination catalyst.

A process for upgrading plastic derived oil includes contacting a plastic derived oil stream with a decontamination catalyst in a first reactor, separating a first reactor effluent from a used decontamination catalyst, passing the first reactor effluent to a second reactor downstream of the first reactor, contacting the first reactor effluent with a cracking catalyst in the second reactor, and separating a second reactor effluent from a used cracking catalyst. The cracking catalyst is different from the decontamination catalyst. The process further includes regenerating the used decontamination catalyst in a decontamination catalyst regenerator to produce regenerated decontamination catalyst, and regenerating the used cracking catalyst in a cracking catalyst regenerator separate from the decontamination catalyst regenerator to produce regenerated cracking catalyst. Regenerating the used cracking catalyst separately reduces deactivation of the cracking catalyst by halogen-containing compounds produced during regeneration of the decontamination catalyst.

The invention discloses a low-sulfur diesel oil production device and method, and belongs to the technical field of low-sulfur diesel oil production.The low-sulfur diesel oil production device comprises a production tank, a touch screen controller is arranged on the outer surface of the production tank, a feeding pipe and a supporting ring are fixedly installed on the outer surface of the production tank, and an electric heating pipe is arranged in a shell cavity of the production tank; the feeding pipe is located above the supporting ring, a plurality of supporting feet are fixedly installed on the bottom face of the supporting ring, and a bottom shell is fixedly installed on the bottom face of the production tank. According to the low-sulfur diesel oil production device, by arranging the driving assembly, the annular turbulent flow assembly and the hydrogen introduction mechanism in a matched mode, during diesel oil production, multi-angle release of hydrogen can be achieved, the production tank can be rapidly filled with the hydrogen, a desulfurization reaction can be rapidly conducted on the hydrogen and the diesel oil under the action of a catalyst, and the production efficiency of the low-sulfur diesel oil is greatly improved; meanwhile, continuous cleaning of the core area of the filtering structure can be synchronously achieved, and blockage caused by continuous accumulation of impurities on the filtering structure is avoided.

A light hydrocarbon aromatization catalyst capable of increasing the yield of light alkane comprises a hydrogen type Silicalite-1 (at) ZSM-5 core-shell molecular sieve, an active metal and / or a binder, the hydrogen type Silicalite-1 (at) ZSM-5 core-shell molecular sieve takes a Silicalite-1 molecular sieve as a core layer and a ZSM-5 molecular sieve as a shell layer, and the particle size of the hydrogen type Silicalite-1 (at) ZSM-5 core-shell molecular sieve is 90-140 nm. The catalyst is applied to light hydrocarbon aromatization reaction, has higher low-carbon alkane yield and lower dry gas yield, and is good in stability, long in one-way reaction period and low in carbon deposit amount.

The present invention provides a zirconium-based metal-organic framework material and a preparation method therefor and the use thereof, and an adsorption separation device and method. The zirconium-based metal-organic framework material has a chemical structural formula of [C18H6O16Zr3]n, and comprises zirconium and an organic ligand forming a coordination bond with zirconium, wherein the organic ligand is diphenylethyne-3,3′,5,5′-tetracarboxylic acid. The molecular structure of the zirconium-based metal-organic framework material of the present invention is a three-position network structure having a one-dimensional channel; and in the present invention, the size of the one-dimensional channel is accurately controlled by changing the aspect ratio of the organic ligand, such that the zirconium-based metal-organic framework material efficiently separates a hexane isomer by means of a kinetic effect.

An adsorbent for removing organic sulfide, and a preparation method therefor and a use thereof, relating to the technical field of desulfurization adsorbents. The adsorbent for removing organic sulfide comprises a high-pore-volume core and a coating layer attached to the high-pore-volume core; the high-pore-volume core is obtained by mixing a nonionic surfactant, an alkali metal precursor and / or an alkaline-earth metal precursor, and an aluminum-containing compound and then carrying out forming and drying on same; and the coating layer is formed by an Ag and Ce co-modified high-silicon molecular sieve and a composition Al2(OH)nCl6-n (n=1-5). The adsorbent has the characteristics of high desulfurization efficiency, wide desulfurization range, high desulfurization precision, mild use conditions, long service life and the like, can achieve deep removal of organic sulfur under normal-temperature and normal-pressure conditions, can remove the organic sulfur in raw materials to 10 ppb or below, and is particularly suitable for desulfurization and purification of liquefied petroleum gas or natural gas.

