3696 results about "Ammonia" patented technology

The invention relates to the technical field of industrial flue gas purification, and discloses a flue gas denitration pollution reduction and carbon reduction method and system based on model prediction control. The method comprises the following steps: collecting flue gas data through a sensor to obtain a flue gas distribution state; the state is processed through a preset model, and a nitrogen oxide concentration predicted value is determined; judging a regulation and control demand based on the predicted value and generating an adjustment coefficient sequence; calculating an opening value of an ammonia spraying distributor by adopting a particle swarm optimization algorithm, and determining ammonia spraying amount distribution; a control instruction is sent according to ammonia spraying amount distribution, and a temperature uniformity index is evaluated based on temperature feedback data; adjusting optimization algorithm parameters according to the indexes, and generating an optimized ammonia spraying strategy; updating the predicted value and determining the stable range of the denitration efficiency; verifying the ammonia escape concentration in the stable range to obtain a system performance index; and forming a continuous regulation and control sequence according to cyclic feedback of the indexes. According to the invention, accurate dynamic regulation and control of ammonia spraying amount are realized, denitration efficiency and system stability are effectively improved, and the risk of ammonia escape is significantly reduced.

The invention discloses a denitration system inlet nitric oxide disturbance and super-emission control method and system, and the method comprises the steps: adjusting the operation oxygen amount and the over fire air ratio in real time based on the measured values of the carbon monoxide concentration and the nitric oxide concentration of the denitration system inlet; based on denitration system operation data, combining actual sampling delay time to carry out sample data alignment and construct a training sample set; constructing a prediction model based on the training sample set, obtaining a nitrogen oxide concentration prediction value of the inlet of the denitration system through the prediction model, and updating the prediction model in real time; based on the difference between the average value of the outlet nitrogen oxide concentration of each partition and a set value and the difference between the concentration value of the nitrogen oxide at the outlet of the denitration system and the set value, and by combining the predicted value of the nitrogen oxide concentration at the inlet of the denitration system, treatment measures after the nitrogen oxide concentration super-emission are set in a segmented mode. The control performance of the denitration system can be improved, the ammonia spraying amount is reduced, the ammonia escape concentration is reduced, and the system automation input rate is increased.

The invention discloses a large-scale pig breeding wastewater purification treatment system, and relates to the technical field of wastewater treatment.The large-scale pig breeding wastewater purification treatment system is characterized in that the ion concentration of anaerobic liquid is monitored through a multi-ion sensing array, and a multi-channel feeding system is controlled to synthesize customized struvite compound fertilizer; the AI prediction control unit predicts the optimal medicament dosage and realizes millisecond-level closed-loop regulation; the multi-dimensional synergistic biochemical treatment module comprises an A / O biochemical treatment unit and an electric field enhanced anaerobic ammonia oxidation reactor, the electric field enhanced anaerobic ammonia oxidation reactor applies a direct-current electric field through an electrode pair, and engineering conductive biochar is used as a carrier to accelerate microbial metabolism; the sludge low-temperature pyrolysis self-consistent circulation module is used for pyrolyzing and converting residual sludge into biochar, biofuel and wood vinegar, and the biochar activation treatment unit is used for preparing engineering conductive biochar and forming a substance closed loop through a self-consistent circulation conveying system; and the digital twinning intelligent management and control platform realizes intelligent management and control of the system.

The invention provides a treatment method of ammonia-nitrogen-containing wastewater, and belongs to the technical field of wastewater treatment. The preparation process comprises the following steps: preparing the wastewater treatment agent; preparing an immobilized microbial compound; and treating the ammonia-nitrogen-containing wastewater. According to the immobilized microbial carrier prepared by the invention, a stable dual-network structure and proper pore channels are formed through the synergistic effect of the polyvinyl alcohol, the carboxymethyl chitosan and the polyurethane; secondary cross-linking significantly enhances the stability of the carrier, optimizes internal pore channels, and is beneficial to attachment and proliferation of microorganisms; after the corn straw biochar is modified by Ca / Al, the specific surface area and functional groups are increased, and the physicochemical adsorption of ammonia nitrogen is enhanced. The three are combined, and ammonia nitrogen in wastewater is efficiently removed through synergism of carrier adsorption and microbial metabolism.

