2106 results about "Interface bonding" patented technology

The invention discloses a flexible fireproof cable and a preparation method thereof, and belongs to the technical field of cables. The cable comprises a conductor, a mica insulation layer, a copper protection layer, a buffer layer and a cable sheath layer. The buffer layer is made of a polyurethane foaming material; the cable sheath layer is prepared from the following components in parts by weight: 80 to 100 parts of methyl vinyl silicone rubber, 18 to 20 parts of modified carbon black, 5 to 8 parts of titanium dioxide, 1 to 2 parts of platinum catalyst, 3 to 6 parts of hydroxyl silicone oil, 0.5 to 1 part of zinc stearate and 0.8 to 1 part of dicumyl peroxide. The modified carbon black is added into the raw materials of the sheath layer, so that the compatibility, the interface bonding force and the flame retardant property of the carbon black and a silicone rubber matrix are effectively improved, and the mechanical property, the wear resistance and the fireproof property of the cable sheath layer are remarkably enhanced.

The invention discloses a special composite enamel coating for a chromium-nickel alloy base material and a preparation method of the special composite enamel coating, when the special composite enamel coating structurally comprises one layer, the special composite enamel coating comprises the following components in parts by mass: 40-65 parts of a basic glass phase, 30-55 parts of a high-melting-point ceramic reinforced phase, 2-10 parts of a thermal expansion coefficient regulator and 0.5-5 parts of an interface bonding accelerant. Compared with the prior art, the enamel coating can achieve nearly perfect thermal expansion coefficient matching with a chromium-nickel alloy matrix, a tough chemical bonding interface is formed, the enamel coating can stably work for a long time in the extreme high-temperature environment of 1,100 DEG C or above, and meanwhile the enamel coating has the excellent abrasion resistance, repeated rapid cooling and rapid heating cycle resistance and thermal shock resistance.

The invention discloses a high-strength wear-resistant self-lubricating drill bit for a coal mine and a preparation method of the high-strength wear-resistant self-lubricating drill bit. The preparation process comprises the steps that a drill bit blank is prepared from low-alloy carbon structural steel, a high-strength and high-toughness matrix is obtained through thermal refining, and then sand blasting activation is conducted to clean and coarsen the surface. After diamond particles are subjected to acid pickling pretreatment, metal modified diamond composite powder is obtained through salt bath metal and reduction prefabrication. The preparation method comprises the following steps: mixing MoS2 with the carbon dioxide, spraying the mixture on the surface of a matrix through high velocity oxy-fuel to form a wear-resistant coating, and then improving the density and interface bonding strength of the coating through high-frequency induction instantaneous remelting, thereby finally obtaining the coal mine drill bit with high hardness, strong bonding force and self-lubricating performance. The metal modified diamond composite coating containing the metal transition layer and the MoS2 lubricating phase is constructed on the steel substrate, and a high-frequency remelting process is combined, so that the wear resistance, the bonding strength and the self-lubricating performance of the drill bit are synergistically improved, and the drill bit has the advantages of high strength and toughness matching and low cost.

The invention belongs to the technical field of metal composite materials and hydrogen storage and transportation materials, and particularly relates to a high-strength hydrogen-embrittlement-resistant layered metal composite material for hydrogen storage and a preparation method and application of the high-strength hydrogen-embrittlement-resistant layered metal composite material. According to the preparation method, the nickel-saving austenitic stainless steel (NEASS) and the 30CrMo steel are alternately overlapped in a multi-layer mode, and the processes of vacuum electron beam welding, high-temperature hot rolling, accumulative ply rolling, multi-stage heat treatment and the like are combined, so that the composite board with the layer number reaching hundreds of layers, firm interface bonding, excellent mechanical performance and good hydrogen embrittlement resistance is prepared; the technical problem that strength, toughness and hydrogen brittleness resistance of an existing metal material in a high-pressure hydrogen environment are difficult to consider at the same time is solved. The obtained composite material has high strength, high plasticity and excellent hydrogen embrittlement resistance, and is suitable for structural materials of high-pressure hydrogen storage tanks, hydrogen conveying pipelines and other key hydrogen energy equipment.

