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2561 results about "Zeolite" patented technology

Zeolites are microporous, aluminosilicate minerals commonly used as commercial adsorbents and catalysts. The term zeolite was originally coined in 1756 by Swedish mineralogist Axel Fredrik Cronstedt, who observed that rapidly heating the material, believed to have been stilbite, produced large amounts of steam from water that had been adsorbed by the material. Based on this, he called the material zeolite, from the Greek ζέω (zéō), meaning "to boil" and λίθος (líthos), meaning "stone". The classic reference for the field has been Breck's book Zeolite Molecular Sieves: Structure, Chemistry, And Use.

High-strength stable solid-waste-based composite cementing material as well as preparation method and application thereof

ActiveCN121085599ASodium metasilicateSlag
The invention relates to a high-strength stable solid waste-based composite cementing material and a preparation method and application thereof in the field of building materials. The high-strength stable solid waste-based composite cementing material is prepared from the following raw materials in parts by weight: 70-85 parts of composite solid waste micro powder; 10 to 20 parts of Portland cement clinker; 3-8 parts of a composite activator; 0.5 to 2 parts of a nano-scale function regulator; wherein the composite solid waste micro powder is prepared by mixing and grinding the following raw materials in parts by weight: 40-60 parts of blast furnace slag powder; 20 to 30 parts of fly ash; 10-20 parts of chemically modified electrolytic manganese residue powder; and 5-15 parts of steel slag powder. According to the preparation method, sodium metasilicate is adopted to assist medium-temperature calcination to chemically modify the electrolytic manganese residues, so that not only is the gelation activity of the electrolytic manganese residues effectively excited, but also free-state manganese, cadmium and other heavy metal ions in the electrolytic manganese residues are fixed in situ in newly formed zeolite-like silicate mineral lattices through thermochemical reconstruction; and a brand new technical path is opened up for safe and high-value utilization of the typical hazardous waste, namely the electrolytic manganese residues.
Owner:LUOYANG INST OF SCI & TECH

Zeolite adsorption and desorption integrated treatment system

The invention discloses a zeolite adsorption and desorption integrated treatment system, and particularly relates to the field of zeolite separation treatment, and the zeolite adsorption and desorption integrated treatment system comprises a process sensing module, a dynamic partition control module, a global optimization control module and a cooling regeneration module. According to the zeolite adsorption and desorption integrated treatment system, the problem of blind operation in the traditional technology is solved through the process sensing module, a data basis is provided for dynamic partition, the intelligent monitoring level is improved, and the performance of an adsorbent is fully exerted; the problem of non-uniform heat and mass transfer of a bed layer is effectively solved through the dynamic partition control module, the desorption heat utilization efficiency is improved, and meanwhile, the service life of an adsorbent is prolonged; a dynamic optimization function is constructed through the global optimization control module, energy consumption, solvent recovery income and stability are comprehensively considered, self-adaptive adjustment of operation parameters is achieved, the energy consumption is reduced while the processing efficiency is guaranteed, and the environmental benefits are remarkably improved.
Owner:QINGDAO ZHONGZHOU LANKAI ENVIRONMENTAL PROTECTION TECH CO LTD

Epoxy molding compound, epoxy molding film and electronic component

The embodiment of the invention discloses an epoxy molding compound, an epoxy molding film and an electronic component, the epoxy molding compound comprises epoxy resin and a zeolite imidazole framework material, and the zeolite imidazole framework material comprises imidazole ligands and metal ions. The zeolite imidazole framework material is used as a curing agent and a nano reinforced phase, imidazole groups on the surface of the zeolite imidazole framework material can be subjected to a ring-opening reaction with epoxy resin to form covalent bonds, the zeolite imidazole framework material can induce the epoxy resin to generate a microcrack deflection mechanism, and the zeolite imidazole framework material can promote curing of the epoxy resin, so that the epoxy resin is cured, and the curing effect is improved. Therefore, the thermal expansion coefficient of the epoxy molding compound is reduced, the fracture toughness of the epoxy resin is improved, and the thermal stability of the epoxy molding compound is improved.
Owner:SHENZHEN INST OF ADVANCED ELECTRONICS MATERIALS