The invention discloses a river nitrogen pollutant source analysis method based on drainage basin nitrogen turnover and isotope, and particularly relates to the technical field of water treatment.The river nitrogen pollutant source analysis method comprises the following steps that a drainage basin to be researched is selected, river water and soil samples in the drainage basin are systematically collected, and physical and chemical indexes and isotope indexes # imgabs0 # of the collected samples are tested. Nitrate marked by nitrogen isotope delta 15N / delta 18O and # imgabs1 # are used as key indication marks to perform high-precision identification on nitrogen sources in a river and an environmental system, the contribution proportion of different nitrogen sources to the nitrate concentration in a water body is quantified through a stable isotope analysis model, and the concentration of the nitrate in the water body is calculated. And in combination with data, the rates of denitrification and anaerobic ammonia oxidation in environmental samples, sediments and soil are directly measured through combined application of an isotopic tracer technology and a membrane inlet mass spectrometer technology.

The invention discloses an A-site high-entropy solid oxide fuel cell cathode material as well as a preparation method and application thereof, and provides an A-site high-entropy solid oxide fuel cell cathode material Pr < 0.2 > M < 0.2 > La < 0.2 > Ba < 0.2 > Sr < 0.2 > Co < 0.8 > Fe < 0.2 > O < 3-delta > with a perovskite phase. The preparation method comprises the following steps: S1, weighing multi-element metal nitrates, and mixing to obtain a first mixed solution; s2, dissolving ethylenediamine tetraacetic acid in ammonia water to obtain a second mixed solution; mixing the first mixed solution, the second mixed solution and citric acid to form a mixed precursor solution; s3, carrying out second heating treatment on the mixed precursor solution, and adjusting the pH value to form a gel precursor; and S4, carrying out pre-sintering treatment, third heat treatment and calcination treatment on the gel precursor to obtain a high-grade powder precursor, and carrying out ball milling and sieving treatment to obtain the A-site high-entropy solid oxide fuel cell cathode material. The cathode material is high in stability and good in chemical compatibility with a barrier layer GDC, provides high-quality mass transfer channels and active sites for O2 / O- / O2-, and has good electrochemical performance at medium and low temperatures.

The invention relates to a continuous flow AOA whole-course anaerobic ammonia oxidation self-enrichment enhanced denitrification system and method, and the system comprises a front anoxic tank, an aerobic tank and a rear anoxic tank which are connected in series, and is filled with a biological filler; the monitoring aeration device comprises an ammonia nitrogen detector and an aeration unit which are connected with the aerobic tank; the reflux device is used for communicating a reflux outlet of the rear anoxic tank with water distribution of the front anoxic tank; and the PID control unit is connected with the monitoring aeration device, the backwashing control valve and the reflux device. The method comprises the following steps: sewage flows into the front anoxic tank, the aerobic tank and the rear anoxic tank; regulating and controlling the reflux ratio to domesticate the biological membrane of the aerobic tank; the ammonia nitrogen concentration of effluent of the aerobic tank is detected in real time through an ammonia nitrogen detector, and the PI D control unit dynamically adjusts the aeration rate of the aerobic tank according to the ammonia nitrogen concentration value and a preset target value, so that the aerobic tank and the rear anoxic tank form an anaerobic ammonium oxidation bacteria self-enrichment environment; the backflow device is used for enabling effluent of the rear anoxic tank to flow back to the front anoxic tank according to a preset proportion, so as to form a whole-process anaerobic ammonia oxidation self-enrichment environment.