The invention discloses a synchronous temperature control method for co-extrusion molding of a multilayer polymer film, and relates to the technical field of high polymer material processing, and the method comprises the following steps: setting a target temperature interval of each polymer layer of the multilayer polymer film, and according to the melting characteristics, heat sensitivity and interface bonding requirements of each layer of material, setting a target temperature interval of each polymer layer of the multilayer polymer film; respectively determining an extrusion temperature set value and an allowable fluctuation range; through layered independent temperature control and preheating matching, thermal behavior synchronization of multiple polymer melts is achieved, and the interface bonding stability is improved; through a die head heat insulation and buffer structure, interlayer heat interference is effectively shielded, and the integrity of a functional layer is guaranteed; through the intelligent closed-loop temperature control system, the state of each temperature control area is predicted and adjusted in real time, and self-adaptive optimization of thermal control is achieved. And the co-extrusion quality, the consistency and the production intelligent level of the multi-layer film are integrally improved.

The invention discloses a preparation method of a toughening environmental barrier coating, and relates to a preparation method of a coating. The invention aims to solve the problem of poor fracture toughness of the existing environmental barrier coating. The method comprises the following steps: 1, pretreating a base material; 2, preparing a bonding layer; and 3, preparing the environmental barrier layer. The high-melting-point metal silicide prepared on the surface of the base material or the bonding layer compounded by the high-melting-point metal silicide and the rare earth silicate has excellent temperature resistance and good interface bonding strength, and due to the addition of the rare earth silicate, the expansion coefficient of the bonding layer is highly matched with that of the base material; according to the prepared yttrium oxide stabilized zirconia fiber, mullite fiber or silicon carbide fiber reinforced rare earth silicate environmental barrier layer, the fracture toughness of pure Yb2SiO5 is improved to 6.5 MPa.m < 1 / 2 >-8.0 MPa.m < 1 / 2 > from about 1.85 MPa.m < 1 / 2 >. The strengthening and toughening environmental barrier coating prepared by the invention has very important significance on development of thermal protection coatings of hot end parts of aircrafts with high thrust-weight ratios in China.

The invention discloses an injection molding aluminum alloy feed and a preparation process thereof, the feed is composed of aluminum alloy powder and a compound binder, and the aluminum alloy powder is composed of Si, Fe, Cu, Mn, Mg, Zn, Cr, Ti, Co and Al; according to the technical scheme, aiming at the technical problems that a brittle phase is easy to form due to high magnesium and silicon content of the 6013 aluminum alloy, the interface bonding force is poor, the sintering shrinkage is difficult to control and the like due to a stable surface oxide film, and through collaborative optimization of a formula and a process, the high-magnesium-silicon-content high-magnesium-silicon-content high-brittleness aluminum alloy is obtained; the feeding and finished product performance is obviously improved; and the prepared aluminum alloy part has the advantages of high sintering density, high hardness, high tensile strength, high elongation and the like, and can meet the manufacturing requirements of high-end fields such as aerospace and traffic transportation on complex precision parts.

The invention relates to the technical field of metal wire processing, and discloses a high-performance metal wire plastic coating process for aerospace engineering, which comprises the following steps: carrying out base material type selection on a metal wire, and carrying out surface treatment of precise cleaning, etching and depth gradient activation; a Ti-Cr alloy and graphene-copper composite transition layer is deposited through a magnetron sputtering technology, and a multi-layer coating structure is formed through electrostatic spraying of a base coating, a fluidized bed dipping function layer and high velocity oxy-fuel spraying of a nano composite coating in sequence; the molybdenum-gold composite sealing layer is prepared by adopting an electric arc spraying technology, and is subjected to vacuum ultraviolet curing enhancement, high-temperature gradient annealing, gradient sintering and vacuum curing treatment; and heat radiation on the surface of the coating is enhanced through laser-induced micro-nano structure regulation and silicon nitride film sputtering. Through collaborative optimization of base material treatment, coating construction, function strengthening and quality control, the interface bonding strength, the comprehensive performance and the environmental adaptability of the spaceflight metal wire coating are remarkably improved, and the service life of the spaceflight metal wire coating is remarkably prolonged.

