2176 results about "Ammonia" patented technology

The invention discloses a large-scale pig breeding wastewater purification treatment system, and relates to the technical field of wastewater treatment.The large-scale pig breeding wastewater purification treatment system is characterized in that the ion concentration of anaerobic liquid is monitored through a multi-ion sensing array, and a multi-channel feeding system is controlled to synthesize customized struvite compound fertilizer; the AI prediction control unit predicts the optimal medicament dosage and realizes millisecond-level closed-loop regulation; the multi-dimensional synergistic biochemical treatment module comprises an A / O biochemical treatment unit and an electric field enhanced anaerobic ammonia oxidation reactor, the electric field enhanced anaerobic ammonia oxidation reactor applies a direct-current electric field through an electrode pair, and engineering conductive biochar is used as a carrier to accelerate microbial metabolism; the sludge low-temperature pyrolysis self-consistent circulation module is used for pyrolyzing and converting residual sludge into biochar, biofuel and wood vinegar, and the biochar activation treatment unit is used for preparing engineering conductive biochar and forming a substance closed loop through a self-consistent circulation conveying system; and the digital twinning intelligent management and control platform realizes intelligent management and control of the system.

The invention belongs to the technical field of industrial flue gas purification, and discloses an ammonia desulfurization optimization control system based on a machine learning algorithm, which comprises a feature extraction module, a working condition clustering module, a dynamic optimization module and a self-adaptive feedback module, the feature extraction module is used for collecting multi-dimensional operation parameters in a coal burning process, performing data dimension reduction through a PCA algorithm, and extracting key working condition features; the working condition clustering module identifies different operation working condition modes; the dynamic optimization module can construct a multi-modal optimization neural network based on different operation condition modes, and generates optimal control parameters in real time. Through PCA dimension reduction processing of the feature extraction module and in combination with a working condition clustering algorithm, automatic mode recognition and strategy switching under complex working conditions are achieved, fluctuation of desulfurization efficiency is reduced, and meanwhile the problems that the ammonia water adding amount depends on experience setting, raw material waste and secondary pollution are likely to be caused, and the operation and maintenance cost is large are solved.

The invention belongs to the technical field of sewage treatment, and particularly relates to an anaerobic ammonia oxidation-photoelectric denitrification deep nitrogen removal method. The method comprises the following steps: firstly, adopting a double-chamber reactor; introducing part of sewage into the cathode chamber, carrying out Anammox reaction under a dark state condition to remove ammonia nitrogen and part of nitrite nitrogen, and synchronously generating nitrate nitrogen; turning on a light source to irradiate the anode chamber, exciting photo-induced electrons by a photosensitizer, transmitting the photo-induced electrons to the cathode chamber through an external circuit, and driving the sulfur autotrophic denitrification sludge to reduce residual nitrite nitrogen and nitrate nitrogen generated by Anammox; the total nitrogen removal rate is close to 100%. According to the invention, photo-induced electrons are used as the only denitrification electron donor, so that the addition of a carbon source / sulfide is thoroughly avoided, and the risk of secondary pollution is eliminated. The method is suitable for green low-carbon deep treatment of sludge digestion liquid and pharmaceutical wastewater high-ammonia-nitrogen low-carbon-nitrogen-ratio sewage.

The invention relates to a vertical flow enhanced biological denitrification device and a sewage treatment method, a denitrification agent adding assembly is additionally arranged at a proper position of an existing vertical flow reaction device, namely the outer side of an outer inclined flow guide part, a corresponding enhanced denitrification agent can be added at a selected point position, a denitrification reaction is further enhanced, and the denitrification effect is improved. The selective reaction of the functional microorganism reaction is improved, nitrate generated by the anaerobic ammonia oxidation reaction is consumed, and a sufficient matrix is provided for anaerobic ammonia oxidation, so that the anaerobic ammonia oxidation reaction is greatly promoted, and the total nitrogen removal rate is further improved; by accurately controlling the dosing position and accurately dosing according to the reaction, the nitrogen removal efficiency of the autotroph is enhanced, the coordination of the minimization of the dosing amount of the medicament and the maximization of the nitrogen removal efficiency is realized, and finally, the green, low-carbon, economical and efficient nitrogen removal target of the sewage is achieved.