Methods for upgrading heavy aromatic waste streams, such as polystyrene, to chemical feedstocks are disclosed. The process involves feeding waste streams to a first pyrolysis zone followed by hydrogenation. The hydrogenation effluent is processed to recover ethylene, propylene, benzene, ethylbenzene, or their precursors. Optionally, the effluents are separated into light and heavy streams. The light stream from the first pyrolysis effluent is sent to hydrogenation, while the heavy stream is either removed, recycled to the first pyrolysis zone, or fed to a second pyrolysis zone. The light stream from the hydrogenation effluent is processed to recover the same chemicals, and the heavy stream is similarly managed. If present, the second pyrolysis effluent is separated into light and heavy streams, with the light stream processed to recover chemicals and the heavy stream managed as before.

The invention provides a Pt-Sn bimetallic catalyst and a preparation method and application thereof.The preparation method comprises the steps that 1, a Y molecular sieve is placed in a mixed solution of KOH and methyl alcohol, centrifugation and washing are conducted till the Y molecular sieve is neutral after stirring, drying and roasting are conducted, and a non-acid KY molecular sieve is obtained; the silica-alumina ratio of the Y molecular sieve is 3-100; 2) taking the non-acidic KY molecular sieve as a carrier, and loading Sn by adopting an atomic layer deposition technology to obtain a Sn-modified non-acidic KY molecular sieve; and 3) loading Pt by using the Sn-modified non-acidic KY molecular sieve as a carrier and adopting an atomic layer deposition technology to obtain the Pt-Sn bimetallic catalyst. According to the preparation method provided by the invention, spatial distribution of Pt and Sn is accurately regulated and controlled by combining an atomic layer deposition technology, so that the electronic state of Pt species is adjusted, alkane is promoted to be dehydrogenated into an olefin intermediate, and the aromatization catalytic activity and the aromatic hydrocarbon selectivity of alkane are improved.

The invention discloses a method for green and efficient removal of thiophene sulfides in fuel oil by using Q [8]. According to the method provided by the invention, a Q [8] solid powder material is adopted to carry out removal treatment on simulated fuel oil containing the thiophene sulfides in a subject-object interaction mode, and the Q [8] solid powder material can be subjected to a regeneration process for reuse through ethanol desorption. The Q [8] solid powder material used in the method is low in cost, the urea is a main raw material for synthesis of the Q [8] solid powder material, and the Q [8] solid powder material is high in selectivity, can be recycled and is more environmentally friendly. The method is simple to operate, convenient to use and low in cost, the combustion simulation oil can be efficiently desulfurized, and environmental pollution is effectively reduced.

Disclosed are antioxidants used in compositions and methods to stabilize synthetic feedstock derived from plastic. Some methods disclosed herein include adding an antioxidant composition to a plastic-derived synthetic feedstock composition. Some methods disclosed herein include heating plastic under substantially oxygen free conditions at a temperature of from about 400° C. to about 800° C. to produce a pyrolysis effluent, distilling the pyrolysis effluent, recovering the synthetic feedstock, and adding a stabilizer to the synthetic feedstock to reduce contamination. The disclosure also provides compositions including a synthetic feedstock derived from plastic and an antioxidant.

The invention belongs to the technical field of catalysis, and discloses a high-density long-chain alkane dehydrogenation catalyst and a preparation method thereof. The invention relates to a high-density long-chain alkane dehydrogenation catalyst, which is a composition of Pt, Sn, Ni, Fe and alkali metal or oxide thereof loaded by using mesoporous and microporous alumina as a carrier. The catalyst is mainly applied to the reaction process of preparing monoolefine through dehydrogenation of long-chain n-alkanes (C10-C13), the catalyst uses a ball-forming high-density carrier, the preparation process is safer and more environment-friendly, the dehydrogenation service life of the catalyst is prolonged, and the dehydrogenation stability is improved by 15-30%.

The invention discloses a shape-selective isomerization catalyst as well as a preparation method and application thereof. The catalyst comprises a ten-membered ring aluminum phosphate molecular sieve, a noble metal active component and a metal oxide auxiliary active component. The ten-membered ring aluminum phosphate molecule is selected from at least one of SAPO-11, MeAPO-11, SAPO-41 and MeAPO-41, and the ten-membered ring aluminum phosphate molecule is selected from at least one of SAPO-11, the noble metal active component is selected from at least one of Pt and Pd; the metal oxide auxiliary agent is selected from at least one of CeO2, Nb2O5 and Ta2O5. Compared with the catalyst prepared in the prior art, the catalyst prepared by the method provided by the invention has higher activity and isomer yield in the isomerization reaction of long-chain n-alkanes.

