1337 results about "Gas barrier" patented technology

The invention discloses an alkaline electrolytic water hydrogen production diaphragm for strengthening hydroxyl ion transfer and a preparation method of the alkaline electrolytic water hydrogen production diaphragm. The diaphragm comprises a supporting base net and a hydrophilic gas insulation coating which is arranged on the supporting base net and contains a hydroxyl ion transfer carrier, the method comprises the steps that a supporting base net is pretreated; the preparation method comprises the following steps: dissolving a polymer binder, a pore-foaming agent, a hydroxyl ion transfer carrier and a hydrophilic metal oxide in an organic solvent according to a mass ratio to obtain hydrophilic slurry; uniformly coating two sides of a supporting base net with the hydrophilic slurry, and then carrying out non-solvent induced phase conversion to obtain the alkaline electrolytic water hydrogen production diaphragm for strengthening hydroxyl ion transfer; polar groups such as hydroxyl, amino and carboxyl are introduced into a traditional composite diaphragm to construct a hydrogen bond network, so that hydroxyl ions can be transmitted in a jumping manner along the dynamic hydrogen bond network in the diaphragm to promote transmission of the hydroxyl ions, the performance of the diaphragm can be improved, the materials are cheap and easy to obtain, the preparation process is simple and convenient, and industrial expanded production is facilitated.

The invention relates to the technical field of composite film preparation, in particular to a multi-layer co-extrusion nano ceramic coating high-barrier medicine packaging composite film and a preparation method thereof.The multi-layer co-extrusion nano ceramic coating high-barrier medicine packaging composite film comprises a base material layer, a gas barrier layer, a bonding transition layer and a nano ceramic functional coating; the base material layer comprises the following components in parts by mass: 80-100 parts of biaxially oriented polypropylene; 20 to 30 parts of metallocene linear low density polyethylene; 5 to 8 parts of nano titanium dioxide; 0.5 to 1 part of beta-(3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid; and 0.3 to 0.6 part of calcium stearate. Through the multi-layer co-extrusion and gradient curing technology and the five-layer co-extrusion technology, it is ensured that the thickness of a base film is uniform and interlayer bonding is firm, the adhesive force of the coating is enhanced through plasma surface treatment, and activity retention and uniform distribution of functional components are guaranteed through the segmented curing strategy of the nano ceramic coating; compared with a traditional hot-pressing compounding or solvent coating process of the composite film, the energy consumption and the solvent residue risk are greatly reduced, meanwhile, the production efficiency and the product consistency are improved, and large-scale application is provided for medicine packaging.

Disclose herein is a pouch film laminate body including a gas barrier layer, a base layer disposed on one surface of the gas barrier layer, and a sealant layer disposed on the other surface of the gas barrier layer. A loop stiffness of the pouch film laminate body in machine direction of the pouch film laminate body may be 750 mN to 1300 mN.

The present invention relates to a pouch film laminate body capable of manufacturing a high-strength battery case with excellent resistance to external stress and a battery case manufactured using the same. The pouch film laminate body of the present invention includes a gas barrier layer having a thickness of 60 μm or greater, a base layer disposed on one surface of the gas barrier layer, and a sealant layer disposed on the other surface of the gas barrier layer. The pouch film laminate layer has a tensile strength of 10 kgf / 15 mm to 20 kgf / 15 mm in a TD direction and an elongation of 150% to 235% in the TD direction.

The invention provides a preparation method of an environment-friendly high-performance gas barrier film, which is characterized in that a solution blending method is adopted to prepare a polyvinyl alcohol / nanocellulose / covalent organic framework nanosheet ternary composite system, and a coating method is adopted to prepare the high-performance gas barrier film under high-temperature evaporation. Multidimensional mixed nanocellulose and covalent organic framework nanosheets are introduced as functional fillers to form a stable intercalation structure with a polyvinyl alcohol matrix, so that the interfacial compatibility of the components is remarkably improved. The multi-component gas barrier film is endowed with high humidity resistance, chemical stability, high gas barrier property and the like by regulating and controlling the heat treatment temperature, the environment-friendly gas barrier film material shows good application prospects in the fields of chemical protective clothing and the like, and a new thought is provided for development of high-performance protective materials.