The invention discloses a Fe / C loaded membrane module, a PN / A-MABR autotrophic nitrogen removal device, a preparation method and a sewage treatment method, and belongs to the technical field of sewage treatment. According to the invention, the problem that the treatment effect is influenced by NO3 <->-N accumulation in the existing membrane aeration coupling partial nitrification-anaerobic ammonia oxidation process is solved. Comprising a frame and a membrane body attached to the outer portion of the frame, the membrane body comprises a hydrophobic organic membrane layer, an iron-carbon material layer and a biological membrane layer which are sequentially arranged, and the hydrophobic organic membrane layer is attached to the outer portion of the frame. The iron-carbon material is added between the hydrophobic organic membrane layer and the biological membrane layer, the iron-carbon micro-electrolysis process is coupled with the dissimilatory process of nitrate generated by microbial metabolism, the removal of NO3 <->-N generated by anaerobic ammonia oxidation is enhanced, and the total nitrogen removal efficiency is improved.

The invention discloses high-purity oxamide with concentrated particle size and spherical morphology, a preparation method of the high-purity oxamide and application of the high-purity oxamide in preparation of a slow-release fertilizer, and belongs to the technical field of oxamide synthesis and application. The method comprises the following steps: mixing an ammonia-alcohol solution and an alcohol ester solution, conveying the mixed solution into a series tubular reactor for reaction, and then conveying the mixed solution into a parallel tubular reactor for reaction after pressure stabilization and flow equalization to obtain a reaction solution containing oxamide; performing flash evaporation on the reaction liquid to obtain flash evaporation liquid and flash evaporation gas, and performing solid-liquid separation on the flash evaporation liquid to obtain solid oxamide and filtrate; and drying the solid oxamide to obtain the oxamide. The method realizes high conversion rate and high purity, and the product has ultrafine particle size distribution. The purity of the prepared oxamide is greater than or equal to 99%, the D50 particle size is concentrated to 50 + / -15 microns, the spherical morphology is uniform, the release is stable, and the oxamide has a very good effect in preparation of long-acting slow-release fertilizers and combustion inhibitors and research on the nitrogen utilization rate.

The utility model provides an algal-bacterial symbiosis synergistic denitrification reaction device based on anaerobic ammonia oxidation, and relates to the technical field of wastewater treatment. The device comprises a reactor and a plurality of biological ribbons arranged in the reactor, a water inlet and a water outlet are formed in the two ends of the reactor respectively, the biological ribbons are vertically distributed in the reactor in the water flow direction and divide the reactor into a plurality of reaction spaces, and the two ends of the tops of the biological ribbons are fixed to the side wall of the reactor; and the height of the biological ribbon is lower than that of the reactor. The anaerobic ammonia oxidation-phycomycete symbiotic system is introduced into the reactor containing the biological ribbons, low-energy-consumption and low-emission treatment of low-C / N urban domestic sewage is achieved, the biological ribbons are selected as a loading material of the reactor, the interior of the reactor is provided with rich pore structures, and the biological ribbons are loaded on the reactor. A large amount of biological attachment surface area is provided for growth and reproduction of algae and other microorganisms in water, and a large amount of attachment sites and powerful growth conditions are provided, so that the sewage treatment effect is improved.

The invention provides a rapid preparation method of tungsten trioxide, which specifically comprises the following steps: step 1, weighing crude tungstic acid, dissolving in ammonia water, heating and stirring to obtain an ammonium tungstate solution; step 2, slowly dropwise adding the ammonium tungstate solution in the step 1 into a poor solvent to obtain an ammonium paratungstate suspension, and step 3, filtering the ammonium paratungstate suspension in the step 2 to obtain an ammonium paratungstate filter cake, and leaching the ammonium paratungstate filter cake with the poor solvent; 4, the ammonium paratungstate filter cake in the step 3 is placed in a drying oven to be dried; and (5) roasting the ammonium paratungstate filter cake in the step (4) at high temperature to obtain a faint yellow irregular flaky tungsten trioxide product. According to the preparation method, a mixed solvent crystallization and high-temperature roasting two-step process is adopted, the solubility of ammonium tungstate in water is reduced by adding a poor solvent, so that an ammonium tungstate solution rapidly reaches a saturated state and is separated out, the crystallization process of ammonium paratungstate is accelerated, and the preparation speed and the crystallization rate of a tungsten trioxide product are high.

