The application discloses an Hf-Ta-Si / (Hf,Zr)B2 layered composite ultrahigh-temperature protective
coating which is composed of a TaSi2 bottom layer, a
ceramic layer
surface layer with (Hf,Zr)B2 ultrahigh-temperature
ceramic as a main phase and a Ta5Si3 interface
reaction layer located at the interface between the substrate and the TaSi2 bottom layer, and the interface between each layer is an in-situ reaction autogenous interface; the
coating is obtained by prepositioning the
slurry of
raw material powder on the surface of a
tantalum alloy,
drying, and then vacuum reaction
sintering in one step; the
coating has excellent ultrahigh-temperature
oxidation resistance, heat scouring resistance and
thermal shock resistance, and can effectively protect the
tantalum alloy material under the conditions of
oxygen, heat scouring and strong
thermal shock at 1000 DEG C to 1800 DEG C; the method can reduce the adverse effects of the melting and
sintering process on the
microstructure and mechanical properties of the
tantalum alloy, avoid the problem of preparing the ultrahigh-temperature
ceramic coating on the surface of a tantalum alloy with a complex shape, and has higher
coating deposition efficiency and lower cost.