4329 results about "Acid anhydride" patented technology

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

The invention discloses an anti-shrinkage light, soft and elastic sole foaming material and a preparation method thereof, and belongs to the technical field of footwear products. The light, soft and elastic sole foaming material is formed by chemically foaming an EVA (Ethylene Vinyl Acetate) composite raw material, the EVA composite raw material is prepared from 50 to 70 parts of EVA, 20 to 40 parts of olefin thermoplastic elastomer, 10 to 20 parts of styrene elastomer, 1.5 to 3 parts of maleic anhydride grafted ethylene-octylene copolymer compatilizer, 0.4 to 0.8 part of peroxide cross-linking agent, 3 to 4 parts of foaming agent, 1 to 1.5 parts of zinc oxide, 1 to 1.5 parts of polyethylene wax substance and 0.5 to 1.5 parts of poly (butylene succinate). 0.3 to 1 part of polyamide 12 microspheres and 2 to 3 parts of nano montmorillonite. The foaming material can resist shrinkage when being used as a shoe sole part, and has good rebound performance and the like, so that the high-quality requirement of sneakers, the mass production stability and the like are met.

The invention relates to a particulate composition comprising, or substantially consisting of, urea, an inhibitor, preferably a urease inhibitor and / or a nitrification inhibitor, and an additive, wherein the additive comprises components (i) and (ii): (i) a carboxylic acid or an anhydride, salt, or derivative thereof; preferably a carboxylic acid salt or a carboxylic acid derivative, more preferably a carboxylic acid salt; and (ii) a polar polymer; preferably a water-soluble polar polymer. The invention further relates to a process for preparing the particulate composition, an additive for a particulate composition, and the use of the particulate composition as a fertilizer.

The invention discloses an interface covalently bonded core-shell structure boron nitride polypropylene composite dielectric material and a method. The interface covalently bonded core-shell structure boron nitride polypropylene composite dielectric material comprises a maleic anhydride grafted polypropylene matrix and a core-shell structure filler dispersed in the maleic anhydride grafted polypropylene matrix, the core-shell structure filler comprises hydroxylated boron nitride nanoparticles covalently grafted on a polymer shell layer on the surface of the core-shell structure filler; the polymer shell layer is polyglycidyl methacrylate; the epoxy group of the polymer shell layer reacts with the anhydride group of the maleic anhydride grafted polypropylene matrix to form a covalent bond. The invention has the characteristics of strong interface bonding force, uniform filler dispersion, and excellent comprehensive electrical properties and processability.

The invention discloses a flame-retardant ABS (Acrylonitrile Butadiene Styrene) composition as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The flame-retardant ABS composition provided by the invention comprises the following components in parts by mass: 50-80 parts of ABS resin; 8 to 12 parts of styrene-acrylonitrile copolymer; 3 to 5 parts of styrene-acrylonitrile-maleic anhydride terpolymer; 2 to 6 parts of a fluorine-containing maleimide copolymer; 5 to 15 parts of graphite nanosheet modified high rubber powder; 12 to 18 parts of brominated flame retardant; 3-7 parts of a phosphorus-based flame retardant; 0.1-1 part of a processing aid; the phosphorus-based flame retardant is prepared from the following components in parts by mass: 80 to 95 parts of diethyl phosphinate; 0.3 to 3 parts of ethyl butyl phosphinate; 0.1 to 2 parts of ethyl phosphonate; and 5 to 20 parts of melamine polyphosphate. The flame-retardant ABS composition prepared by the invention is good in flame retardant property, good in welding strength and low in cost.

The invention discloses a high-weatherability sound insulation wood plastic wallboard and a preparation method thereof, the high-weatherability sound insulation wood plastic wallboard comprises the following raw materials by weight: 30-40 parts of wood flour or plant fiber, 25-35 parts of a sound insulation functional filler, 35-45 parts of high density polyethylene, 2-2.5 parts of maleic anhydride grafted high density polyethylene, 1-1.5 parts of stearic acid, 3-4.5 parts of a weatherability auxiliary agent, and 1-1.5 parts of azodicarbonamide. The problems of cracking, deformation and the like caused by moisture absorption expansion are relieved by optimizing the proportion and compatibility of the wood flour and the plastic, and then the problems of weather resistance and sound insulation of the wallboard outdoors are solved by filling the porous sound absorption material.