The invention discloses a fermentation process of citric acid residues, and relates to the technical field of organic acid fermentation. The fermentation process comprises the following steps: mixing and crushing citric acid residues and wheat bran according to a mass ratio of (4-5): 1 to obtain a mixed material; spraying an ammonia water solution, a magnesium sulfate solution and a zinc sulfate solution into the mixed material, adjusting the pH value to 5.0-5.5, sterilizing, adding a urea solution and a basic nutrient solution, and uniformly mixing to obtain slurry; aspergillus niger and saccharomycopsis fibuligera are mixed according to the spore number ratio of 100: 1, then sterile water is added, the mixture is stirred to be uniform, and bacterial liquid with the spore concentration of 1 * 10 < 7 >-5 * 10 < 7 > / mL is obtained; spraying the bacterial liquid to the surface of the slurry, performing aerobic culture for 40-48 hours under the conditions that the temperature is 30-35 DEG C and the humidity is 80-85%, then cooling to 25-30 DEG C, reducing the humidity to 70-75%, spraying methanol at the same time, and performing sealed culture for 5-6 days; performing drying; and the acid yield and the nutrient substance yield in the finally obtained fermentation product are obviously improved.

The invention belongs to the technical field of sulfonamide synthesis, and particularly relates to a green and environment-friendly sulfonamide amidation preparation method. Comprising the following steps: adding chlorosulfonic acid into a reactor, stirring, heating, adding o-nitrochlorobenzene, carrying out staged heat preservation, cooling, and adding thionyl chloride to obtain 2-nitro-4-chlorine sulfonate-chlorobenzene; the method comprises the following steps: separating and filtering 2-nitro-4-chlorine sulfonate-chlorobenzene, adding ammonia water, stirring, preserving heat, and carrying out filter pressing to obtain 2-nitro-4-amine sulfonate-chlorobenzene; the preparation method comprises the following steps: adding liquid caustic soda into 2-nitro-4-amine sulfonate-chlorobenzene, stirring, heating, and adjusting the pH value to obtain 2-nitro-4-amine sulfonate-phenol; the method comprises the following steps: adding water, a catalyst and hydrazine hydrate into 2-nitro-4-amine sulfonate-phenol, heating, stirring, and carrying out filter pressing to obtain 4-sulfonamide-2-amino-phenol. According to the preparation method of sulfonamide, generated tail gas is subjected to falling film absorption treatment, and the product prepared by the preparation method is high in purity.

The utility model belongs to the technical field of rare earth hydrometallurgy and comprehensive utilization of resources, and particularly relates to a device for synthesizing a rare earth mixed precipitant in an ammonia-carbon reinforced manner. The utility model discloses a device for intensively synthesizing a rare earth mixed precipitator by ammonia carbon, which comprises an ammonia carbon intensified synthesis reactor, the ammonia carbon intensified synthesis reactor consists of five groups of plate bundles formed by welding herringbone corrugated plate sheets, and the five groups of plate bundles comprise two groups of gasification plate bundles for gasifying liquid carbon dioxide; the three groups of reaction plate bundles are used for mixing ammonia water and water and reacting with the bulk carbon dioxide, the five groups of plate bundles are wrapped by a metal shell, and an ammonia water, water and liquid carbon dioxide inlet and a circulating cooling water inlet and outlet are reserved outside the shell. Compared with a traditional tower reactor, the tower reactor has the remarkable advantages of being high in equipment integration degree, high in reaction efficiency, low in energy consumption and the like, the energy consumption is saved by 50%, the total investment of equipment is reduced by 50%, the occupied space of the equipment is reduced by 90%, and remarkable innovation is achieved.