The invention relates to the technical field of crude oil decalcification, in particular to a low-corrosivity crude oil decalcification agent and a preparation method thereof. The low-corrosivity crude oil decalcifying agent is prepared from the following raw materials: acetic acid, citric acid, modified chitosan, ethanol and deionized water, wherein the modified chitosan is prepared by synthesizing N-hydroxyacrylamide, performing sulfonation treatment, and grafting poly (N-isopropylacrylamide) with carboxymethyl chitosan. The preparation method comprises the following steps: adding deionized water and modified chitosan into a blending kettle, heating to 65-75 DEG C, stirring, sequentially adding acetic acid and citric acid, continuously stirring, finally adding ethanol, stirring, and cooling to obtain the decalcifying agent. The decalcifying agent can efficiently remove organic calcium, equipment corrosion is reduced through temperature-sensitive film forming, chelate is stable at high temperature, sewage COD is low, the decalcifying agent adapts to an existing electro-desalting process, and industrial application is easy.

The invention relates to a venturi separator, which is characterized in that the venturi separator comprises a venturi tube and a liquid phase collecting tube surrounding at least one part of structure of the venturi tube, and the venturi tube comprises the following sections which are communicated in sequence: an optional equal-diameter section, a reducing section, a throat part and an expanding section, the venturi separator is provided with a gas phase inlet, a liquid phase inlet, a liquid phase outlet and a gas phase outlet, an opening is formed in the side wall or the tail end of the expanding section of the venturi tube, and the opening leads to the liquid phase collecting tube, so that a liquid phase leaves the venturi tube and enters the liquid phase collecting tube under the action of centrifugal force. The invention also relates to the use of such a Venturi separator in a chemical process.

An integrated process having an ultra-low GHG footprint for converting Camelina based biomass to liquid fuels and lubricant base stocks in which a Camelina based biomass feed is converted to liquids by a multistep hydroprocessing method and the liquids are upgraded to produce premium hydrocarbon fuels and lubricants.

The utility model relates to the technical field of diesel hydrofining, in particular to a diesel hydrofining catalytic device which comprises a diesel hydrofining catalytic device mounting box, a liquid storage barrel is arranged at the top of the diesel hydrofining catalytic device mounting box, and uniform mixing assemblies are arranged inside and outside the liquid storage barrel; the uniform mixing assembly comprises a supporting frame arranged on the outer wall of the left side of the diesel oil hydrofining catalytic device mounting box, a liquid adding tank is arranged at the top of the supporting frame, the bottom end of the liquid adding tank is connected with a connecting pipe, and a suction pump is arranged at the other end of the connecting pipe. The anchor stirrer is used for stirring liquid and a catalyst in the liquid storage barrel to enable the liquid and the catalyst to be mixed more uniformly, the temperature sensor is used for detecting temperature, the branch nozzles are used for adding the liquid, the liquid is more convenient to add, and therefore the use efficiency of the diesel hydrofining catalytic device is improved conveniently.

The invention relates to a method for treating a liquid feedstock comprising at least partly carbonaceous products resulting from a hydrothermal liquefaction treatment, known as biocrude feedstock (1), with a view to reducing the content of mineral compounds, such as said treatment comprises - a step (a) dilution of the biocrude feedstock with a diluent (8) comprising an organic liquid phase, so as to obtain a dilute biocrude (9), - a step (b) contacting the dilute biocrude obtained in step (a) with at least one solvent (3) which comprises a liquid aqueous phase, with counter-current liquid-liquid extraction, so as to obtain, on the one hand, a raffinate (5) comprising the mineral-depleted biocrude and the diluent, and on the other hand an extract (4) comprising the solvent enriched with mineral compounds, - a step (c) of separation of the raffinate (5) obtained in step (b), so as to obtain, on the one hand, the biocrude depleted in mineral compounds (7) and on the other hand a phase comprising the diluent (8).

The invention belongs to the technical field of new energy battery materials, and particularly relates to coated asphalt for a negative electrode of a new energy battery as well as a preparation method and application of the coated asphalt. The method comprises the following steps: mixing an ethylene tar raw material and a cross-linking agent, and carrying out a first hydroxide cross-linking reaction in an oxygen-containing atmosphere to obtain a reaction liquid after the first hydroxide cross-linking reaction; transferring the reaction liquid after the first hydroxide cross-linking reaction into a protective gas atmosphere, and carrying out a second hydroxide cross-linking reaction to obtain a reaction liquid after a second hydroxide cross-linking reaction; and cooling the reaction liquid after the second hydroxide cross-linking reaction to room temperature, and performing liquid phase volatilization, so that the obtained coated asphalt has the characteristics of high softening point, low quinoline insoluble content, low coating thickness, high integrity, high compactness and high yield, is easy to realize industrial application, and can solve the recycling problem of ethylene tar.