Concrete anti-cracking self-repairing agent and preparation method thereof

The invention relates to a concrete anti-cracking self-repairing agent in the technical field of building materials, and aims to solve the problem that concrete cracks are difficult to self-repair. According to the technical scheme, the self-repairing agent is characterized by comprising a microbial repairing unit formed by ZSM-5 type zeolite molecular sieve loaded bacillus pasteurii spores, mesoporous silica particles loaded with L-calcium aspartate and Fe3O4 (at) SiO2 core-shell nanoparticles which are fixed through an in-situ polymerization coating layer to form a magnetic thermal response capsule layer coating the surface of the microbial repairing unit, pLGA microspheres containing yeast extract are positioned on an interface of zeolite and hydrogel, and a trehalose-anhydrous calcium chloride eutectic compound is used as a directional mineralization accelerant. The concrete anti-cracking self-repairing agent provided by the invention is mainly used for intelligent identification and self-repairing of concrete cracks, and efficient repairing is realized through a microbial mineralization, calcium ion slow release and magnetic thermal response synergistic mechanism.
Owner:GUANGZHOU CITY CONSTR COLLEGE

Nanoscale high-entropy intermetallic compound catalyst as well as preparation method and application thereof

The invention relates to the technical field of proton exchange membrane fuel cell cathode catalysts, and discloses a nanoscale high-entropy intermetallic compound catalyst and a preparation method and application thereof. According to the nanoscale high-entropy intermetallic compound catalyst, a nitrogen-doped porous carbon material derived from zeolite imidazole skeleton-8 is taken as a carrier, and the metal elements of a high-entropy intermetallic compound comprise platinum, copper, cobalt, nickel and iron or platinum, ruthenium, copper, cobalt, nickel and iron. The preparation method of the catalyst comprises the following steps: step 1, preparing a zeolite imidazole framework 8; 2, preparing and purifying a nitrogen-doped porous carbon material carrier; step 3, loading a metal precursor; and 4, preparing the nano-scale high-entropy intermetallic compound catalyst. Nanoscale, high dispersity and structure ordering of the high-entropy intermetallic compound are achieved, the high-entropy intermetallic compound serves as a PEMFC cathode catalyst, the ORR quality activity and durability can be remarkably improved, and Pt loading capacity and cost are effectively reduced.
Owner:SHAANXI HYDROGEN ENERGY RES INST CO LTD

SSZ-39 molecular sieve as well as preparation and application thereof

The invention relates to an SSZ-39 molecular sieve and preparation and application thereof.The preparation method comprises the following steps that 1, after water, an alkali source and a template agent are mixed, mesoporous Y zeolite and a silicon source are added, the mixture is stirred to be uniform, and the mixture is aged to be in a white gel shape; (2) transferring the obtained white gel into a reaction kettle, carrying out crystallization treatment, and filtering, washing, drying and calcining a crystallized product to obtain a Na-SSZ-39 molecular sieve; (3) carrying out ammonium ion exchange on the Na-SSZ-39 molecular sieve, filtering, washing, drying and calcining to obtain an H-SSZ-39 molecular sieve; and (4) carrying out copper ion exchange on the H-SSZ-39 molecular sieve, filtering, washing, drying and calcining to obtain the Cu-SSZ-39 catalyst. Aluminum used in the method is provided by mesoporous Y zeolite, the pure-phase SSZ-39 molecular sieve can be synthesized in a wide gel range, the crystallization time is shortened to 24 h, and after copper ion exchange, the pure-phase SSZ-39 molecular sieve shows high denitration activity in the selective catalytic reduction reaction of nitrogen oxide ammonia.
Owner:SHANGHAI INST OF TECH

Olefin production process

The present invention addresses the problem of providing a method for producing olefins that can sufficiently remove polyamides from waste plastics. [Solution] The method for producing olefins according to the present invention includes a thermal decomposition step of thermally decomposing a waste plastic raw material containing polyolefins and polyamides to obtain a hydrocarbon stream, a separation step of separating a thermal decomposition product of the polyamides from the hydrocarbon stream that has undergone the thermal decomposition step, and a catalytic cracking step of catalytically cracking the hydrocarbon stream that has undergone the separation step in the presence of a catalyst containing zeolite to obtain olefins.
Owner:SUMITOMO CHEM CO LTD

Organic waste gas treatment device based on adsorption and desorption treatment of zeolite molecular sieve

