3838 results about "Polyimide" patented technology

The invention belongs to the technical field of composite material design, and discloses a polyimide-based composite material design method and system based on experiment-machine learning collaborative optimization. The method comprises the following steps: S1, experimental database construction and machine learning performance modeling; S2, machine learning model construction and training; S3, model evaluation and performance index output; and S4, intelligent design of the polyimide-based composite material. The multi-objective performance collaborative optimization design and preparation of the polyimide-based ternary carbon heterostructure composite material are carried out by taking experimental data as a main material and machine learning as an auxiliary material. According to the method, an experiment-model-optimization closed-loop iterative design system is constructed based on an experiment-machine learning collaborative optimization method, the method has the advantages of high prediction precision, high optimization efficiency, good multi-target adaptability and the like, the development efficiency of the polyimide-based composite material is remarkably improved, and the development cost of the polyimide-based composite material is reduced. The method is suitable for intelligent design and large-scale application and popularization of the high-performance heat-conducting electromagnetic shielding material.

The invention discloses a lithium ion battery composite diaphragm, a preparation method and a lithium ion battery, and relates to the technical field of lithium ion batteries. The lithium ion battery composite diaphragm comprises a base membrane and a functional coating arranged on the negative electrode side of the base membrane, the functional coating sequentially comprises an ion conducting layer, a thermal barrier layer and a self-repairing layer from the position close to the base film to the position far away from the base film; wherein the base membrane is a polyimide and aramid nanofiber blended electrostatic spinning membrane; the ion conducting layer comprises a compound of a modified fast ion conductor and polyvinylidene fluoride-hexafluoropropylene; the thermal barrier layer comprises a cross-linked network of boron nitride nanosheets and polybenzimidazole; the self-repairing layer comprises polyurethane microspheres loaded with dynamic disulfide bonds. The composite diaphragm provided by the invention can remarkably inhibit a purple area on the surface of a negative electrode, and enhance high-temperature self-protection and interface self-repairing of the lithium ion battery, so that the cycle and safety performance of the lithium ion battery are remarkably improved.

The invention belongs to the technical field of protective coatings, and discloses an anti-corrosion, wear-resistant and high-temperature-resistant coating as well as a preparation method and application thereof. The coating comprises a primer, a middle transition layer and a finish; the raw materials of the primer comprise a primer material and a primer curing agent component; the primer material comprises modified epoxy phenolic resin, a primer functional filler, a first mixed solvent, a high-temperature-resistant coupling agent and an anti-settling agent; the raw materials of the middle transition layer comprise a middle transition layer material and a middle curing agent component; the materials of the middle transition layer comprise polyimide modified epoxy resin, a wear-resistant filler, a reactive diluent, a carbon nanotube, a first dispersant and a compatilizer; the raw materials of the finishing paint comprise a finishing paint material and a finishing paint curing agent component; the finishing paint material comprises organic silicon modified fluorocarbon resin, finishing paint functional filler, a second mixed solvent, a second dispersing agent and a flatting agent. According to the invention, a resin-based composite coating system is synergistically designed through multi-phase materials, so that optimal balance of corrosion resistance, wear resistance, toughness and high temperature resistance of the coating is realized.

The invention discloses a multi-layer protection cable resistant to an extreme environment, and belongs to the technical field of cables. The cable is of a seven-layer composite structure design and sequentially comprises a conductor, an insulating layer, a shielding layer, a buffer layer, a waterproof layer, a heat insulation layer and a protective outer layer from inside to outside, and the conductor is made of high-purity oxygen-free copper; the insulating layer is made of a polyimide material and has high temperature resistance, low temperature resistance and excellent insulating property; the shielding layer is composed of a tinned copper wire woven mesh and a high-permeability permalloy foil, and electromagnetic interference is effectively shielded; the buffer layer is made of an elastic rubber material to relieve mechanical stress; the waterproof layer adopts a nanoscale fluorosilicone resin coating and has excellent waterproof performance; the heat insulation layer is made of ceramic fibers and aerogel, and efficient heat insulation is provided; and the protective outer layer is made of a high-strength and corrosion-resistant polyether-ether-ketone (PEEK) material. The cable has excellent high temperature resistance, low temperature resistance, corrosion resistance and electromagnetic interference resistance, is suitable for extreme environments, and ensures stable transmission of electric power and signals under extreme conditions.

