3802 results about "Zeolite" patented technology

Improved performance ion exchange membranes for use in REM, AEM and DMFC fuel cells, buffered fuel cells, hydrolysis, other applications comprise a molecular matrix of homopolymers, di-monomer, heteropolymers, copolymers, or block-polymers of fluorocarbon and hydrocarbon compounds combined with (i) skeletal support grid to improve durability, handling, reduce membrane swelling, and sequester dopants and nanoparticles from leakage; (ii) microporous membrane formed using a sacrificial filler process enhancing conductivity and limiting fuel crossover; (iii) hetero-ionomeric matrix of two-or-more membrane-bound acids e.g. sulphonic and phosphonic acid expanding usable range; (iv) permanent fillers enhancing conductivity and porosity including nanoparticles, metal-oxides, zeolites, silicates, GOs, CNTs, MOFs, POSS, and others; (v) ionic liquid doping to enhance membrane conductivity; (vi) membrane nanocoating preventing H2O2 diffusion; and / or (vii) catalytic nanocoating with metals, metal-oxides, and MOFs preventing atmospheric toxin catalyst poisoning. Combined with a heterogenous GDI, the IEM is integrated into iBFC power blade and energy bank applications.

The invention discloses a p-methyl benzyl chloride production process and a production system thereof, p-xylene side chains and chlorine are subjected to a gas phase substitution reaction under micro negative pressure and visible light catalysis to generate crude methyl benzyl chloride and hydrogen chloride, and 99.0% methyl benzyl chloride, a small amount of benzyl dichloride and 31% hydrochloric acid are respectively generated through rectification and absorption; the device consists of four working sections of chlorination, rectification, hydrochloric acid absorption and distillation. According to the method, the defects in the prior art are overcome, on one hand, chlorine is introduced, and an aromatic ring chlorination reaction is carried out under visible light catalysis; on one hand, a supported catalyst filler is arranged at the bottom of a chlorination tower, and a zeolite molecular sieve modified by long-chain alkylsilane and supported by metal salt is used as a catalyst to catalyze chloromethylation reaction, on the other hand, the hydrophobicity of the modified catalyst is obviously enhanced, and meanwhile, the density of acidic sites is not reduced; the contact opportunity of the catalyst and a reaction substrate is greatly increased, and the catalytic efficiency of the catalyst is improved.

The invention belongs to the technical field of cement manufacturing, and particularly relates to high-strength weather-resistant environment-friendly cement and a preparation method thereof. The environment-friendly cement is prepared from the following raw materials in parts by mass: 40 to 55 parts of Portland cement, 15 to 25 parts of fly ash, 10 to 15 parts of slag powder, 6 to 12 parts of biomass reinforced composite mineral material, 2 to 4 parts of nano silicon dioxide, 1 to 4 parts of modified polymer emulsion and 1 to 3 parts of additive. The biomass reinforced composite mineral material is prepared from zeolite, bentonite, sepiolite and chitosan; the modified polymer emulsion comprises a modified polyacrylate emulsion and a modified polystyrene-butadiene emulsion in a mass ratio of (1-3): 1; the additive is prepared from basalt fiber, sodium lignin sulfonate, a rosin thermopolymer and sodium gluconate. The environment-friendly cement prepared by the invention not only has high strength and good weather resistance, but also remarkably reduces carbon footprint and saves natural resources.

The invention relates to a high-strength stable solid waste-based composite cementing material and a preparation method and application thereof in the field of building materials. The high-strength stable solid waste-based composite cementing material is prepared from the following raw materials in parts by weight: 70-85 parts of composite solid waste micro powder; 10 to 20 parts of Portland cement clinker; 3-8 parts of a composite activator; 0.5 to 2 parts of a nano-scale function regulator; wherein the composite solid waste micro powder is prepared by mixing and grinding the following raw materials in parts by weight: 40-60 parts of blast furnace slag powder; 20 to 30 parts of fly ash; 10-20 parts of chemically modified electrolytic manganese residue powder; and 5-15 parts of steel slag powder. According to the preparation method, sodium metasilicate is adopted to assist medium-temperature calcination to chemically modify the electrolytic manganese residues, so that not only is the gelation activity of the electrolytic manganese residues effectively excited, but also free-state manganese, cadmium and other heavy metal ions in the electrolytic manganese residues are fixed in situ in newly formed zeolite-like silicate mineral lattices through thermochemical reconstruction; and a brand new technical path is opened up for safe and high-value utilization of the typical hazardous waste, namely the electrolytic manganese residues.

