2023 results about "Thermal decomposition" patented technology

The invention relates to the technical field of hydrogen preparation, and provides a hydrogen storage device based on a solid hydrogen storage material and a hydrogen production method thereof.The device comprises a fuel tank internally provided with a reaction cavity used for containing an aluminum hydride material and mixed powder; the heater is arranged on the outer side of the fuel tank; the first end of the water recycling assembly is communicated with the reaction cavity, and the second end of the water recycling assembly is communicated with the fuel cell system so as to recycle water generated by the fuel cell system to the reaction cavity; the first end of the hydrogen discharging assembly is communicated with the reaction cavity, and the second end is communicated with a fuel cell system. According to the hydrogen storage device provided by the invention, through the application of the high-specific-energy solid hydrogen storage material aluminum hydride which can be stored at normal pressure and release hydrogen at a relatively low temperature, the thermal decomposition process of the metal hydride in the fuel tank and the coupling reaction process of the metal hydride and water are optimized, and the hydrogen is produced by utilizing the hydrolysis reaction of the aluminum hydride thermal decomposition reactant simple substance aluminum and the water; meanwhile, thermal decomposition of aluminum hydride is promoted through heat released by hydrolysis reaction, hydrogen release is coupled, and effective utilization of heat is achieved.

The invention belongs to the technical field of catalysts, and particularly relates to a supported catalyst as well as a preparation method and application thereof. The preparation method of the supported catalyst provided by the invention comprises the following steps: mixing soluble transition metal salt, a carrier, an alkaline aqueous solution and water, and dipping to obtain a primary catalyst; the soluble transition metal salt comprises transition metal oxalate, transition metal formate or transition metal citrate; and carrying out microwave roasting on the primary catalyst to obtain the supported catalyst. According to the method, the transition metal salt is used as a roasting precursor, the transition metal is subjected to in-situ reduction in the reducing atmosphere generated during thermal decomposition of the transition metal salt in the roasting process, roasting and reduction are completed through microwave roasting one-step heating, the preparation steps are simplified, and meanwhile energy consumption is reduced. The supported catalyst is used in a catalytic condensation coupling hydrogen transfer reaction, has high conversion rate and coupling product selectivity, and can stably operate for a long time.

The numerical control machine tool base casting machining equipment comprises a forming mold and a casting ladle mechanism, and the forming mold comprises a mold body, a buckling mechanism, an exhaust mechanism and an air extraction mechanism; the casting ladle mechanism comprises a hoisting mechanism, a casting ladle body and a casting ladle driving mechanism. On the basis that casting machining is not affected, gas generated by thermal decomposition of organic matter in coated sand can be effectively and efficiently exhausted, and therefore the defects of air holes, pits and the like of castings are prevented; and the controllability of casting construction can be improved, so that the safety risk of casting construction is reduced.

The invention discloses an environment-friendly high-strength water-stop belt and a preparation method thereof, and relates to the technical field of high-molecular compound composition water-stop belts. The environment-friendly high-strength water-stop belt is prepared from the following components in parts by mass: 100 parts of ethylene propylene diene monomer, 40 to 70 parts of reinforcing filler, 10 to 25 parts of environment-friendly plasticizer, 1 to 5 parts of interface modifier, 1.5 to 3.5 parts of vulcanizing agent, 3 to 8 parts of active agent, 1 to 3 parts of anti-aging agent and 5 to 15 parts of flame retardant. White carbon black and calcium carbonate are adopted as reinforcing filler to replace traditional carbon black, and energy consumption and pollution emission in the production process are remarkably reduced. By optimizing the formula and the preparation process, the tensile strength, the elongation at break, the tearing strength and other mechanical properties of the waterstop are remarkably improved. Aluminum hydroxide is added as a flame retardant, absorbs heat during thermal decomposition and forms a barrier layer, so that oxygen is effectively diluted, and fire spreading is prevented.