The invention belongs to the technical field of industrial flue gas purification, and discloses an ammonia desulfurization optimization control system based on a machine learning algorithm, which comprises a feature extraction module, a working condition clustering module, a dynamic optimization module and a self-adaptive feedback module, the feature extraction module is used for collecting multi-dimensional operation parameters in a coal burning process, performing data dimension reduction through a PCA algorithm, and extracting key working condition features; the working condition clustering module identifies different operation working condition modes; the dynamic optimization module can construct a multi-modal optimization neural network based on different operation condition modes, and generates optimal control parameters in real time. Through PCA dimension reduction processing of the feature extraction module and in combination with a working condition clustering algorithm, automatic mode recognition and strategy switching under complex working conditions are achieved, fluctuation of desulfurization efficiency is reduced, and meanwhile the problems that the ammonia water adding amount depends on experience setting, raw material waste and secondary pollution are likely to be caused, and the operation and maintenance cost is large are solved.

The invention belongs to the technical field of sewage treatment, and particularly relates to an anaerobic ammonia oxidation-photoelectric denitrification deep nitrogen removal method. The method comprises the following steps: firstly, adopting a double-chamber reactor; introducing part of sewage into the cathode chamber, carrying out Anammox reaction under a dark state condition to remove ammonia nitrogen and part of nitrite nitrogen, and synchronously generating nitrate nitrogen; turning on a light source to irradiate the anode chamber, exciting photo-induced electrons by a photosensitizer, transmitting the photo-induced electrons to the cathode chamber through an external circuit, and driving the sulfur autotrophic denitrification sludge to reduce residual nitrite nitrogen and nitrate nitrogen generated by Anammox; the total nitrogen removal rate is close to 100%. According to the invention, photo-induced electrons are used as the only denitrification electron donor, so that the addition of a carbon source / sulfide is thoroughly avoided, and the risk of secondary pollution is eliminated. The method is suitable for green low-carbon deep treatment of sludge digestion liquid and pharmaceutical wastewater high-ammonia-nitrogen low-carbon-nitrogen-ratio sewage.

The invention provides a low C / N sewage nitrogen and phosphorus removal method based on MABR-DPR-anaerobic ammonia oxidation, which couples anaerobic, membrane aeration anoxic and anaerobic ammonia oxidation processes, forms an anoxic environment in a water phase of a membrane aeration reactor, and enriches denitrifying phosphorus-accumulating bacteria. And the anaerobic phosphorus release and anoxic denitrification nitrogen and phosphorus removal processes of the denitrifying phosphorus-accumulating bacteria are realized through the backflow of the sludge between the anaerobic tank and the membrane aeration reactor. Nitrite accumulated in effluent of the membrane aeration reactor supplements an electron acceptor for a subsequent anaerobic ammonia oxidation deep denitrification process, and meanwhile, a carbon source is obviously consumed in an anoxic denitrification nitrogen and phosphorus removal process of the membrane aeration reactor, so that inhibition of influent organic matters on an anaerobic ammonia oxidation process is effectively weakened. The process solves the problem that the carbon source is seriously insufficient in the nitrogen and phosphorus removal process of the low C / N sewage, and the stable and efficient nitrogen and phosphorus removal effect can still be maintained under the condition that an external carbon source is not needed.

The invention provides an ammonium sulfate production process control method based on model prediction, which comprises the following steps: acquiring real-time data of flue gas flow, sulfur dioxide concentration, slurry PH value and ammonia water concentration, analyzing dynamic change characteristics of the flue gas flow, the sulfur dioxide concentration, the slurry PH value and the ammonia water concentration under different coal types and load working conditions, and constructing a flue gas component mutation characteristic library; transmitting an ammonia water adding amount and / or material transfer pump rotating speed control instruction to a desulfurization tower control system, executing dynamic adjustment of an absorption circulating tank, updating real-time monitoring data, comparing output prediction results, calculating deviation, and generating an optimized future prediction sequence; and judging whether the pH value and the ammonium sulfate concentration of the absorption circulating tank can continuously meet the preset upper and lower limit range conditions in the future preset time or not by comparing the prediction result sequences before and after optimization, if so, completing a dynamic adjustment period, and if not, recalculating the adjustment value of the ammonia water addition amount and / or the rotating speed of the material transfer pump.