The invention provides an organic waste gas treatment device based on zeolite molecular sieve adsorption and desorption treatment. The organic waste gas treatment device comprises an efficient pretreatment unit, a composite zeolite molecular sieve adsorption tower group, a plasma-assisted microwave-hot air regeneration unit, a multi-mode tail gas treatment unit, a digital twin intelligent regulation and control system and a modular expansion interface. By integrating the high-precision VOCs analyzer, the self-adaptive airflow controller, the infrared spectrometer, the multi-channel heat recoverer, the high-performance edge computing server and the intelligent pneumatic valve system, the optimized processing method realizes accurate execution of a formula, the VOCs removal rate is remarkably increased, and carbon loss and energy consumption are reduced. The method has the remarkable advantages in the aspects of VOCs removal rate, zeolite regeneration efficiency, energy consumption control and operation cost, meanwhile, through deep intelligent regulation and multi-mode treatment, the efficient, stable and low-cost VOCs treatment requirements under complex working conditions are met, and an innovative solution is provided for industrial waste gas treatment.
Owner:JIANGSU QIQING ENVIRONMENTAL TECH CO LTD

Composite material as well as preparation method and application thereof

The invention belongs to the technical field of wastewater treatment, and particularly relates to a composite material as well as a preparation method and application thereof. According to the composite material, blended hydrogel of sodium alginate and polyvinyl alcohol is used as a matrix, zeolite molecular sieves, activated charcoal and zero-valent iron particles are embedded into the matrix to form microspheres, sulfate reducing bacteria are immobilized on the surfaces of the microspheres, the composite material is directly added into a mine water anaerobic reactor, the sulfate radical removal rate exceeds 92%, and the sulfate radical removal rate exceeds 92%. Heavy metals such as Cu, Pb and Cr in the mine water can be synchronously precipitated, and the treatment efficiency and stability of the anaerobic system are remarkably improved.
Owner:SHANDONG JIANZHU UNIV

Cracking dechlorination catalyst as well as preparation method and application thereof

The invention discloses a cracking dechlorination catalyst as well as a preparation method and application thereof. The cracking dechlorination catalyst comprises zeolite, an adsorbent and a carrier, the zeolite is selected from at least one of an MFI structure, an FAU structure and an MEL structure; the adsorbent is selected from at least one of metal oxide and carbonate; and the carrier is selected from one of a carbon material and carbide. The invention provides a catalyst for one-step catalytic cracking-dechlorination of waste plastics, which can realize oil recovery and chlorine impurity removal in one step in catalytic cracking of chlorine-containing waste plastics.
Owner:DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES +1

Damp and hot nanometer crystal nucleus early strength agent, tailing solidification filling material and preparation method and application of damp and hot nanometer crystal nucleus early strength agent and tailing solidification filling material

The invention belongs to the technical field of nanocrystal nucleus early strength agents, and provides a damp and hot nanocrystal nucleus early strength agent, a tailing solidification filling material and a preparation method and application of the damp and hot nanocrystal nucleus early strength agent and the tailing solidification filling material. The invention discloses a molybdenum ore tailing slurry which is prepared from the following raw materials in parts by weight: 1 part of Portland cement, 4 to 6 parts of molybdenum ore tailings, 0.06 to 0.1 part of zeolite powder, 0.07 to 0.1 part of nanoscale attapulgite powder, 0.06 to 0.1 part of gamma-glycidyl ether oxypropyl trimethoxy silane, 0.03 to 0.1 part of potassium silicate, 0.04 to 0.1 part of sodium hydroxide, 0.06 to 0.1 part of calcium formate, 0.04 to 0.1 part of lithium metaaluminate and 1.25 to 1.75 parts of water. According to the technical scheme, the problem that a filling body prepared from an early strength agent in the prior art is low in early and later strength is solved, and meanwhile, the early strength agent is simple and convenient in preparation mode, low in cost and wide in application range.
Owner:HEBEI GUANGKAI BUILDING MATERIALS TECH CO LTD

Humic acid coated zeolite-based nutrient slow-release fertilizer as well as preparation method and application thereof

