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6425 results about "Ionic liquid" patented technology

An ionic liquid (IL) is a salt in the liquid state. In some contexts, the term has been restricted to salts whose melting point is below some arbitrary temperature, such as 100 °C (212 °F). While ordinary liquids such as water and gasoline are predominantly made of electrically neutral molecules, ionic liquids are largely made of ions and short-lived ion pairs. These substances are variously called liquid electrolytes, ionic melts, ionic fluids, fused salts, liquid salts, or ionic glasses.

Advanced ion exchange membranes and applications thereof

Improved performance ion exchange membranes for use in REM, AEM and DMFC fuel cells, buffered fuel cells, hydrolysis, other applications comprise a molecular matrix of homopolymers, di-monomer, heteropolymers, copolymers, or block-polymers of fluorocarbon and hydrocarbon compounds combined with (i) skeletal support grid to improve durability, handling, reduce membrane swelling, and sequester dopants and nanoparticles from leakage; (ii) microporous membrane formed using a sacrificial filler process enhancing conductivity and limiting fuel crossover; (iii) hetero-ionomeric matrix of two-or-more membrane-bound acids e.g. sulphonic and phosphonic acid expanding usable range; (iv) permanent fillers enhancing conductivity and porosity including nanoparticles, metal-oxides, zeolites, silicates, GOs, CNTs, MOFs, POSS, and others; (v) ionic liquid doping to enhance membrane conductivity; (vi) membrane nanocoating preventing H2O2 diffusion; and / or (vii) catalytic nanocoating with metals, metal-oxides, and MOFs preventing atmospheric toxin catalyst poisoning. Combined with a heterogenous GDI, the IEM is integrated into iBFC power blade and energy bank applications.
Owner:WILLIAMS RICHARD KENT

Ion gel film with microstructure on the surface, preparation method and ionization sensor

The present invention belongs to the field of sensors, and relates to an ion gel film with a microstructure on the surface, a preparation method, and an ion-type sensor. The preparation method comprises: sandblasting on a precursor substrate to obtain a substrate, forming a mixed solution of a polymer and an ionic liquid on the substrate to obtain a wet film, and drying and curing the wet film to obtain an ion gel film, wherein the precursor substrate has an arc-shaped recess array, and the sandblasting conditions include: the sandblasting particle size is 5000 mesh to 10000 mesh, and the sandblasting pressure is 2 bar to 10 bar. The ion gel film is used for an ion-type sensor, which can improve the detection sensitivity of the sensor.
Owner:WUTONG SENSATION CONTROL (BEIJING) TECH CO LTD +1

Two-dimensional magnetic material device and preparation method and regulation and control method thereof

ActiveCN119562753Aregulation and stabilitySmall working currentMagnetic anisotropyIonic liquid
The invention discloses a two-dimensional magnetic material device and a preparation method and a regulation and control method thereof, and the regulation and control method comprises the steps: enabling ionic liquid to cover the surface of a two-dimensional magnetic material, enabling the ionic liquid to be in contact with a grid electrode, a source electrode, a drain electrode and the two-dimensional magnetic material, and continuously applying current from the grid electrode to the source electrode and to the drain electrode, and the regulation and control of the two-dimensional magnetic material device are completed. According to the two-dimensional magnetic material device and the preparation method and the regulation and control method thereof provided by the invention, the ionic liquid containing the cationic molecular chains with different lengths is selected to perform intercalation on the two-dimensional magnetic material device, so that regulation and control on the two-dimensional magnetic material device are realized, and the regulation and control flexibility of the two-dimensional magnetic material is greatly improved; and the coercive field, the magnetic anisotropy energy and the carrier concentration of the two-dimensional magnetic material can be changed.
Owner:NANJING UNIV OF POSTS & TELECOMM

Methods for controlling the pitch of self-assembled ionic liquid crystal (ILC) structures

