57627results about "Li-accumulators" patented technology

Systems, methods, and articles for a portable power case are disclosed. The portable power case is comprised of at least one battery and at least one PCB. The portable power case has at least two access ports and at least one USB port. The portable power case is operable to supply power to an amplifier, a radio, a wearable battery, a mobile phone, and a tablet. The portable power case is operable to be charged using solar panels, vehicle batteries, AC adapters, non-rechargeable batteries, and generators. The portable power case provides for modularity that allows the user to disassemble and selectively remove the batteries installed within the portable power case housing.

A lithium battery includes: a housing in which an accommodation space is formed; a core disposed in the accommodation space; a negative cover disposed at a first end of the housing; a positive cover disposed at a second end of the housing; a positive current collecting disk disposed on a side of the positive cover close to the core; and a support member disposed between the positive cover and the positive current collecting disk and abutting against the positive current collecting disk.

The present invention provides a composite binder for a sulfide solid-state battery, a preparation method thereof and an application thereof, wherein the composite binder comprises a binder A, a binder B and a solvent, wherein the mass ratio of the binder A to the binder B is (1-10):(5-1), and the mass ratio of the total mass of the binder A and the binder B to the solvent is 1:(10-100). The present invention adopts a binder having a polar functional group and a low-polarity / non-polar binder for combination, thereby making the prepared composite binder have good compatibility with the sulfide solid electrolyte, that is, it does not affect the ionic conductivity of the sulfide solid electrolysis, and at the same time makes the sulfide solid electrolyte membrane have good mechanical properties and flexibility.

Solid-state laminate electrode assemblies and various methods for making the solid-state laminate electrode assemblies involve a lithium metal layer reactively bonded to a lithium ion conducting sulfide glass layer. During manufacture, highly reactive surfaces of the lithium metal layer and the lithium ion conducting sulfide glass layer are maintained in its substantially unpassivated state until they have been reactively bonded. An intermediary solid electrolyte structure has a Li ion conducting solid electrolyte layer covered with a thin as-deposited lithium phosphorus nitride film. A surface protected solid electrolyte having a solid electrolyte layer having a first major surface that is covered by a composite protective film, the composite protective film having a lithium phosphorus material component and a phosphorus nitride material component. A physical vapor deposition target for the deposition of a composite protective film, the target having a compacted composite material target having a mosaic structure.

The present invention relates to the technical field of battery separators and provides a coated modified composite separator, a preparation method thereof and a coating slurry for preparing the composite separator. The coated modified composite separator includes a base membrane and a coating, wherein the coating is coated on either any one side or both sides of the base membrane, and the coating comprises at least two of the following: b2.1 high temperature resistant polymer microspheres, b2.2 high temperature resistant polymer nanofibers, and b2.3 inorganic particles. The coating in the modified composite separator of the present invention notably enhances the thermal dimensional stability of the base membrane, decreases the areal density of the composite separator, boosts the battery's energy density, lowers the probability of occurrence of thermal runaway, and improves battery safety.

The invention discloses an energy storage lithium battery device capable of rapidly dissipating heat and cooling, and relates to the technical field of energy storage batteries, the energy storage lithium battery device comprises an energy storage lithium battery main body, a protective shell and a sealed liquid storage box, the bottom of the energy storage lithium battery main body is connected with the protective shell in a wrapping manner, and air cooling heat dissipation mechanisms are mounted on two sides of the protective shell; and the middle part of the bottom end of the protective shell is fixedly connected with a sealed liquid storage tank. Transmission gears at the two ends can be driven to rotate through a double-head servo motor and a motor rotating shaft, so that a driven gear block and a first cooling fan can be conveniently driven to rotate, and heat generated by an energy storage lithium battery main body in the protective shell can be dissipated to realize efficient air-cooling heat dissipation; and meanwhile, when the conveying hose is extruded, the heat dissipation liquid in the sealed liquid storage tank is extracted and circulates in the liquid cooling heat exchange pipe, and the heat dissipation liquid can absorb heat in the protective shell in the circulation process to achieve liquid cooling heat dissipation.

The invention relates to the technical field of solid-state lithium batteries, in particular to a cellulose acetate modified PEO-based solid-state electrolyte membrane, a solid-state lithium battery and a preparation method thereof.The preparation method comprises the steps that lithium bis (trifluoromethanesulfonyl) imide, cellulose acetate and polyethylene oxide are dissolved in a solvent, and a mixed solution is obtained; and curing the mixed solution in a mold to obtain the cellulose acetate modified PEO-based solid electrolyte membrane. According to the invention, the cellulose acetate is introduced to modify the polyethylene oxide solid electrolyte, and the prepared cellulose acetate modified PEO-based solid electrolyte membrane can generate a stable solid electrolyte interface rich in Li2O and LiF on the surface of a lithium negative electrode in situ in the application of a solid lithium battery, so that the growth ability of lithium dendrites is effectively inhibited, and the performance of the lithium battery is improved. The interface impedance is reduced, and the operating temperature range of the solid-state lithium battery is widened.