The invention discloses a zeolite adsorption and desorption integrated treatment system, and particularly relates to the field of zeolite separation treatment, and the zeolite adsorption and desorption integrated treatment system comprises a process sensing module, a dynamic partition control module, a global optimization control module and a cooling regeneration module. According to the zeolite adsorption and desorption integrated treatment system, the problem of blind operation in the traditional technology is solved through the process sensing module, a data basis is provided for dynamic partition, the intelligent monitoring level is improved, and the performance of an adsorbent is fully exerted; the problem of non-uniform heat and mass transfer of a bed layer is effectively solved through the dynamic partition control module, the desorption heat utilization efficiency is improved, and meanwhile, the service life of an adsorbent is prolonged; a dynamic optimization function is constructed through the global optimization control module, energy consumption, solvent recovery income and stability are comprehensively considered, self-adaptive adjustment of operation parameters is achieved, the energy consumption is reduced while the processing efficiency is guaranteed, and the environmental benefits are remarkably improved.

The invention relates to the technical field of analysis of physical and chemical properties of soil, in particular to a dry farming soil fertility rapid detection and fertility improvement method, which comprises the following steps: sorting a colloidal phase and a dissolved phase of a humic acid complex based on density difference and dielectric property difference through a gradient centrifugation and dielectrophoresis enriched physical field synergistic separation technology; a two-channel detection time sequence is optimized by adopting a genetic algorithm, a non-overlapping time sequence signal flow is generated by taking a signal interference suppression ratio as a fitness function, and time domain cross interference is suppressed. A programmable resistance-capacitance compensation model is constructed, parallel capacitor array parameters are dynamically adjusted to correct electrochemical phase angle offset, and a three-dimensional fertility distribution curved surface and a residual map are generated in combination with a Kriging interpolation model. On the basis of residual spectrum spatial distribution characteristics, a cross-linked slow-release system is deployed to improve the organic matter binding capacity of a humic acid deficiency area, a mesoporous zeolite-based passivator is applied to regulate and control an ion migration path, a closed-loop feedback mechanism is formed through dynamic phase response monitoring, and accurate detection and directional remediation of soil fertility are achieved.

The embodiment of the invention discloses an epoxy molding compound, an epoxy molding film and an electronic component, the epoxy molding compound comprises epoxy resin and a zeolite imidazole framework material, and the zeolite imidazole framework material comprises imidazole ligands and metal ions. The zeolite imidazole framework material is used as a curing agent and a nano reinforced phase, imidazole groups on the surface of the zeolite imidazole framework material can be subjected to a ring-opening reaction with epoxy resin to form covalent bonds, the zeolite imidazole framework material can induce the epoxy resin to generate a microcrack deflection mechanism, and the zeolite imidazole framework material can promote curing of the epoxy resin, so that the epoxy resin is cured, and the curing effect is improved. Therefore, the thermal expansion coefficient of the epoxy molding compound is reduced, the fracture toughness of the epoxy resin is improved, and the thermal stability of the epoxy molding compound is improved.

The invention provides a zeolite imidazate framework fluorescent material and a preparation method and application thereof, and belongs to the technical field of detection material preparation and environment. Quantum dots, a molecular imprinting technology and an MOFs material are combined, firstly, Mg and N co-doped graphene quantum dots and ZIF-8 are compounded, then imprinting is carried out on the surface of ZIF-8, and the zeolite imidazate framework fluorescent material based on MOFs is obtained. In the zeolite imidazate framework fluorescent material, Mg and N co-doped graphene quantum dots not only have good fluorescence performance, but also can generate electron transfer with SDZ to form hydrogen-bond-like acting force, imprinted holes similar to a target object in size and shape are reserved in the surface of the imprinted material, and the target object needing to be detected can be selectively recognized; the zeolite imidazate framework fluorescent material can be used for detecting sulfadiazine in the environment and has good practicability.