The application discloses a kind of nano magnetic flocculants and its preparation method and application, belong to drinking water processing technical field, including the following steps: step S1, modified ferroferric oxide nanosphere is ultrasonically dispersed in ammonia alcohol solution, while stirring, slowly drop adding tetraethyl orthosilicate, continue stirring after drop, after centrifugal separation, wash, obtain silica coated ferroferric oxide nanoparticles;Step S2, phenylalanine modified chitosan is added into glacial acetic acid solution, after completely swelling and dissolving, add silica coated ferroferric oxide nanoparticles and ultrasonic treatment, under low pressure ultraviolet lamp, then with anhydrous ethanol wash purification, vacuum drying to constant weight, obtain nano magnetic flocculants;The method of the application is simple and easy to operate, the nano magnetic flocculants prepared can be quickly adsorbed to the surface of sulfonamide antibiotics, produce flocculation and can be magnetically separated, very suitable for trace sulfonamide antibiotics in drinking water source efficient removal.

The invention relates to the technical field of electrophoretic display, in particular to a preparation method of black electrophoretic particles with low reflectivity and high charge quantity. The method comprises the following steps: S1, mixing pre-dried black electrophoretic particles with ethanol, water and zirconium beads, adjusting the pH value by using ammonia water, and carrying out ball milling; transferring to a four-neck flask, adding a silane coupling agent, adjusting the pH value again, reacting at 80 DEG C, washing, centrifuging and drying to obtain modified particles; s2, carrying out ball milling on the modified particles, a monomer 1, a monomer 2 and a solvent, transferring into a four-neck flask, heating to 50 DEG C under the protection of nitrogen, adding an initiator, and reacting at 70-85 DEG C; after cooling, adding 3-5 parts of monomers and a solvent, repeatedly heating, adding an initiator, and reacting at 70-85 DEG C; and cooling again, supplementing the monomer 2 or 3, reacting under the same condition, and finally centrifuging, washing and drying to obtain the modified electrophoretic particle with the controllable shell structure. According to the invention, controllable regulation and control of low reflectivity and high charge quantity of the black electrophoretic particles are realized.

The utility model relates to a device for removing ammonia nitrogen in high-salinity wastewater. The device comprises a buffer tank, a raw material conveying pump, a raw material preheater, a concentration tower I, a concentration tower II and a concentration tower III which are connected in sequence, tower kettles of the concentration tower I, the concentration tower II and the concentration tower III are respectively connected with corresponding reboilers and tower kettle liquid delivery pumps, and tower tops of the concentration tower I, the concentration tower II and the concentration tower III are respectively connected with corresponding tower top liquid reflux tanks, tower top reflux pumps and tower top coolers; and the tower top liquid return tanks of the concentration tower II and the concentration tower III are respectively connected with corresponding deep coolers. According to the device, three-tower triple-effect differential pressure thermal coupling rectification is adopted, ammonia nitrogen in the high-salinity wastewater is effectively removed, all effective components are recycled, purified water at the top of each tower can be used for preparing 20 (wt)% of ammonia water, and concentrated liquid at the bottom of the tower can be used for refining saline water in the chlor-alkali chemical industry; the tower top steam of the concentration tower I can be used as a heat source of the concentration tower II, and the tower top steam of the concentration tower II can be used as a heat source of the concentration tower III, so that the steam consumption is greatly reduced.

The invention relates to the technical field of gas impurity separation, in particular to an ammonia-process desulfurization system and method, and the ammonia-process desulfurization system comprises a desulfurization tower which comprises an oxidation section, a concentration section, an absorption section, a purification section and a demisting section which are sequentially arranged from bottom to top. The inside of the oxidation section is used for accommodating ammonia-containing desulfurization liquid, and the middle upper part of the oxidation section is provided with a reflux inlet and a first outlet lower than the reflux inlet. A second outlet and an oxygen inlet are formed in the bottom of the oxidation section. A flue gas inlet is formed in the middle of the concentration section, a concentration spraying layer is arranged on the upper portion of an inner cavity of the concentration section and communicated with the upper end of a concentration circulating tank through a liquid supply pipeline, the concentration circulating tank is communicated with the lower end of the concentration section through a liquid return pipe, and a concentration circulating pump is arranged on the liquid supply pipeline. A deamination spraying layer and two desulfurization spraying layers are sequentially arranged in the absorption section from top to bottom, the desulfurization spraying layers are communicated with the first outlet through a first pipeline, and the deamination spraying layer is communicated with the second outlet through a second pipeline.

