The present application relates to the technical field of
anode slime treatment, and discloses a method for removing
antimony and
tellurium from
anode slime by multi-stage pressurization and
chlorine-free process, which comprises the following steps: S1,
anode slime pretreatment, S2, multi-stage pressurization treatment, S3, separation of
antimony and
tellurium from the anode slime, S4, preparation of
sodium antimonate, S5,
tail gas treatment, S6, waste liquid treatment, S7, post-treatment. The method is characterized by the following: one-stage pressurized
thiourea transformation is used for deep
copper removal, and two-stage pressurized sulfuration is used for
chlorine-free
antimony and
tellurium removal. The process flow does not involve
chlorine-containing substances, and the pressurized leaching of alkaline medium does not produce substances with strong corrosivity, thereby reducing the damage to the equipment. In the process of removing antimony and tellurium, the harmful substances generated during the reaction can be treated by
waste gas and waste liquid treatment, and the by-products, precipitates, incompletely removed heavy
metal ions,
trace pollutants and the like in the
tail liquid can be removed or converted into harmless substances, so that the
tail liquid meets the
discharge standard and the environmental
pollution caused by the tail liquid
discharge is reduced.