The invention relates to a concrete anti-cracking self-repairing agent in the technical field of building materials, and aims to solve the problem that concrete cracks are difficult to self-repair. According to the technical scheme, the self-repairing agent is characterized by comprising a microbial repairing unit formed by ZSM-5 type zeolite molecular sieve loaded bacillus pasteurii spores, mesoporous silica particles loaded with L-calcium aspartate and Fe3O4 (at) SiO2 core-shell nanoparticles which are fixed through an in-situ polymerization coating layer to form a magnetic thermal response capsule layer coating the surface of the microbial repairing unit, pLGA microspheres containing yeast extract are positioned on an interface of zeolite and hydrogel, and a trehalose-anhydrous calcium chloride eutectic compound is used as a directional mineralization accelerant. The concrete anti-cracking self-repairing agent provided by the invention is mainly used for intelligent identification and self-repairing of concrete cracks, and efficient repairing is realized through a microbial mineralization, calcium ion slow release and magnetic thermal response synergistic mechanism.

The invention relates to the technical field of proton exchange membrane fuel cell cathode catalysts, and discloses a nanoscale high-entropy intermetallic compound catalyst and a preparation method and application thereof. According to the nanoscale high-entropy intermetallic compound catalyst, a nitrogen-doped porous carbon material derived from zeolite imidazole skeleton-8 is taken as a carrier, and the metal elements of a high-entropy intermetallic compound comprise platinum, copper, cobalt, nickel and iron or platinum, ruthenium, copper, cobalt, nickel and iron. The preparation method of the catalyst comprises the following steps: step 1, preparing a zeolite imidazole framework 8; 2, preparing and purifying a nitrogen-doped porous carbon material carrier; step 3, loading a metal precursor; and 4, preparing the nano-scale high-entropy intermetallic compound catalyst. Nanoscale, high dispersity and structure ordering of the high-entropy intermetallic compound are achieved, the high-entropy intermetallic compound serves as a PEMFC cathode catalyst, the ORR quality activity and durability can be remarkably improved, and Pt loading capacity and cost are effectively reduced.

The invention relates to an SSZ-39 molecular sieve and preparation and application thereof.The preparation method comprises the following steps that 1, after water, an alkali source and a template agent are mixed, mesoporous Y zeolite and a silicon source are added, the mixture is stirred to be uniform, and the mixture is aged to be in a white gel shape; (2) transferring the obtained white gel into a reaction kettle, carrying out crystallization treatment, and filtering, washing, drying and calcining a crystallized product to obtain a Na-SSZ-39 molecular sieve; (3) carrying out ammonium ion exchange on the Na-SSZ-39 molecular sieve, filtering, washing, drying and calcining to obtain an H-SSZ-39 molecular sieve; and (4) carrying out copper ion exchange on the H-SSZ-39 molecular sieve, filtering, washing, drying and calcining to obtain the Cu-SSZ-39 catalyst. Aluminum used in the method is provided by mesoporous Y zeolite, the pure-phase SSZ-39 molecular sieve can be synthesized in a wide gel range, the crystallization time is shortened to 24 h, and after copper ion exchange, the pure-phase SSZ-39 molecular sieve shows high denitration activity in the selective catalytic reduction reaction of nitrogen oxide ammonia.

The present invention addresses the problem of providing a method for producing olefins that can sufficiently remove polyamides from waste plastics. [Solution] The method for producing olefins according to the present invention includes a thermal decomposition step of thermally decomposing a waste plastic raw material containing polyolefins and polyamides to obtain a hydrocarbon stream, a separation step of separating a thermal decomposition product of the polyamides from the hydrocarbon stream that has undergone the thermal decomposition step, and a catalytic cracking step of catalytically cracking the hydrocarbon stream that has undergone the separation step in the presence of a catalyst containing zeolite to obtain olefins.