The invention relates to the field of electromagnetic functional composite materials, and particularly discloses a multi-layer composite structure flexible frequency selective surface material and a preparation method thereof. The ultra-high molecular weight polymer fiber-reinforced polymer-based composite material thin-film mechanical enhanced band-pass frequency selection array sequentially comprises an acrylic acid polyvinylidene fluoride organic polymer coating environment-resistant layer, a metal oxide organic film isolation layer, an ultra-high molecular weight polymer fiber-reinforced polymer-based composite material thin-film mechanical enhanced layer, a band-pass frequency selection layer and a packaging protection layer from top to bottom, and the band-pass frequency selection layer is a hexagonal / circular ring nested band-pass frequency selection pattern array. The packaging protection layer is formed by printing a conductive coating composed of conductive filler / polymer resin matrix, and the packaging protection layer is an ink coating. The flexible frequency selective surface material has the characteristics of light weight, high strength, salt fog / rain / ultraviolet and other severe environments, frequency selective wave transmission and multiple functions, has good gas barrier property, is beneficial to maintaining the shape of an inflatable hangar made of a skin and ensuring normal operation of radar equipment, and has good practical engineering application value.

A method for producing a photoelectric conversion element according to the present disclosure comprises: (A) forming a first electrode layer on a gas barrier layer; (B) removing a portion of the first electrode layer using a pulsed laser to form through holes that penetrate the first electrode layer and partially overlap each other; (C) forming a light absorption layer on the first electrode layer and the gas barrier layer exposed by the through holes; and (D) forming a second electrode layer on the light absorption layer.

The invention discloses a PHA-acrylic acid structural unit water-based dispersion based on interface engineering regulation and control, a preparation method thereof and application of a paper-based barrier coating, and belongs to the technical field of high polymer materials, interface engineering and water-based coatings. The stable interface layer is constructed in situ between the crystalline PHA and the acrylic resin through the amphiphilic polymer, so that the problems of poor compatibility and film forming defects of a bio-based material are effectively solved. The dispersion can realize excellent waterproof, oil-proof and gas barrier effects by only needing a relatively low coating weight, and the material consumption is remarkably reduced. The unique gradient structure of the coating has excellent mechanical adhesive force and efficient re-pulping and recycling characteristics, and the technical defect that a traditional barrier coating is difficult to recycle is overcome. And an ideal solution with high performance and high safety is provided for green packaging.

The invention relates to the technical field of desulfurization slurry treatment, and discloses a vacuum dehydration device and a dehydration treatment system and method for desulfurization gypsum. The device comprises a belt conveyor, filter cloth is arranged on the belt conveyor, a filter assisting component is arranged above the filter cloth, and the filter assisting component can extend into a filter cake layer on the filter cloth and damage a surface air blocking layer on the top of the filter cake layer. According to the technical scheme provided by the invention, the surface air barrier layer at the top of the filter cake layer is destroyed by the filter aid part, and the air pressure difference formed on the two sides of the filter cake layer due to suction filtration is recovered, so that free moisture in gypsum slurry is separated from the gypsum slurry under the dual effects of pushing force generated by the air pressure difference and self gravity; the desulfurized gypsum with relatively low water content is obtained.

The invention belongs to the technical field of insulating materials, and particularly discloses an insulating material for an insulating soft sling for extra-high voltage working and a preparation method and application of the insulating material. The insulating material is prepared by mixing ZIF-8 particles and polytetrafluoroethylene powder according to a specific mass ratio and utilizing a dry process. And soaking and coating by using a polydimethylsiloxane (PDMS) solution to obtain a double-layer composite insulating material, and cutting and weaving to obtain the insulating soft sling. The high porosity and excellent gas adsorption performance of ZIF-8 and the insulating performance of PTFE and PDMS are combined, and the comprehensive performance of the insulating material is improved. The introduction of the ZIF-8 particles enhances the mechanical strength and the gas barrier property of the material, the PTFE and the PDMS provide good insulativity and corrosion resistance, and the synergistic effect of the PTFE, the PDMS and the ZIF-8 particles realizes the high-performance application of the insulating sling in a complex environment. Meanwhile, the preparation method and device are easy to operate and low in cost, and large-scale production can be achieved.