The invention relates to the technical field of insulating materials, in particular to insulating powder and a preparation method thereof. The invention discloses a flame-retardant coating which comprises the following components in parts by weight: 15-25 parts of epoxy resin, 10-20 parts of aluminum hydroxide, 5-12 parts of nano boron nitride, 1-3 parts of a silane coupling agent KH-560, 3-8 parts of polytetrafluoroethylene micro powder, 2-6 parts of fluorine-modified montmorillonite, 4-9 parts of melamine cyanurate, 2-5 parts of nano titanium dioxide, 1-4 parts of a fluorine-modified graphene oxide-polyaniline composite material and 0.5-2 parts of pentaerythritol stearate. The anti-corrosion coating is prepared from the following components in parts by weight: 1 to 3 parts of nano zinc oxide, 5 to 10 parts of glass fiber, 2 to 5 parts of polyhedral oligomeric silsesquioxane-polyimide copolymer, 1 to 4 parts of ferrocenyl epoxy resin and 0.5 to 2 parts of perfluorooctyltriethoxysilane. The insulation powder is high in corrosion resistance, excellent in insulation, heat dissipation and mechanical performance, environmentally friendly in processing, good in adaptability, capable of prolonging the service life of equipment and reducing the cost, suitable for special environments and wide in popularization prospect.

The invention discloses a shielding protection adhesive tape for semiconductor integrated circuit packaging and a preparation method thereof, and relates to the technical field of semiconductor integrated circuit packaging. The shielding protective adhesive tape for packaging the semiconductor integrated circuit is prepared by taking polyimide as a base material and coating a coating, and the coating comprises the following raw materials in parts by weight: 3-5 parts of modified nano silicon dioxide, 30-40 parts of N, N-dimethylformamide, 1-3 parts of a curing agent and 1-3 parts of a curing agent. The invention discloses a high-temperature-resistant epoxy resin coating which is prepared from the following components in parts by weight: 25-30 parts of N, N-dimethylformamide, 25-30 parts of a modified acrylate copolymer, 17-26 parts of ethyl acetate, 12-15 parts of epoxy resin, 1-2 parts of a silane coupling agent KH-550, 0.5-1 part of an antioxidant 1010, 0.3-0.8 part of an ultraviolet absorbent UV-327, 1-2 parts of carboxyl-terminated nitrile rubber, 2-4 parts of decabromodiphenyl ether, 0.1-0.3 part of an organic siloxane defoaming agent, 0.2-0.5 part of an acrylate flatting agent and 10-11 parts of diaminodiphenyl sulfone. The adhesive tape contains the modified nano silicon dioxide, the modified acrylate copolymer and other components, so that the performance of the adhesive tape is guaranteed; pretreatment is meticulous, preparation steps are standard, and mass production is easy; a finished product can be effectively shielded, and the packaging yield and the product stability can be improved.

The invention discloses a dry-process high-temperature-resistant lithium battery diaphragm and a preparation method thereof, and relates to the technical field of lithium battery diaphragms. The specific preparation method comprises the following steps: activating and cross-linking polypropylene, polyimide, a PP-b-PI block copolymer and a cross-linking agent BIBP under the protection of nitrogen to prepare a polypropylene-polyimide matrix; after melting, adding a pre-sintered ZrO2-coated Al2O3 core-shell filler, hydroxylated boron nitride and zinc borate, and carrying out double-stage screw extrusion, ultrasonic orientation, nitrogen annealing and cold roller quenching to obtain a mixed melt; carrying out warm stretching and hot air circulation heat treatment to prepare a hard elastic crystal base film; carrying out stretching, thermal relaxation and thermal shaping to obtain a microporous base membrane; after slitting, plasma activation is carried out, epoxy silane and tetraethyl orthosilicate / polybenzimidazole aerogel precursors are sprayed, and a nano closed-pore coating is formed through pre-curing and heat shrinkage curing; and finally eliminating static electricity and rolling to obtain a finished product. The lithium battery diaphragm prepared by the invention is excellent in high temperature resistance and low in thermal shrinkage rate.