The invention relates to a high-toughness anti-crack magnetic decorative film and a preparation method thereof. The decorative film is prepared from the following raw materials in parts by weight: 40 to 60 parts of poly (dihydrothiophene-vinyl ether) copolymer, 10 to 25 parts of shell layer self-assembly modified Fe3O4 nanosheets, 5 to 15 parts of polyether ester block elastomer, 0.5 to 2 parts of sodium dodecyl benzene sulfonate, 0.5 to 1.5 parts of fluorosilane coupling agent, 0.1 to 1.0 part of 2-hydroxybenzotriazole ultraviolet absorbent, 3 to 6 parts of bisphenol A type epoxy curing agent and 0.05 to 0.5 part of imidazole catalyst. The flexible copolymer is synthesized through copolymerization of dihydrothiophene and vinyl ether, the modified Fe3O4 nanosheets form a Fe3O4 structure through coprecipitation of ferric chloride and ferrous chloride and regulation and control of ammonia water, and shell self-assembly coating is carried out through tetraethoxysilane and a block micromolecule interface agent. The material has excellent tensile strength, elongation at break, magnetic adsorption force and cycling stability, and is suitable for the application fields of flexible magnetic films and high-adhesion decorations.

The invention relates to the technical field of sewage treatment, and discloses a low-carbon-nitrogen-ratio ammonia-nitrogen wastewater treatment method, which comprises the following steps: measuring the carbon source concentration, ammonia-nitrogen concentration, flow and temperature of wastewater, inputting the carbon source and ammonia-nitrogen concentration into a prediction model to obtain a microbial activity predicted value, and determining the carbon source dosage based on the difference between the predicted value and an activity threshold value; converting the carbon source feeding amount into a reference feeding rate, and performing compensation correction on the denitrification rate through a temperature correction function to obtain an initial carbon source feeding rate; taking the subsequently monitored nitrogen-containing pollutant concentration of the effluent of the denitrification area as a feedback signal, comparing the feedback signal with the target concentration, and iteratively adjusting the feeding rate. According to the method, accurate matching of the carbon source feeding amount and the microbial metabolism requirement is achieved, the problems of unstable denitrification efficiency and secondary pollution caused by inaccurate carbon source feeding in a traditional process are effectively solved, and the effluent quality guarantee capacity is remarkably improved.

The pure membrane MBBR sewage treatment system comprises an anoxic denitrification zone, an anaerobic ammonia oxidation zone, an aerobic oxidation zone, a high-density sedimentation zone, an MBBR biological filtration zone, a backwashing water tank and an equipment room, the anoxic denitrification region is used for carrying out amination reaction, organic matter hydrolysis reaction and denitrification reaction on the sewage and nitrate and nitrite in the anoxic denitrification region; the anaerobic ammonia oxidation zone is used for reacting the sewage with nitrite to generate nitrogen; the aerobic oxidation zone is used for promoting microorganisms to degrade organic matters in sewage and convert ammonia nitrogen; the high-density settling zone is used for separating muddy water in sewage; the MBBR biological filtration area is used for filtering suspended matters in the sewage; the backwashing water tank is used for providing backwashing make-up water for the MBBR biological filtration area; and the equipment room is used for placing disinfection equipment, a fan and a power distribution control system.