The invention discloses a tail gas self-treatment low-emission zero-carbon ammonia hydrogen engine system and a control method, and the tail gas self-treatment low-emission zero-carbon ammonia hydrogen engine system comprises a pure ammonia flameless combustion ammonia decomposition system, a NOx decomposition system, an ammonia hydrogen engine, an air source and an ammonia gas source. The NOx decomposition system utilizes a thermal decomposition technology of nitrogen oxide to realize the reutilization of waste heat of combustion tail gas of the pure ammonia hedging type flameless combustion furnace and decompose the nitrogen oxide in the engine tail gas into nitric oxide, and the ammonia-hydrogen engine utilizes the combustion of the engine to do work, so that the tail gas of the pure ammonia hedging type flameless combustion furnace can be recycled, and the nitrogen oxide in the tail gas of the pure ammonia hedging type flameless combustion furnace can be recycled. Heat utilization of ammonia gas is achieved, and combustion-supporting tail gas needed by the pure ammonia opposite-flushing type flameless combustion furnace is generated.

[Problem] To provide a method for efficiently producing a chemical product from waste tires by improving steps in a series of processes and also efficiently obtaining a carbide. [Solution] Provided is a method for producing a chemical product and a carbide, the method comprising: a thermal decomposition step for obtaining a first gas, a thermal decomposition oil and a residue through thermal decomposition of fragmented waste tires; a carbide recovery step for recovering a carbide from the residue; a low temperature hydrogenation step for subjecting a raw material oil containing at least a portion of the thermal decomposition oil to a low temperature hydrogenation treatment at a temperature of 180-350ºC to obtain a low temperature hydrogenated oil; a hydrocracking step for subjecting a raw material oil that contains at least a portion of the low temperature hydrogenated oil to a hydrocracking treatment at a temperature higher than that in the low temperature hydrogenation treatment so as to obtain a second gas, a light fraction having a boiling point of 350°C or lower and a heavy fraction having a boiling point of higher than 350°C; and a steam cracking step for steam cracking a steam cracking raw material oil that contains at least a portion of the light fraction so as to obtain a chemical product and a raw material for carbide production, which comprises a heavy fraction having a 10% distillation temperature of 190°C or higher. The thermal decomposition temperature in the thermal decomposition is 350-750ºC.

The invention discloses a pyrolysis recovery system for cooperative treatment of waste wind power blades by a power station boiler, and belongs to the technical field of solid waste recovery. The system comprises a power station boiler, a pyrolyzing furnace, a mixed flue, a nitrogen air flue and a controller. Oxygen is accurately controlled by mixing flue gas at different temperature levels and mixing nitrogen, and a safe and stable heat source is provided for the pyrolyzing furnace; pyrolysis gas returns to a boiler hearth through an outlet flue to be burnt out, and recyclable fibers and residues are conveyed out through a chain grate stoker; and the controller is linked with each sensor to execute oxygen control, temperature regulation, fiber quality protection and safety interlocking operation. The problems that in pyrolysis of the waste wind power blade, heat source adaptability is poor, oxygen concentration is out of control, fiber quality is poor, the risk is high, and pyrolysis gas is difficult to dispose are solved, and gradient utilization of energy, intrinsically safe operation, high-quality and high-purity recovery of fibers and collaborative treatment of pollutants are achieved.

The invention discloses a lubricant composition and application thereof in processing of a high-weather-resistance PC hollow plate, and relates to the technical field of lubricant compositions. The lubricant composition comprises the following components in parts by mass: 40-60 parts of base oil, 5-15 parts of a weather-resistant stable additive, 3-8 parts of an anti-wear reagent at extreme pressure, 2-6 parts of a dispersing agent, 1-4 parts of an antioxidant, 0.5-2 parts of a coupling agent and 20-30 parts of a solvent. Through the molecular collaborative design of the polar base oil and the solvent, the thermal decomposition tendency in the processing process is remarkably reduced, and a lubricating system is promoted to be upgraded to a low-volatilization and low-pollution green process direction. A weather-resistant additive molecular skeleton with anti-oxidation and anti-ultraviolet characteristics is innovatively constructed, integration of multiple protection mechanisms in material processing and service stages is realized, and dependence on secondary addition of auxiliaries in a traditional process is reduced.