The invention discloses a humic acid coated zeolite-based nutrient-loaded slow-release fertilizer as well as a preparation method and application thereof. The slow-release fertilizer comprises a zeolite-based core and a humic acid polymer coating coated outside the zeolite-based core. The slow release fertilizer provided by the invention not only retains the original high-loading nutrient loading function of the nano composite zeolite material, but also endows the nano composite zeolite material with chemically stable ion exchange and adsorption functions, thereby thoroughly getting rid of the original'instant nutrient fertilizer salt core '; the slow-release fertilizer provided by the invention takes artificial humic acid as a coating material, so that the use of chemical organic materials and solvents is completely avoided. According to the invention, the conversion of the inorganic fly ash solid waste and the organic biomass solid waste from raw materials to the ecological slow-release fertilizer is realized. Meanwhile, the efficient conversion of zeolitization and humification in the chemical industrial process realizes the large-scale production of the zeolite-based material doped with the heterogeneous metal in the pore cage frame structure and the carbon-negative humic acid polymer material.
Owner:SHENZHEN CTRUST TESTING TECH CO LTD

Oxygen generator with oxygen output concentration monitoring and pre-compensation functions

The invention relates to the technical field of oxygen generators, in particular to an oxygen generator with oxygen output concentration monitoring and pre-compensation functions. The oxygen generator comprises a lower buffer valve, a lower buffer communication valve, an upper buffer valve, a lower buffer valve, a data acquisition module, a data processing module and an adjusting module, wherein the data acquisition module is used for acquiring pressure data and oxygen concentration at an outlet of the oxygen generator; the data processing module is used for obtaining the high-pressure degree of each circulation according to the pressure data and the oxygen concentration at the outlet of each cycle of each circulation of oxygen discharge, and then determining the high-pressure duration and the current compensation demand degree; acquiring a slow voltage-sharing demand factor according to the current compensation demand degree and the duration of the high-voltage duration; and the adjusting module is used for adjusting opening and closing of the valve according to the slow pressure equalizing demand. According to the invention, the influence of temperature on the adsorption efficiency of the zeolite molecular sieve is reduced, the concentration of oxygen produced by the oxygen generator is maintained, and the pre-compensation of the oxygen concentration is realized.
Owner:HUNAN ETER ELECTRONICS MEDICAL PROJECT

Saline-alkali soil improvement and disease resistance double-effect controlled release fertilizer and preparation method thereof

The invention discloses a saline-alkali soil improvement and disease resistance double-effect controlled release fertilizer and a preparation method thereof. The fertilizer comprises 18-22% of biochar, 12-18% of furfural residues, 8-12% of cow dung compost and 6-10% of potassium humate. 5-7% of aluminum sulfate, 4-6% of sulfur and 3-5% of zeolite; the microbial inoculum comprises the following components in percentage by weight: 1.5 to 2.5 percent of saline-alkaline bacillus, 0.8 to 1.2 percent of bacillus subtilis and 0.8 to 1.2 percent 8-12% of a sodium polyacrylate coating, 4-6% of a sulfur coating and 1-3% of polyglutamic acid; 0.8 to 1.2 percent of humic acid chelated iron, 0.8 to 1.2 percent of algal polysaccharide and 0.8 to 1.2 percent of urease inhibitor; 0.8 to 1.2 percent of zinc sulfate, 0.5 to 1.0 percent of manganese sulfate and 0.5 to 1.0 percent of borax. The fertilizer can reduce the pH and conductivity of soil, increase the organic matter content of the soil and effectively improve the physicochemical properties of the soil, meanwhile, by adding the microbial agent, the disease resistance of crops can be effectively improved, the morbidity and disease index of the crops can be reduced, and nutrient release of the fertilizer has a sustained and controlled release characteristic; the initial release rate and the cumulative release rate of nitrogen are both lower than those of common chemical fertilizers, and the cumulative release rate of nitrogen is moderate within 60 days, so that the nutrient requirements of crops in different growth stages can be met.
Owner:HUBEI EZHONG ECOLOGICAL AGRI TECH CO LTD

Needle-like graphic nano-structure SERS substrate and preparation method thereof

The invention discloses an SERS (Surface Enhanced Raman Scattering) substrate with a needle-like diagram nanostructure and a preparation method of the SERS substrate, and belongs to the field of nanotechnology and detection. The preparation method of the needle-like Turing nano-structure SERS substrate comprises the following steps: by taking a silver needle as a carrier, carrying out electrochemical etching on the surface of the silver needle to induce to form a Turing nano-structure with fractal topological characteristics, and then inducing to conformally grow a layer of zeolite imidazole framework-8 material as a shell layer by utilizing the nano curvature characteristics of the fractal structure, so as to prepare the needle-like Turing nano-structure SERS substrate. And a composite SERS enhanced platform with an electromagnetic field hot spot aggregation effect and a molecular screening and enriching capability is constructed. The platform has the advantages of high structural uniformity, expandability in manufacturing, synergy of signal enhancement and molecular recognition and the like, remarkably improves the detection sensitivity and the signal reproducibility, and is suitable for trace analysis in a complex sample system, such as related application in the fields of food safety, environmental pollution monitoring, biomedicine and the like.
Owner:JIANGNAN UNIV