The invention provides a method for preparing a nearly 3.5-valent vanadium electrolyte by reducing ammonium metavanadate with coke oven gas, which comprises the following steps: (1) reducing and calcining ammonium metavanadate in coke oven gas to obtain a reduced product; (2) carrying out replacement deamination on the reduced product in the step (1) to obtain a nearly 3.5-valent vanadium oxide, wherein the nearly 3.5-valent vanadium oxide contains V4O7; and (3) a mixed sulfuric acid solution and the approximately 3.5-valent vanadium oxide are subjected to a dissolution reaction, and the approximately 3.5-valent vanadium electrolyte is obtained. The process method disclosed by the invention is simple and easy to implement, the approximately 3.5 valence vanadyl sulfate electrolyte product with high vanadium concentration and low ammonia content can be obtained by taking the ammonium metavanadate and the coke oven gas as raw materials, and the application prospect is wide.

The invention relates to the technical field of electrochemical catalysis, and particularly discloses a preparation method of a cobalt-based catalyst for synthesizing ammonia through electrocatalysis of nitrate. The method comprises the following steps: placing melamine on the upstream of ZIF-67 powder, carrying out two-step temperature-programmed pyrolysis treatment in a high-purity nitrogen protective atmosphere, and naturally cooling to obtain the cobalt-based catalyst which takes rhombic carbon as a substrate and on which Co-NC nanoparticles are anchored. In the prepared catalyst, nitrogen atoms are doped on the surfaces of cobalt clusters to form Co-NC sites, the local electronic structure of cobalt can be accurately regulated and controlled, and the Faraday efficiency and yield of electrocatalytic nitrate reduction synthesis of ammonia are effectively improved.

The application discloses a kind of water-soluble sulphur-based compound fertilizer preparation method, belong to compound fertilizer technical field.The steps include as follows:(1) in reaction kettle, concentrated sulfuric acid and potassium chloride are reacted under heating condition, reaction temperature is 105-115 DEG C, reaction time is 25-45 minutes, slurry is sent to cooling kettle;(2) in cooling kettle, temperature is reduced to 40-60 DEG C, slurry is sent to mixed acid tank;(3) in mixed acid tank, add dilute phosphoric acid, potassium bisulfate solution and slurry, reaction temperature is 65-75 DEG C, slurry is sent to tubular reactor;(4) in tubular reactor, add ammonia, washing liquid and slurry, reaction temperature is 150-180 DEG C, slurry is sent to granulator;(5) in granulator, add alkaline compound fertilizer raw material, return material and slurry for granulation, granulation temperature is 80-95 DEG C, return material ratio is 1:1.5-2.0;(6) the granules obtained from granulator are cooled and screened to obtain product.

The invention discloses a method for realizing deep autotrophic nitrogen removal of sludge digestion liquid based on alternate intermittent aeration of a double-membrane aeration bio-membrane reactor (MABR). The process device comprises a sludge digestion liquid raw water tank, a single-stage double-MABR reactor, two MABR devices and a water outlet tank. According to the method, sludge digestion liquid enters the single-stage double-MABR reactor, the two MABR devices are alternately and intermittently aerated, the state of one aeration and one aeration stopping is always kept, and ammonia nitrogen in raw water is converted into nitrite through ammonia oxidizing bacteria enriched on the inner side of an MABR membrane. And simultaneously supplying to anaerobic ammonium oxidation bacteria enriched on the outer sides of the two MABR membranes through matrix diffusion for denitrification and generation of nitrate. Denitrifying bacteria enriched on the outer side of the MABR membrane utilize raw water organic matters to drive short-cut denitrification to synchronously supply nitrite to anaerobic ammonium oxidation bacteria so as to realize deep autotrophic nitrogen removal. According to the invention, a double-anaerobic ammonia oxidation reaction hot area is constructed through alternate intermittent aeration of double MABRs, and efficient deep autotrophic nitrogen removal of the sludge digestion liquid can be stably realized.