The invention belongs to the technical field of 3PE corrosion prevention, and particularly relates to a high-temperature-resistant and cathodic disbonding-resistant 3PE corrosion-resistant pipeline and a preparation method thereof. A pipeline epoxy bottom layer, a middle adhesive layer and a polyethylene surface layer are subjected to systematic chemical synergistic modification, specifically, the epoxy bottom layer is modified with phenolic resin and amino silane, and a heat-resistant compact barrier is formed; the middle layer reacts with maleic anhydride grafted polyethylene through amino silane to construct a chemical bridge for simultaneously connecting the upper layer and the lower layer; the surface layer is grafted with high-density polyethylene through fluoroprimary amine modified glycidyl methacrylate, and a hydrophobic and oleophobic chain and a reactive functional group are introduced; according to the structure, through the synergistic effect of the high-temperature stability of the bottom layer, the two-way chemical bridging capacity of the middle layer and the inert hydrophobic characteristic of the surface layer, the long-term use temperature upper limit, the stripping resistance and the medium infiltration resistance of the pipeline are improved, and a solution is provided for long-term protection of the pipeline in the severe environment.

The invention relates to the technical field of preparation of building external wall thermal insulation materials, in particular to a building external wall thermal insulation board based on pearl wool and a preparation method of the building external wall thermal insulation board. The core layer is prepared from the following raw materials in parts by weight: 40 to 60 parts of pearl wool particles, 5 to 15 parts of graphene-loaded expanded graphite, 3 to 10 parts of nano silicon dioxide aerogel, 10 to 20 parts of ammonium polyphosphate, 5 to 12 parts of pentaerythritol, 3 to 8 parts of melamine, 15 to 25 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride grafted polyethylene, 2 to 6 parts of nano montmorillonite and 1 to 5 parts of silicon carbide whisker; the composite material is prepared from the following components in parts by weight: 0.5-2 parts of a silane coupling agent KH560, 0.2-0.8 part of an antioxidant 1010, 3-8 parts of amino-terminated polyether and 0.3-1 part of a hindered amine light stabilizer 770. The thermal insulation board is excellent in thermal insulation, mechanical property and flame retardant property, good in weather resistance, stable in size and high in construction adaptability, pearl wool can be recycled, and the thermal insulation board has practical and environment-friendly values.

The invention belongs to the technical field of lithium ion batteries, and discloses a carboxyl-containing copolyimide binder, a lithium ion battery silicon negative electrode, a lithium ion battery and a preparation method, and polyamide acid is prepared by using a carboxyl-containing diamine monomer, an amino-terminated long aliphatic chain diamine monomer and an anhydride monomer as raw materials; and carrying out chemical imidization, precipitation and washing on the polyamide acid to obtain the carboxyl-containing copolyimide binder. The prepared carboxyl-containing copolyimide binder has good solubility in a conventional electrode manufacturing solvent, and the solution system of the obtained carboxyl-containing copolyimide binder is uniform and stable. When the carboxyl-containing copolyimide binder is applied to preparation of a silicon negative electrode of a lithium ion battery, the carboxyl-containing copolyimide binder can generate dual covalent interface interaction with silicon active material particles and conductive material particles, so that the migration efficiency of lithium ions in an electrode system is remarkably improved, the transmission dynamics performance is enhanced, and the high-rate charge-discharge capacity of the battery is effectively improved.

The invention provides a high-temperature-resistant corrosion-resistant cable material for a control line and a preparation method of the high-temperature-resistant corrosion-resistant cable material, and belongs to the field of metallocene polyolefin materials. The cable material is prepared from the following chemical raw materials: 45 to 65 parts of maleic anhydride grafted metallocene polyolefin, 5 to 10 parts of maleic anhydride grafted polyolefin elastomer, 3 to 6 parts of epoxy group modified polyhedral oligomeric silsesquioxane, 2 to 5 parts of polyether amine, 5 to 10 parts of ion response type core-shell structure sustained release microspheres, 8 to 15 parts of multi-dimensional reinforcement, 15 to 25 parts of halogen-free flame retardant, 0.5 to 1.5 parts of antioxidant and 0.5 to 1.5 parts of processing aid. The chemical raw materials with specific functions are accurately selected, a synergistic effect system is constructed, and meanwhile, the high temperature resistance and corrosion resistance of the cable material for the control line are improved.