Carbon quantum dot / metal organic framework composite material as well as preparation method and application thereof

The invention discloses a carbon quantum dot / metal organic framework composite material as well as a preparation method and application thereof, and the method is characterized in that carbon quantum dots derived from waterborne polyurethane are embedded into a zeolite imidazate framework 8 to prepare the carbon quantum dot / metal organic framework composite material. The composite material can be used as a ratio type fluorescent probe for trace detection of tetracycline, a dual-emission fluorescence signal of the probe is derived from tetracycline which quenches blue fluorescence of puCDs at 450 nm through an inner filter effect, and the coordination effect between Zn < 2 + > and tetracycline triggers an aggregation-induced emission effect, so that new fluorescence emission is generated, and the detection sensitivity is improved. The intensity of the two signals changes in proportion to the concentration of tetracycline, the wide linear concentration detection range and the low detection limit are achieved, the probe has the high recovery rate and the large adsorption capacity in detection, the problems that a traditional detection method is insufficient in sensitivity, poor in anti-interference capacity, high in cost and the like are solved, and the application prospect is wide. A new thought is provided for constructing a ratio type fluorescent probe with a removal function.
Owner:HUNAN UNIV OF TECH

Intelligent integrated oxygen production and cooperative regulation and control method for micro-pressure oxygen cabin

The invention relates to the technical field of micro-pressure oxygen cabins, in particular to an intelligent integrated oxygen generation and coordinated regulation and control method for a micro-pressure oxygen cabin, which comprises the following steps: supplying air to a cabin body of the micro-pressure oxygen cabin by adopting an air compressor, stably increasing the pressure in the micro-pressure oxygen cabin and stabilizing the pressure at a preset treatment pressure of 30kPa-50kPa through an intelligent pressure regulation and control system, high-pressure air in the micro-pressure oxygen cabin body serves as an oxygen production source and is conveyed to the VPSA oxygen production main machine; the VPSA oxygen production main machine adsorbs nitrogen through a zeolite molecular sieve filled in the VPSA oxygen production main machine and collects oxygen; s2, pressurizing the oxygen collected in the step S2 to 0.1-0.4 MPa or above through a supercharger, conveying the oxygen back into the micro-pressure oxygen cabin body, and allowing the user to breathe through an oxygen supply device; an intelligent cooperative control system is constructed, integrated management is carried out on the whole process of pressure boosting, pressure stabilization, oxygen generation, oxygen supply, safety and environment regulation and control, the occupied area and the purchase cost of equipment are reduced, the human error risk is reduced, and the micro-pressure oxygen treatment requirement under multiple scenes is met.
Owner:WEIHAI BERLIN VONCON OXYGEN TECHNOLOGY CO LTD +1

Low-concentration carbon dioxide trapping system and method

The invention discloses a low-concentration carbon dioxide trapping system and method, and belongs to the technical field of gas separation and trapping. The system comprises an air filter, a zeolite adsorption rotating wheel, a desorption heater, a desorption fan, a centrifugal fan, a pressure swing adsorption module (at least comprising double towers), a vacuum pump, a CO2 storage tank, a rear-end purification and utilization system and a control system. According to the method, trapping is realized through pretreatment, first-stage adsorption concentration, desorption transfer, second-stage purification, collection and storage and circulating operation. The zeolite adsorption rotating wheel is used for adsorbing and concentrating low-concentration CO2, and then the low-concentration CO2 is purified through the pressure swing adsorption module, so that the problems of low low-concentration trapping efficiency and high energy consumption in the prior art are solved. The device has the advantages of high trapping efficiency, low energy consumption, continuous operation, wide application scene and the like, is suitable for trapping low-concentration CO2 in atmosphere and industrial tail gas, and provides an efficient technical scheme for carbon emission reduction.
Owner:SHANDONG SHANLAN ENVIRONMENTAL GROUP CO LTD