Embodiments of improved methods are provided to form ordered structures on a surface of a substrate using direct self-assembly (DSA) of ionic liquid crystals (ILCs). More specifically, various embodiments of methods are provided to control the pitch of a layered structure formed on a substrate surface via self-assembly of ILCs having cation head groups, alkyl tail groups and anions. In the embodiments disclosed herein, the pitch of the layered structure is controlled by: (a) controlling the cation / anion charge ratio of the cation head groups and anions included within the ILCs, and / or (b) adding an ionic liquid to a solution comprising the ILCs.
Owner:TOKYO ELECTRON LTD

Preparation process of modified porous carbon material catalyst

The invention discloses a preparation process of a modified porous carbon material catalyst. The preparation process comprises the following steps: (1) mixing and calcining a biomass precursor and a template agent to prepare graded porous carbon; (2) low-frequency plasma pretreatment and high-frequency plasma fluorination modification are adopted; (3) introducing the pulse plasma into a nitrogen doping site; (4) spraying ionic liquid and activating H2 plasma to form a B / F co-doped layer; and (5) loading alloy nanoparticles such as PtRu through pulse electrodeposition. According to the obtained catalyst, biomass derived porous carbon serves as a carrier, a fluorine / nitrogen co-doped active layer is constructed on the surface of the carrier through multi-frequency plasma synergistic modification and ionic liquid auxiliary modification, superfine precious metal nanoparticles are loaded, the hydrogen evolution overpotential of the catalyst is smaller than or equal to 28 mV under the current density of 10 mA / cm < 2 >, the activity attenuation is smaller than 5% after 1000 times of circulation, and the catalyst has a good catalytic activity. The water electrolysis hydrogen production device is suitable for a large-scale water electrolysis hydrogen production device.
Owner:ZHENGZHOU NORMAL UNIV +1

CO2 trapping absorbent, trapping regeneration device and trapping process

The invention discloses a CO2 trapping absorbent which comprises 20%-50% of proton type ionic liquid, 20%-50% of a phase conversion driving agent and 20%-40% of water, and the phase inversion driving agent is one or a mixture of more of N, N-dimethyl formamide, N-methyl pyrrolidone, pentamethyldiethylenetriamine, tetramethylethylenediamine, tetramethylethylenediamine, tetramethylenediamine, tetramethylethylenediamine and dimethyl piperazine, and the phase inversion driving agent is one or a mixture of more of N, N-dimethyl formamide, N-methyl pyrrolidone, pentamethyldiethylenetriamine, tetramethylethylenediamine, tetramethylethylenediamine and dimethyl piperazine. The absorbent disclosed by the invention has the outstanding advantages of low viscosity, high absorption rate, high regeneration efficiency, high circulation capacity and low regeneration energy consumption, and has a good application prospect.
Owner:NANJING UNIV

Three-dimensional network polymer gel electrolyte, positive plate and solid-state lithium battery

The invention provides a three-dimensional network polymer gel electrolyte, a positive plate and a solid-state lithium battery. The three-dimensional network polymer gel electrolyte comprises 80-98% of an organic solvent, 5-15% of a lithium salt, 2-8% of lignosulfonate, 2-10% of a polymeric monomer and 2-8% of an ionic liquid, and the polymeric monomer is selected from acrylamide, polyethylene glycol dimethacrylate, 3-(methacryloyloxy) propyl trimethoxy silane or tetrahydrofurfuryl acrylate and the like. Under ultraviolet light, lignosulfonate can spontaneously generate quinonyl photochemical free radicals and hydroxyl photochemical free radicals in a mixed solution of ionic liquid and specific polymer monomers, and under the action of the photochemical free radicals, the lignosulfonate reacts with unsaturated double bonds on a polymer through phenolic groups, so that the photochemical free radicals are formed. The gel electrolyte with a three-dimensional network structure is formed, the mechanical strength can be improved, the growth of lithium dendrites in a lithium metal battery can be inhibited, and the metal lithium battery containing the gel electrolyte has excellent cycle life and safety performance.
Owner:HUNAN LIFANG NEW ENERGY SCI & TECH