The invention provides gel with a three-dimensional network structure, a preparation method of the gel and a lithium battery, and belongs to the technical field of lithium batteries. The gel provided by the invention comprises the following raw materials: polyethylene glycol dimethacrylate (PEGDMA) and / or a derivative thereof, a fluorine-containing carbonate compound, a cross-linking agent, a lithium salt, a flame retardant and an organic solvent. The PEGDMA and / or the derivative thereof and the fluorine-containing carbonic ester compound generate a three-dimensional network structure under the action of the cross-linking agent, the fluorine-containing carbonic ester compound can improve the interface stability between the gel and the electrode material, reduce the interface side reaction and improve the thermal stability of the gel, and the performance of the electrode material is improved. Meanwhile, the three-dimensional network structure has relatively high porosity and liquid absorption capacity, so that an ion transmission channel is improved, and the ionic conductivity of the gel is further improved. The room-temperature ionic conductivity of the gel with the three-dimensional network structure is larger than or equal to 3 mS / cm, and the thermal decomposition initial temperature is larger than or equal to 250 DEG C.

To provide a hydrogen production system that can perform aqueous reaction to superheated steam by utilizing high-temperature gas exhausted from a carbonization furnace.SOLUTION: A hydrogen production system 1 that hydrolyzes biomass into pellets by using a continuous-type subcritical water comprises: a carbonization furnace 3 which incompletely burns and carbonizes pellets; a carbonization rate measuring device 31 which measures a ratio of carbide; a superheated steam generator 4 which generates superheated steam; a thermal decomposition furnace 5 which generates thermally decomposed gas; a water gas recovery device 6; and a control device 90, where the carbonization furnace 3 has: an input port 301a into which pellets are input; a housing part 301 which houses the input carbide; an exhaust port 301b which exhausts carbide created by carbonizing pellets; and a carbonization degree evaluation part 313 which evaluates a carbonization degree of the created carbide, where a control device 90 controls an atmospheric temperature inside the housing part 301 such that a ratio of the carbide measured by the carbonization rate measuring device 31 and a carbonization degree evaluated by the carbonization degree evaluation part 313 become constant.SELECTED DRAWING: Figure 1

The invention discloses a method for preparing lithium carbonate from positive electrode material waste liquid, and relates to the technical field of lithium carbonate preparation. Comprising the following steps: adding hydrogen peroxide and sulfuric acid into the positive electrode material waste liquid, and carrying out solid-liquid separation to obtain an iron phosphate / carbon black solid mixture and a lithium-containing solution; adding a flocculating agent into the lithium-containing solution to perform primary impurity removal, filtering, performing secondary impurity removal through electric descaling, and performing suction filtration to obtain a lithium-containing purified solution; heating and concentrating the lithium-containing purified solution to obtain a concentrated solution; a sodium carbonate solution is added into the concentrated solution for a lithium precipitation reaction, and crude lithium carbonate and lithium precipitation mother liquor are obtained; uniformly mixing the crude lithium carbonate with water to obtain slurry, introducing CO2, carrying out hydrogenation reaction under a supergravity condition, and filtering after the reaction is finished to obtain a lithium bicarbonate solution; and carrying out thermal decomposition reaction on the lithium bicarbonate solution under a supergravity condition, adding a nucleating agent at the same time, and after crystals are separated out, carrying out suction filtration to obtain a lithium carbonate product and crystallization mother liquor. According to the method, lithium carbonate is prepared under the supergravity condition, coating and inclusion of foreign ions in the nucleation growth process can be avoided to a great extent, and a lithium carbonate product with relatively high purity is prepared.

The present invention addresses the problem of providing a method for producing olefins that can sufficiently remove polyamides from waste plastics. [Solution] The method for producing olefins according to the present invention includes a thermal decomposition step of thermally decomposing a waste plastic raw material containing polyolefins and polyamides to obtain a hydrocarbon stream, a separation step of separating a thermal decomposition product of the polyamides from the hydrocarbon stream that has undergone the thermal decomposition step, and a catalytic cracking step of catalytically cracking the hydrocarbon stream that has undergone the separation step in the presence of a catalyst containing zeolite to obtain olefins.

