The invention provides a polymer back panel of a solar battery assembly. The polymer back panel comprises a base film layer, binding layers on both sides of the base film layer, a fourth thin film layer and a fifth thin film layer on the other two sides of the binding layers, wherein the base film layers contain at least one of the following components: polyamide polymers, polypropylene and acrylic polymers, polyethylene and ethylene polymers, polyvinylidene chloride, styrene polymers, ABS (acrylonitrile butadiene styrene) resins, liquid crystal polymers, acrylic acid polymers, polyphenyl ether, polycarbonate and polymer alloy of polycarbonate and poly(C2-6 alkal terephthalate). In addition, the invention also provides a manufacture method of the back panel. By adopting a thin film structure made of one or more of the above polymers to substitute for the conventional PET (polyethylene terephthalate) layer, the polymer back panel has excellent processing formation performance, material mechanical performance, barrier performance and anti-aging performance; and a back panel laminated film can be prepared by molten co-extrusion or extrusion composite process, with the advantages of significantly improved bonding strength between the films and simplified production process.