The invention relates to the technical field of ammonia water preparation, in particular to a raw water reverse osmosis treatment device for ammonia water preparation, which comprises a shell, the shell is formed by fixing an upper shell and a lower shell, a water inlet pipe is fixed in the middle of the top of the shell, a high-pressure water inlet component is arranged at the top of the water inlet pipe, and a concentrated water outlet pipe is fixed in the middle of the bottom of the shell. A drain valve is fixedly mounted at the bottom of the concentrated water outlet pipe; and the water pressure stabilizing assembly is arranged at the top of the inner wall of the shell. A multi-level pressure regulation and control mechanism is constructed in the reverse osmosis process, the problem of instantaneous pressure impact when the high-pressure pump is started is solved, physical damage to the membrane is avoided, a dual anti-blocking system of active rotary cleaning and back flushing is constructed, the membrane blocking probability is greatly reduced, meanwhile, the impact force of water flow is fully weakened in the back flushing stage, and the reverse osmosis efficiency is improved. It is ensured that the reverse osmosis membrane bears stable pressure all the time, and the problem of secondary damage to the reverse osmosis membrane caused by too large instantaneous pressure in the backwashing stage is avoided.

The invention discloses a device and a method for realizing low-carbon-nitrogen-ratio sewage autotrophic and heterotrophic coupled deep nitrogen and phosphorus removal based on a continuous flow membrane aeration bio-membrane reactor. A hollow fiber membrane is arranged in the continuous flow reactor, and an oxygen concentration gradient is formed through a bubble-free membrane aeration technology. In the biomembrane area, spatial partitions of functional bacteria such as nitrifying bacteria and anaerobic ammonium oxidation bacteria are established, and the two anoxic areas realize efficient nitrogen removal through short-cut denitrification coupling anaerobic ammonium oxidation (PD / A) and synchronous nitrification and denitrification. In the aspect of phosphorus removal, the system adopts an anaerobic-aerobic operation mode, phosphorus-accumulating bacteria release phosphorus anaerobically and absorb excessive phosphorus aerobically, and finally, phosphorus removal is realized through residual sludge discharge. The system integrates an internal carbon source extraction process, recovers a sludge carbon source and supplements an electron donor required by denitrification, and reduces the operation cost and carbon emission. The continuous flow MABR denitrification system enhances the denitrification efficiency of the PD / A system, is suitable for large-scale operation, and efficiently and stably realizes deep denitrification of a low-carbon-nitrogen-ratio urban sewage treatment plant.

The invention relates to the field of wastewater treatment, and discloses a method for treating nitrogen-containing wastewater based on sulfur autotrophic DNRA and anaerobic ammonia oxidation, which comprises the following steps: firstly, introducing nitrogen-containing wastewater into an Anammox reactor, inoculating granular sludge taken from a secondary sedimentation tank of a sewage treatment plant into the Anammox reactor, carrying out anaerobic ammonia oxidation reaction, controlling hydraulic retention time, and carrying out anaerobic ammonia oxidation treatment on the sludge; the method comprises the following steps: pumping effluent and sulfur source inlet water into an sDNRA reactor together, inoculating ordered batch sDNRA sludge into the sDNRA reactor, performing DNRA action under sulfide driving in a stirring state, and controlling hydraulic retention time to realize automatic effluent. According to the method disclosed by the invention, a carbon source does not need to be added, byproducts generated along with complex carbon metabolism can be effectively reduced, the cost can be effectively reduced while secondary pollution is avoided, the total nitrogen removal rate of the system can be successfully improved, and the generation of greenhouse gas N2O is reduced.