The present application relates to the technical fields of laser additive manufacturing, and discloses a kind of metal matrix composite composite additive manufacturing methods, comprising: the mixing of pre-prepared composite powder, substrate pretreatment, laser bottom layer cladding preparation bottom layer structure;Electron beam selective melting additive preparation main functional layer, obtain rough parts;Rough parts post-processing.The present application improves the wettability between metal matrix and TiC reinforcing phase through the transition effect of laser cladding bottom layer and hot isostatic pressing post-processing, improves the interface bonding strength, avoids the interface peeling problem under load;Through laser cladding, realize rapid bottom layer forming, electron beam selective melting ensures high-precision functional layer manufacturing, and is suitable for the integrated manufacturing of complex structure (such as hollow, thin-walled) metal matrix composite parts.

The invention discloses a cable insulating material which comprises the following components in parts by weight: 40-60 parts of low-density polyethylene, 20-30 parts of an ethylene-vinyl acetate copolymer EVA, 2-5 parts of a composite anti-aging agent, 5-10 parts of a core-shell structure nano composite modifier, 1-2 parts of a lubricant, 3-8 parts of a compatilizer, 20-30 parts of a composite flame retardant, 5-10 parts of a nano reinforcing agent and 2-4 parts of phenylsilane. The core-shell structure modifier strengthens interface bonding, and cooperates with the modified nano reinforcing agent to disperse stress, so that the mechanics and high and low temperature resistance are improved; the composite anti-aging agent inhibits multi-path aging and improves the aging resistance. The material has the advantages of excellent mechanical properties, high and low temperature resistance and outstanding aging resistance, and meets the insulation quality and efficiency requirements of cables in complex use environments.

The invention discloses a copper-molybdenum alloy component and a manufacturing method thereof, and belongs to the technical field of alloy manufacturing. Mo powder is sequentially subjected to vacuum drying treatment, oxidation-reduction treatment and coating treatment, so that the Mo powder has good flowability and powder laying uniformity; under the preset 3D printing condition, the porous Mo framework which is stably formed and complex in structure can be obtained, the problems that an existing rolling composite method is complex in technological process, strict in technological requirement and the like are solved, and the method is suitable for manufacturing parts with small sizes or complex shapes; the porous Mo framework is subjected to vacuum thermocuring and Cu infiltration treatment, and the obtained copper-molybdenum alloy component is excellent in compactness, high-temperature stability, interface bonding strength, heat conduction, electrical conductivity and the like. The problems that a copper-molybdenum alloy obtained in the prior art is poor in wettability and low in density and uniformity, and the mass content of copper is lower than 30%, so that the heat conductivity, the electric conductivity, the air tightness and other performance are low are solved.

The invention relates to the technical field of electrode paste, in particular to electrode paste for a submerged arc furnace and a preparation method of the electrode paste. Comprising three-level grain size distribution anthracite aggregate which is electrically calcined at high temperature and modified by a KH-550 silane coupling agent, a modified silicon carbide whisker and boron-doped graphene-like carbon nitride composite filler, a maleic anhydride-mediated compatible medium-temperature pitch-polyborosiloxane binder and a graphite powder-borax functional additive. A step-by-step mixing and two-stage sintering process is adopted in the preparation process, a covalent bond interface bridging structure is constructed through the coupling agent, the composite dispersing agent regulates and controls the multi-dimensional network distribution of the filler, and the process synergistically improves the compactness and the interface bonding force of the green body. The electrode paste is firm in interface bonding, can form a ceramic protective phase at a high temperature, has excellent conductivity and mechanical strength, and prolongs the service life of the electrode paste for the submerged arc furnace.