The invention provides a preparation method and application of a wear-resistant polyimide material, and the preparation method comprises the following steps: S1, adding a polyimide material into an alkali solution for reaction, cleaning reactants with acid and ethanol, and drying to obtain an activated polyimide material; s2, adding the activated polyimide material into a silane coupling agent solution for reaction, cleaning reactants with ethanol and water, and drying to obtain a modified polyimide material with silicon-oxygen bond active sites on the surface; s3, adding the modified polyimide material with silicon-oxygen bond active sites on the surface into a modified epoxy resin solution, adjusting the pH value to be acidic, and reacting to obtain the wear-resistant modified polyimide material, wherein the modified epoxy resin solution is obtained by reacting a silane coupling agent with acrylate. According to the method, the wear resistance of the polyimide can be improved on the premise that other properties of the polyimide material are not influenced.

The invention discloses a preparation method of a high-temperature-resistant high-strength polyimide composite material, and relates to the technical field of polyimide composites.The preparation method comprises the following preparation steps that S1, a customized silane coupling agent is prepared; s2, preparing a bionic dynamic interface modified reinforcing filler, wherein the modified reinforcing filler is synergistically modified through a bionic coating and a customized silane coupling agent; and S3, preparing a polyimide precursor solution containing the dynamic network. According to the preparation method of the high-temperature-resistant high-strength polyimide composite material, through the integrated design of'customized silane coupling agent + bionic dynamic interface modification + dynamic network-containing polyimide precursor + gradient hot-pressing curing ', the glass-transition temperature of the prepared composite material is greater than or equal to 335 DEG C, the tensile strength is greater than or equal to 208 MPa, and meanwhile, the thermal repair efficiency at 180-250 DEG C is greater than or equal to 87%; the technical bottleneck that high temperature resistance, mechanical strength and repairing performance of the material are difficult to consider at the same time in the prior art is solved.

The invention discloses an insulating tape for a new energy battery and a preparation method of the insulating tape, and relates to the technical field of new energy battery assemblies. The insulating tape for the new energy battery is prepared by coating pretreated glass fiber cloth with a coating, the coating is prepared from the following raw materials in parts by weight: 15 to 20 parts of modified polyimide resin, 2 to 4 parts of epoxy resin E-51, 71 to 77 parts of an ethanol / butanone mixed solvent, 3 to 5 parts of modified nano silicon dioxide, 0.2 to 0.4 part of a silane coupling agent KH-550, 0.1 to 0.3 part of polydimethylsiloxane, 0.1 to 0.2 part of paraffin-based mineral oil and 0.3 to 0.5 part of triethylene tetramine. The glass fiber cloth pretreatment material comprises deionized water and a 5%-8% sodium hydroxide solution. The insulating adhesive tape for the new energy battery contains the modified polyimide resin, so that the high temperature resistance and electrolyte resistance of the adhesive tape can be enhanced, the insulativity is improved, and the modified nano silicon dioxide is good in dispersity. The preparation process is fine, the glass fiber cloth is fully pretreated, the preparation process is standard, and the use requirements of new energy batteries can be met.

The invention belongs to the field of advanced materials, and particularly relates to polyimide resin with low curing temperature and high heat resistance and a preparation method thereof. According to the invention, pararosaniline is introduced into the molecular chain structure of the phenylacetylene-terminated polyimide resin, and the curing temperature of the phenylacetylene-terminated polyimide resin is reduced by changing the spatial distortion degree of the polyimide molecular chain and introducing free radicals to catalyze the curing process. The polyimide resin can be cured and molded at a relatively low temperature, and keeps excellent heat resistance and mechanical properties. The forming temperature of the high-performance polyimide and the composite material thereof is effectively reduced, so that the manufacturing difficulty and cost are reduced, and the preparation method has important application prospects.