All-solid-state battery cell and preparation method and application thereof

The invention discloses an all-solid-state battery cell as well as a preparation method and application thereof, and relates to the technical field of solid-state batteries. The cured insulation paste is attached to the edge of the positive electrode active layer, the size difference between the positive electrode active layer and the negative electrode active layer is supplemented through the cured insulation paste, the ends of the positive electrode active layer and the negative electrode active layer are flush, the insulation paste plays a supporting role under extrusion, and the problems of collapse, short circuit and the like caused by the size difference between the positive electrode active layer and the negative electrode active layer are avoided; the insulation paste at the edge can be bonded with the negative electrode under a high pressure condition, so that when the positive electrode is charged and discharged, the problem of poor cycle performance caused by volume change of the positive electrode plate in the charging and discharging process can be effectively relieved, and the cycle performance of the battery is improved; and the problems of material falling at the edge of the positive pole piece and the like can be effectively avoided. The electrolyte membrane is arranged between the positive active layer and the negative active layer, and the ionic liquid treatment layer on the electrolyte membrane is utilized, so that the impedance between the electrolyte membrane and the pole piece is reduced, and the battery performance is improved.
Owner:四川新能源汽车创新中心有限公司

Methods for patterning a semiconductor substrate using metalate salt ionic liquid crystals

Embodiments of improved process flows and methods are provided to pattern a semiconductor substrate using direct self-assembly (DSA) of metalate salt ionic liquid crystals (ILCs) having metalate anions. After self-assembly of the metalate salt ILCs into ordered structures, an oxidation process is used to remove the organic components of the ordered structures and convert the metalate anions into metal oxide patterns. In addition to providing a robust metal oxide pattern, which can be transferred to the underlying substrate, the process flows and methods disclosed herein enable ILCs to be used as pitch multipliers in advanced patterning techniques.
Owner:TOKYO ELECTRON LTD

Epoxy resin solid electrolyte and preparation method and application thereof

The invention belongs to the technical field of electrochemical materials, and discloses an epoxy resin solid electrolyte as well as a preparation method and application thereof. The preparation raw materials are as follows: 100 parts of epoxy resin, 5-15 parts of an ionic conductive group compound, 5-15 parts of a high ionic conductive lithium salt, 2-20 parts of an ionic liquid, 10-30 parts of a flexible chain segment compound, 1-20 parts of a pore forming agent and 20-50 parts of a curing agent. The ionic conductive group compound comprises a sulfonic compound, a quaternary ammonium salt or a carboxyl compound; the flexible chain segment compound comprises one or more of polyester, polyurethane, polyacrylate, polyacrylic acid, polyamide and polyether-ether-ketone. According to the invention, the epoxy resin is used as a main matrix, the ionic liquid provides an ionic migration path, meanwhile, an ionic conductive group is grafted into an epoxy resin molecule, a flexible chain segment is introduced to reduce the crosslinking density, and the cured electrolyte matrix can form an effective ion channel, so that the conductivity is improved.
Owner:SHENZHEN NO 1 FINE CHEM CO LTD

Recombinant collagen ionic liquid composition as well as preparation method and application thereof

The invention provides a recombinant collagen ionic liquid composition as well as a preparation method and application thereof, and relates to the technical field of cosmetics. The recombinant collagen ionic liquid composition provided by the invention is prepared from the following components in parts by mass: 19.8 to 79.99 parts of lysine citric acid ionic liquid, 20 to 80 parts of glycerol and 0.01 to 0.2 part of recombinant collagen, the lysine citric acid ionic liquid is mainly composed of lysine and citric acid, and the molar ratio of the lysine to the citric acid is (4-1): (2-1). The recombinant collagen ionic liquid composition is good in solubility, high in transdermal efficiency, small in irritation, short in preparation period, simple in process and capable of being continuously produced.
Owner:CHENGDU ANKEXING TECHNOLOGY CO LTD

Ionic liquid-based modified polyimide nanofiber film and air purification filter screen based on ionic liquid-based modified polyimide nanofiber film