The invention relates to a composite solid electrolyte and a preparation method and application thereof. The preparation method of the composite solid electrolyte comprises the following steps: S1, mixing an inorganic filler and a fluorine-containing compound, and reacting at 70-90 DEG C under an acidic condition to obtain an inorganic filler wrapped by a fluorinated layer; then adding a fluorine ion complexing agent and a silane coupling agent for reaction to obtain a modified filler; adding a thermal decomposition type cross-linking agent into the polymer, and carrying out melt blending to obtain a cross-linked polymer; s2, uniformly mixing the modified filler, a cross-linked polymer, a lithium salt and a solvent to obtain a plurality of slurries containing the modified filler with different volume concentrations; and molding the slurry to prepare the composite solid electrolyte. According to the method, the fluorinated layer and the siloxane network are constructed step by step, so that the interface impedance is reduced, and efficient dissociation of the lithium salt is promoted; a three-dimensional network structure is combined, so that the tensile strength is improved; the modified filler is further designed in a gradient manner to improve the lithium ion transference number.

The invention discloses a multi-metal borate nano-particle as well as a preparation method and application thereof. The preparation method comprises the following steps: in the presence of small molecules with alkyl chains, performing high-temperature thermal decomposition on an organic metal compound or a metal salt compound precursor and organic borate in a solvent, and then centrifuging, modifying, performing ultrafiltration, dialyzing and purifying to obtain the multi-metal borate nanoparticles. The preparation method disclosed by the invention has the characteristics of mildness, high efficiency and strong controllability. The multi-metal borate nanoparticles prepared by the preparation method disclosed by the invention have the advantages of monodisperse size, relatively high magnetic property and good biocompatibility. Therefore, the prepared multi-metal borate nanoparticles not only have multi-modal imaging functions such as magnetic resonance imaging, near-infrared two-region imaging, nuclear medicine imaging and magnetic particle imaging, but also can be used for various treatment means such as magnetocaloric therapy and boron neutron capture therapy; potential advantages are realized in biomedical applications such as magnetic targeting tumor treatment and imaging contrast agents, and high practical values are realized.

The invention discloses a gel electrolyte raw material high-temperature mixing device, and relates to the technical field of stirring and mixing, the gel electrolyte raw material high-temperature mixing device comprises a base, the base is fixedly connected with a stirring barrel, the stirring barrel is fixedly connected with a cover plate, the inner bottom of the stirring barrel is fixedly connected with a ring-shaped heating plate, the stirring barrel is internally fixedly connected with a conversion cylinder, and the conversion cylinder is fixedly connected with the cover plate. Through holes which are evenly distributed in the circumferential direction are formed in the side, close to the heating plate, of the conversion cylinder. On the basis of stirring and mixing of the first stirring blades, raw materials flow up and down and are mixed through the spiral conveying frame, the uniform mixing degree of the raw materials is enhanced, the raw materials flow to the low-temperature area through the high-temperature area, the raw materials are integrally and synchronously heated, and local overheating caused by uneven heating is avoided; therefore, thermal decomposition or chemical reaction initiation of some raw materials is avoided, harmful by-products are prevented from being generated, the chemical stability and electrochemical performance of the electrolyte are prevented from being influenced, meanwhile, the phenomena of phase separation and inconsistent viscosity change caused by temperature difference are avoided, and the formation of a non-uniform mixture is avoided.