The invention relates to a foam material, in particular to a polyimide / ionic liquid composite foam material and a preparation method thereof. The polyimide (PI) polymer with a rigid molecular structure and high temperature resistance is successfully synthesized, meanwhile, high-compatibility ionic liquid (ILs) molecules are introduced into adjacent PI molecular chains, the polyimide / ionic liquid composite foam material is formed through supercritical foaming, the foaming capacity is remarkably improved, and the polyimide / ionic liquid composite foam material has excellent performance.

A method for improving the wear resistance of carbon fibers sized with polyimide, the method relating to the field of materials. The method for improving the wear resistance of carbon fibers in the present invention comprises the following steps: using an impregnation method to attach a water-based sizing agent to carbon fibers for surface sizing, and drying same at 140-260℃. The wear resistance of the carbon fibers is improved by changing the drying temperature in the carbon fiber sizing process. The sized carbon fibers have the advantages of good wear resistance and minimal fuzzing, thus being capable of withstanding further weaving and processing.

The utility model belongs to the technical field of electromagnet coils, particularly relates to a magnetic suspension electromagnet coil, and aims to solve the problems that a coil with a large number of turns can generate a strong magnetic field under the same current, so that the coil with a large number of turns can be adopted to generate a strong and stable magnetic field, but the large number of turns can cause some problems. In order to solve the problems that the energy loss is further increased and even the coil is possibly damaged due to the fact that the resistance of the coil is increased and heating is increased, the utility model provides the following scheme: the coil comprises a hollow framework, a plurality of turns of coils are wound on the hollow framework, and a protective sleeve is wound on the whole outer wall of the plurality of turns of coils; and the outer wall of a single copper wire of the multi-turn coil is covered and sprayed with an insulating layer. When the magnetic suspension electromagnet coil is used, through the design of the protective sleeve, the ceramic insulating coating, the heat dissipation fins, the heat extraction fan, the heat dissipation holes and the like which are made of polyimide film materials, the heat dissipation efficiency and durability of the coil are effectively improved, and stable operation of a magnetic suspension electromagnet is ensured.

The invention provides a liquid crystal aligning agent, a liquid crystal alignment film, a liquid crystal display element and a manufacturing method of the liquid crystal aligning agent. The liquid crystal aligning agent can obtain a liquid crystal alignment film which has excellent adhesion and can inhibit AC ghosting at a high level. A liquid crystal aligning agent containing a polymer component P containing one or more polymers, a compound C1, and a compound C2, the polymer component P containing at least one polymer p selected from the group consisting of polyimide precursors and polyimides that are imides of the polyimide precursors. Compound C1 is a compound having two or more structures represented by formula (c-1). The compound C2 is a compound represented by formula (c-2).

The invention provides a preparation method of a hyperbranched polyimide-derived silicon-carbon negative electrode material, which comprises the following steps: S1, preparation of a carbon precursor: mixing 1, 3, 5-tris (4-aminophenyl) benzene and 4, 4 '-(hexafluoroisopropenyl) diphthalic anhydride for reaction to prepare hyperbranched polyimide; s2, preparing porous carbon; and S3, vapor phase silicon carbon deposition. The invention also correspondingly provides a silicon-carbon negative electrode, a lithium ion battery and an electrochemical device. According to the hyperbranched polyimide-derived silicon-carbon negative electrode material, the volume expansion of silicon in the lithium intercalation process is effectively relieved, the active material is prevented from falling off, and the cycling stability of the battery is improved.

The invention discloses a biaxial flexible strain sensor based on laser induced graphene. Comprising a flexible substrate, a flexible sensitive layer, a flexible spacing layer and a flexible upper cover, both the flexible substrate and the flexible upper cover are made of a polydimethylsiloxane (PDMS) material, the flexible sensitive layer is generated on a mixed substrate of polyimide (PI) and multi-walled carbon nanotubes (MWCNTs) through a laser ablation process, and then the sensitive layer is transferred to the PDMS substrate through a substrate transfer process. The flexible sensitive layer adopts an I-shaped structure, and two ends of the flexible sensitive layer are coated with electrode layer external wires. The method can be applied to the fields of wearable electronic equipment and medical monitoring. By means of the I-shaped structure, the sensitive layers in different directions can detect the strain in the main direction, and meanwhile interference caused by the strain in different directions is avoided. The preparation method is simple and efficient, a special gas environment is not needed, patterning preparation of graphene can be completed only through one step, and the production cost is reduced.