Organic-inorganic composite silicon-calcium-magnesium fertilizer as well as preparation method and application thereof

The invention relates to the technical field of agricultural fertilizers, in particular to an organic-inorganic composite silicon-calcium-magnesium fertilizer and a preparation method and application of the organic-inorganic composite silicon-calcium-magnesium fertilizer. The high-temperature activated silicon-calcium-magnesium mineral powder is composed of calcined wollastonite powder, calcined serpentine powder, dolomite powder and zeolite powder; 2%-5% of an organosilane modifier, wherein the organosilane modifier is composed of gamma-aminopropyl triethoxy silane and gamma-glycidyl ether oxypropyl trimethoxy silane, and the organic silane modifier is composed of gamma-aminopropyl triethoxy silane and gamma-glycidyl ether oxypropyl trimethoxy silane; 18%-35% of a functional organic matter complex, wherein the functional organic matter complex is composed of mineral source sodium humate, bioactive small peptide, sodium alginate and polyglutamic acid; and 3%-8% of auxiliary functional components, so that the solubility and the bioavailability of silicon, calcium and magnesium elements in minerals are remarkably improved.
Owner:YISI (HEILONGJIANG) BIOTECHNOLOGY DEVELOPMENT CO LTD

Fungicide compound fertilizer for sand land and preparation method of fungicide compound fertilizer

The invention provides a microbial agent compound fertilizer for sandy land and a preparation method thereof, and relates to the technical field of compound fertilizers. The invention relates to a microbial inoculum compound fertilizer for sandy land. The soil conditioner is prepared from the following raw materials in parts by mass: 40 to 60 parts of compost, 0.3 to 0.8 part of nitrogen-fixing bacteria, 0.3 to 0.8 part of phosphate solubilizing bacteria, 0.3 to 0.8 part of potassium bacteria, 8 to 12 parts of charcoal, 8 to 12 parts of zeolite, 9 to 13 parts of perlite, 4 to 6 parts of vermiculite, 1 to 3 parts of seaweed extract, 2 to 4 parts of humic acid, 1 to 7 parts of waste cellulose nanocrystals, 30 to 40 parts of insect debris, 0.3 to 3 parts of nano carbon dots, 3 to 9 parts of lime and 8 to 15 parts of wood fiber. The compound fertilizer disclosed by the invention not only is rich in various necessary nutrient elements, but also has a good slow release effect and a good soil improvement function, can effectively improve soil fertility and promote plant growth through the action of various biological strains, and also has the characteristics of environmental protection and no pollution by utilizing the waste cellulose nanocrystals and the insect remains.
Owner:TIANJIN YIKANGYUAN AGRICULTURAL TECHNOLOGY DEVELOPMENT CO LTD

Volatile organic compound (VOC) waste gas recovery treatment device for color-coated sheet production

The invention discloses a VOC waste gas recovery treatment device for color-coated sheet production, and relates to the technical field of VOC waste gas recovery treatment. The VOC waste gas recovery treatment device for color-coated sheet production comprises a shell and a zeolite rotating wheel assembly installed in the shell, an adsorption area, a desorption area and a cooling area are arranged on the zeolite rotating wheel assembly, and the VOC waste gas recovery treatment device further comprises a filter screen disc which is arranged on a waste gas inlet path of the zeolite rotating wheel assembly, located on the upstream of the adsorption area and used for filtering waste gas entering the adsorption area. Reverse back flushing of desorption gas of the zeolite rotating wheel assembly is utilized, non-contact cleaning of sweeps on the filter screen discs is achieved, additional ventilation is not needed, the cost is reduced, step-by-step interception and dynamic cleaning of particulate matter in waste gas are achieved through arrangement of the multiple layers of filter screen discs and time-sharing rotation control, and the service life of the filter screen discs is prolonged. Physical abrasion of a traditional scraper cleaning mode to the filter screen is effectively avoided, and the service life of a filtering system is remarkably prolonged.
Owner:山东三谊工贸有限公司