The invention relates to a vertical flow enhanced biological denitrification device and a sewage treatment method, a denitrification agent adding assembly is additionally arranged at a proper position of an existing vertical flow reaction device, namely the outer side of an outer inclined flow guide part, a corresponding enhanced denitrification agent can be added at a selected point position, a denitrification reaction is further enhanced, and the denitrification effect is improved. The selective reaction of the functional microorganism reaction is improved, nitrate generated by the anaerobic ammonia oxidation reaction is consumed, and a sufficient matrix is provided for anaerobic ammonia oxidation, so that the anaerobic ammonia oxidation reaction is greatly promoted, and the total nitrogen removal rate is further improved; by accurately controlling the dosing position and accurately dosing according to the reaction, the nitrogen removal efficiency of the autotroph is enhanced, the coordination of the minimization of the dosing amount of the medicament and the maximization of the nitrogen removal efficiency is realized, and finally, the green, low-carbon, economical and efficient nitrogen removal target of the sewage is achieved.

The invention discloses a Fe-Beta molecular sieve for N2O catalytic decomposition and a preparation method of the Fe-Beta molecular sieve. According to the method, chitosan and metal Fe < 3 + > ions are complexed to form a chitosan Fe < 3 + > complex, and then the complex, a silicon source, an aluminum source and a template agent are used as raw materials to prepare the Fe-Beta molecular sieve in one step through a hydrothermal method. Hydroxyl, amino and other groups rich in a chitosan molecular chain can effectively complex metal Fe < 3 + > ions to form a stable chitosan Fe < 3 + > complex, and the stable chitosan Fe < 3 + > complex is used as a Fe source to realize uniform dispersion of Fe species in the molecular sieve and effectively reduce formation of FexOy clusters and Fe2O3 nanoparticles, so that the N2O decomposition catalytic performance of the Fe-Beta molecular sieve is improved. Inorganic alkali metal ions are not introduced, so that a large amount of ammonia-nitrogen wastewater generated in a subsequent tedious ammonium exchange process can be avoided, the synthesis period is effectively shortened, and energy consumption, material consumption and environmental pollution are reduced.

This application relates to the field of ceramsite, and specifically discloses a preparation process for two-stage water-retaining ceramsite from coal gangue. The preparation process includes green pellet preparation, drying section, pyrolysis section, decarbonization section, first roasting section, soaking section, second roasting section, and cooling section; the green pellet preparation includes: wetting coal gangue powder with an organic solution, stirring evenly, and kneading with biomass material. The mass ratio of coal gangue powder to biomass material is 1 kg:(3-9) g to obtain green pellets; the soaking section includes: transferring the green pellets after the first roasting section to the soaking section, with the material layer temperature below 900 °C, and evenly spraying nano-silica during the transfer process, spraying 1-2.5 g per 100 g of green pellets; the cooling section includes: using one of sodium bicarbonate solution, ammonium bicarbonate, and ammonia water to form a water mist mixed with air to cool the roasted ceramsite. The prepared ceramsite has a rich and gradient pore structure, can quickly absorb water, and has excellent water-retaining performance.

The present application relates to wastewater treatment technical field, specifically to a kind of ammonia nitrogen wastewater treatment method, the composite modified zeolite material in the present application has excellent physical adsorption capacity to ammonia nitrogen by virtue of its unique pore structure and surface properties, ammonia nitrogen molecules in wastewater can be quickly captured, then through the synergistic effect of composite photocatalyst under light and ultrasonic, strong oxidizing free radicals are generated, ammonia nitrogen molecules not completely adsorbed by zeolite material are deeply degraded, through the synergistic effect of adsorption and photocatalysis, the removal efficiency of ammonia nitrogen is significantly improved;After adsorption and photocatalytic treatment, the ammonia nitrogen concentration in wastewater has been greatly reduced, and resin adsorption treatment is used as a subsequent step, which can selectively adsorb residual trace amounts of ammonia nitrogen and other impurities, thereby realizing deep purification of wastewater and ensuring that the effluent quality meets or exceeds relevant discharge standards.