PendingCN119524652AIncrease stretching timeExtend stretching timeMembranesSemi-permeable membranesAir filtrationPolymer science
The invention discloses an ionic liquid modified polyimide nanofiber film and an air purification filter screen based on the ionic liquid modified polyimide nanofiber film, and belongs to the technical field of film filtering materials. The preparation method comprises the following steps: firstly, selecting a diamine monomer and a dianhydride monomer to carry out low-temperature polycondensation reaction, and then carrying out solvent replacement and freeze drying to obtain polyamide acid powder; dissolving the powder to obtain a polyamide acid spinning solution, preparing an ionic liquid / polyamide acid spinning solution on the basis, and carrying out electrostatic spinning to obtain an ionic liquid / polyamide acid nanofiber membrane; and finally, carrying out high-temperature thermal imidization treatment to prepare the ionic liquid / polyimide nanofiber membrane. The method is simple and efficient, the problems of low resistance, high pressure drop and the like of a traditional nanofiber film in air filtration are solved, development and application of the nanofiber film in the field of air filtration are further widened, and the nanofiber film has important scientific significance and application value in the fields of high-temperature filtration, gas adsorption and the like.
Owner:SHAANXI UNIV OF SCI & TECH

Silicon-carbon negative electrode material based on nanocellulose as well as preparation method and application of silicon-carbon negative electrode material

The invention belongs to the field of electrochemistry, and discloses a silicon-carbon negative electrode material based on nanocellulose and a preparation method and application thereof. The preparation method comprises the following steps: dispersing cellulose in deionized water, and carrying out physical stripping and ionic liquid assisted acidolysis to obtain a cellulose colloidal solution; and dispersing the conductive agent and the carbon source into the colloidal solution, adding the coupling agent and the silicon source, and carrying out spray drying and sintering. According to the invention, nano cellulose preparation and silicon carbon preparation processes are combined, so that an intermediate separation process is reduced, and the process is simplified. Meanwhile, in the silicon-carbon balling process, the ionic liquid and the coupling agent in the slurry can induce and promote surface combination of the carbon source and the silicon source; the nano cellulose promotes nano-micro forming of components such as silicon and carbon, and is coupled with the conductive agent in the carbonization process to form an internal conductive network and a coating layer; in the carbonization process, hydrolysis catalyst metal ions play a role in catalyzing gas source cracking deposition to form a stable coating carbon layer. The silicon-carbon material is novel in route, rapid electron transmission and capacity exertion are guaranteed through the conducting layers from inside to outside, and the cycling stability of the material can be improved through the multi-carbon-layer coating structure.
Owner:龙子湖新能源实验室 +1

Epoxy resin-based NTC composite material containing ionic liquid and carbon black as well as preparation method and application of epoxy resin-based NTC composite material

PendingCN120271964AActive agentFirming agent
The invention discloses an epoxy resin-based NTC (Negative Temperature Coefficient) composite material containing ionic liquid and carbon black as well as a preparation method and application of the epoxy resin-based NTC composite material. The preparation method of the material comprises the following steps: mixing the ionic liquid and the epoxy curing agent, heating on a heating table, stirring and mixing at the same time, then adding the epoxy resin, the carbon black, the surfactant and the solvent, mechanically stirring and uniformly mixing, and heating in a vacuum oven to remove the solvent to obtain the material. And then carrying out hot pressing for a certain time through a press vulcanizer at a certain temperature to obtain the epoxy resin-based NTC composite material containing the ionic liquid and the carbon black. The epoxy resin-based NTC composite material containing the ionic liquid and the carbon black has the advantages of high B value, good mechanical strength, high heat conductivity coefficient, high crosslinking density and the like, and the preparation method is simple to operate, mild in reaction condition, low in raw material cost and suitable for large-scale industrial production and application.
Owner:SOUTH CHINA UNIV OF TECH

Ionic liquid catalyst for producing renewable fuel from waste oil as well as preparation method and application of ionic liquid catalyst