The invention discloses a high-resilience eTPU foaming material and a preparation process thereof, and belongs to the technical field of foaming materials. The process comprises the steps of raw material premixing and TPU chain extension reaction, precursor system injection, in-situ phase change energy storage core-shell particle generation, supercritical two-fluid foaming and molding post-treatment. Wherein the SiO2-coated TiO2 core-shell particles are prepared by a non-hydrolytic sol-gel method, the porous SiO2 core adsorbs and fixes the micro-crosslinked polyurethane-based phase change material, the TiO2 shell provides sealing and supporting, the particles are combined with the TPU matrix through covalent bonds, and the micro-crosslinked polyurethane-based phase change material has a unique micro-crosslinked network structure, so that the thermal conductivity of the TPU matrix is improved, and the thermal conductivity of the TPU matrix is improved. The hidden danger of leakage of the phase change material in the using process can be effectively eliminated, and meanwhile the interface bonding effect between the inorganic particles and the TPU matrix is synchronously enhanced. The eTPU foaming material prepared by the invention has the characteristics of high resilience, strong interface bonding, excellent energy storage stability and low compression set, and is suitable for shoe materials, automotive interiors and other scenes.

The invention discloses a UV curing adhesive for coating a low-refractive-index optical fiber and a processing method thereof, belongs to the technical field of adhesive preparation, and is used for solving the technical problem that the refractive index and the damp-heat resistance of the UV curing adhesive for coating the optical fiber in the prior art need to be further improved. The preparation method comprises the following steps: introducing a low-refractive-index hybrid siloxane prepolymer, a multi-component interface bonding prepolymer and a modified branched polyester prepolymer into a system together, and constructing a compact and uniform organic-inorganic three-dimensional network in a curing process by utilizing silica condensation, interface chemical bonding and a flexible chain segment cross-linking reaction, the low-refractive-index hybrid siloxane prepolymer endows a film layer with a stable refractive index, the multi-component interface bonding prepolymer enhances the binding force of a base material, the modified branched polyester prepolymer improves stress buffering and toughness, and the obtained cured film is low in refractive index, firm in interface bonding and small in mass change in a humid and hot environment and shows excellent optical stability and long-term reliability.

The invention relates to the technical field of basalt fiber reinforced composite material pipelines and preparation methods thereof, and discloses a pipeline named as a basalt fiber reinforced composite material pipeline and a preparation method thereof and a preparation method thereof. The invention aims to overcome the defects of continuity, interface bonding and mechanical properties of the conventional basalt fiber reinforced composite material pipeline. The pipeline is composed of a lining layer, a basalt fiber winding reinforcing layer and an outer protective layer, the reinforcing layer is formed by compounding basalt fiber bundles subjected to surface treatment and a resin matrix, and the reinforcing layer is of a multi-layer structure with different winding angles. The preparation method comprises the following steps: roughening the inner lining layer, infiltrating and accurately winding the fiber bundles, performing multi-section curing and forming the outer protective layer. According to the scheme, the macroscopic mechanical property of the pipeline is remarkably improved, the interface combination of fibers and a matrix is optimized, the integrity of the fibers is kept, efficient preparation is achieved, and the pipeline has the advantages of being excellent in corrosion resistance and ultraviolet resistance, long in service life and the like.

The invention discloses self-repairing concrete based on modified carbon fibers and a preparation method thereof, and belongs to the technical field of building materials. An existing concrete crack repairing technology has two major problems that bonding between carbon fibers and a matrix is poor, and the repairing effect is limited; microbial self-repairing and nutrient adding can reduce the strength of the concrete. According to the solution provided by the invention, firstly, the surface of the carbon fiber is modified by an MICP method to form a stable three-dimensional calcium carbonate coating layer, so that the surface roughness is enhanced, the interface bonding capacity of the carbon fiber and a gelling matrix is greatly improved, and the carbon fiber is stably attached to an interface; then, the modified carbon fibers and concrete raw materials are accurately mixed according to a specific proportion, and the high-strength and good-crack-resistance self-repairing concrete is prepared. When cracks are generated, the carbon fibers limit crack propagation with high strength and high ductility, and surface microorganisms generate calcium carbonate through physiological reaction to fill the cracks; the strength, crack resistance and self-repairing capacity of a concrete structure are improved, the service life is prolonged, and the concrete is suitable for a hydraulic concrete structure in a complex environment and wide in application prospect.