The embodiment of the invention relates to a lithium cobalt oxide positive electrode material with a composite phase as well as a preparation method and application of the lithium cobalt oxide positive electrode material. The chemical general formula of the lithium cobalt oxide positive electrode material with the composite phase is AXCo (1-y) M (1y) O2, wherein x is more than or equal to 0.5 and less than or equal to 1, y is more than or equal to 0 and less than or equal to 0.03, A is Li or Li and Na, and M1 is one or more of A1, Zr, Ni, Mn, Y, Nb, La, Fe, Cu, Cr, Ti, W, Mg, Mo or Yb; the composite phase of the lithium cobalt oxide positive electrode material comprises an O2 phase, a T2 phase and an O3 phase; wherein the sum of the molar ratios of the O2 phase and the T2 phase in the composite phase is greater than or equal to 90%, and the molar ratio of the O3 phase is less than or equal to 10%. By regulating and controlling the composite phase proportion of the lithium cobalt oxide positive electrode material, the rate capability, the structural stability under high voltage, the stability of a thermodynamic structure, the specific capacity, a discharge platform and other characteristics of the positive electrode material can be effectively improved, so that the lithium cobalt oxide positive electrode material with high energy density and high stability is realized.

A lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and / or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.

The invention relates to the technical field of functional materials, in particular to a hollow multi-shell material as well as a low-temperature preparation method and application thereof, which comprises the following steps: 1) mixing a water or alcohol solution of a precursor A with an oil phase to prepare a water-in-oil emulsion, or dispersing the water solution of the precursor A into liquid drops by a spraying method; 2) freezing the emulsion or liquid drops obtained in the step 1) at low temperature to obtain ice template particles containing a precursor A; (3) adding the ice template particles obtained in the step (2) into a precursor B solution, controlling the temperature by a program, melting the ice template, and carrying out precipitation or polymerization reaction on A and B to obtain metal fluoride, carbonate or other hollow multi-shell materials; and 4) using the hollow multi-shell layer obtained in the step 3) as an electrolyte additive. The electrolyte additive can improve the viscosity of an electrolyte, improve the ionic conductivity, stabilize a solid electrolyte interface film, effectively inhibit the growth of lithium dendrites, improve the coulombic efficiency of a battery and prolong the cycle life of the battery.

Embodiments described herein relate generally to systems and methods for continuously and / or semi-continuously manufacturing semi-solid electrodes and batteries incorporating semi-solid electrodes. In some embodiments, the process of manufacturing a semi-solid electrode includes continuously dispensing a semi-solid electrode slurry onto a current collector, separating the semi-solid electrode slurry into discrete portions, and cutting the current collector to form a finished electrode.

The invention discloses a carbon-silicon negative electrode material and a preparation method and application thereof, and the preparation method comprises the following steps: S1, carrying out mixed reaction on a lithium source compound, a lanthanum source compound and a titanium source compound to obtain a mixed reactant; mixing the mixed reactant with a carbon source compound, and dispersing and emulsifying to obtain element-doped microspheres; s2, carbonizing the element-doped microspheres in the step S1 to obtain carbides, and activating the carbides to obtain a porous carbon material; and S3, performing silicon deposition on the porous carbon material in the S2 to obtain silicon deposition porous carbon, and performing carbon deposition on the silicon deposition porous carbon to obtain the carbon-silicon negative electrode material. The carbon-silicon negative electrode material disclosed by the invention is high in lithium ion transmission rate, the problem of poor electronic conductivity of silicon is solved, and the electrical property of a battery can be effectively improved.

Embodiments described herein relate to electrochemical cells with one or more current collectors divided into segments, and methods of producing the same. A current collector divided into segments comprises a substantially planar conductive material including a connection region and an electrode region. The electrode region includes one or more dividers defining a plurality of electron flow paths. The plurality of electron flow paths direct the flow of electrons from the electrode region to the connection region. In some embodiments, the current collector includes a fuse section disposed between the electrode region and the connection region. In some embodiments, the fuse section can include a thin strip of conductive material, such that the thin strip of conductive material melts at a melting temperature and substantially prevent electron movement between the electrode region and the connection region.