The invention discloses an ionic liquid catalyst for producing renewable fuel from waste grease as well as a preparation method and application of the ionic liquid catalyst, and belongs to the technical field of waste grease treatment. The self-synthesized ionic liquid catalyst is adopted to catalyze hydrogenation of the waste oil and fat to produce renewable fuel, impurities in the waste oil and fat can be adsorbed or converted into products, the yield and quality of the products are improved, and a foundation is laid for industrial production of second-generation biodiesel from the waste oil and fat.
Owner:QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI +1

Early-strength high-fluidity geopolymer grouting material and preparation method thereof

The invention belongs to the technical field of civil engineering materials, and provides an early-strength high-fluidity geopolymer grouting material and a preparation method thereof. The method comprises the following steps: firstly, carrying out heat treatment and chemical regulation on fly ash and granulated blast furnace slag to generate a pre-reaction phase with high reaction activity, and improving the alkali excitation reaction efficiency; then, by preparing a lubricating particle dispersion liquid and utilizing the synergistic effect of a silane coupling agent and interface lubricating particles, the uniform dispersity of the particles is enhanced; by adding the ionic liquid and the functionalized acylamino polymer, the dissolution and activation of the aluminosilicate are accelerated by utilizing the high polarity, the ion shielding effect and the dissolution enhancing performance of the ionic liquid; meanwhile, the amido polymer inhibits particle aggregation and stabilizes the particle dispersion state through the adsorption effect, the amido polymer and the amido polymer cooperate to form a lubricating layer in the slurry, reduce the viscosity of the slurry and improve the fluidity, and the early strength of the material is further improved by accelerating the generation of a gel phase.
Owner:ZHEJIANG UNIV OF SCI & TECH

Ionic liquid, electrolyte including the same, and lithium secondary battery including the same

PendingUS20250070226A1Li-accumulatorsOrganic electrolytesReductive decompositionElectrical battery
Disclosed are an ionic liquid, an electrolyte including the ionic liquid, and a lithium secondary battery including the same. The ionic liquid is capable of forming a film having high ionic conductivity on an anode upon reductive decomposition of cations contained therein, and delaying the decomposition of anions.
Owner:HYUNDAI MOTOR CO LTD +1

Method for preparing photosensitive polyion liquid photoelectric device through dispensing

ActiveCN119505155AEasy to manufactureRealize programmatic controlPolymer scienceComputer printing
The invention belongs to the technical field of preparation of isocyanate polymerization products, and discloses a method for preparing a photosensitive polyion liquid photoelectric device through dispensing. The method comprises the following steps: firstly, preparing a photosensitive material and ionic liquid, and carrying out polymerization reaction on the photosensitive material and the ionic liquid to obtain a polyionic liquid photoelectric conversion material; and sequentially printing the first conductive layer, the polyion liquid photoelectric conversion material and the second conductive layer through a microelectronic printer to obtain the photosensitive polyion liquid photoelectric device. According to the invention, the preparation process is obviously simplified, and programmed control and batch production can be realized; and the consistency of photoelectric properties of the device is improved.
Owner:SICHUAN UNIV

Preparation method of metal ion liquid modified co-doped biochar and application of metal ion liquid modified co-doped biochar in tetracycline removal

The invention discloses a preparation method of metal ion liquid modified co-doped biochar and application of the metal ion liquid modified co-doped biochar in tetracycline removal, and belongs to the technical field of water pollution treatment and adsorption material preparation. The preparation method comprises the following steps: mixing a biochar precursor with a metal ion liquid containing transition metal and a heteroatom source, and carrying out high-temperature carbonization to obtain the metal ion liquid modified co-doped biochar. Multiple modification of the biochar is realized through one-time high-temperature carbonization (transition metal elements and heteroatoms are introduced into a biochar skeleton, abundant surface active sites are provided, and the specific surface area and pore volume of the biochar are improved), so that the adsorption performance of the biochar on tetracycline antibiotics is remarkably improved. The preparation method is simple in process, raw materials are easy to obtain, and the obtained metal ion liquid modified co-doped biochar has excellent adsorption performance on antibiotic pollutants such as tetracycline and is suitable for purification treatment of water polluted by antibiotics.
Owner:CHINA AGRI UNIV