The invention discloses a wide-temperature energy storage aerogel / polymer composite material and a preparation method thereof.The preparation method comprises the steps that oxide aerogel with a three-dimensional skeleton structure is subjected to silanization treatment to obtain hydrophobic oxide aerogel, then the hydrophobic oxide aerogel is dispersed into a solvent to obtain dispersion liquid, and then the dispersion liquid is subjected to ultrasonic treatment to obtain the wide-temperature energy storage aerogel / polymer composite material. The preparation method comprises the following steps: sequentially adding a diamine monomer and an anhydride monomer into a dispersion liquid, reacting under stirring to obtain a polyamide acid precursor solution dispersed with hydrophobic oxide aerogel, carrying out film casting on the polyamide acid precursor solution to obtain a dry film, and carrying out imidization treatment on the dry film to obtain the aerogel / polymer composite material. The obtained aerogel / polymer composite material can still maintain high energy storage performance and stability even at extreme ambient temperature.

The invention belongs to the technical field of packaging materials, and discloses a high-temperature-resistant heat-seal straw-pluggable easy-to-tear cover and a preparation method thereof.The body comprises a PET layer, a blocking layer and a PE layer which are sequentially compounded from outside to inside, the blocking layer is an AL layer, laser invisible pre-scribed lines are arranged on the easy-to-tear cover, the laser invisible pre-scribed lines only penetrate through the PET layer and the blocking layer and do not penetrate through the PE layer, the thickness of the PET layer ranges from 12 micrometers to 20 micrometers, and the thickness of the PE layer ranges from 12 micrometers to 20 micrometers. The barrier layer is an AL layer, the thickness of the AL layer is 7-12 microns, the thickness of the PE layer is 40-60 microns, and the PET layer is prepared from the following raw materials in parts by weight: 80-95 parts of PET resin, 5-10 parts of composite modified nano silicon dioxide, 3-6 parts of a heat stabilizer and 0.5-2 parts of a lubricant; the composite modified nano silicon dioxide is maleic anhydride grafted polybutadiene composite modified nano silicon dioxide, and the composite modified nano silicon dioxide is uniformly dispersed in a PET matrix by virtue of good compatibility with PET resin, so that the overall toughness and heat sealability of the easy-to-tear cover are remarkably enhanced.

The invention discloses a degradable express bag material and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a degradable express bag material. The composite material is prepared from the following raw materials in parts by weight: 40 to 50 parts of poly (butylene adipate-co-terephthalate), 20 to 30 parts of polycaprolactone, 5 to 8 parts of modified bamboo fiber, 2 to 4 parts of modified nano montmorillonite, 3 to 6 parts of tributyl citrate, 0.1 to 0.3 part of antioxidant 1076, 1 to 2 parts of iron dithiocarbamate master batch, 2 to 3 parts of maleic anhydride grafted poly (butylene adipate-co-terephthalate) and 0.3 to 0.6 part of zinc stearate. 0.1 to 0.3 part of baicalein; and 1 to 3 parts of chitosan-sorbitol composite coating liquid. According to the degradable express bag material, poly (butylene adipate-co-terephthalate) and polycaprolactone are used as main degradable raw materials, modified bamboo fibers and modified nano-montmorillonite are matched to enhance the mechanical property, an antioxidant 1076, baicalein and the like are added to guarantee the stability and functionality, temperature is accurately controlled in the preparation process, multi-step modification is adopted for optimizing component combination, and the degradable express bag material is prepared. The performance is improved through the composite coating, degradability is achieved, and good usability is achieved.

The invention discloses an insulated wire, a coil and electronic / electrical equipment, and relates to the technical field of insulated wires. The modified polyamide-imide insulating layer is composed of an insulating material obtained by reacting diisocyanate with mixed anhydride, wherein the mixed anhydride comprises short-chain anhydride and long-chain anhydride. According to the insulated wire coated with the polyamide-imide insulating layer, the wire flexibility is improved, the insulated wire is suitable for closer arrangement of complex groove types, and then the motor groove fullness rate is improved, so that the size of a stator iron core is reduced under the same power, the motor weight is indirectly reduced, and the requirement for light weight is met.