The invention relates to the field of data processing, in particular to a crude oil vacuum degassing intelligent control system based on real-time data processing, which is provided with a degassing analysis module used for acquiring degassing data of raw materials to extract degassing state characteristics of the raw materials and calculating degassing stability characterization values of the raw materials based on the degassing state characteristics, the degassing stability degree categories of the corresponding raw material degassing processes are divided; the analysis calling module is used for selectively calling the degassing evaluation module or the conventional adjustment module according to the degassing stability degree category, predicting a flash point value at a preset prediction frequency, and adaptively evaluating and analyzing the degassing of the raw material; the response early warning module responds to the judgment result of the degassing evaluation module and sends out an early warning prompt signal, through the reliable safety monitoring process, the efficiency of the crude oil vacuum degassing process is improved, potential safety risks can be recognized in advance, and therefore production safety is guaranteed.

The present application belongs to the technical field of cracking and dechlorination of chlorinated mixed plastics, and particularly relates to a preparation method of a red mud-based chlorinated mixed plastic pyrolysis composite dechlorination agent and a dechlorination method. First, the coffee grounds are converted into biochar through a hydrothermal carbonization reaction, and at the same time, the reducing gas released during the carbonization of the coffee grounds is used to reduce part of the hematite in the red mud to Fe3O4; then, through a high-temperature carbon thermal reaction, the residual hematite in the red mud is completely reduced to Fe3O4, and at the same time, the composite with the added CaO is realized, and finally, the composite dechlorination agent composed of the modified red mud, the biochar and the CaO is obtained. The dechlorination agent has a suitable specific surface area and an adjustable pore structure, can effectively fix HCl during the cracking of chlorinated mixed plastics, and can further obtain plastic pyrolysis oil with ultra-low chlorine content, and realize the high-value utilization of the red mud and coffee grounds solid waste.

A method of transporting hydrogen may comprise providing hydrogen gas comprising a first hydrogen gas portion produced by a method with no direct carbon emissions to the atmosphere and a second hydrogen gas portion produced by a method with direct carbon emissions to the atmosphere; at a first hydrocarbon processing facility, hydrogenating a hydrocarbon feed in the presence of the hydrogen gas to form a hydrogenated effluent; transporting a portion of the hydrogenated effluent from the first hydrocarbon processing facility to a second hydrocarbon processing facility; and at the second hydrocarbon processing facility, dehydrogenating the portion of the hydrogenated effluent to form a hydrogen gas product. On average, a mass flow rate of the first hydrogen gas portion may be at least 90% of a mass flow rate of the hydrogen gas product. The first hydrocarbon processing facility and the second hydrocarbon processing facility may be separated by a distance of at least 100 km.

The invention provides a hydroisomerization catalyst and an application thereof in an isomerization reaction of n-alkanes. The hydroisomerization catalyst comprises a Ni modified SAPO-11 molecular sieve and an active component loaded on the Ni modified SAPO-11 molecular sieve, the pore diameter of the Ni modified SAPO-11 molecular sieve is 5.4-14.5 nm, the Ni dispersity is 0.31-0.40, and the specific surface area is 195-288 m < 2 > / g.

The present disclosure provides a method for preparing a Sustainable Aviation Fuel (SAF), the method comprising: a step of preparing a renewable feedstock, a step of preparing a renewable feedstock, a step of preparing a renewable feedstock, a step of preparing a renewable feedstock, a step of preparing a renewable feedstock, a step of preparing a renewable feedstock, a step of preparing a renewable feedstock, and a step of preparing the SAF, and a step of preparing the SAF. And a step for introducing the renewable feedstock as a reactant into a hydrogenation reaction in the presence of a catalyst comprising a metal and a zeolite, the zeolite being a 1D (dimensional) 10MR (membered-rns) zeolite, the conversion rate of the hydrogenation reaction of a fraction exceeding the boiling point of the SAF being 50% or less. The process enables the production of aviation fuels from environmentally friendly feedstocks. In addition, the SAF prepared by the method can replace aviation fuels previously prepared from fossil raw materials. In addition, the emission of carbon dioxide into the atmosphere can be reduced, and therefore it is expected that global warming caused by the emission of carbon dioxide can be suppressed.

The disclosure provides compositions and methods for removing ions from hydrocarbon mediums. A method may include removing a first anion from a liquid hydrocarbon. The method may include contacting an ion exchange resin having a second anion with a water-soluble organic solvent to form a treated ion exchange resin, contacting the treated ion exchange resin with the liquid hydrocarbon, and removing the first anion from the liquid hydrocarbon by exchanging the first anion with the second anion. A composition may include the hydrocarbon medium and the ion exchange resin or treated ion exchange resin.