The invention belongs to the technical field of sewage treatment, and discloses a two-stage MABR-based efficient denitrification system, method and application, the system comprises an MABR-PN / DN reactor, an MABR-PN / A reactor, a peristaltic pump, an aeration hollow fiber membrane module, a carrier, an aeration pump, a gas flowmeter, a pressure gauge and a liquid flowmeter, and the MABR-PN / DN reactor and the MABR-PN / A reactor are arranged along the vertical direction. According to the system, the series design of the MABR-PN / DN and the MABR-PN / A is utilized, the adverse effect of organic matter in sewage on anaerobic ammonia oxidation treatment of high-concentration ammonia nitrogen wastewater is reduced, nitrate nitrogen generated by the MABR-PN / A flows back to the first-stage MABR-PN / DN to achieve denitrification, the denitrification limitation of a single reactor and a single denitrification path is broken through, and the overall total nitrogen removal rate of the system is higher than 90%.

The invention discloses a split-flow type flexible dynamic green ammonia synthesis system which comprises a synthesis gas compressor unit, a recycle gas compressor unit, a hot gas-gas heat exchanger, an ammonia synthesis tower, a water cooler, a cold gas-gas heat exchanger, at least one ammonia cooler and an ammonia separator, the method is characterized in that the feed gas is divided into two streams, one stream enters the hot gas heat exchanger to exchange heat with the reacted synthesis gas, and the other stream directly enters the ammonia synthesis tower through a first shunting pipeline to adjust the temperature of a bed layer in the ammonia synthesis tower. The condensation temperature of the synthesis gas, including the condensation temperature of the synthesis gas at the outlets of the water cooler, the cold gas heat exchanger and the ammonia cooler, is adjusted step by step according to the operation load condition of the device, so that the ammonia content in the synthesis loop is controlled step by step, the loop circulation gas amount is adjusted step by step, and the stable fluctuation of the pressure of the ammonia synthesis loop is maintained; and flexible dynamic operation of the device is realized.

The present invention belongs to the technical field of petroleum fracturing production enhancement and modification, and specifically discloses a fracturing fluid pre-fluid for optimizing the size of in-situ autogenous proppant and its application, which is used to solve the problem of small particle size of proppant particles generated by hydrothermal reaction of formation minerals. The fracturing fluid pre-fluid is suitable for calcium-rich reservoirs and is composed of clean water, phosphate, pH regulator and Ca 2+ The chelating agent composition comprises 1 to 10 parts by weight of phosphate relative to 100 parts by weight of clean water, a volume molar concentration of the pH regulator is 1 to 5 mol / L, and Ca 2+ The molar concentration of the chelating agent is 0.001~1mol / L; the pH regulator is urea, ammonia, propionamide, etc. 2+ The chelating agent is EDTA, glutamic acid, etc. The present invention increases the average particle size of proppant particles generated by hydrothermal reaction of formation minerals, thereby improving the supporting effect thereof in micro-fractures of the formation.

The invention discloses a Fe / C loaded membrane module, a PN / A-MABR autotrophic nitrogen removal device, a preparation method and a sewage treatment method, and belongs to the technical field of sewage treatment. According to the invention, the problem that the treatment effect is influenced by NO3 <->-N accumulation in the existing membrane aeration coupling partial nitrification-anaerobic ammonia oxidation process is solved. Comprising a frame and a membrane body attached to the outer portion of the frame, the membrane body comprises a hydrophobic organic membrane layer, an iron-carbon material layer and a biological membrane layer which are sequentially arranged, and the hydrophobic organic membrane layer is attached to the outer portion of the frame. The iron-carbon material is added between the hydrophobic organic membrane layer and the biological membrane layer, the iron-carbon micro-electrolysis process is coupled with the dissimilatory process of nitrate generated by microbial metabolism, the removal of NO3 <->-N generated by anaerobic ammonia oxidation is enhanced, and the total nitrogen removal efficiency is improved.