Lithium metal battery, manufacturing method thereof and electric equipment

The invention relates to the field of lithium metal batteries, and provides a lithium metal battery, a manufacturing method thereof and electric equipment, which are at least beneficial to improving the interface stability and safety of the lithium metal battery. The manufacturing method comprises the following steps: preparing an initial battery cell, injecting a first electrolyte into the initial battery cell, and then carrying out a first formation process, the first electrolyte comprising the following components: 8-23 wt% of a lithium salt, 0.01-5 wt% of carbon dots, 0.1-10 wt% of lithium nitrate and an ether solvent; a second formation process is carried out after a second electrolyte is injected into the initial battery cell, the second electrolyte comprises the following components: 8-23 wt% of a lithium salt, 5-40 wt% of a film-forming additive and an ionic liquid, and the ionic liquid comprises pyrrolidinium cations.
Owner:JINKO SOLAR CO LTD +1

Gel polymer electrolyte membrane and preparation method therefor, and secondary battery

The present invention relates to a gel polymer electrolyte membrane and a preparation method therefor, and a secondary battery. The gel polymer electrolyte membrane comprises an ionic liquid and a polyionic liquid obtained by polymerizing the ionic liquid. Further provided is a gel polymer electrolyte membrane having both a high ionic conductivity and high mechanical properties.
Owner:EVE ENERGY CO LTD

Preparation method of photocatalytic nanofiltration membrane based on IL-GQDs

The invention discloses a preparation method of a photocatalytic nanofiltration membrane based on IL-GQDs. The method comprises the following steps: pretreating bagasse, and applying the pretreated bagasse and imidazole ionic liquid (IL) to preparation of ionic liquid functionalized graphene quantum dots (IL-GQDs); the IL-GQDs are uniformly distributed on the surface of the base membrane by utilizing a vacuum-assisted low-temperature interfacial polymerization technology to form an ultrathin photocatalytic active layer; and finally, curing and cleaning to obtain the photocatalytic nanofiltration membrane based on the IL-GQDs. According to the prepared IL-GQDs, the membrane surface is endowed with high specific surface area and excellent photocatalytic activity, and meanwhile, an additional water transmission channel can be established under the condition that the pore diameter of the membrane is not changed, so that the problem of trade-off of a traditional membrane is solved. In addition, through combination of low-temperature and vacuum-assisted interfacial polymerization technologies, the membrane structure is more uniform and compact, defects on the surface of the membrane are reduced, and the stability and the anti-pollution capacity of the membrane are improved. The membrane disclosed by the invention shows relatively high water flux, salt recovery rate and long-term stability in water treatment application.
Owner:XIAN UNIV OF SCI & TECH

Ionic liquid additive for solid-state lithium metal battery electrolyte and application of ionic liquid additive

The invention provides an ionic liquid additive for a solid-state lithium metal battery electrolyte and a method for preparing the solid-state lithium metal battery electrolyte by using the ionic liquid additive. The bistrifluoromethanesulfonyl imide salt containing terphenyl and lithium carboxylate obtained through Michael addition reaction is captured by open metal sites of the MOF material UiO-66-NH2, the structural stability of the material can be improved, more transmission channels are provided for lithium ions, and therefore the transference number of the lithium ions is increased, the performance of the lithium metal battery is improved, and the service life of the lithium metal battery is prolonged. Especially in the aspect of charge and discharge rate. The electrolyte material disclosed by the invention has good stability with lithium metal, so that electrolyte decomposition can be prevented, and an unstable phenomenon, such as lithium dendrite growth, on the surface of an electrode can be avoided, so that a lithium metal battery can show excellent electrochemical performance, including better cycling stability, high coulombic efficiency and longer battery life.
Owner:TIANNENG BATTERY GROUP

Ionic liquid type waterborne polyurethane dispersion, and preparation method therefor and use thereof