Air separation processes using zeolite ITQ-55

This disclosure relates to the adsorption and separation of fluid components, such as oxygen, in a feed stream, such as air, using zeolite ITQ-55 as the adsorbent. A process is disclosed for adsorbing oxygen from a feed stream containing oxygen, nitrogen and argon. The process comprises passing the feed stream through a bed of an adsorbent comprising zeolite ITQ-55 to adsorb oxygen from the feed stream, carrying out an equalization step to improve recovery, thereby producing a nitrogen product stream depleted in oxygen as well as a waste stream can be collected to have enriched oxygen. The feed stream is exposed to the zeolite ITQ-55 at effective conditions for performing a rapid cycle of kinetic separation, in which oxygen exhibits greater kinetic selectivity than nitrogen and argon.
Owner:EXXONMOBIL TECHNOLOGY & ENGINEERING CO

Oxygen separation device for pressure swing adsorption system

The invention discloses an oxygen separation device for a pressure swing adsorption system, and relates to the technical field of oxygen separation. The oxygen separation device for the pressure swing adsorption system comprises an oxygen separation tank; the central shaft is arranged in the oxygen separation tank in the axial direction of the oxygen separation tank and can rotate around the axis of the central shaft; the zeolite molecular sieves sleeve the outer side of the central shaft and are uniformly distributed along the axial direction of the central shaft; and the up-down transposition mechanism is arranged on the zeolite molecular sieve, can synchronously act along with the rotation of the central shaft, and is used for driving the zeolite particles to generate position alternation in the axial direction. By arranging the up-down transposition mechanism synchronously acting with the rotary drum, the zeolite particles are driven to continuously perform ordered position alternation in the axial direction, so that dynamic cyclic replacement of adsorption areas is realized, the zeolite particles at different positions alternately participate in the adsorption process, the load of each area is effectively balanced, and local premature failure is prevented.
Owner:WEIKAIRUI ENERGY EQUIPMENT TECHNOLOGY (SHANDONG) CO LTD

Sequential pressurization treatment method to form a silver-silicalite coated substrate

A method of making a silver-silicalite coating on a surface of a stainless-steel substrate is provided. The method includes mixing metakaolin with an aqueous solution of NaOH to form a first mixture. The method further includes mixing silica gel and silver nitrate with the first mixture to form a second mixture. Furthermore, the method includes mixing Zeolites Socony Mobil-5 (ZSM-5) with the second mixture to form a third mixture. The method further includes hydrothermally treating the stainless-steel substrate with the third mixture to form the silver-silicalite coating on the surface of the stainless-steel substrate. The hydrothermal treatment is carried out in the absence of an organic template. The stainless-steel substrate coated with the silver-silicalite coating, prepared by the method of the present disclosure, has lower corrosion in comparison to the same stainless-steel substrate without the silver-silicalite coating.
Owner:IMAM ABDULRAHMAN BIN FAISAL UNIV

Method for improving yield of components of aviation kerosene prepared by ethylene oligomerization through combination of fixed bed and slurry bed

The invention relates to a heterogeneous catalysis technology, and aims to provide a method for improving the yield of components of aviation kerosene prepared by ethylene oligomerization through combination of a fixed bed and a slurry bed. Comprising a fixed bed reactor and a slurry bed reactor which are sequentially connected in series, the fixed bed reactor is filled with a metal modified mesoporous zeolite molecular sieve catalyst, and the slurry bed reactor is filled with a mesoporous zeolite molecular sieve catalyst. The method comprises the following steps: firstly, carrying out ethylene oligomerization reaction in a fixed bed reactor to generate a product containing C4-C8 olefin; the reaction product is directly introduced into the fixed bed reactors connected in series for secondary reaction, and the final product comprises C5-C16 + liquid phase olefin as an aviation fuel component. By adopting a fixed bed-slurry bed reactor combined method, the ethylene conversion rate can be greatly improved; secondary oligomerization is carried out by using an acidic mesoporous zeolite molecular sieve catalyst, so that the selectivity of aviation kerosene components is improved; the mesoporous catalyst prepared by an alkali treatment method has a good diffusion effect and keeps high activity for a long time.
Owner:ZHEJIANG UNIV