The invention belongs to the technical field of fuel cell non-noble metal catalyst material preparation, and particularly relates to a composite carbon nanofiber catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, combining metal ions with an organic ligand in an organic solvent at room temperature to successfully prepare a zeolite imidazate framework material (ZIFs); the preparation method comprises the following steps: carrying out primary carbonization on a prepared ZIFs material in an inert atmosphere high-temperature furnace to obtain a metal nitrogen carbon material, then uniformly mixing the metal nitrogen carbon material with a spinning solution, carrying out electrostatic spinning to obtain composite nanofibers, and then carrying out secondary carbonization in an inert atmosphere to finally successfully prepare the composite carbon nanofiber catalyst (MN-CNF). The catalyst has excellent electrocatalytic activity, can effectively improve the efficiency of oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), and also has excellent catalytic stability.

The invention discloses light self-repairing concrete and a preparation method thereof, and relates to the technical field of concrete. The method comprises the following steps: firstly, efficiently packaging a calcium nitrate solution in hollow glass beads by utilizing a negative pressure impregnation technology; then growing a porous zeolite crystal coating on the surface of the microbead in situ by adopting a sol-gel method to form a self-repairing filler with a core-shell-hole gradient structure; when the concrete cracks to cause the cracking of the microbeads, the Ca < 2 + > in the cavity is quickly released, and the Ca < 2 + > adsorbed in the zeolite layer is gradually dissociated along with water permeation, so that the new microcracks are continuously repaired. Then, uniformly coating the surface and pores of the carboxymethyl cellulose hydrogel network with polydopamine in an in-situ oxidative polymerization manner to form composite hydrogel with photo-thermal responsiveness; lighting and heating to trigger dynamic coordination bond dissociation; meanwhile, heat drives rapid directional crystallization of a repair product by promoting the ion diffusion rate, and a compact mineralization layer is formed. The concrete prepared by the invention has the effects of light weight and self-repairing.

The invention discloses high-strength corrosion-resistant pervious concrete and a preparation method thereof, and belongs to the technical field of concrete. The concrete is prepared from the following raw materials in parts by weight: 200-300 parts of cement, 1000-1300 parts of coarse aggregate, 20-30 parts of a composite admixture, 10-20 parts of a reinforcing agent, 1-1.5 parts of a water reducing agent, 3-5 parts of an additive and 100-130 parts of water, the reinforcing agent is prepared from modified basalt fiber and styrene-acrylic emulsion according to the mass ratio of (8 to 10): 1; the additive is a SiO2 (at) PDA (at) zeolite composite material; the composite admixture is composed of fly ash and modified steel slag powder according to a mass ratio of 2: 1. According to the invention, by optimizing the proportion of a plurality of composite materials, the interface bonding property with a gel material matrix is improved, the mechanical property and durability are remarkably improved while the water permeability is maintained, and the corrosion resistance of the concrete matrix is enhanced.

The invention provides an organic waste gas treatment device based on zeolite molecular sieve adsorption and desorption treatment. The organic waste gas treatment device comprises an efficient pretreatment unit, a composite zeolite molecular sieve adsorption tower group, a plasma-assisted microwave-hot air regeneration unit, a multi-mode tail gas treatment unit, a digital twin intelligent regulation and control system and a modular expansion interface. By integrating the high-precision VOCs analyzer, the self-adaptive airflow controller, the infrared spectrometer, the multi-channel heat recoverer, the high-performance edge computing server and the intelligent pneumatic valve system, the optimized processing method realizes accurate execution of a formula, the VOCs removal rate is remarkably increased, and carbon loss and energy consumption are reduced. The method has the remarkable advantages in the aspects of VOCs removal rate, zeolite regeneration efficiency, energy consumption control and operation cost, meanwhile, through deep intelligent regulation and multi-mode treatment, the efficient, stable and low-cost VOCs treatment requirements under complex working conditions are met, and an innovative solution is provided for industrial waste gas treatment.

The invention discloses a method for immobilizing growth-promoting rhizobacteria by taking decarburized gangue-based biochar as a carrier, a solid waste-based microorganism immobilization ball prepared by the method and application of the solid waste-based microorganism immobilization ball, and relates to the technical field of solid waste utilization. The method comprises the following steps: preparing gangue-based zeolite by microwave activation and decarburization of coal gangue; preparing gangue-based biochar by utilizing phosphorus modification; and preparing the solid-waste-based microorganism solidification balls by utilizing an adsorption-embedding-crosslinking method. The decarburized gangue-based biochar is used as a carrier material for immobilizing the growth-promoting rhizosphere bacteria, and is used for restoring the sandy degraded soil in the northwest arid mining area. According to the technology, the survival time and functional activity of the growth-promoting rhizobacteria in the soil environment can be improved, and a new way is provided for consumption of bulk gangue solid waste. The method also has the technical advantages of improving the carbon source utilization rate of the gangue and increasing the phosphate fertilizer and the organic carbon library of the soil.