The invention discloses an interfacial film for an ion battery, a preparation method of the interfacial film, the ion battery and an electric device, the interfacial film for the ion battery is finally obtained by performing multi-step modification on a carbon nano tube and reacting the carbon nano tube with a prepolymer solution, so that the interfacial film can effectively reduce the interfacial impedance and promote ion transmission, and the performance of the ion battery is improved. The modified carbon nanotubes are combined with polyimide through the action of covalent bonds, so that the mechanical property of an interfacial film is improved, dendritic crystal puncture can be physically inhibited through the high mechanical strength of the interfacial film, and the cycling stability and the rate capability of the battery are improved; and meanwhile, the interfacial film can inhibit side reaction between the negative electrode and electrolyte, reduce interface impedance and promote ion transmission, so that the overall electrochemical performance of the battery is improved.

The invention discloses a paper-based electrode based on liquid metal assisted laser-induced graphene and a preparation method thereof.The paper-based electrode comprises a substrate layer, a functional layer, a conductive layer and a hydrophobic layer which are sequentially arranged, the substrate layer is made of paper, the functional layer is formed by coating liquid metal nanoparticles, and the conductive layer is formed by coating liquid metal nanoparticles. The conductive layer is an electrode formed by a laser-induced graphene technology, and the hydrophobic layer is a fluid control area formed by wax packaging. According to the invention, paper is used as a substrate, liquid metal is combined with a laser-induced graphene technology, surface modification is carried out through eutectic gallium indium (EGaIn), polyimide (PI) and N-methyl pyrrolidone (NMP) composite slurry, and then a conductive electrode pattern is formed on the surface of the paper substrate by using a laser-induced graphene (LIG) technology. The method has the advantages of simple preparation, low cost, environmental friendliness and the like, and the prepared paper-based electrochemical biosensor has excellent conductivity, mechanical flexibility and electrochemical activity.

The invention discloses a photoelectric composite aluminum alloy conductor aerospace cable and a preparation method, and belongs to the technical field of photoelectric composite cables, the cable comprises an optical fiber unit, a conductor unit, an insulating layer, an anti-electromagnetic unit and a sheath layer; the anti-electromagnetic unit is obtained by weaving double-layer metallized polyimide fibers; the double-layer metallized polyimide fiber sequentially comprises a polyimide fiber, a first metal coating and a second metal coating from inside to outside. The surface of the polyimide fiber is coated with modified polydopamine; the first metal coating is copper; and the second metal coating is silver and / or nickel. The double-layer metal coating can form a more compact metal outer layer on the surface of the polyimide fiber, the requirements of the severe external environment of aerospace are met, a conductive network with higher stability is formed, and the electromagnetic shielding effect is remarkably improved. Moreover, the polyimide fiber is coated with a polydopamine coating, so that the fiber is not damaged, and the overall high and low temperature resistance and radiation resistance can be improved.

The invention provides a light and heat-dissipating aerospace small-sized calibration lamp mounting seat, which relates to the technical field of aerospace optical small-sized calibration lamp structure fixation, and comprises a substrate mounting seat module, a conductive module, an insulating module and a heat conduction module. The conductive module comprises two chamfered semi-cylindrical conductive copper blocks and two wires with soldering lugs; the insulating module comprises an insulating polyimide isolating layer; the heat conduction module comprises a heat conduction insulation pad which is installed above two copper blocks, the positive electrode and the negative electrode of the two copper blocks are separated through an insulation polytetrafluoroethylene isolation layer, and the semi-cylindrical conductive copper blocks, the polytetrafluoroethylene isolation layer and the substrate installation base are positioned through pin holes. The soldering lug wire is installed on the left semi-cylindrical conductive copper block and the right semi-cylindrical conductive copper block in a pressing mode through top screws. The structure distribution is friendly, the anti-seismic performance is good, a good heat dissipation way is provided for the calibration lamp, and an effective and feasible implementation scheme is provided for fixing the small aerospace calibration lamp.

