The invention provides an
energy storage lithium battery online
lithium precipitation detection framework and method based on an
impedance spectrum and a safety threshold value, relates to the field of
energy storage battery safety state diagnosis and
energy management, and solves potential safety hazards caused by
lithium precipitation in the operation process of an
energy storage power station. According to the method, the relaxation
time distribution characteristic value of the battery
impedance spectrum is obtained by identifying the shelving state of the energy storage battery after charging and applying
alternating current excitation with specific frequency combination and combining high-speed sampling and
impedance spectrum analysis technologies. According to the method, no additional
reference electrode is needed, in-situ and online detection is achieved, and the influence of the charging process on impedance change is effectively avoided. Through multiple times of detection and comparison of characteristic value changes, normalization and differentiation are carried out, then comparison with a lithium
precipitation safety threshold value is carried out, and if the threshold value is exceeded, lithium precipitation occurs. According to the method, a reliable lithium precipitation detection means is provided for safety diagnosis and state
estimation of the energy storage
power station, the charging strategy can be optimized, abnormal attenuation of the
battery capacity is prevented, and the probability of occurrence of safety accidents is reduced.