The invention discloses a sulfur-oxidizing bacterium screening and enriching nutrient solution, a sulfur-oxidizing bacterium enriching method and a deodorizing method. The sulfur-oxidizing bacterium screening and enriching nutrient solution comprises 1.0 g.L <-1 > of K2HPO4, 0.5 g.L <-1 > of NaHCO3, 0.05 g.L <-1 > of NH4Cl, 0.225 g.L <-1 > of Na2S. 9H2O and 0.001 g.L <-1 > of trace elements, wherein the trace elements comprise 0.5 g.L <-1 > of EDTA (Ethylene Diamine Tetraacetic Acid), 0.01 g.L <-1 > of (NH4) 6Mo7O24. 4H2O, 0.04 g.L <-1 > of ZnSO4. 7H2O, 0.03 g.L <-1 > of MnCl2. 7H2O, 0.02 g.L <-1 > of CuSO4. 5H2O The deodorization performance of the municipal sewage treatment plant is improved through synchronous desulfurization and deamination of the acidophilic sulfur-oxidizing bacteria, and compared with a traditional deodorization process, the synchronous desulfurization and deamination process can enrich high-abundance sulfur-oxidizing bacteria in a short time and shows higher ammonia gas and hydrogen sulfide removal capacity.

The present invention relates to the field of environmental protection and discloses a method for removing tetracycline from water. The method uses an iron single-atom material to adsorb tetracycline in water. The iron single-atom material is prepared according to the following steps: (1) mixing ethanol, dimethylformamide, ammonia water, and water to obtain a mixed solution; (2) mixing zinc chloride, iron triacetylacetonate, and triazole with the mixed solution, stirring and reacting, to obtain an iron-doped metal-organic framework material; and (3) pyrolyzing the iron-doped metal-organic framework material at 850 to 950° C. under a protective gas atmosphere to obtain the iron single-atom material. The method provided by the present invention can be applied in complex water environments and has great significance for environmental protection. At the same time, the present invention proposes for the first time the use of an iron single-atom material as an adsorbent for adsorbing tetracycline in water, providing a new application for the iron single-atom material.

The utility model discloses a coke oven raw gas negative pressure pipeline high-pressure ammonia water purging device, which comprises a high-pressure ammonia water pipeline, a splicing slot is arranged at the upper end of a support frame, the lower end of an expansion screw block is connected with the negative pressure pipeline, a nut is sleeved on the outer wall of the expansion screw block, an inspection hole is arranged at the upper end of the high-pressure ammonia water pipeline, and the inspection hole is communicated with the high-pressure ammonia water pipeline. And a threaded mounting block is spirally inserted into the edge of the upper end of the inspection opening. According to the coke oven raw gas negative-pressure pipeline high-pressure ammonia water purging device, four groups of high-pressure ammonia water valves, connecting sleeves and high-pressure ammonia water nozzles are distributed in parallel between the high-pressure ammonia water pipeline and the negative-pressure pipeline, multi-group spray washing is carried out, the cleaning effect is good, the extension pipeline and the connecting sleeves are adjusted in a telescopic mode, and the cleaning efficiency is improved. Therefore, the high-pressure ammonia water spray head can be driven to reset and turn over through the reset rotating shaft and the connecting pipe, the spray-washing angle can be adjusted, the connecting sleeve and the extending pipeline can be conveniently and rapidly inserted, disassembled and assembled with the negative pressure pipeline through the splicing inserting groove and the splicing inserting block, and replacement and use are convenient.

The present invention relates to an ammonia decomposition catalyst and a manufacturing method thereof, and more particularly to an ammonia decomposition catalyst containing alumina (Al2O3), cerium (Ce), lanthanum (La), ruthenium (Ru) and potassium (K).

The invention discloses a method for realizing pollution reduction and carbon reduction by phosphogypsum recycling. The method comprises the following steps: (1) washing phosphogypsum with water to remove soluble impurities, neutralizing residual acid, and calcining and activating; (2) pretreatment of the landfill leachate: magnesium salt and phosphate are added, the pH of the landfill leachate is adjusted, and free ammonia NH3 is released through low-temperature heating; (3) the pretreated landfill leachate is sprayed to capture CO2 in the flue gas, and a (NH4) 2CO3 solution is obtained; (4) fully mixing a (NH4) 2CO3 solution with the pretreated ardealite, and controlling the reaction conditions in a closed reactor, so that the ardealite and (NH4) 2CO3 are subjected to a heterogeneous reaction to generate CaCO3 and (NH4) 2SO4; and (5) product purification: carrying out solid-liquid separation on the mixed solution by adopting a multi-stage crystallization process to obtain a building material, and carrying out gradient cooling and recrystallization purification on the filtrate to obtain the nitrogen fertilizer. According to the method, recycling of the landfill leachate and the ardealite is achieved, and CO2 in the flue gas is efficiently removed.