The present invention discloses a kind of preparation method and use method of anti-abrasion concrete admixture under freeze-thaw-solution environment, the admixture includes the components of following parts by weight:50~60 parts of STG powder, 5~8 parts of polyimide fibers, 1~3 parts of hydroxypropyl methyl (HPMC) cellulose, 10~13 parts of polycarboxylate water-reducing agent, 10~15 parts of antifreeze, 10~13 parts of expansion agent, wherein STG powder includes modified silica fume-glass powder, silicon carbide titanium, graphene oxide. Anti-abrasion concrete admixture under freeze-thaw-solution environment of the present invention can effectively suppress the decomposition of calcium hydroxide, and can refine pore structure, make hydraulic concrete more compact, while improving the ability of hydraulic concrete to resist dissolution, enhance its anti-abrasion performance, the admixture has good low temperature resistance, can be applicable to cold low temperature environment, for the anti-abrasion strength under low temperature conditions there is obvious improvement.

The invention relates to the field of tension and pressure sensors, in particular to a tension and pressure sensor with a compensation function, which comprises an elastic body, a strain gauge, a compensation gauge and a wiring terminal, the strain gauge and the compensation gauge are respectively arranged on the surface of the elastic body, the strain gauge, the compensation gauge and the wiring terminal are electrically connected through a plurality of high-temperature-resistant cables to form a bridge circuit, at least the strain gauge and the compensation gauge are respectively limited in the first heat insulation layer and the protection layer, and the first heat insulation layer is located between the elastic body and the protection layer. At least a first heat insulation layer used for protection, heat insulation, pressure resistance and sealing is used for wrapping a strain gauge and a compensating gauge which are packaged by a polyimide film and can resist the high temperature of 260 DEG C, so that the actual temperature of the strain gauge and the compensating gauge has a remarkable temperature difference with the current environment temperature; the actual temperature of the strain gauge and the compensating gauge is obviously lower than the environment temperature, so that the strain gauge and the compensating gauge are respectively in an ideal temperature range, and the force measurement precision of the pull pressure sensor is ensured.

The invention relates to the technical field of thermal insulation materials, in particular to an aerogel felt and a preparation method thereof.The aerogel felt is composed of a composite fiber base material and multi-component aerogel loaded in the composite fiber base material, the composite fiber base material comprises 65%-75% of alkali-free glass fibers, 15%-20% of modified polyimide fibers, 4%-6% of nanoscale carbon fibers and 8%-12% of basalt fibers, and the multi-component aerogel is loaded in the composite fiber base material. According to the multi-component aerogel, 78%-82% of tetraethoxysilane, 12%-14% of methyltrimethoxysilane, 4%-6% of dimethyldimethoxysilane and 2%-4% of vinyltrimethoxysilane serve as precursors, 1.5%-2.5% of aluminum oxide, 0.8%-1.5% of titanium oxide nanoparticles and 3%-4% of zinc borate are added, a multi-stage reinforced structure is formed, the mechanical property and flexibility of the aerogel felt are remarkably improved, the tensile strength reaches 400 kPa or above, and the tensile strength reaches 400 kPa or above. The flexibility is excellent.

The invention discloses a single-layer liquid crystal reflection type liquid crystal color display module and a preparation method thereof. The display module comprises a light absorption layer, a lower substrate, a red-green-blue three-primary-color reflection type cholesteric liquid crystal layer and an upper substrate which are sequentially arranged. The lower substrate is provided with a TFT electrode, the upper substrate is provided with a conductive indium tin oxide layer, the face, containing the TFT electrode, of the lower substrate is arranged upwards, the red-green-blue three-primary-color reflective cholesteric liquid crystal layer comprises a plurality of polyimide separating walls, and a micron-sized thin-wall container is formed between every two adjacent polyimide separating walls. And three adjacent micron-sized thin-wall containers form a group of pixel strips. Through formula improvement and process upgrading, the reflectivity of the display module is remarkably enhanced, color reflection is brighter, the visual angle characteristic of a display device is improved, the sensitivity to the observation angle is reduced, the display brightness and the light utilization rate are improved, and systematic optimization of reflection efficiency is achieved.