Disclosed in the present application is an ionic liquid type waterborne polyurethane dispersion, which is characterized in that a cationic waterborne polyurethane dispersion is obtained by grafting a cationic liquid to a waterborne polyurethane resin main body by means of a chemical reaction, wherein the cationic liquid is derived from an ionic liquid alcohol. Further provided in the present application are a preparation method for and the use of the ionic liquid type waterborne polyurethane dispersion. In the present application, the cationic liquid is grafted to the waterborne polyurethane resin main body by means of a chemical reaction, thereby solving the problems of low conductivity and a low lithium ion transference number of a polymer-based electrolyte.
Owner:INST OF CORROSION SCI & TECH

Corrosion-resistant and wear-resistant copper insert and preparation method thereof

The invention relates to the technical field of corrosion resistance, in particular to a corrosion-resistant and wear-resistant copper insert and a preparation method thereof.The copper insert is subjected to plating treatment in an ionic liquid electroplating mode, then the surface of a plating layer is subjected to hole sealing treatment, and a nickel-copper-composite halloysite nanotube layer is electrically deposited on the surface of the formed copper insert; the preparation method comprises the following steps: taking a halloysite nanotube as a nano loader of a corrosion inhibitor, and coating with dopamine to obtain a composite halloysite nanotube; in the hole sealing liquid, the composite halloysite nanotube is used as a filler, silane modified polyurethane is used as a base material, the silane modified polyurethane is a prepolymer synthesized by using isophorone diisocyanate and polytetramethylene ether glycol as raw materials, octylamine ring-opened 3-(2, 3-epoxypropoxy) propyltrimethoxysilane is used as a chain extender, and the silane modified polyurethane is used as the base material. And 2-(perfluorodecyl) ethanol and aminopropyltriethoxysilane are used as end-capping reagents, so as to prepare the high-temperature-resistant coating.
Owner:LINHAI YIHENG COPPER CO LTD

Method for modifying zinc-bromine battery positive electrode material by using ionic liquid bromine complexing agent

The invention belongs to the field of electrochemistry, and relates to a method for modifying a zinc-bromine battery positive electrode material by an ionic liquid bromine complexing agent, which innovates the use mode of the ionic liquid bromine complexing agent as an electrolyte additive in a zinc-bromine battery and performs surface modification on an original carbon electrode. The method comprises the following steps: firstly, treating an electrode to improve the surface hydrophilicity and improve the internal pore structure type of the material; then, the ionic liquid is uniformly distributed on the surface of the electrode and in the internal pore diameter in a dipping-ultrasonic-spraying combined mode, uniform modification of an electrode material is realized, and finally, a total battery is assembled to evaluate the practicability of the experimental strategy. Ionic liquid which can have strong interaction with polybromine species is optimized, the defects that the ionic liquid serving as an electrolyte additive and bromine species generate out-of-phase complexation products to be dispersed in an electrolyte, the utilization rate of active substances is low, reaction kinetics is slow and the like are overcome, and by means of effective attachment of the ionic liquid on the surface of an electrode, the reaction efficiency is improved. Effective fixation of bromine species on the surface of the electrode is achieved, and battery capacity loss caused by the shuttle effect of the bromine species is relieved. The method comprises an original electrode pretreatment method, an electrode material modification method and ionic liquid selection. The zinc-bromine battery prepared by the invention has the advantages of high charge-discharge efficiency, low battery self-discharge rate, fast reaction kinetics and the like.
Owner:ZHENGZHOU ZHONGKE EMERGING IND TECH RES INST +2

Thermal interface material based on vinyl imidazole ionic liquid as well as preparation method and application of thermal interface material

The invention provides a thermal interface material based on vinyl imidazole ionic liquid as well as a preparation method and application of the thermal interface material. The thermal interface material is prepared from the following raw materials: the vinyl imidazole ionic liquid, a heat-conducting filler subjected to surface treatment by a silane coupling agent, an initiator and a cross-linking agent. The thermal interface material is based on the vinyl imidazole ionic liquid and the heat-conducting filler, the limitation of a traditional thermal interface material base body is broken through, dispensing can be achieved, no solvent is needed in the preparation process, the adverse effect of solvent residues on the performance of a chip when the thermal interface material is applied to the chip subsequently can be avoided, and the thermal interface material has ideal interface bonding strength; the heat conduction effect is remarkable and stable, the heat stability is good, the material can be well attached to an interface, the problems of stress concentration, cracks and the like are not prone to occurring, and the material can be widely applied to the heat conduction and heat dissipation fields of aerospace, advanced energy, electronic information, military industry and the like.
Owner:SHENZHEN INST OF ADVANCED ELECTRONICS MATERIALS