Provided herein are processes for recycling hydrocarbons in a used high performance lubricant such as wind turbine gear oil. In the present process and methodologies, the used high performance lubricant is not mixed with another type of used oil. The used high performance oil is contacted with a solvent in an extraction process. Contaminates are extracted and circular hydrocarbons are formed. Solvent can be recovered, and the circular hydrocarbon combined with a high performance base stock for use as a high performance lubricant in a mechanical system.

Processes for decontaminating a plastic derived oil include contacting a plastic derived oil stream containing halogen-containing compounds with a decontamination catalyst at a reaction temperature of 350-450° C. to produce a decontaminated plastic derived oil and a used decontamination catalyst. The decontamination catalyst includes from 5-40 wt. % red mud particles, from 20-60 wt. % matrix material, and from 10-30 wt. % binder, per unit weight of the decontamination catalyst. Contacting the plastic derived oil stream with the decontamination catalyst at the reaction conditions causes halogen-containing compounds to react to form hydrocarbons and hydrogen halides, which further react with the red mud particles to produce metal halides on surfaces of the red mud particles. The decontaminated plastic derived oil has a concentration of the halogen-containing compounds less than a concentration of the halogen-containing compounds in the plastic derived oil stream.

A method can include: in a heat exchanger, cooling a biocrude oil emulsion stream received from a biocrude oil emulsion source, wherein the emulsion can include a biocrude oil phase, an aqueous phase, and solids; in a first mixing vessel, mixing the emulsion with a solvent to dissolve the biocrude oil phase and form a biocrude-solvent solution; in a first separator assembly, separating the biocrude-solvent solution from the aqueous phase and the solids; in a solvent recovery apparatus, recovering solvent from the biocrude-solvent solution; in a second mixing vessel, mixing the solvent with the aqueous phase and the solids received from the first separator assembly to dissolve biocrude oil remaining in the aqueous phase and the solids; and supplying the solvent and biocrude oil to the first mixing vessel as the solvent. In some examples, such a method can more effectively separate biocrude oil from the emulsion than conventional techniques.

An olefin production system (1) comprises: a reactor (10) that generates water and a hydrocarbon, which contains a lower olefin, from a feedstock containing hydrogen and carbon dioxide and / or carbon monoxide; a first gas-liquid separation tank (20) that separates the product generated by the reactor (10) into a gas containing the lower olefin and a liquid containing water and a hydrocarbon that contains the lower olefin; and a second gas-liquid separation tank (30) that is connected to the first gas-liquid separation tank (20) and separates the gas containing the lower olefin from the liquid transferred from the first gas-liquid separation tank (20). The lower olefin contains at least one substance selected from the group consisting of ethylene, propylene, butene and butadiene.

The invention relates to the technical field of catalysts, in particular to a platinum-nickel alloy / carrier type catalyst and a preparation method and application thereof. The preparation method of the platinum-nickel alloy / carrier type catalyst comprises the following steps: mixing TiO2 with soluble Pt salt and soluble Ni salt, and carrying out hydrothermal reaction to induce alloy generation to obtain an alloy solution; and carrying out suction filtration on the alloy solution, drying and calcining to obtain the platinum-nickel alloy / carrier type catalyst. The prepared catalyst has the unique advantages that the particle size of the alloy nanoparticles is controlled to be 4-5 nm, the particle size is smaller than that of other catalysts, and more excellent performance is shown. The alloy nano-particles are uniform in dispersion and accurate in size, and show remarkable high efficiency in the aspects of activity, stability and selectivity of a target product.

The invention belongs to the technical field of petroleum processing, and particularly relates to a preparation method and application of a catalyst. The catalyst comprises a metal active component and a molecular sieve, a metal complex is added in situ in the synthesis process of the molecular sieve, anchoring of metal in a molecular sieve cage is realized by using a confinement effect in the molecular sieve cage, sub-nanometer approaching of a metal site and an acid site is realized, and the synergistic effect of the metal site and the acid site is improved; the catalytic cracking catalyst is used for synergistic catalytic cracking of biomass pyrolytic oil and petroleum distillate oil. The high-activity confinement type catalyst is synthesized, the synthesis time of the catalyst is greatly shortened by adding the metal complex while the HY molecular sieve is synthesized, the original crystal structure is kept, metal dispersion is promoted, and the catalytic reaction activity is improved. The catalyst provided by the invention is simple and controllable in active component loading capacity and size, and can be applied to the co-catalytic cracking process of biomass pyrolytic oil and / or a model compound thereof and petroleum distillate oil and / or VGO.