The invention discloses a BDD
electrode material and a preparation method thereof. The preparation method comprises the following core steps: pretreating the surface of a
porous titanium substrate; depositing a nanoscale
TiN film layer on the surface of the pretreated
porous titanium substrate in advance; depositing a layer of single-walled
carbon nanotube network on the
TiN thin film layer by using an
electrophoretic deposition method; growing a highly-doped BDD layer on the single-walled
carbon nanotube network by adopting a
plasma enhanced
chemical vapor deposition technology; repeating the two steps to form a multi-layer SWCNT / BDD
composite structure, and controlling the thickness of the multi-layer SWCNT / BDD
composite structure to be 1-50 microns; and finally, depositing a low-doped BDD
active layer with the thickness of 1-5 microns by adopting a
hot filament chemical vapor deposition (HFCVD) technology. According to the pulse
laser assisted preparation process provided by the invention, the
femtosecond laser pulse is introduced to replace traditional
plasma treatment, so that the process flow is simplified, and the efficiency is improved; according to the technology, the process is simplified, the quality of the
TiN film is improved through accurate energy input, and a new way is opened up for further improving the performance of the BDD
electrode.