The invention discloses a lithium iron phosphate positive electrode material and a preparation method and application thereof, and belongs to the technical field of lithium iron phosphate positive electrode materials. The lithium iron phosphate positive electrode material comprises a lithium iron phosphate matrix and a carbon coating layer coating the surface of the lithium iron phosphate matrix, the average standard deviation of the thickness of a carbon coating layer in the lithium iron phosphate positive electrode material is # imgabs0 #, and sigma (d) is more than or equal to 0.05 nm and less than or equal to 0.35 nm; the average standard deviation of the carbon content in the lithium iron phosphate positive electrode material is sigma (Cwt%), and sigma (Cwt%) is larger than or equal to 0.02 wt% and smaller than or equal to 0.35 wt%. The lithium iron phosphate positive electrode material has a uniform carbon coating layer, and the thickness of the carbon coating layer and the carbon content at each position are relatively consistent, so that the improvement of the carrier mobility of the lithium iron phosphate positive electrode material is facilitated, and the further improvement of the electrochemical performance of a battery prepared from the lithium iron phosphate positive electrode material is facilitated.

A rechargeable battery includes a wound-type electrode assembly, a heat pipe, a can, and a cap plate. The heat pipe is disposed inside of the electrode assembly at a distance from a wound center of the electrode assembly, and the heat pipe surrounds the wound center. The can includes an internal space in which the electrode assembly and the heat pipe are positioned. The cap plate is coupled to an end of an opening of the can to close and seal the can, the cap plate is connected heat pipe, and the cap plate is configured to provide dissipation of heat from the heat pipe.

The invention discloses a dry-method electrode film and a preparation method thereof, an electrode and a battery, and belongs to the technical field of batteries. The method comprises the following steps: mixing polytetrafluoroethylene, an active substance and a conductive agent, and crushing to obtain a crushed mixture; performing primary airflow grinding and shearing on the crushed mixture to obtain a ground and sheared mixture; the primary shearing conditions are as follows: the airflow temperature is-10 to 10 DEG C, the airflow pressure is 0.7 to 0.9 MPa, and the rotating speed is 8000 to 12000 rpm; carrying out secondary airflow grinding, shearing and fibration on the ground and sheared mixture to obtain a fibration material; and carrying out secondary fibration treatment on the fibration material to obtain the dry-method electrode film. The method can significantly improve the tensile strength of the electrode film, improve the liquid absorption rate of the electrode and reduce the resistivity of the electrode.

The present disclosure relates to a carbon-based nanomaterial composition that may be formed from a gas mixture and a sulfur powder. The gas mixture may include a carbon based gas, an oxygen gas, and a hydrogen gas. The carbon-based nanomaterial composition may include sulfur doped nanospheres.

The invention discloses a composite polycrystalline positive electrode material which is prepared by permeating and coating a polycrystalline positive electrode material with an oxyhalide solid electrolyte, and the oxyhalide solid electrolyte comprises one or more of Li-Ta-O-Cl, Li-Nb-O-Cl, Li-Zr-O-Cl and Li-Al-O-Cl. The specific oxyhalide electrolyte is adopted to carry out permeation coating on the polycrystalline positive electrode material, uniform coating on the surface of the polycrystalline positive electrode material and grain boundaries in particles is completed, capacity utilization in the particles of the polycrystalline positive electrode material is achieved, and the capacity utilization rate of the particles of the polycrystalline positive electrode material is improved through the coating effect of the oxyhalide with high ionic conductivity. Ion transmission inside and in gaps of the polycrystalline positive electrode material particles is regulated, interface impedance is reduced, energy density is improved, and the application prospect is wide.

The invention provides a preparation method of a porous carbon-silicon composite negative electrode material of a lithium battery. The preparation method comprises the following steps: constructing a multi-stage template system; carrying out carbon precursor impregnation and gradient temperature carbonization on the multistage template system; removing the template to form a gradient porous carbon carrier; carrying out gradient temperature zone silane deposition; and plasma-assisted carbon coating and nitrogen doping are carried out. According to the method, a silicon dioxide sphere hard template is combined with cetyltrimethylammonium bromide and a block copolymer soft template to form a porous carbon carrier with a micropore-mesopore-macropore three-stage structure, and gradient distribution of silicon in porous carbon is realized by utilizing a three-temperature-zone fluidized bed reactor and a pulse type deposition technology, so that the silicon-based porous carbon composite material is obtained. The problem of volume expansion of the silicon material is effectively relieved and the material cycling stability is improved. The porous carbon-silicon composite negative electrode material prepared by the invention has high specific surface area, excellent ion transmission channel and good structural stability, and can be applied to a high-energy-density lithium ion battery.