The invention relates to a chemical mechanical grinding system and method for a hard and brittle semiconductor wafer, and the chemical mechanical grinding method comprises the following steps: preparing an oil-based thermal activity-optical activity composite grinding fluid by adopting an organic thermal decomposition type oxidizing agent, an organic optical decomposition oxidizing agent, polyethylene glycol, glycerol and vegetable oil; building an ultraviolet light-diamond abrasive grinding wheel chemical mechanical grinding platform which has an ultraviolet light irradiation function and is adjustable and controllable in irradiation intensity and ultraviolet light wavelength; the chemical mechanical grinding platform and the minimal quantity lubrication liquid supply device are started, and the wafer to be machined and the diamond abrasive grinding wheel are controlled to rotate relative to each other for opposite grinding; turning on an ultraviolet light generator to accurately irradiate the thermal activity-optical activity composite grinding liquid drops on the surface of the wafer, inducing a thermal decomposition type oxidizing agent and an optical decomposition type oxidizing agent to generate active free radicals by utilizing grinding heat energy and ultraviolet light irradiation energy, and initiating a free radical oxidation reaction of a wafer surface layer material to form an oxidation layer with low interface bonding force; the oxide layer on the surface of the wafer is removed through small-load micro-cutting of the diamond abrasive, and the semiconductor wafer with the subsurface almost free of mechanical damage is efficiently obtained.

The invention discloses a preparation method of modified self-extinguishing insulating oil with flame-retardant and self-repairing functions. Wherein the insulating liquid is mixed oil of mineral oil and palm oil-based modified natural ester, and the inherent high flash point characteristic of the natural ester improves the fireproof safety of the insulating oil. The modified hexagonal boron nitride (h-BN), the magnesium hydroxide nano material and the microcapsule repairing agent are added into the insulating oil, and the h-BN can capture free electrons in the oil, so that the formation and expansion of electric arcs are inhibited, and the breakdown voltage is improved. Magnesium hydroxide is heated to decompose and absorb heat, the fault temperature is reduced, and therefore the arc self-extinguishing effect is achieved. Under the action of a high electric field and a high temperature, the capsule wall of the microcapsule repairing agent is broken, meanwhile, the repairing material is released, a chemical reaction is carried out, and the insulating property of the insulating oil is repaired. The modified insulating oil prepared by the invention has high insulating strength and high flame retardance, and also has a performance self-repairing function, so that the service life of the insulating oil is prolonged.

The invention discloses a method for synthesizing an oxide dispersion strengthened molybdenum-rhenium alloy through a liquid-liquid doping process. The method comprises the following steps that S1, a molybdenum-rhenium mixed solution is prepared; s2, preparing a molybdenum-rhenium-doped mixed solution, namely dissolving precursor nitrate of an oxide into water, and then adding into the molybdenum-rhenium mixed solution; s3, heating treatment is conducted, specifically, the molybdenum-rhenium-doped mixed solution is mechanically stirred, then water is evaporated through heating to obtain a crystallized product, and then the crystallized product is filtered, dried and sieved to obtain composite powder; s4, calcining and thermal decomposition: calcining the composite powder to obtain pyrolysis powder; s5, thermal reduction is conducted, specifically, hydrogen is introduced into the muffle furnace, and the pyrolysis powder is reduced into oxide-doped molybdenum-rhenium alloy powder; and S6, bar preparation is conducted, specifically, the bar is obtained through cold isostatic pressing, high-temperature hydrogen sintering, forging and rotary swaging treatment. The oxide is stably dispersed in the molybdenum-rhenium alloy in a nanoscale form, and the performance of the alloy at the high temperature can be remarkably improved.

The invention provides a method and a system for predicting residual compression strength of a carbon fiber composite material after lightning stroke, and belongs to the technical field of electric digital data processing. According to the method, by considering the pyrolysis degree of the lightning stroke CFRP composite material, the non-linear mechanical property parameters related to the pyrolysis degree actually measured based on the test and the thermal and mechanical damage results predicted based on the electric-thermal-mechanical multi-physics field coupling model are calculated; an actually measured nonlinear mechanical property thermal damage factor and a mechanical damage factor caused by impact damage are introduced into a constitutive relation of the CFRP composite material, and a finite element simulation method capable of quantitatively predicting the residual compression strength after lightning stroke is established by virtue of finite element software ABAQUS; the problems that in the prior art, the influence mechanism of lightning stroke damage on the mechanical property of the CFRP composite material is not clear, and a simulation modeling method capable of being directly used for calculating and predicting the residual compression strength after lightning stroke is lacked are solved.