The invention relates to the technical field of polymer composite materials, in particular to a carbon fiber reinforced nylon 66 / polyphenylene sulfide composite material and a preparation method thereof.The carbon fiber reinforced nylon 66 / polyphenylene sulfide composite material is prepared from, by weight, 40-55 parts of nylon 66, 30-45 parts of polyphenylene sulfide, 15-30 parts of carbon fibers, 5-6 parts of compatilizer, 0.8-1.2 parts of antioxidant and 3-4 parts of flexibilizer, the flexibilizer is ethylene-octylene copolymer grafted maleic anhydride, the grafting rate is 1.2-1.5%, the flexibilizer is ethylene-octylene copolymer grafted maleic anhydride, the grafting rate is 0.8-1.0%, and the antioxidant is a mixture of an antioxidant 1010 and an antioxidant 168 according to a mass ratio of 1: 1. The composite material prepared by the invention is suitable for medium-high temperature scenes, not only solves the problems of insufficient high temperature resistance and poor mechanical properties of traditional materials, but also has good processability and environmental tolerance.

The invention relates to the technical field of polyolefin cable materials, in particular to a photovoltaic weather-resistant anti-cracking low-smoke halogen-free flame-retardant polyolefin cable material and a preparation method thereof.The photovoltaic weather-resistant anti-cracking low-smoke halogen-free flame-retardant polyolefin cable material is prepared from, by weight, 90-150 parts of polyolefin resin, 1-3 parts of antioxidant, 2-5 parts of ultraviolet light absorber, 30-70 parts of composite flame retardant, 10-25 parts of carbon black and 3-5 parts of cross-linking agent; the composite flame retardant comprises a core material, a first shell material and a second shell material, the core material comprises a halloysite nanotube adsorbed with a flame retardant, the first shell material comprises epoxy resin, and the second shell material comprises maleic anhydride grafted polyethylene. According to the polyolefin cable material provided by the invention, the purpose of efficient flame retardance can be achieved by adding the halloysite nanotubes and the flame retardant system, the interfacial compatibility between the flame retardant and the matrix resin can be improved by adding the maleic anhydride grafted polyethylene, and the flame retardance of the polyolefin cable material can be improved by combining the added halloysite nanotubes and epoxy resin. The purpose of improving weather resistance, stress resistance and crack resistance of matrix resin is achieved.

The present invention relates to the field of polyurethane materials and particularly to a temperature-induced color-changing vehicle film and a preparation method therefor. The method of the present invention comprises: firstly, using polyurethane to wrap vanadium dioxide powder to obtain color-changing microcapsules; then using 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-allyloxy-1,2-propanediol as raw materials to synthesize an organosilicon-modified diol, and enabling trimellitic anhydride to react with toluene diisocyanate to synthesize a dicarboximide compound; enabling the organosilicon-modified diol and the dicarboximide compound to undergo an esterification reaction and a polymerization reaction to obtain an organosilicon-modified imide polyester diol; then mixing the organosilicon-modified imide polyester diol with polytetrahydrofuran ether glycol 2000, and then enabling the mixture to react with toluene diisocyanate to obtain a polyurethane elastomer; and mixing the polyurethane elastomer, the color-changing microcapsules, a silane coupling agent, a plasticizer, an antioxidant, and an ultraviolet light absorber, followed by melt extrusion and blow molding into a film, so as to obtain the temperature-induced color-changing vehicle film.

The invention relates to the technical field of polypropylene compositions and modified polymer materials thereof, and discloses a high-performance polypropylene-based green energy-saving cable insulation layer composition which comprises an isotactic polypropylene matrix, a maleic anhydride grafted polyolefin elastomer distributed in a dispersed phase and an amide nucleating agent distributed on a non-polar phase interface, an anchoring structure is constructed on a phase interface through hydrogen bond interaction, a matrix molecular chain is induced to grow to form a radial needle-shaped crystal cluster penetrating through the phase interface, and a three-dimensional interpenetrating crystal bridging network is constructed. Through the crystal bridging network, interface deep traps are converted into continuous shallow trap diversion channels, charges are guided to migrate orderly, space charge accumulation is inhibited, and the three-dimensional interpenetrating crystal bridging network is constructed. And the steric effect generated by the interface anchoring structure cooperatively restrains the thermal expansion of the dispersed phase, so that the high-temperature dimensional stability and dielectric property of the material are improved.