The invention relates to a honeycomb sandwich type vacuum insulation panel and a vacuum insulation panel system, and provides the honeycomb sandwich type vacuum insulation panel and the vacuum insulation panel system. An insulating panel mounted between a main gas barrier and an auxiliary gas barrier of a low-temperature liquid fuel tank is formed as a honeycomb sandwich panel having a honeycomb structure, so that insulation of the low-temperature liquid fuel tank can be improved and maximized, and heat loss thereof can be minimized. The cryogenic liquid fuel tank includes a primary gas barrier, an insulating panel, and a secondary gas barrier such that cryogenic liquid fuel containing liquefied hydrogen is contained therein, the cryogenic liquid fuel tank including: a honeycomb sandwich panel mounted between the primary gas barrier and the secondary gas barrier to insulate the cryogenic liquid fuel tank; a vacuum film accommodating and evacuating the honeycomb sandwich panel; and a breakage-proof pad installed at each corner of the honeycomb sandwich panel in contact with the vacuum film and preventing damage to the vacuum film.

This invention discloses a one-piece molded all-plastic flexible hose sheet and its composite hose, belonging to the field of polymer material technology. The one-piece molded all-plastic flexible hose sheet of this invention has a three-layer structure: an outer PE film, an intermediate layer, and an inner PE film. The intermediate layer is selected from one of the following: an intermediate polymer layer, a three-layer composite layer formed by an intermediate polymer layer, a polyethylene layer, and an intermediate polymer layer, or a three-layer composite layer formed by an intermediate polymer layer, an ethylene-vinyl alcohol copolymer layer, and an intermediate polymer layer; the intermediate layer may have a double-sided coated or uncoated adhesive layer; the intermediate polymer layer is polymerized from 2,6-dihydroxyisophthalic acid, diaminoalkane, and 4,4'-tetraphenylsilane. The all-plastic flexible hose sheet provided by this invention is formed in one piece using a five-layer co-extrusion machine, possessing excellent gas barrier properties, water vapor barrier properties, high mechanical strength, and good interlayer peel strength.

The invention discloses a paper-based composite film, which adopts a four-layer structural design, and the outer layer is an ultraviolet shielding layer formed by coating TiO2 with lignin; the transition layer is composed of 32-64 PLA / PBAT alternating microlayers, and the multiple alternating transition layers form a zigzag gas barrier path; ag-coated ZIF-8 nanoparticles are loaded on the paper base layer, so that long-acting antibiosis is realized by slowly releasing silver ions; and the inner layer adopts a PPC / PBS blend to support the heat sealing layer with adjustable heat sealing strength. According to the preparation process, a gradient micro-layer structure is constructed through a multi-runner co-extrusion die head and a layer multiplier, silver ions are loaded to ZIF-8 through an ultrasonic-vacuum impregnation process, the hydroxyl density of the surface of the paper base layer is improved through plasma treatment, good interlayer strength is achieved, ester bond crosslinking is induced in a pre-irradiation mode, and the product is prepared. The paper-based composite film has ultraviolet shielding, gradient blocking, slow-release antibacterial and controllable heat sealing performance, the interface bonding strength of a traditional paper-based composite film is greatly improved, all components are biodegradable, and the paper-based composite film is suitable for packaging of food, medicine and the like.