Embodiments described herein relate generally to electrochemical cells having semi-solid electrodes that include a gel polymer additive such that the electrodes demonstrate longer cycle life while significantly retaining the electronic performance of the electrodes and the electrochemical cells formed therefrom. In some embodiments, a semi-solid electrode can include about 20% to about 75% by volume of an active material, about 0.5% to about 25% by volume of a conductive material, and about 20% to about 70% by volume of an electrolyte. The electrolyte further includes about 0.01% to about 1.5% by weight of a polymer additive. In some embodiments, the electrolyte can include about 0.1% to about 0.7% of the polymer additive.

The invention discloses a pre-lithiated silicon-carbon negative electrode material as well as a preparation method and application thereof. The pre-lithiated silicon-carbon negative electrode material comprises composite particles and a surface coating layer coating the outer surfaces of the composite particles, the mass of the composite particles accounts for 85%-99% of the total mass of the pre-lithiated silicon-carbon negative electrode material; the composite particles are compounds of pre-lithiated porous carbon and nano silicon particles; the composite particles are obtained by uniformly depositing nano silicon particles in pores of pre-lithiated porous carbon; the mass of the pre-lithiated porous carbon accounts for 15-95% of the total mass of the composite particles; the pre-lithiated porous carbon comprises lithium metal particles and porous carbon, and the lithium metal particles are attached to the surfaces of pores of the porous carbon; the mass of the lithium metal particles accounts for 0.1-10% of the total mass of the pre-lithiated silicon-carbon negative electrode material; when the pre-lithiated silicon-carbon negative electrode material is applied to the lithium battery, the first-circle coulombic efficiency of the lithium battery can be improved.

The invention discloses a solid-state battery cell manufacturing method and device based on single-sided rubber frame forming, and relates to the technical field of solid-state battery manufacturing. The method comprises the following steps: manufacturing a rubber frame on one surface of a first pole piece positioned at a forming station; the second pole pieces and the first pole pieces with the rubber frames are sequentially and alternately conveyed to a lamination station, and the first pole pieces and the second pole pieces are sequentially and alternately laminated, so that the second pole pieces are embedded into the rubber frames of the first pole pieces; wherein the electrodes of the first pole piece and the second pole piece are opposite, and the thickness of the rubber frame is greater than or equal to that of the second pole piece. According to the invention, two times of rubber frame forming on one pole piece are not needed, so that the connectivity between the pole pieces is improved, and the conditions that the solid electrolyte layer and the pole pieces deviate relatively and the two adjacent pole pieces are short-circuited are avoided.

The invention belongs to the technical field of batteries, and discloses a negative pole piece and a preparation method thereof, a non-negative lithium battery and a lithium battery. The negative pole piece comprises a current collector and a lithium-loving active layer, the lithium-loving active layer is arranged on at least one side of the current collector, the lithium-loving active layer comprises nanowires and conductive particles dispersed on the nanowires, and when lithium metal is deposited, the nanowires provide nucleation sites for the lithium metal. According to the negative pole piece provided by the invention, the coulombic efficiency and the cycling stability of the negative-electrode-free lithium battery can be improved.

Disclosed in the present invention are a bimetallic-atom-loaded porous carbon framework material, and a preparation method therefor and the use thereof. The preparation method comprises: by taking a metal organic framework as a precursor raw material, and by using the self-polymerization of a high-molecular polymer on the surface of the metal organic framework, forming a polymer-coated metal-based organic framework material (PM@MOF) having a core-shell structure; and then capturing the metal of a metal chloride salt solution by using surface functional groups of the PM@MOF dispersed in n-hexane, so as to obtain a bimetallic element-doped polymer-coated metal-based organic framework material, and subjecting same to a high-temperature treatment in an argon gas atmosphere so as to obtain a bimetallic-atom-loaded porous carbon-based material (MD@PC). In the present invention, by loading bimetallic atoms on a nitrogen-doped porous carbon matrix to form MD-NX coordination sites, which have the dual functions of sulfur fixation and catalysis, the agglomeration degree of intermediate phase lithium sulfide can be reduced, thereby guaranteeing that the lithiation reaction of sulfur is more sufficient, rapid and efficient.

Methods are disclosed of controlling operation of a Li-ion battery system. Such methods include obtaining a predicted state of the Li-ion battery system from a reduced order model either with degradation (in first methods) or without degradation (in second methods), and correcting said predicted state by applying a Kalman filter to the predicted state and battery measurements such that an improved predicted state is generated. In second methods, degradation is modelled through degradation model separated or independent from reduced order model without degradation. Li-ion battery system is controlled based on the improved predicted state of the Li-ion battery system. Systems, computing systems and computer programs are also disclosed which are suitable to perform said methods.