Zeolite rotating wheel waste gas treatment device

The invention relates to the technical field of waste gas treatment, in particular to a zeolite rotating wheel waste gas treatment device which comprises a filtering mechanism, and the filtering mechanism comprises a filtering assembly arranged on the inner side of a treatment tank; the treatment mechanism comprises a driving assembly arranged at the top of the treatment tank, the surface of the driving assembly is in transmission connection with an opening and closing part and a rotating part, the opening and closing part and the rotating part are in linkage through an output rod, and opening and closing of an air inlet pipe can be controlled through an opening and closing plate to achieve air inlet and air closing adjustment; an extrusion rod, a moving plate, a rotating ring and the like can be used for driving a second filter cartridge to rotate, the second filter cartridge is vibrated under the action of an extrusion block, a vibration block, a concave plate and the like, impurities are conveniently collected into a collecting box through a discharging pipe, and then the impurities are staggered with filter holes in the surface of a first filter cartridge under the rotating action of the second filter cartridge; and the pollution to the environment caused by exhaust of the waste gas when the impurities are discharged is greatly reduced.
Owner:JINAN WORLD EXPO COATING ENVIRONMENTAL PROTECTION EQUIP CO LTD

Small-grain mordenite molecular sieve as well as preparation method and application thereof

The invention discloses a small-grain mordenite molecular sieve as well as a preparation method and application thereof, a crystallization process is directionally controlled by adopting a sectional regulation and control crystallization method, so that the morphology and acid distribution of the molecular sieve are regulated and controlled, and the synthesis method is simple in process and suitable for large-scale industrial production; the grain diameter of the small-grain mordenite molecular sieve obtained by the method disclosed by the invention is 15-300nm; the B acid center of the 8-membered ring pore channel accounts for gt of the total B acid center; the catalyst is used for the carbonylation reaction of dimethyl ether, and has good activity and stability.
Owner:DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

Method for improving selectivity of light aromatic hydrocarbon in biomass product catalyzed and pyrolyzed by zeolite molecular sieve catalyst

The invention belongs to the technical field of biomass energy utilization, and particularly relates to a method for improving the selectivity of light aromatic hydrocarbon in a biomass product through catalytic pyrolysis of a zeolite molecular sieve catalyst. The content of medium-strong acid sites in the zeolite molecular sieve catalyst is found to have relatively strong positive correlation with the selectivity of light aromatic hydrocarbons prepared during catalytic pyrolysis of biomass, so that when the zeolite molecular sieve catalyst is used for catalytic pyrolysis of biomass, the content of the medium-strong acid sites in the zeolite molecular sieve catalyst can be increased by increasing the proportion of the medium-strong acid sites in the zeolite molecular sieve catalyst; the selectivity of light aromatic hydrocarbon in the catalytic pyrolysis product is improved.
Owner:HUAZHONG UNIV OF SCI & TECH

A rapid detection and evaluation method for zeolite loading and zeolite loading uniformity in zeolite composite materials

The present application relates to the field of product quality inspection and evaluation of composite materials, and in particular, a method for rapid inspection and evaluation of zeolite loading and zeolite loading uniformity in zeolite composite materials, specifically as follows: in a multi-component system containing zeolite, by sequentially performing selective coloring operations and enhanced color development operations on zeolite microparticles, the originally colorless zeolite microparticles are transformed into zeolite particles with a specific dark color, and the color of the non-zeolite components is not changed during the above-mentioned treatment process, thereby transforming the microscopic zeolite loading determination technical problem into a macroscopic color depth analysis problem. The inspection and evaluation method of the present application has the advantages of being fast, low-cost, and capable of parallel operation. Based on the inspection and evaluation method provided by the present application, an analysis technology for continuous and non-omission load uniformity information of the inspection area can be developed.
Owner:HANGZHOU INNOVATIVE MATERIALS TECH CO LTD

Zeolite / silver / copper ternary inorganic nano antibacterial and antiviral material as well as preparation method and application thereof

The invention discloses a zeolite / silver / copper ternary inorganic nano antibacterial and antiviral material as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing a mixed solution of a template agent and an anchoring agent, loading a metal precursor, adding a silicon source, performing hydrothermal crystallization and performing post-treatment. According to the zeolite / silver / copper ternary inorganic nano antibacterial and antiviral material disclosed by the invention, Ag-Cu bimetallic nanoparticles are formed by introducing copper nitrate and silver together, so that the catalytic activity, selectivity and stability of the zeolite / silver / copper ternary inorganic nano antibacterial and antiviral material are remarkably enhanced, and the dosage of noble metal silver can be reduced.
Owner:CHINA BUILDING MATERIALS ACADEMY CO LTD +1