The invention discloses a glufosinate-ammonium production waste gas treatment device and method, and relates to the technical field of waste gas treatment.The glufosinate-ammonium production waste gas treatment device comprises an adsorption mechanism, an air pipeline and a heating decomposition mechanism, and the adsorption mechanism comprises an adsorption disc and a power structure driving the adsorption disc to rotate; the adsorption disc comprises a plurality of annularly distributed adsorption units; the air pipeline wraps one side of the adsorption disc to form an adsorption area, and the adsorption area is used for adsorbing and filtering pollutants in waste gas in the air pipeline; the heating decomposition mechanism wraps the other side of the adsorption disc to form a desorption area, and the desorption area is used for releasing the adsorbed pollutants from the adsorption unit, decomposing the adsorbed pollutants into harmless substances and recovering the activity of the adsorption unit; the adsorption disc is driven by the power structure to continuously rotate, so that the dynamic switching between the adsorption area and the desorption area is realized, and the continuous operation of waste gas treatment is realized. Dynamic switching between the adsorption area and the desorption area is achieved, pollutants are efficiently captured by adsorption particles in the adsorption unit, shutdown is not needed, and the requirement for continuous operation of glufosinate-ammonium production is met.

The invention relates to the field of multifunctional coatings, in particular to a multifunctional coating based on acrylic resin and a production process of the multifunctional coating. Comprising the following raw materials in parts by weight: 40-60 parts of water-based acrylic resin emulsion, 0.3-0.6 part of a defoaming agent, 3-5 parts of modified nano hydroxyapatite, 0.3-0.5 part of a flatting agent, 2-5 parts of a dispersing agent, 1-3 parts of a curing agent, 3-5 parts of modified nano aluminum oxide and 30-50 parts of deionized water. The grafted chloroprene rubber can improve the interfacial compatibility of the nano-hydroxyapatite and a matrix and endows the coating with wear resistance, and after the nano-alumina is grafted with polybenzimidazole, a benzimidazole ring interacts with the matrix to enhance the interfacial compatibility of the nano-alumina and the matrix, so that the nano-alumina forms a high-temperature-resistant structure in the coating, and the wear resistance of the coating is improved. And the aromatic heterocyclic structure of the polybenzimidazole can endow the coating with higher thermal decomposition temperature, so that the coating has high temperature resistance.

According to the monolithic catalyst packed bed process system and the corresponding method for fluidized carbonate reduction based on the monolithic catalyst, by adopting the monolithic catalyst, full contact of a gas phase, a solid phase and a solid phase is guaranteed, the efficiency of carbonate reduction reaction is improved, and the utilization rate of the catalyst is increased. Meanwhile, the problem of separation of a subsequently generated oxide solid product and a catalyst solid is avoided, and continuous operation of the system is realized. According to the present invention, the heating decomposition reaction of the metal carbonate and the hydrogenation reduction reaction of the in-situ carbon dioxide are coupled, and the monolithic catalyst is adopted to perform catalysis so as to obtain the high-value metal oxide and the synthesis gas or methanol product, and compared with the prior art, the process reaction temperature is substantially reduced so as to easily promote energy saving and emission reduction.

The invention relates to an active and passive integrated fireproof insulation board and a preparation method thereof. The active and passive integrated fireproof insulation board comprises n passive fireproof layers and n or n + 1 active fireproof layers, the passive fireproof layer and the active fireproof layer are laminated into a whole; the passive fireproof layer comprises inorganic fiber felt and aerogel; the aerogel is obtained by curing an adhesive aerogel stock solution, and the stock solution comprises the following components in parts by mass: 1000-4000 parts of silica sol, 50-150 parts of silicate, 10-50 parts of a phosphate adhesive, 5-20 parts of quick lime, 5-50 parts of titanium dioxide, 10-50 parts of calcium stearate, 5-50 parts of a hydrophobic modifier, 5-50 parts of an acid-base regulator and 1000-4000 parts of a solvent; the active fireproof layer is at least one of inorganic fireproof plates such as a gypsum fireproof plate and the like which can actively consume energy after being heated and decomposed. The problems that an existing fireproof insulation board is high in organic matter content, poor in flame retardance and high in hygroscopicity, and the thermal insulation performance and safety are obviously reduced after the fireproof insulation board is used are solved.