To provide a resin film and a laminate film having excellent water vapor permeability even in low-humidity environments and excellent gas barrier properties.SOLUTION: There is provided a resin film 2 in which a water-based polyurethane and a cross-linking agent are blended, the cross-linking agent comprises one or two or more selected from the group consisting of a titanium compound and a metal chelating compound and there is provided a laminate film 1 comprising the resin film 2 in which the blending amount of the cross-linking agent is 35 pts.mass or more based on 100 pts.mass of the blending amount of the water-based polyurethane and a base material layer 3 provided on the resin film 2.SELECTED DRAWING: Figure 1

The invention discloses high-crystallinity copolyester based on furandicarboxylic acid as well as a preparation method and application of the high-crystallinity copolyester. The structural formula of the high-crystallinity copolyester is as follows: # imgabs0 # R1 is-O (CH2) aO-, R2 is-O (CH2) bO-, a, b, x, y, z and n are integers, a = 2-6, b = 6-12, x = 1-10, y = 1-10, z = 1-10, and n = 20-100; and (x + z): y = 1: 1-1: 10. The present invention also provides a highly crystalline copolyester article made from the highly crystalline copolyester. The high-crystallinity copolyester disclosed by the invention not only has excellent crystallization capacity, relatively high crystallinity, excellent thermal stability and mechanical property, but also has excellent barrier property, and has obvious advantages in various gas barrier aspects compared with PET (Polyethylene Terephthalate) on the market; the material can be widely applied to the fields of high-temperature-resistant materials, express packages, food packages, food tableware and the like.

A gas barrier laminate including: a substrate layer which contains a polyolefin resin; a barrier layer; and an overcoat layer which contains a polyvinyl alcohol resin, the overcoat layer having a surface which has a surface hardness of 1.5 GPa or less, as measured by a nanoindentation method.

The invention discloses a degradable preservative film for fruit preservation and a preparation method thereof, and belongs to the technical field of preservative films. Comprising the following raw materials in parts by weight: 40-60 parts of polylactic acid, 15-25 parts of polyvinyl alcohol, 6-12 parts of cellulose, 10-20 parts of modified chitosan and 3-9 parts of a lubricant. The prepared preservative film takes polylactic acid as a matrix, so that the preservative film is endowed with relatively high transparency, heat resistance and degradability; wherein the polyvinyl alcohol is a degradable material and can enhance the gas barrier property of the preservative film; wherein the cellulose can improve the thermal stability and the mechanical property of the preservative film; wherein the modified chitosan can enhance the antibacterial property, the heat resistance, the water barrier property and the mechanical property of the preservative film, and the properties are long-lasting and stable; therefore, the prepared preservative film is excellent in mechanical property and good in barrier property, has stable and efficient antibacterial property and heat resistance, is environment-friendly and degradable, and has important application value in the technical field of preservative films.

A barrier laminated film includes at least an unstretched laminated film and a vapor deposited film. The laminated film includes at least a polyolefin resin layer and a gas barrier resin layer, and the vapor deposited film is disposed on the gas barrier resin layer.

The invention relates to the technical field of packaging materials, and discloses a high-barrier multilayer co-extrusion composite film which sequentially comprises an inner layer, a first bonding layer, a first barrier layer, a second bonding layer, a second barrier layer, a third bonding layer and an outer layer from bottom to top. And the second barrier layer is a nano silicon dioxide modified polyvinyl alcohol layer. The two different barrier layers are arranged, the first barrier layer has a good barrier effect on gas, the second barrier layer has outstanding barrier performance on water vapor, and the two barrier layers have a synergistic effect, so that the comprehensive barrier performance of the composite film on oxygen, water vapor, peculiar smell and the like is remarkably improved, the shelf life of a packaged product can be effectively prolonged, and the packaging cost is reduced. According to the high-barrier film, the high-barrier property is ensured, the quality and the performance of a product are ensured, and the use of expensive materials and a complex production process is avoided and the production cost is reduced by reasonably selecting each layer of material and optimizing the structural design on the premise of ensuring the high-barrier property.