The invention discloses a Pt-loaded hierarchical pore HY molecular sieve double-effect catalyst and a preparation method and application thereof.The preparation method comprises the steps that firstly, an acid solution and an HY molecular sieve are mixed, heated and stirred, and the hierarchical pore HY molecular sieve is obtained; then, Pt salt is loaded on the hierarchical pore HY molecular sieve through an impregnation method, and the hierarchical pore HY molecular sieve is dried, calcined and then reduced. The concentration of the acid solution is not higher than 0.1 mol / L; the catalyst is used for hydrocracking of polyethylene or polypropylene. According to the Pt-loaded hierarchical pore HY molecular sieve double-effect catalyst disclosed by the invention, Pt atoms have excellent C-H bond activation capability, meanwhile, the hierarchical pore HY molecular sieve carrier has an open connection mesoporous structure and an acid site, and the mesoporous structure constructed by acid pickling and dealumination is beneficial to diffusion of a reaction intermediate and improvement of the yield of a liquid product; more orifice acid can be exposed by surface erosion, so that the initial cracking of reaction raw materials is facilitated, and the catalytic performance is improved.

According to the caisson wharf and the construction method thereof, a layered structure of a steel slag-rubber particle composite lower layer and a regenerated resin-basalt fiber composite upper layer is adopted for a base, and interface bonding is enhanced in combination with a silane coupling agent; the foundation bed is assembled by precast concrete modules and is poured by nano mortar; the caisson main body is provided with a positioning plate which is inserted into the guide groove, the caisson main body is filled with multi-graded steel slag fragments, and an independent airbag cavity is pre-buried in a bottom plate; the buoyancy control system dynamically adjusts the water injection rate based on multi-sensor data; the ecological permeable pipeline network adopts a diatomite-zeolite coating; the prestressed steel strand towing system is regulated and controlled in real time through the friction damper. The caisson wharf and the construction method thereof have the remarkable advantages in the aspects of structural stability, ecological friendliness, construction efficiency, intelligence and automation, the problems existing in a traditional caisson wharf can be effectively solved, and the requirements of modern port construction are met.

An oxygen evolution reaction electrocatalyst and a method for preparing said oxygen evolution reaction electrocatalyst are disclosed. The method comprises the steps of contacting a porous zeolite with a solution containing a noble metal precursor to form a noble metal doped zeolite, pyrolyzing the noble metal doped zeolite to form nanocrystals comprising at least the noble metal and a second metal, said nanocrystals being confined within a layer of carbon-based material, wherein the second metal and the carbon-based material are derived from the pyrolyzed zeolite, and annealing said layer of carbon-based material confined nanocrystals to form isolated noble metal atoms singly dispersed within a metal oxide lattice of the second metal as an oxygen evolution reaction electrocatalyst.

The invention provides a high-stability in-situ crystallization catalyst as well as a preparation method and application thereof, and belongs to the technical field of oil refining catalysts. The preparation method comprises the following steps: firstly preparing kaolin microspheres, then roasting the kaolin microspheres into high soil balls and partial soil balls, and mixing the high soil balls and partial soil balls with a silicon source, sodium hydroxide, a seed crystal and a silicon-aluminum activator for in-situ crystallization, so that not only is the activation degree of silicon dioxide in kaolin promoted, but also the timely insertion of active silicon species into a NaY zeolite skeleton in the crystallization process is accelerated, and the activity of the NaY zeolite is improved. The high-stability in-situ crystallization catalyst is prepared by carrying out ammonium salt and rare earth exchange, roasting and phosphorus or boron modification treatment on the crystallized microspheres, and has the characteristics of strong heavy oil conversion and metal pollution resistance and high total liquid yield when being used for catalyzing heavy oil cracking.