The invention is suitable for the technical field of material science and electrochemical energy, and provides a lyophilic polyolefin master batch and a preparation method and application thereof.The lyophilic polyolefin master batch is prepared from polyolefin, modified polyolefin, a cross-linking agent and a compatilizer, the modified polyolefin comprises polyolefin grafted with polar functional groups, and the cross-linking agent comprises a cross-linking agent and a compatilizer; the polar functional group can be selected from one or more of carboxyl, hydroxyl, amido, epoxy group, anhydride group, sulfonic acid group, cyano group and ether group, and the technical problem of poor lyophilic property of the polyolefin diaphragm is creatively solved by scientifically proportioning and compounding the modified polyolefin with the polar functional group, the common polyolefin, the cross-linking agent and the compatilizer. The components in the material system have a synergistic effect: the modified polyolefin provides lyophilic property, the cross-linking agent prevents the product from being degraded, the compatilizer improves the compatibility of the components and improves the polarity, and the comprehensive improvement of the performance of the diaphragm is realized through the combined effect.

The invention discloses a method and a device for removing alcamines in NMP (N-Methyl Pyrrolidone), which comprises the following steps: reacting anhydride substances with NMP containing the alcamines substances to generate NMP containing amide substances; the NMP solution containing the amide substances is rectified to remove the amide substances, and NMP with the alcohol amine substances removed is obtained; the boiling point of the product is increased in a manner that anhydride substances react with alcohol amine substances in NMP to generate amide, so that the difference value between the reacted product and the boiling point of NMP is greater than the difference value between the alcohol amine substances and the boiling point of NMP, high-purity NMP is more easily separated in a subsequent rectifying tower, the energy consumption of the rectifying tower for separating the product and impurities can be reduced, and the production cost is reduced. In addition, due to the fact that different alcohol amine additives do not need to be added additionally, universality is improved, meanwhile, the anhydride reaction belongs to amidation reaction, reaction products are more stable, free amine cannot be decomposed in the high-temperature heating process, and therefore the purity of the separated NMP can be further improved.

The invention relates to the technical field of cable processing, and discloses a mica tape cross-linked polyethylene insulated cable which comprises a copper conductor, a mica tape, a cross-linked polyethylene insulating layer, a filling material, a wrapping layer and a cable sheath from inside to outside, the mica tape comprises mica paper, a reinforcing material and an adhesive, and the adhesive comprises tung maleic anhydride type mica glue and MgO / gamma-Al2O3 composite filler. The adhesive adopted by the mica tape comprises the MgO / gamma-Al2O3 composite filler and the tung maleic anhydride type mica glue, and the MgO / gamma-Al2O3 composite filler can improve the heat conductivity coefficient and the dielectric property of the tung maleic anhydride type mica glue, so that the heat conductivity and the insulativity of the mica tape are improved.

The invention relates to the technical field of electrode paste, in particular to electrode paste for a submerged arc furnace and a preparation method of the electrode paste. Comprising three-level grain size distribution anthracite aggregate which is electrically calcined at high temperature and modified by a KH-550 silane coupling agent, a modified silicon carbide whisker and boron-doped graphene-like carbon nitride composite filler, a maleic anhydride-mediated compatible medium-temperature pitch-polyborosiloxane binder and a graphite powder-borax functional additive. A step-by-step mixing and two-stage sintering process is adopted in the preparation process, a covalent bond interface bridging structure is constructed through the coupling agent, the composite dispersing agent regulates and controls the multi-dimensional network distribution of the filler, and the process synergistically improves the compactness and the interface bonding force of the green body. The electrode paste is firm in interface bonding, can form a ceramic protective phase at a high temperature, has excellent conductivity and mechanical strength, and prolongs the service life of the electrode paste for the submerged arc furnace.