The invention belongs to the technical field of building materials, and discloses a special emulsion for large-particle-size high-air-permeability soft porcelain and a preparation method and application thereof, and the emulsion comprises a seed phase, a core emulsion phase, a hard-shell pre-emulsion phase, an initiation system and a post-treatment auxiliary agent; the core emulsion phase comprises deionized water, 2-ethylhexyl acrylate, glycidyl methacrylate, a toughening aid, ethyl phosphate methacrylate and an OP-10 emulsifier; the toughening aid is a polyether-polyester block copolymer; the post-treatment auxiliary agent comprises an antibacterial flame retardant, an organic silicon defoaming agent and ammonia water, the antibacterial flame retardant is a benzisothiazolinone derivative containing phosphorus and nitrogen, performance complementation is achieved through the layered design of a core-shell structure, and meanwhile the stability and adhesive force are improved by means of the reactive emulsifier and the functional monomer; in addition, the polyether polyester block type reactive toughening aid and the phosphorus and nitrogen-containing benzisothiazolinone derivative antibacterial flame retardant are added, so that synergistic optimization of toughening, antibacterial and flame retardant is realized.

The invention relates to the technical field of wood board processing gas filtration, and discloses an atmospheric dust removal device for high-frequency hot-pressing wood-plastic composite veneer processing, the atmospheric dust removal device comprises a tank shell, the outer wall of the tank shell is provided with a water level observation line, the bottom of the tank shell is fixedly connected with a support frame, the top of the tank shell is internally provided with a transmission fixed column, and the transmission fixed column is fixedly connected with the support frame. A filtering mechanism is arranged at the top of the tank shell, an air dispersing mechanism, a first reciprocating lead screw, a reciprocating moving rod and an inclined material guiding plate are arranged in the tank shell, the air inlet rotating opening is rotationally connected to the inner wall of the tank shell, and the first reciprocating lead screw is rotationally connected to the inner wall of the tank shell; in the rotating process of the material closing piece, blockage to the feeding pipe is lost, then sodium hydroxide is discharged from the material closing piece, then the sodium hydroxide is mixed with reciprocating movement of the spoiler under rotating stirring of the spraying head, smoke, ammonia water and sodium hydroxide in the material closing piece are mixed, reaction is promoted, and therefore formaldehyde generated by gas in plate machining is better removed.

The invention relates to a full-load self-adaptive ammonia spraying dynamic coordination control method for an SNCR-SCR coupling system, and belongs to the technical field of industrial flue gas denitration control. The method comprises the following steps: monitoring an SNCR reaction zone temperature field, SCR inlet multi-dimensional parameters and boiler operation characteristics in real time, constructing a coupling dynamic prediction model, and performing dynamic correction; a feedforward-feedback composite control framework and rolling time domain optimization are adopted, ammonia spraying modes are automatically switched, and system fluctuation is adapted; evaluating an activity state based on the catalyst activity influence factor, establishing a dynamic mapping relation between the activity state and an ammonia nitrogen molar ratio, and reversely correcting SNCR spray gun ammonia amount distribution by combining with SCR inlet reducing agent distribution uniformity; a risk assessment index is generated by fusing hearth temperature field uniformity and catalyst activity attenuation characteristics, and a dual-system boundary condition and operation state collaborative adaptive mechanism is established. The ammonia spraying dynamic coordination control in the full-load range is realized, the denitration efficiency and the operation stability are improved, and the ammonia consumption and the ammonia escape are reduced.

The invention provides a domestic sewage treatment method and system based on shortcut nitrification and anaerobic ammonia oxidation of Anammox bacteria preposed alkali reduction, and relates to the technical field of sewage treatment. The method comprises the following steps: anaerobic treatment: converting an organic suspended solid into an easily degradable carbon source through hydrolytic acidification bacteria; the carbon source is absorbed by denitrifying phosphorus-accumulating bacteria and denitrifying glycogen-accumulating bacteria and is stored as an intracellular carbon source; primary anoxic treatment: reacting ammonia nitrogen with nitrite through Anammox bacteria, and synchronously reducing alkalinity; aerobic treatment: under the condition of low alkalinity, in combination with low dissolved oxygen control, Comamox bacteria oxidize ammonia nitrogen into nitrite and accumulate the nitrite; and secondary anoxic treatment: denitrifying residual oxidation nitrogen into nitrogen by using intracellular carbon through denitrifying glycogen-accumulating bacteria. Through the synergistic effect of the hydrolytic acidification bacteria, the denitrifying phosphorus-accumulating bacteria, the Anammox bacteria, the Commox bacteria and the denitrifying glycogen-accumulating bacteria, efficient nitrogen and phosphorus removal is realized.