The invention discloses a high-temperature-stripping-resistant epoxy structural adhesive as well as a preparation method and application thereof, and belongs to the technical field of high-performance composite materials. The epoxy structural adhesive comprises bisphenol A type epoxy resin, novolac epoxy resin, polysiloxane-polyurethane modified epoxy resin, core-shell modified epoxy resin, PEEK ultrafine powder and other components, and through mutual cooperation of all the components, the problems that in a high-temperature service environment, the adhesive layer modulus of traditional adhesive is rapidly attenuated, and a bonding interface is prone to failure are solved; the epoxy structural adhesive provided by the invention has both rapid curing and heat resistance, is stable in interface bonding, has the highest modulus of 1.28 GPa at 80 DEG C, the highest peel strength of 7.8 N / mm at 80 DEG C, and a damage mode of cohesion or high-proportion mixed damage, and is especially suitable for structural bonding requirements of harsh scenes such as peripheral structures of automobile engines, high-temperature areas of electronic equipment and the like.

The invention provides a sulfide solid electrolyte with an MOF structure, and a preparation method and application thereof, the process is designed from a molecular level, and lithium ions and sulfur elements are used as basic components for constructing an MOF skeleton through in-situ combination of excellent ion conduction capability of the sulfide electrolyte and structural advantages of an MOF material; the bulk sulfide electrolyte with a regular three-dimensional multi-channel crystalline MOF structure is directly synthesized and constructed by taking a sulfur element as an inherent component of an MOF skeleton in a breakthrough manner, so that the intrinsic design of the sulfide MOF skeleton electrolyte is realized, and the problems of interface bonding, performance stability and ion transmission path are fundamentally solved; a sulfur element in the electrolyte is derived from sulfur atoms (such as-SH and-S-) of a ligand and participates in construction of an MOF skeleton, the electrolyte has the advantages of good interface stability, regular ion transmission channels, adjustable mechanical properties and the like, and the problems of poor interface stability, irregular ion transmission paths and the like of a sulfide electrolyte in the prior art are solved.

The invention relates to the technical field of bridge load tests, and provides a bridge load test crack increment change observation method and system, and the method comprises the steps: collecting prestressing tendon circumferential strain distribution data and dual-wavelength strain response data; calculating an interface bonding stiffness change parameter; pre-stress modulation effect compensation and polar coordinate system conversion are carried out on the strain response data and the rigidity change parameters, and micro-crack characteristic signals are obtained; load data and beam group arrangement parameters are collected, and a micro-crack propagation prediction model is established in combination with the interface bonding stiffness change parameters; inputting the micro-crack characteristic signal into a micro-crack propagation prediction model, and outputting a micro-crack development trend prediction result; and adjusting sampling parameters of a dual-wavelength time division multiplexing algorithm and characteristic extraction parameters of prestress modulation effect compensation according to a micro-crack development trend prediction result. According to the invention, the precision of observing the increment change of the micro-crack in the bridge load test is improved, and the automatic monitoring and prediction of the micro-crack of the prestressed concrete bridge are realized.