A negative electrode-free lithium metal battery, and a preparation method therefor and a use thereof. The negative electrode-free lithium metal battery comprises: a positive electrode, comprising a positive electrode current collector and a positive electrode active material layer containing a lithium supplementing additive; a negative electrode current collector; an electrolyte, comprising at least one boron-containing lithium salt and a fluorinated amide compound solvent; and a separator. The fluorinated amide electrolyte and the lithium supplementing additive are used in combination, so that a thin lithium layer having a dense deposition structure can be formed in situ on the negative electrode current collector when the negative electrode-free lithium metal battery is charged for the first time, and is taken as additional stored lithium to make up for irreversible lithium loss, thereby remarkably prolonging the cycle life of the negative electrode-free lithium metal battery while keeping high energy density.

The invention relates to a high-voltage-resistant deep eutectic-based in-situ polymerization solid electrolyte as well as preparation and application thereof. The in-situ polymerization solid electrolyte is obtained through an in-situ polymerization reaction of a precursor solution comprising 30-80 wt% of a deep eutectic solution, 10-50 wt% of a polymerizable monomer, 1-30 wt% of an additive and 0.05-10 wt% of an initiator; the deep eutectic solution comprises a lithium salt and a hydrogen bond donor organic solvent; the hydrogen bond donor organic solvent comprises a nitrile solvent and a non-nitrile solvent; the polymerizable monomer comprises a monomer for free radical-initiated polymerization or ring-opening polymerization; the additive comprises lithium nitrate and fluoroethylene carbonate. The high-voltage-resistant in-situ polymerization solid electrolyte formed by in-situ compounding of an organic framework formed by in-situ polymerization of a deep eutectic solution, an additive and a monomer has the excellent characteristics of wide electrochemical window, high ionic conductivity, high mechanical strength, good flame retardance, wide-temperature applicability and the like, and can be suitable for a high-voltage system of 4.6 V or above; the solid-solid contact problem of a solid-state battery interface is effectively solved, and the side reaction between the electrolyte and the lithium metal negative electrode is reduced.

Provided in the present application are a lithium secondary battery and an electric device. The lithium secondary battery comprises an electrolyte and a negative electrode sheet, wherein the electrolyte comprises a chain carboxylic ester and a cyclic carbonate, and the negative electrode sheet comprises a negative electrode current collector and a negative electrode film layer located on at least one side of the negative electrode current collector. Based on the total mass of the electrolyte, the mass content W1 of the chain carboxylic ester and the mass content W2 of the cyclic carbonate satisfy: 0.1≤W2 / W1≤2, and the mass content W1 of the chain carboxylic ester and the thickness H of the negative electrode film layer satisfy: 0.2≤H / 100W1≤20, with the unit of H being μm. The lithium secondary battery has good fast charging performance and cycling performance.

The invention discloses a lithium battery life prediction method and system based on a Mama model, and relates to the field of energy storage of a new energy power system, and the method comprises the steps: obtaining aging feature matrixes of a plurality of lithium batteries, substituting the aging feature matrixes into the Mama model for training, extracting a hidden state matrix sequence of each lithium battery according to the trained model, and obtaining a hidden state matrix sequence of each lithium battery; through norm calculation and variational mode decomposition, a cycle number sequence corresponding to the target cycle life prediction point of each lithium battery is obtained; on the basis of the cycle number sequences corresponding to the target health states of all the lithium batteries and the cycle number sequences corresponding to the target cycle life prediction points of all the lithium batteries, constructing a linear relation model of lithium battery life prediction; and according to the linear relation model for lithium battery life prediction, calculating to obtain a cycle number sequence corresponding to the target health state of the to-be-predicted lithium battery. The interpretability and calculation efficiency of lithium battery life prediction are improved, and the application range of the prediction model is expanded.

The invention provides a secondary battery, a preparation method thereof and an electric device. The secondary battery comprises a copper foil, the copper foil comprises copper crystal grains with different particle sizes, the copper crystal grains comprise copper crystal grains with the particle size smaller than or equal to 0.5 mu m and copper crystal grains with the particle size larger than 0.5 mu m, the number of the copper crystal grains with the particle size smaller than or equal to 0.5 mu m accounts for 70%-95% of the total number of the copper crystal grains, and the number of the copper crystal grains with the particle size larger than 0.5 mu m accounts for 10%-20% of the total number of the copper crystal grains. And the amount of the copper grains with the grain size larger than 0.5 mu m accounts for 5%-30% of the total amount of the copper grains. The current collector has excellent mechanical strength and plasticity.