The utility model discloses a thermal hydrolysis cyanide breaking device, which relates to the technical field of wastewater treatment and comprises a cyanide breaking reactor, a wastewater heat exchanger, a pipeline mixer, a steam mixer, an instrument control valve and the like. After being heated by the wastewater heat exchanger, the wastewater enters a cyanide breaking reactor, and steam enters a steam mixer to heat the wastewater to a specified temperature and then enters the cyanide breaking reactor. The characteristic that the cyanide aqueous solution is easy to hydrolyze is utilized, so that the cyanide aqueous solution is hydrolyzed at the temperature of higher than 140 DEG C to produce sodium formate and ammonia, the toxicity of cyanide is eliminated, high-temperature wastewater discharged from the cyanide breaking reactor enters the wastewater heat exchanger to exchange heat with wastewater to be treated, and heat is recovered; the pressure of the reactor is controlled through a wastewater heat exchanger outlet wastewater outlet pipeline pressure regulating valve. The cyanide wastewater treatment device is reasonable in design, only a small amount of sodium hydroxide is needed for adjusting the pH of wastewater, no chemical agent needs to be added in other procedures, the cyanide wastewater treatment efficiency is improved, and the cost is saved.

The invention discloses high-purity oxamide with concentrated particle size and spherical morphology, a preparation method of the high-purity oxamide and application of the high-purity oxamide in preparation of a slow-release fertilizer, and belongs to the technical field of oxamide synthesis and application. The method comprises the following steps: mixing an ammonia-alcohol solution and an alcohol ester solution, conveying the mixed solution into a series tubular reactor for reaction, and then conveying the mixed solution into a parallel tubular reactor for reaction after pressure stabilization and flow equalization to obtain a reaction solution containing oxamide; performing flash evaporation on the reaction liquid to obtain flash evaporation liquid and flash evaporation gas, and performing solid-liquid separation on the flash evaporation liquid to obtain solid oxamide and filtrate; and drying the solid oxamide to obtain the oxamide. The method realizes high conversion rate and high purity, and the product has ultrafine particle size distribution. The purity of the prepared oxamide is greater than or equal to 99%, the D50 particle size is concentrated to 50 + / -15 microns, the spherical morphology is uniform, the release is stable, and the oxamide has a very good effect in preparation of long-acting slow-release fertilizers and combustion inhibitors and research on the nitrogen utilization rate.

The utility model provides an algal-bacterial symbiosis synergistic denitrification reaction device based on anaerobic ammonia oxidation, and relates to the technical field of wastewater treatment. The device comprises a reactor and a plurality of biological ribbons arranged in the reactor, a water inlet and a water outlet are formed in the two ends of the reactor respectively, the biological ribbons are vertically distributed in the reactor in the water flow direction and divide the reactor into a plurality of reaction spaces, and the two ends of the tops of the biological ribbons are fixed to the side wall of the reactor; and the height of the biological ribbon is lower than that of the reactor. The anaerobic ammonia oxidation-phycomycete symbiotic system is introduced into the reactor containing the biological ribbons, low-energy-consumption and low-emission treatment of low-C / N urban domestic sewage is achieved, the biological ribbons are selected as a loading material of the reactor, the interior of the reactor is provided with rich pore structures, and the biological ribbons are loaded on the reactor. A large amount of biological attachment surface area is provided for growth and reproduction of algae and other microorganisms in water, and a large amount of attachment sites and powerful growth conditions are provided, so that the sewage treatment effect is improved.