The invention discloses a fiber-reinforced thermoplastic resin-based composite material based on dynamic reversible interface interaction and a preparation method and a recycling method thereof. The fiber-reinforced thermoplastic resin-based composite material comprises a modified thermoplastic resin matrix and a modified fiber reinforcement which are compounded with each other, the modified thermoplastic resin matrix and the modified fiber reinforcement are bonded and connected through dynamic bonds with dynamic reversible interface interaction. Through construction of dynamic reversible interface interaction in the fiber-reinforced thermoplastic resin-based composite material, infiltration compounding and interface bonding between a fiber reinforcement and a high-viscosity thermoplastic resin melt can be enhanced, and interface debonding and total-value recycling of the fiber reinforcement in the composite material recycling process can be effectively promoted; therefore, the bottleneck problems of poor wettability in the forming process, low bonding fastness at a heterogeneous interface, insufficient mechanical properties, low waste recovery value and the like confronted by the development of the fiber-reinforced thermoplastic composite material are effectively solved.

The application relates to the technical field of composite materials, and particularly discloses a carbon fiber / epoxy electromagnetic shielding composite material with strong interface bonding and a preparation method thereof, which comprises the following steps: hydrothermal reaction of oxidized carbon fibers O-CF, an organic ligand and an iron source in a solvent, washing and drying of the fibers to obtain MIL-loaded carbon fibers, carbonization treatment to obtain iron-based oxide-loaded carbon fibers dF@CF, vacuum-assisted introduction of epoxy resin into the multilayer carbon fibers dF@CF, and curing to obtain the carbon fiber / epoxy electromagnetic shielding composite material. The organic ligand and trivalent iron ions are used to synthesize a large number of rhombic MILs on the active sites on the surface of the carbon fibers, the MILs are reduced into iron-based oxide nanoparticles after carbonization, the iron-based oxide nanoparticles are closely loaded on the surface of the carbon fibers, the interface bonding performance is improved, the electromagnetic shielding efficiency is increased, and the carbon fiber / epoxy composite material with both the interface and the electromagnetic shielding efficiency is realized.

The invention discloses an additive manufacturing method for in-situ regulation and control of a TiB / TiC titanium-based heterostructure through laser deposition, and belongs to the technical field of composite material preparation. According to the method, laser path planning is carried out based on three-dimensional modeling and layered slicing; the preparation method comprises the following steps: ball-milling and mixing titanium alloy powder, nano boron carbide powder and trace rare earth powder according to a specific proportion, and carrying out vacuum drying; and addition of trace rare earth is beneficial to grain refinement and improvement of reinforcement phase distribution and interface bonding. Under the action of a high-energy laser beam, the mixed powder is fused in an argon protective atmosphere, an in-situ reaction is carried out at the same time, and TiB and TiC reinforced phases are generated; the gradient component design can be implemented in the laser deposition process, specifically, the powder feeding proportion of B4C powder is dynamically controlled through a program, the gradient of the B4C powder is increased from the bottom layer to the surface layer in the direction perpendicular to the substrate, and therefore the gradient heterostructure with the enhanced phase content and performance gradually changed is formed. According to the method, the problems of non-uniform reinforcement phase distribution, obdurability mismatch, plasticity loss and the like in a traditional method are solved, the prepared composite material or gradient component has high strength (the tensile strength reaches 987.66 MPa) and good plasticity and toughness matching, no crack defect exists, and the method is suitable for manufacturing of high-performance parts in the fields of aerospace and high-end machine manufacturing.

The invention belongs to the technical field of continuous basalt fiber impregnating compounds, and particularly relates to an impregnating compound of a modified basalt fiber reinforced nylon composite material as well as a preparation method and application of the impregnating compound. The impregnating compound comprises the following effective components in percentage by mass: 70%-90% of a film-forming agent, 4.0%-8.0% of an organosilane coupling agent, 0.1%-1.5% of a lubricating agent, 1.0%-10% of a dispersing agent, 0.1%-1.0% of a wetting agent and 3%-10% of nano particle oxide. Related tests verify that the ablated basalt fiber which is not effectively treated is smooth in surface, and the nylon composite material reinforced by the ablated basalt fiber is in a state that the fiber is loosely bonded with a resin matrix and the surface is clean after the fiber is pulled out at a fracture interface, which shows that the interface bonding force is extremely weak and the stress transmission efficiency is low. Compared with the prior art, the basalt fiber treated by the nano ZnO modified impregnating compound provided by the invention has the advantages that the section form of a reinforced composite material is fundamentally improved: the fiber and resin interface bonding is very tight, and the fiber surface is coated by a large amount of resin, so that the obvious improvement of the interface bonding strength is clearly revealed.