Method for recovering bisphenol A and cyclic carbonate by coupling polycarbonate with epoxy compound

The invention discloses a method for recovering bisphenol A and cyclic carbonate by coupling polycarbonate with an epoxy compound, and belongs to the technical field of depolymerization and recovery of high polymer materials. The method comprises the following steps: constructing a reaction system comprising bisphenol A polycarbonate, an epoxy compound, Lewis acid, alkali and ionic liquid; placing the reaction system at the temperature of 70-150 DEG C in an air atmosphere, and carrying out a reaction for more than or equal to 10 min to obtain bisphenol A and cyclic carbonate; wherein the epoxy compound comprises at least one of styrene oxide, 1, 2-epoxypropane, 1, 2-epoxybutane, 1, 2-epoxydodecane, n-butyl glycidyl ether, epoxy propyl phenyl ether, 2-toluene glycidyl ether and 3-(1-naphthyloxy)-1, 2-epoxypropane, and the epoxy compound comprises at least one of styrene oxide, 1, 2-epoxypropane, 1, 2-epoxybutane, 1, 2-epoxydodecane, n-butyl glycidyl ether, epoxy propyl phenyl ether, 2-toluene glycidyl ether and 3-(1-naphthyloxy)-1, 2-epoxypropane; the alkali is inorganic alkali or organic alkali; the method is mild in reaction condition, high in resource utilization efficiency, good in operation safety and high in chemical monomer yield, and has a wide application prospect in the field of waste plastic treatment.
Owner:ZHEJIANG UNIV

Functionalized liquid metal-based temperature response type hydrogel material and preparation method thereof

ActiveCN120574362APolymer scienceLiquid metal
The invention relates to a functional liquid metal-based temperature-responsive hydrogel material and a preparation method thereof, and belongs to the technical field of functional polymer hydrogel materials.The preparation method comprises the following steps that a temperature-responsive hydrogel composite material comprises a hydrophobic association polymer gel and a hydrogel monomer, the hydrophobic association polymer gel comprises a hydrophobic association polymer monomer, a functional filler and an initiator. The functional filler is liquid metal gallium with the edge modified by graphene oxide, and has triple functions: firstly, the functional filler is used as an electrostatic crosslinking node to form a crosslinking network with anionic ionic liquid; secondly, dynamic repair is promoted, and Ga < 3 + > is released to promote dynamic bond recombination. In addition, as a functional filler, the hydrogel is endowed with excellent photo-thermal and electro-thermal conversion performance, and the multi-stimulus response capability is enhanced. The composite material realizes structural assembly by means of hydrophobic association, shows reversible phase change and repeated self-assembly characteristics under various stimuli such as photo-thermal, electric heating, direct heating and the like, and has wide application potential.
Owner:SOUTHWEST PETROLEUM UNIV

Antistatic warm-keeping fiber and preparation method thereof

The invention relates to the technical field of fibers, and discloses an antistatic warm-keeping fiber and a preparation method thereof. The preparation method comprises the following steps: carrying out graft modification on a far infrared material graphene oxide through functionalized POSS, introducing the modified graphene oxide and an ionic liquid into polypropylene, carrying out melt grafting to prepare an antistatic polypropylene master batch, introducing the master batch into polypropylene slices for spinning, and carrying out a synergistic antistatic effect of an inorganic antistatic agent graphene and an organic antistatic agent ionic liquid to prepare a composite material. The prepared fiber has antistatic performance and far infrared heating performance, and meanwhile, the POSS structure with excellent thermal stability is introduced, so that the heat resistance of the fiber is further improved.
Owner:BOSIDENG DOWN WEAR LTD +1