The invention belongs to the technical field of folding screens, and discloses an optical conductive film for a folding screen and a preparation method thereof.The optical conductive film for the folding screen comprises a composite base material, an interface transition layer, a gradient refractive index optical adjustment layer, a hybrid conductive layer and a scratch-resistant wear-resistant layer which are sequentially stacked from bottom to top; the composite base material is a blending modification layer of polyimide and transparent polyamide, the hybrid conductive layer is formed by compounding silver nanowires, a graphene sheet layer and PEDOT: PSS according to a preset proportion, and the refractive index of the gradient refractive index optical adjustment layer is gradually reduced in the direction away from the composite base material. And the difference value between the refractive index of the gradient refractive index optical adjustment layer and the refractive index of the hybrid conductive layer is not greater than 0.05. The mechanical stability, the light transmission efficiency, the conductive stability, the scratch resistance and the wear resistance of the film are improved, the performance is stable after folding circulation, the use requirements of a folding screen are met, and application in different scenes can be met.

The invention discloses a liquid gutta-percha toughened and modified polyimide foam material and a preparation method thereof, and belongs to the technical field of high polymer materials. The gutta-percha adhesive is prepared from the following raw materials: liquid gutta-percha, a component A and isocyanate in a weight ratio of (5-40): 100: 58, the component A is prepared from the following raw materials in parts by weight: 40-45 parts of aromatic dianhydride, 5-10 parts of low molecular alcohol, 100-120 parts of a solvent, 8-10 parts of a foaming agent, 1-3 parts of a catalyst and 6-8 parts of a foam stabilizer. The liquid gutta-percha is added, so that the toughening of the polyimide foam material is realized, and meanwhile, the polyimide foam material keeps good heat resistance and mechanical properties. The method is suitable for preparing the polyimide foam material with high toughness.

Aerogels comprising a hydrophobic polyimide moiety, including hydrophobic polyimide aerogels, as well as methods of manufacture and applications thereof, are generally described.

The present invention discloses a class of imide ring-containing dimercapto monomers, imide ring-containing diene monomers and preparation methods thereof, a light-responsive polyimide material and preparation method thereof, and relates to the technical field of light-driven materials. The present invention uses a dibasic acid anhydride as the basic monomer unit, and prepares a dimercapto monomer containing an imide structure and a monomer containing an imide ring-containing diene monomer by reacting with a monothiol compound and a monoalkyne compound, respectively. The two monomers are subjected to a thiol-alkyne click reaction to finally obtain a high molecular weight polyimide. The polyimide obtained by the present invention has excellent solubility, high tensile strength, good heat resistance and light transmittance; the polyimide material is placed under an ultraviolet lamp for uneven photocrosslinking to quickly obtain a light driver with excellent reversible driving performance.

The invention discloses a high-temperature-resistant high-performance neodymium-iron-boron permanent magnet material and a preparation method thereof, and belongs to the technical field of neodymium-iron-boron permanent magnet materials. The material is prepared from neodymium iron boron magnetic powder, auxiliary metal, hyperbranched polyimide polymer modified nano zirconium oxide and a silane coupling agent through mixing, smelting, crushing, sintering, tempering, coating and curing. The hyperbranched polyimide polymer modified nano-zirconia is introduced into the components, so that the permanent magnet material has excellent thermal stability, the permanent magnet material can still keep stable magnetic performance and mechanical performance at high temperature, the attenuation resistance is good, the thermal demagnetization is low, and the interface bonding strength is improved after the nano-zirconia is modified by hyperbranched polyimide. The interfacial compatibility between the nano zirconium oxide and the polyimide is enhanced through click chemical reaction, and the interfacial bonding strength of the nano zirconium oxide on a neodymium iron boron matrix is improved. The three-dimensional branched structure of the hyperbranched polyimide can form physical crosslinking points in the material, so that the mechanical strength of the material is enhanced.