The invention relates to the technical field of foaming, and discloses a multi-layer co-extrusion foaming buffer cotton continuous production forming process which comprises the following steps: pretreating raw materials, respectively placing polyolefin resin, biodegradable polyester and foaming agent master batch in a vacuum drying oven, drying at 60 + / -5 DEG C for 2-4 hours, controlling the water content to be less than 0.1 wt%, melting and co-extruding to obtain the multi-layer co-extrusion foaming buffer cotton. When multi-layer co-extrusion synchronous foaming is carried out, by establishing a melt pressure dynamic threshold standard and setting differential pressure control parameters for different functional layers, the stability of interface bonding of all co-extrusion layers is guaranteed, and meanwhile, melt pressure fluctuation in the supercritical fluid injection process is subjected to feedback analysis in real time; according to the method, whether the problem of abnormal fluctuation of melt pressure occurs on a co-extrusion layer interface or not can be detected in real time, the structural integrity of interlayer bonding is guaranteed, the risk of cell collapse is further reduced, and when foaming ratio mismatch is detected, temperature field distribution can be adjusted in real time according to preset gradient foaming parameters.

The invention relates to a flame-retardant PVC material for a drag chain cable and a preparation method of the flame-retardant PVC material, and belongs to the technical field of cable materials. According to the invention, the flame-retardant compatibilizer is prepared, a trichlorophenyl structure in the flame-retardant compatibilizer has good compatibility with a PVC phase, and a siloxane structure in the flame-retardant compatibilizer can be crosslinked with siloxane in a modified TPU master batch in a heat treatment crosslinking process, so that the compatibility with a TPU phase is improved; the flame-retardant component is creatively used as a third component compatibilizer, so that the problem of non-uniform dispersion of the flame-retardant component in the PVC / TPU composite material is solved, the interface bonding force of a PVC phase and a TPU phase is effectively improved, the modification effect of TPU on PVC is improved, and the finally obtained flame-retardant PVC material has more excellent dynamic adaptability and environmental tolerance.

The invention relates to a comprehensive optimization method and system for thermal conductive plastic performance in the technical field of new materials, and the method comprises the following steps: obtaining initial dispersion state data of an inorganic filler in thermal conductive plastic, and analyzing spatial distribution of filler particles through a scanning electron microscope to obtain characteristic parameters of random distribution of the filler; according to the characteristic parameters of the random distribution of the filler, calculating the heat transfer efficiency among filler particles by adopting a finite element simulation method, and determining the distribution rule of the phonon scattering phenomenon; according to the improved interface bonding strength parameters, the Monte Carlo method is adopted to simulate orientation distribution of filler particles in a matrix, and a preliminary scheme of filler orientation control is obtained; for optimization parameters of complex mold forming, a particle swarm optimization algorithm is adopted to adjust the filler proportion and distribution, and the structure configuration of the efficient three-dimensional heat conduction network is generated; and according to the structure configuration of the efficient three-dimensional heat-conducting network, the improvement degree of the heat-conducting plastic performance is analyzed and verified through a heat-conducting finite element, and final heat transfer efficiency data is obtained.