The invention discloses a preparation method and application of a bio-based zinc adenine salt environment-friendly PVC heat stabilizer, and belongs to the field of fine chemical synthesis and plastic additive application. The nitrogen-containing organic metal heat stabilizer adenine zinc complex is prepared by taking adenine and zinc acetate as main raw materials through a one-step method. The method is simple and environment-friendly in preparation process, easily available in raw materials and suitable for industrial production. The prepared heat stabilizer zinc adenine is used as a heat stabilizer, can effectively absorb hydrogen chloride generated by PVC thermal decomposition, and can replace allyl chlorine atoms, so that the heat stability of a PVC product is improved, PVC has more excellent heat stability, and the heat stabilizer is expected to replace a traditional commercially available heat stabilizer.

The invention belongs to the field of soft magnetic functional materials, and particularly relates to a low-loss high-superposition Fe-Si-Al magnetic powder core and a preparation method thereof, and the preparation method comprises the following steps: preparing a coating agent, passivating coated powder, bonding and lubricating, and pressing and annealing. According to the method, based on the hydrolysis characteristic of metasilicic acid and the hydrolysis promotion effect of the alkaline catalyst, nano-porous silicon dioxide is prepared as a coating agent, meanwhile, the etching effect of alkaline matter on silicon dioxide can effectively increase the specific surface area of the nano-porous silicon dioxide, and the bonding strength of the nano-porous silicon dioxide and iron-silicon-aluminum powder is improved; the vacuum calcination treatment not only removes residual reagents, but also promotes sufficient thermal decomposition of metasilicic acid into silicon dioxide for in-situ coating, and stabilizes the lattice structure of the metasilicic acid. The coating layer of the low-loss high-superposition Fe-Si-Al magnetic powder core is firm in combination, thin and uniform in thickness and stable and compact in structure, the hysteresis loss of the Fe-Si-Al magnetic powder core can be effectively reduced, the direct-current bias performance is improved, and rising of eddy-current loss is avoided.

The invention discloses a production process of high-purity lithium oxide, and relates to the technical field of lithium oxide preparation. The production process of the high-purity lithium oxide comprises the following steps: mixing lithium hydroxide and hydrogen peroxide with the mass concentration of 90-99%, and carrying out peroxidation reaction to obtain a mixture containing lithium peroxide and lithium hydroxide; carrying out solid-liquid separation on the mixture containing the lithium peroxide and the lithium hydroxide to obtain a supernatant containing the lithium hydroxide and a solid containing the lithium peroxide; and carrying out drying treatment on the supernatant containing the lithium hydroxide to obtain the recycled lithium hydroxide, and carrying out thermal decomposition on the solid containing lithium peroxide in an inert gas protective atmosphere to obtain the high-purity lithium oxide powder. According to the technical scheme, the high-purity lithium oxide is prepared by adopting a process of peroxidizing lithium hydroxide into lithium peroxide and then carrying out thermal decomposition, the powder can be obtained without grinding, and the method has the advantages of high production efficiency, low energy consumption and high raw material utilization rate.

The invention provides a cocatalyst for promoting Fe < 3 + > reduction in the electro-Fenton application process and a preparation method thereof, and relates to the field of wastewater treatment.The preparation method comprises the steps that sodium molybdate, thiourea and coal gasification fine slag are evenly dispersed in deionized water, the mass ratio of sodium molybdate to thiourea is (0.30-2.5): (1.5-3.5), and a mixed system is obtained; the mixed system is subjected to heat preservation treatment at the temperature of 120-180 DEG C, sodium molybdate is subjected to a reduction reaction with thiourea after being subjected to thermal decomposition, nano lamellar cluster-shaped molybdenum sulfide is obtained, and reaction liquid is obtained; sediments in a reaction solution are subjected to microwave drying and freeze drying to obtain the cocatalyst for promoting Fe < 3 + > reduction in the electro-Fenton application process, Fe < 3 + > reduction can be promoted through valence change of molybdenum ions dissolved out of a solution and the unsaturated property of sulfur, and therefore Fenton reaction is enhanced to generate strong oxidizing free radicals to treat organic wastewater.