A process includes feeding atmospheric air to an air separation unit to produce a flow of nitrogen and a flow of oxygen; combining the oxygen with a hydrocarbon flow and water in an auto-thermal reformer to produce a retentate stream to a membrane water gas shift reactor (M-WGSR); generating, from the retentate stream to the M-WGSR, a permeate stream from the M-WGSR that includes a first flow of carbon dioxide and a first combined flow of hydrogen and nitrogen; feeding a retentate stream to a membrane steam methane reformer (M-SMR) to produce a permeate stream from the M-SMR that includes a second flow of carbon dioxide and a second combined flow of hydrogen and nitrogen; feeding the first and second combined flows to an ammonia synthesis unit to produce ammonia; and feeding the first and second flows of carbon dioxide and the ammonia to a urea synthesis unit to produce a flow of urea by fully utilizing the carbon dioxide.

The invention discloses a methanol water reforming hydrogen production method, and relates to the technical field of hydrogen energy preparation, and the method comprises the following steps: 1) catalytic reforming reaction; and 2) separation and purification. The preparation method comprises the following steps: performing nitrogen doping modification on activated carbon by a hydrothermal method to prepare an N-AC carrier; then Co is preferentially anchored to the carrier at low temperature by utilizing the steric hindrance effect of a cobalt-ammonia complex, and a highly dispersed CoxOy active center is formed through thermal decomposition; and finally, co-dipping Cu and Zn precursors, precipitating and reducing to form a Cu-Zn active center, and constructing a Cu-Zn-CoxOy / N-AC bifunctional concerted catalytic system which is used for hydrogen production by reforming methanol and water. After methanol and desalted water are mixed and gasified, the mixture is introduced into a reforming reactor loaded with a Cu-Zn-CoxOy / N-AC catalyst for reaction, generated reformed gas is subjected to cooling and gas-liquid separation and then is purified through a CO adsorption bed and a pressure swing adsorption system, and high-purity hydrogen is obtained.

The invention discloses an ammonia escape control system of a selective catalytic reduction denitration system, and relates to the technical field of flue gas denitration of thermal power generating units. Accurate data support is provided for fine adjustment of the ammonia spraying amount by collecting and feeding back the nitrogen oxide concentration at the key position in the flue, so that the area with low local denitration efficiency is identified; meanwhile, the ammonia spraying amount is controlled through independent ammonia supply mother pipes and independent electric control valves on the basis of a plurality of ammonia spraying areas arranged in a matched mode of the measuring unit, a closed-loop control system with the regional nitrogen oxide concentration as a core feedback variable is formed, and each ammonia spraying area can respond independently; the problem of excessive or insufficient ammonia caused by traditional'one-step 'ammonia spraying is avoided, the ammonia spraying uniformity is improved, and the ammonia escape rate and the ammonia salt accumulation degree are reduced.

The invention relates to an island energy system based on deep reinforcement learning. The island energy system comprises an energy device, an electrolysis device, an energy storage battery, a hydrogen storage device, an oxygen storage device, a pressure swing adsorption device, an ammonia synthesis device, a seawater desalination device and a scheduling device, the energy device inputs electric energy to the electrolysis device, the energy storage battery, the pressure swing adsorption device and the seawater desalination device; the electrolysis device is used for decomposing water provided by the seawater desalination device into hydrogen and oxygen; the pressure swing adsorption device provides nitrogen; the hydrogen storage device stores hydrogen, and then the hydrogen and nitrogen are input into the ammonia synthesis device; the oxygen storage device stores oxygen; the scheduling device constructs the real-time operation state of the system into a multi-dimensional state vector, forms an electricity-hydrogen-oxygen-ammonia-water multi-energy flow coupled balance constraint system, makes a decision on the multi-dimensional state vector based on a near-end strategy optimization algorithm, and outputs an optimal strategy parameter. According to the system, the electrolysis device serves as a hub, the global relation between electrolysis hydrogen production and multi-energy combined supply is optimized, and the low-carbon energy supply, ecological restoration and load requirements are met.