The invention relates to a waterproof sealing gasket material for a shield tunnel and a preparation method of the waterproof sealing gasket material. The preparation method comprises the following steps: plastifying raw rubber to obtain plastified raw rubber; the preparation method comprises the following steps: stirring and mixing plasticated raw rubber, carbon black N550, calcium carbonate, paraffin oil, zinc oxide, stearic acid, calcium oxide, an anti-aging agent and an organic magnesium compound, mixing in a mixing mill, and cooling to room temperature to obtain a mixture I; stirring and mixing the mixture I, modified NPE particles and an accelerant, mixing, and cooling to room temperature to obtain a mixture II; uniformly mixing the mixture II and sulfur in a mixing mill, vulcanizing at high temperature, and standing at room temperature for 24 hours to obtain the waterproof sealing gasket material. According to the waterproof sealing gasket material, the modified NPE particles of the core-shell structure are added, the compatibility of a water-swelling material and non-polar rubber is improved, the organic magnesium compound is added as a multifunctional auxiliary agent, the interface bonding, vulcanization network and flame retardant performance are synergistically improved, and the waterproof sealing gasket material has good waterproof performance. The prepared sealing gasket material has excellent mechanical properties, heat aging resistance, compression set resistance and flame retardance.

The invention discloses a high-specific-gravity and high-toughness tungsten-nickel-copper material and a preparation method thereof, and belongs to the technical field of non-ferrous metal materials. The material comprises the following components in percentage by mass: 6-15% of nickel; 2-5% of copper; 2-5% of manganese, and the balance tungsten and inevitable impurities. The preparation method of the material comprises the following steps: preparing materials (pure tungsten powder, pure nickel powder, pure copper powder and pure manganese powder), mixing the powder, pressing, sintering, and carrying out recrystallization annealing heat treatment. In the burdening step, two kinds of tungsten powder with different particle size grades are selected and added, and the gradient particle size ratio is adjusted. By adding the strengthening element manganese, combining the gradient particle size ratio and enhancing interface bonding, the high specific gravity and high strength of the material are kept, meanwhile, excellent toughness can be kept, and the material is suitable for aerospace gyroscope rotors and balance weight parts, electronic industry precise instrument parts, medical instrument ray shielding materials and national defense military industry kinetic energy armor-piercing weapon parts.

The invention discloses a preparation method of heat-conducting silica gel for packaging a power module chip, which comprises the following steps of: optimizing diamond micro-powder filling, surface etching and particle size compounding, so that the heat conductivity coefficient of the prepared heat-conducting silica gel can reach 3.8-4.5 W / (m.K) which is far higher than that of common silica gel (generally less than or equal to 3.0 W / (m.K)); meanwhile, the specific surface area of the diamond and the interface bonding force between the diamond and silica gel are improved through surface etching, the interface thermal resistance is reduced, a more efficient heat conduction path is formed, the packing stacking density is maximized through particle size compounding, air gaps are reduced, and a more stable and communicated heat conduction network is constructed; the SiC device is high in power density and high in switching speed, and the chip junction temperature is the key to restrict performance and reliability. The material can quickly and uniformly transfer heat of a chip to a heat dissipation substrate, obviously reduce junction temperature and temperature gradient in a module, and improve power density and long-term reliability.

The embodiment of the invention provides a plastic-coated steel pipe and a plastic coating process thereof, and relates to the technical field of plastic-coated steel pipes. The plastic-coated steel pipe comprises a steel pipe base body, a metal transition layer, an inner anticorrosive coating, a fiber reinforced winding layer and an outer protective coating are sequentially arranged on the outer surface of the steel pipe base body from inside to outside, and the metal transition layer is a nickel-chromium-aluminum-yttrium alloy layer and is formed on the surface of the steel pipe base body through a supersonic plasma spraying process. And the inner anticorrosive coating is formed by a mixture of bisphenol F type epoxy resin and novolac epoxy resin, and is doped with silicon nitride and zirconium oxide composite nanoparticles subjected to surface treatment. By arranging a multi-stage composite structure of the metal transition layer, the high-temperature-resistant anti-corrosion coating, the fiber reinforcement layer and the self-repairing outer layer and arranging the detachable heat insulation sheath, the interface bonding strength, heat resistance, mechanical damage resistance and corrosion resistance of the plastic-coated steel pipe are improved; and the service life of the composite material in high-temperature, strong-corrosion and complex construction environments is effectively prolonged.