The invention belongs to the technical field of wastewater treatment, and particularly relates to a composite material as well as a preparation method and application thereof. According to the composite material, blended hydrogel of sodium alginate and polyvinyl alcohol is used as a matrix, zeolite molecular sieves, activated charcoal and zero-valent iron particles are embedded into the matrix to form microspheres, sulfate reducing bacteria are immobilized on the surfaces of the microspheres, the composite material is directly added into a mine water anaerobic reactor, the sulfate radical removal rate exceeds 92%, and the sulfate radical removal rate exceeds 92%. Heavy metals such as Cu, Pb and Cr in the mine water can be synchronously precipitated, and the treatment efficiency and stability of the anaerobic system are remarkably improved.

According to the microbial composite soil conditioner and the preparation method thereof, decomposition of organic matters in soil can be promoted through multiple microorganisms in the microbial composite soil conditioner, and the air permeability and the water-retaining property of the soil are improved. Meanwhile, the zeolite powder and the rice hull powder ash can improve the pore structure of the soil and improve the drainage capacity and the air permeability of the soil, so that the growth environment of the plant root system is optimized. The decomposed organic fertilizer and the edible fungus residue organic matter are rich in nutrient elements of nitrogen, phosphorus and potassium, and can provide continuous and stable nutrient supply for crops. In addition, the amino acid stock solution, the pyroligneous liquor and the molasses liquor contain various trace elements and bioactive substances, so that the disease resistance and the growth vitality of crops can be enhanced. Due to the improvement of the soil structure, the improvement of fertility and the enhancement of microbial activity, crops can better absorb nutrients and moisture, the occurrence of diseases and pests is reduced, and the increase of the crop yield and the crop quality are effectively improved.

The utility model discloses a zeolite rotating wheel adsorption and desorption purification waste gas treatment device, and belongs to the field of waste gas treatment. A zeolite rotating wheel adsorption and desorption purification waste gas treatment device comprises a filter box internally provided with a zeolite rotating wheel module and at least two filter screens arranged in the filter box, an ash receiving disc is arranged below the plane where the filter screens are located, and the zeolite rotating wheel adsorption and desorption purification waste gas treatment device further comprises a driving rod arranged at the air inlet ends of the filter screens in a sliding mode. The driving rod slides in the vertical direction of the plane where the filter screen is located, the wing plate is rotationally connected to the driving rod, the cleaning head is arranged at the free end of the wing plate, and when the driving rod slides, the cleaning head gets close to or away from the center of the plane where the filter screen is located. The cleaning system is independent of the filter screen, so that the whole protective cover or the filter screen assembly does not need to be disassembled when the filter screen is cleaned, and the maintenance time and cost are saved.

The invention discloses a metal particle Ni supported catalyst based on fly ash. The preparation method comprises the following steps: firstly, carrying out alkali fusion on fly ash to prepare powder; dissolving the powder and Ni (NO3) 2.6 H2O in a mixed solution of distilled water and absolute ethyl alcohol, adding polyethylene glycol, and performing ultrasonic stirring to obtain uniform dispersion liquid; and finally, continuously performing ultrasonic stirring on the dispersion liquid, performing hydrothermal reaction, cooling, performing centrifugal separation, drying, calcining, cooling and grinding to obtain the catalyst. The coal ash derivative zeolite is adopted as a carrier of the catalyst, Ni is loaded on the carrier to improve the specific surface and effective active sites of the carrier, the effective catalytic specific surface area of the catalyst is effectively improved, and the catalytic activity is improved, so that a stable and safe catalyst material for preparing methane through CO2 hydrogenation with high activity and selectivity is obtained; the space time yield of methane is high.

The invention discloses a high-efficiency composite catalyst for waste gas purification and a use method thereof, belongs to the technical field of catalysts, and aims to solve the technical problems that a zeolite molecular sieve used as a VOCs catalyst in the prior art is high in hydrophilicity, easy to cause a catalyst poisoning phenomenon and low in adsorption efficiency. The method comprises the following steps; the preparation method comprises the following steps: mixing styrene, divinyl benzene, a hydrophobic metal catalyst and a polar monomer, adding a related auxiliary agent to obtain an oil phase, mixing the oil phase and a water phase, and carrying out post-process treatment to obtain the high-efficiency composite catalyst for waste gas purification. A zeolite molecular sieve is used as a carrier, a hydrophobic inorganic adsorption material is prepared through modification of a modified fluorine-containing silane coupling agent, then the hydrophobic inorganic adsorption material is soaked in a mixed transition metal oxide solution, and the hydrophobic metal catalyst is obtained and has the advantage of being high in catalytic efficiency.

