The invention belongs to the technical field of
lithium organic batteries, and provides a conjugate extended
lithium-containing organic positive
electrode material and a preparation method and application thereof. The synthesis process of the positive
electrode material comprises the following steps: firstly, taking tetraamino p-
benzoquinone as a
raw material, and carrying out oximation modification reaction on the tetraamino p-
benzoquinone to generate tetraamino p-oximic acid; then, carrying out composite treatment on the TAPO and a
lithium source to obtain lithium tetraamino p-oximate; and finally, through a condensation
polymerization reaction, further preparing to obtain the polybenzoquinone-
pyrazine extended lithium oximate. Through specific
chemical treatment, the organic material contains a lithium element, so that the dependence on an external lithium source (such as a
metal lithium negative
electrode or a lithium supplement agent) is eliminated. Through ingenious molecular design and synthesis strategies, the
conductivity of the material is improved, and the rate capability, the
solubility resistance, the high-temperature stability and the cycle life of the material are remarkably enhanced, so that a
solid foundation is laid for long-term stable operation and high-performance expression of a battery.