The utility model belongs to the technical field of gas barrier. In view of the problems of excessive gas leakage, environmental pollution and resource waste caused by untimely maintenance of the existing RTP-based gas barrier mechanism, the utility model discloses an RTP-based gas barrier mechanism, which comprises a gas transmission assembly, and the gas transmission assembly comprises a gas pressure sensor arranged on the outer side of an RTP pipe body; the supporting assemblies are symmetrically arranged on the outer side of the RTP pipe body. The RTP pipe body is provided with a blocking assembly, and the blocking assembly comprises a connecting pipe arranged between the RTP pipe bodies; the shell penetrates through the connecting pipe; the motor is arranged at the top of the shell; the threaded rod is arranged at the output end of the motor; the threaded sleeve sleeves the outer side of the threaded rod; the sealing plate is arranged on the outer side of the threaded sleeve, gas is blocked through the blocking assembly, and environmental pollution and resource waste caused by excessive gas leakage are avoided.

A production method including: a step of forming, on a substrate layer containing a polypropylene resin or a polyester resin, a metal oxide layer by a vacuum film forming process; a step of applying a gas barrier coating layer-forming composition on the metal oxide layer to form a coating film; a step of preheating the coating film by infrared radiation; and a step of heating and thereby curing the coating film preheated by infrared radiation in an atmosphere at 50 to 120°C to form a gas barrier coating layer, in which the gas barrier coating layer-forming composition contains at least one selected from the group consisting of an alkyl silicon alkoxide and its hydrolysate, and a water-soluble polymer.

The invention discloses a flexible packaging material and a preparation method and application thereof. The flexible packaging material comprises a sandwich structure formed by sequentially stacking a polymer elastomer with a viscoplastic surface layer, a self-adaptive gas barrier layer and a polymer elastomer with a viscoplastic surface layer, wherein the viscoplastic surface layer of the polymer elastomer consists of a non-polar viscoelastic molecular network and a plastic polar polymer microdomain; the self-adaptive gas barrier layer is at least one of liquid metal, hygroscopic gel and viscous hygroscopic liquid; and the viscoplastic surface layers of the upper and lower polymer elastomers are respectively contacted with two surfaces of the self-adaptive gas barrier layer, so that a sandwich structure is formed. The flexible packaging material not only can be flexibly stretched, but also has ultrahigh gas barrier property, and has important significance and value for promoting the practical application and industrialization process of flexible electronic devices.

A gas barrier film includes a substrate containing polypropylene as a main component, a gas barrier layer on a first surface of the substrate, and a coating layer on the gas barrier layer. Infrared spectroscopy of the first surface indicates a peak intensity (I1) at 1360 to 1390 cm−1 and a peak intensity (I2) at 1440 to 1480 cm−1 in a ratio satisfying the formula: (I1) / I(2)≤1.65.

To provide a gas barrier film that facilitates replacement with a mono-material and has excellent productivity.SOLUTION: A gas barrier film 1 includes: a substrate layer 10 containing polypropylene or polyethylene as a main component; and a gas barrier layer 20 formed on a first surface 10a side of the substrate layer 10. A composition ratio H / Si of hydrogen to silicon, measured by Rutherford backscattering analysis and recoil scattering analysis, is more than or equal to 1.0 at a position of the gas barrier layer 20 equivalent to 25% of a film thickness of the gas barrier layer 20 from the first surface 10a of the substrate layer 10 in a thickness direction of the gas barrier layer 20.SELECTED DRAWING: Figure 1

A gas barrier laminate according to one aspect of the present disclosure is a gas barrier laminate including a paper base material, a first resin layer, a vapor-deposited layer, and a second resin layer in this order, in which the gas barrier laminate has a density of 0.9 g / cm3 or higher and 1.5 g / cm3 or lower, and a dimensional change percentage in a CD direction of a dimension under conditions of 40° C. and 90% RH with respect to a dimension under conditions of 40° C. and 20% RH of the gas barrier laminate is 0.8% or less.

A gas barrier laminate according to the present disclosure has a laminated structure comprising a polyolefin-based substrate layer, a first polyvinyl alcohol-based resin layer, a vapor deposition layer, and a second polyvinyl alcohol-based resin layer in this order, wherein the vapor deposition layer directly contacts the first polyvinyl alcohol-based resin layer and the second polyvinyl alcohol-based resin layer, and a pressing hardness measured with a nanoindenter in a cross-section of the second polyvinyl alcohol-based resin layer is not more than 0.5 GPa.