The invention discloses a method for synthesizing artificial soil by using solid waste, which comprises the following steps: a, primary mixing: mixing 1-3 parts by weight of river sludge, 1-2 parts by weight of fly ash, 1-2 parts by weight of livestock manure, 0.2-0.4 part by weight of zeolite powder and 0.1-0.2 part by weight of leavening agent by using solid waste mixing equipment, b, fermenting and covering a film for high-temperature oxygen-consuming fermentation to obtain a mixture A, and c, mixing: mixing the mixture A and the mixture B in parts by weight to obtain the artificial soil. 2-4 parts of the mixture A, 1-3 parts of fly ash, 0.2-2 parts of desulfurized gypsum, 0.02 part of zeolite powder, 0.01-1 part of an ecological mineral nutrient modifier and 0.01-0.05 part of an ecological nutrient rejuvenation agent are mixed, d, synthesis is conducted, after a high-speed blade crusher is used for scattering, a blowing-away machine is used for blowing away, and the artificial soil is obtained. The problem that in the prior art, solid waste and an added modifier are difficult to evenly mix, and consequently part of areas are not suitable for crop growth is solved.

The invention discloses a cracking dechlorination catalyst as well as a preparation method and application thereof. The cracking dechlorination catalyst comprises zeolite, an adsorbent and a carrier, the zeolite is selected from at least one of an MFI structure, an FAU structure and an MEL structure; the adsorbent is selected from at least one of metal oxide and carbonate; and the carrier is selected from one of a carbon material and carbide. The invention provides a catalyst for one-step catalytic cracking-dechlorination of waste plastics, which can realize oil recovery and chlorine impurity removal in one step in catalytic cracking of chlorine-containing waste plastics.

The invention discloses a lithium slag composite admixture, low-carbon lithium slag concrete and a preparation method thereof, and belongs to the technical field of concrete. The method comprises the following steps: preparing calcium type lithium slag synthetic zeolite from lithium slag; waste liquid generated in the preparation process of synthesizing zeolite from the calcium-type lithium slag is used for preparing lithium slag-based negative calcium mesoporous silicon dioxide; and finally, mixing the calcium type lithium slag synthetic zeolite, the lithium slag-based negative calcium mesoporous silica and the original lithium slag to obtain the composite admixture. The problem that the content of SO3 in the lithium slag concrete is too high under the large mixing amount is solved, meanwhile, the technical defects that the activity of the lithium slag is insufficient and the concrete strength is low are overcome, the cracking risk of the lithium slag concrete is effectively reduced, the compactness and the working performance of the lithium slag concrete are comprehensively improved, and high-added-value resource utilization of the lithium slag solid waste is achieved.

The invention belongs to the technical field of nanocrystal nucleus early strength agents, and provides a damp and hot nanocrystal nucleus early strength agent, a tailing solidification filling material and a preparation method and application of the damp and hot nanocrystal nucleus early strength agent and the tailing solidification filling material. The invention discloses a molybdenum ore tailing slurry which is prepared from the following raw materials in parts by weight: 1 part of Portland cement, 4 to 6 parts of molybdenum ore tailings, 0.06 to 0.1 part of zeolite powder, 0.07 to 0.1 part of nanoscale attapulgite powder, 0.06 to 0.1 part of gamma-glycidyl ether oxypropyl trimethoxy silane, 0.03 to 0.1 part of potassium silicate, 0.04 to 0.1 part of sodium hydroxide, 0.06 to 0.1 part of calcium formate, 0.04 to 0.1 part of lithium metaaluminate and 1.25 to 1.75 parts of water. According to the technical scheme, the problem that a filling body prepared from an early strength agent in the prior art is low in early and later strength is solved, and meanwhile, the early strength agent is simple and convenient in preparation mode, low in cost and wide in application range.