The invention provides an antibacterial ceramic glaze sintering process optimization and intelligent temperature control method and system. According to the method, the molecular vibration characteristics of the antibacterial agent at different temperatures are dynamically obtained, and a thermal decomposition dynamic fingerprint database is constructed according to the attenuation law of the molecular vibration characteristics; meanwhile, a three-dimensional temperature field of the glaze layer is reconstructed based on a coupling relation between sound wave propagation parameters and glaze thermal expansion. And carrying out transfer learning on the fingerprint database and historical process data, predicting a glaze thermal stability attenuation parameter, and calculating a temperature gradient and molecular chain fracture compensation coefficient. And fusing the temperature field and the attenuation parameter, and dynamically regulating and controlling the sintering temperature curve and preserving heat by combining the compensation coefficient. The adjusted parameters generate closed-loop feedback by verifying the matching degree of the glaze microstructure and the antibacterial indexes, the compensation coefficient is corrected, and it is ensured that the antibacterial performance of the glaze is stabilized within the process allowance. The temperature control precision and the antibacterial performance stability of antibacterial ceramic glaze sintering are improved.

The invention discloses a preparation method of a high-purity ultra-clean hydroxylamine aqueous solution. A four-stage purification process comprises the following steps: 1) low-temperature chelation-ceramic membrane metal removal; 2) molecular sieve membrane rectification decomposition prevention; 3) pulse electrodialysis reversal deep desalination; and 4) gradient filtration terminal refining. According to the preparation method of the high-purity ultra-clean hydroxylamine aqueous solution, a low-temperature molecular sieve membrane rectification technology is adopted, hydroxylamine liquid-phase thermal decomposition is avoided through a vapor phase separation mechanism, and the decomposition rate is reduced to 1t from 15% of a traditional process; the method comprises the following steps of: removing metal through chelation-electrodialysis synergistically, ensuring that Fe and Cu ion residues are less than or equal to 0.05 ppb through a thiosemicarbazide-bipolar membrane system, ensuring the nitrogen environment in the whole process, ensuring that the dissolved oxygen is less than or equal to 5ppb, replacing liquid phase distillation with molecular sieve membrane vapor phase separation, solving hydroxylamine liquid phase thermal decomposition, and breaking through the trace metal removal limit by combining thiosemicarbazide-bipolar membrane synergistically removing impurities. And then through nanoscale terminal filtration, the metal / particle control reaches ppb-level limit which is superior to the SEMI standard, and double spanning of quality and cost is realized.

The invention belongs to the technical field of inorganic powder material modification, and discloses an aluminum hydroxide powder modification treatment method which comprises the following steps: step 1, plasma pretreatment, step 2, in-situ coordination reaction, step 3, nano-composite coating and step 4, post-treatment. The performance of aluminum hydroxide is remarkably improved through a plasma pretreatment-in-situ coordination-nano coating synergistic process, specifically, surface hydroxyl groups are reduced by 45% through plasma treatment, and a contact angle is larger than or equal to 120 degrees, the thermal decomposition temperature is increased by 55 DEG C, and LOI is increased to 31.8% by combining Al-O-P bonding and a SiO-GQDs composite coating layer. According to the process, the energy consumption of the pulse plasma is reduced by 40%, the cost of the spray drying coating process is reduced by 60%, and the GQDs are derived from the graphite waste, so that resource circulation is realized; and the material is non-toxic, has no stripping on a cold-hot cycle interface, meets the green flame-retardant standard, and provides an efficient solution for sustainable development of inorganic fillers.