The invention relates to the technical field of high polymer materials, and discloses a conductive shielding material for a high-voltage cable. Comprising the following components in parts by weight: 40 to 70 parts of main body polyolefin resin, 10 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 15 parts of maleic anhydride grafted polyolefin, 20 to 40 parts of surface modified conductive carbon black, 0.5 to 2 parts of peroxide cross-linking agent, 0.5 to 3 parts of functionalized silane coupling agent, 0.1 to 1 part of processing aid and 0.1 to 1 part of antioxidant, the surface modified conductive carbon black is high-structure conductive carbon black which is subjected to plasma oxidation treatment, solution graft polymerization and surface coupling agent pretreatment. The conductive carbon black is subjected to multi-step surface modification including plasma oxidation, solution graft polymerization and surface coupling agent pretreatment, and the in-situ chemical bonding effect of maleic anhydride grafted polyolefin is matched, so that the agglomeration problem of the conductive carbon black caused by high surface energy is effectively solved.

The invention relates to the technical field of films, in particular to a high-surface tension aluminized base film and a preparation method thereof. The method comprises the following steps: grafting modified fumed silica with a silane coupling agent KH-570, and grafting a ternary polymerization shell layer composed of 2-acrylamide-2-methylpropanesulfonic acid, lauryl methacrylate and glycidyl methacrylate on the surface of the modified fumed silica to obtain organic anti-sticking silica; secondly, synthesizing an aromatic sulfonated polyester prepolymer, loading nano titanium dioxide, and carrying out melt blending extrusion with polypropylene to form polar cluster polypropylene master batches; and finally, blending polypropylene resin, the master batch and maleic anhydride grafted polypropylene, and carrying out melt extrusion, air cooling and slow cooling and two-way stretching molding. The obtained base film is high in surface tension, high in aluminized layer adhesive force, excellent in oxygen and water vapor barrier property, good in thermal stability and suitable for the field of high-end packaging.

The invention relates to a high-strength wear-resistant archaized brick and a preparation method thereof, and belongs to the technical field of archaized bricks, the high-strength wear-resistant archaized brick comprises the following raw materials: 25-30 parts of fly ash, 30-35 parts of superfine slag powder, 30-35 parts of clay, 8-10 parts of coke powder, 10-12 parts of diatomite, 12-15 parts of potassium feldspar, 10-15 parts of a modified binder and 8-12 parts of a reinforcing agent; according to the technical scheme, a polyhydroxy compound is combined with a silanization reinforcing filler, then combined with an anhydride compound and then combined with novolac epoxy resin, then an amine curing agent is added, and curing is conducted to obtain the modified binder; fly ash, superfine slag powder, clay and coke powder are subjected to ball milling, diatomite, potassium feldspar, a modified binder and a reinforcing agent are added, and the high-strength wear-resistant archaized brick is obtained through stirring, calcining and compression molding. The mechanical property, thermal stability and wear resistance of the archaized brick are improved on the whole, the densification degree of the archaized brick is enhanced, and the comprehensive performance is good.

The invention provides a high-sealing-performance flame-retardant composite film and a preparation method thereof, and belongs to the technical field of composite film material preparation, the high-sealing-performance flame-retardant composite film comprises an outer layer, a middle layer, a transition layer and an inner sealing layer which are sequentially stacked, the material of the middle layer comprises a polypropylene matrix, modified aluminum hydroxide and zinc borate, the material of the transition layer comprises epoxy resin and nano silicon carbide, and the material of the inner sealing layer comprises ethylene-vinyl acetate copolymer and maleic anhydride grafted polyethylene; the flame-retardant PET also contains 12 to 20 weight percent of phosphorus-nitrogen synergistic flame retardant; the outer layer and the middle layer are combined in a physical entanglement mode, and the transition layer and the inner sealing layer are combined in a chemical crosslinking mode. The high-sealing-performance flame-retardant composite film provided by the invention has excellent flame-retardant performance and sealing performance, and is suitable for packaging of new energy automobile batteries and high-end electronic equipment.