The present invention provides a coating agent for a vapor deposition film, which contains a urethane resin (A) and an aqueous medium (B), and is characterized in that the urethane resin (A) is a reaction product of a composition that contains a polyester (A3) that is a polycondensate of a polycarboxylic acid component (A1) and a polyol component (A2), an active hydrogen group-containing compound (A4) having a hydrophilic group, and a diisocyanate (A5), the urethane resin (A) has an ester skeleton derived from the polyester (A3), and contains 10-100 mass% of at least one of an aromatic dicarboxylic acid and an acid anhydride thereof with respect to 100 mass% of the total amount of the polycarboxylic acid (A1), and the polyol component (A2) contains an alkylene glycol having 2-6 carbon atoms. The coating agent for a vapor deposition thin film exhibits excellent gas barrier properties and adhesiveness even in a normal state and after a retort treatment.

The invention discloses an electric flame stove capable of eliminating ozone. The electric flame stove comprises a stove body, a magnetic energy box mounted at the upper end of the stove body and a burner mounted in the stove body, and a magnetron is arranged at the microwave emission port in the magnetic energy box. The high-frequency electromagnetic wave is adopted to excite the initial plasma, so that the temperature and efficiency of the electric flame are improved, and the high-temperature cooking requirements such as stir-frying in a kitchen are met; the reaction between active particles (oxygen ions O or oxygen atoms O) in plasma and ozone is accelerated by adopting high-frequency electromagnetic waves, and finally ozone molecules are decomposed and reduced, so that ozone overflow is inhibited; in a non-pot state, the density of the plasma in the double hearths is small, the microwave switch is switched off, the magnetron stops working, and microwave leakage is completely eradicated from the source; the cooling tank is annularly distributed on the side wall of the second hearth to form a continuous gas barrier surrounding the second hearth, so that the magnetron and the side wall of the second hearth are prevented from being influenced by ultrahigh temperature.

The invention discloses a supercritical CO2 phase change cooling heat prevention and control system and method for an energy storage and power battery. According to the invention, the thermophysical property change of supercritical CO2 near a critical point is utilized, so that the volume is greatly reduced, and extremely high heat dissipation efficiency is realized; a multi-stage energy recovery framework is adopted, and gradient utilization of energy is achieved through the synergistic effect of the heat exchanger and the heat regenerator; the phase change evaporation module effectively solves the problem of high-power-density heat dissipation; the modular design enables the thermal management system to occupy a very small area; the battery can stably operate in an environment temperature range of 0-100 DEG C, and is suitable for harsh working conditions such as variable-rate frequent charging and discharging; a thermal runaway emergency system is integrated, liquid direct injection can be completed within seconds, an inert gas barrier is formed, and a triple protection system of'active cooling-emergency inerting protection-environment moisture prevention 'is constructed in cooperation with a refrigeration main cycle and a condensation dehumidification module; the method is also applied to new energy electric vehicle power batteries, 5G base station standby power supplies, satellite and space station energy storage systems and other scenes.

To provide a gas barrier laminate having a gas barrier coating film excellent in oxygen barrier properties and transparency and having steam barrier properties more excellent than those of a conventional gas barrier coating film, and to provide a coating composition capable of efficiently forming the gas barrier coating film.SOLUTION: The gas barrier laminate has a gas barrier coating film on a substrate, and is characterized in that it is free from coloration derived from organic compounds such as amine compounds and carboxylic acid compounds, the content ratio (P / Zr) of Zr (Zr-kα) and P (P-kα) in fluorescent X-ray measurement of the coating film is in the range of 1.39 to 2.59, and the ratio (P2 / P1) of the peak area (P2) at 2600 to 3700 cm-1 to the peak area (P1) at 850 to 1350 cm-1 in the infrared absorption spectrum of the coating film is less than 0.772.SELECTED DRAWING: None