The invention relates to the field of free radical
solution polymerization programmed
monomer supplementation, in particular to a
polyacrylonitrile spinning solution with an adjustable
molecular sequence and a preparation method thereof.The preparation method comprises the steps that
polymerization solution formula components and dosage ranges are determined, and the components comprise
acrylonitrile,
itaconic acid,
methyl methacrylate or fumaramide and the like; the thermodynamic
reaction temperature ranges from 60 DEG C to 66 DEG C, the total
monomer concentration ranges from 18 wt% to 26 wt%, and the initiator concentration ranges from 0.072 wt% to 0.103 wt%. When preparation is started, all components except for partial
itaconic acid are added, then
itaconic acid is supplemented in batches, and the supplementing time and the proportion range interval can be calculated according to a specific formula. The itaconic acid is supplemented in a manner of body
nitrogen blowing or metered addition after
dissolution, and the solution concentration is less than or equal to 55wt%. According to the method, the
molecular sequence can be accurately regulated and controlled, the homogeneity of the
copolymer is improved, heat release in the
polymerization process is uniform, a stable environment is provided for industrial production, meanwhile, a
reaction system is optimized, and the reaction efficiency and the product yield are improved.