The invention discloses an antiskid sewage-resistant waterborne coating and a preparation method thereof, and relates to the technical field of tableware coatings. The water-based paint comprises a liquid A and a liquid B, the liquid A comprises the following components in parts by weight: 35-60 parts of emulsion type organic silicon aqueous dispersion resin; 3 to 10 parts of maleic anhydride grafted polypropylene wax emulsion; 5-10 parts of an elastomer modified acrylic dispersion; 0.5 to 1.2 parts of a dispersant; 1-3 parts of a thickening agent; 3-8 parts of a nanoscale aluminum oxide dispersion liquid; 15-25 parts of a water-based color paste; 0.3-1 part of an emulsifying ripple auxiliary agent; 0.1-1 part of a substrate wetting agent; 0.1 to 1 part of a defoaming agent; 3-5 parts of deionized water; the liquid B comprises the following components in parts by weight: 90-100 parts of a water-based isocyanate curing agent, 0.3-0.8 part of a dehydrating agent, 5-8 parts of an adhesion promoter and 2-5 parts of a coalescing agent. The invention provides an innovative two-component water-based paint system, through the synergistic effect of the components after the liquid A and the liquid B are mixed, the multiple requirements of tableware or catering auxiliary appliances on the skid resistance, stain resistance, adhesive force and environment friendliness of the coating are comprehensively met, and the coating completely meets the high-standard requirements of food contact materials.

The invention belongs to the field of functional composite materials, and particularly relates to low-viscosity and high-dispersity aluminum oxide slurry and a preparation method thereof.The low-viscosity and high-dispersity aluminum oxide slurry is prepared from a newly-designed phosphono-carboxyl block copolymer and biquaternary ammonium salt polyether silane as composite modifiers; and efficient anchoring and stable dispersion of the surfaces of alumina particles are realized through the synergistic effect of molecular structures. The phosphono-carboxyl block copolymer is prepared through controllable polymerization and deprotection reaction, and strong chemical bonding is formed between a phosphono group and the surface of aluminum oxide; the biquaternary ammonium salt polyether silane is subjected to click chemical synthesis, and electrostatic adsorption of quaternary ammonium salt and the steric hindrance effect of a polyether chain are combined. When the slurry is prepared, the two modifiers are sequentially added into water, the aluminum oxide powder is added after the pH value is adjusted, finally, the isobutylene maleic anhydride copolymer and the defoaming agent are introduced, and the slurry is obtained through vacuum defoaming and filtering. The slurry prepared by the method has the characteristics of high solid content, low viscosity and good dispersion stability.

The invention relates to the technical field of polypropylene, in particular to an antibacterial modified polypropylene material and a preparation method thereof. The problems of poor antibacterial property and mechanical property of the polypropylene material are solved. According to the invention, the carbon nanotube is used as a carrier, ZnO nanoparticles are grafted on the surface, and the carbon nanotube and the polypropylene resin are subjected to interface synergy and functional complementation, so that the mechanical property and antibacterial activity of the material are synchronously improved; through the short-range-long-range synergistic effect of the short carbon fibers and the glass fibers treated by the silane coupling agent KH550, the fracture resistance of the material is remarkably improved; through the molecular-level synergistic effect of hydroxylated boron nitride nanosheets and maleic anhydride grafted polypropylene, the interfacial compatibility of the nanofiller and a polypropylene matrix is optimized, and the mechanical property of the material is improved; the antibacterial microcapsule is prepared by taking chitosan as a carrier, wrapping hinokitiol and loading nano titanium dioxide, and the material is endowed with long-acting antibacterial performance.

The invention belongs to the technical field of high polymer materials, and particularly relates to special resin for a polyethylene film as well as a preparation method and application thereof. The special resin for the polyethylene film is prepared from the following components in parts by weight: 50 to 70 parts of HDPE (High-Density Polyethylene) resin, 20 to 30 parts of LLDPE (Linear Low Density Polyethylene) resin, 0.5 to 3 parts of nano zinc oxide, 5 to 10 parts of maleic anhydride grafted POE (Polyolefin Elastomer) and 0.1 to 0.5 part of antioxidant. The HDPE, the LLDPE and the grafted POE form a three-phase topological structure, so that the bending modulus and the notch toughness can be synchronously improved. The special resin for the polyethylene film, which is prepared by adopting a low-temperature second-order blending process, can keep the toughening effect of an elastomer. The special resin for the polyethylene film prepared by the invention can realize ultrahigh toughness while keeping high rigidity, has long-acting weather resistance, can meet the requirements of packaging films and other high-end fields, is high in processing adaptability, and is suitable for a high-speed film blowing production line.