The application belongs to the technical field of
lithium batteries, and relates to a preparation method of a double-coated
silicon-carbon
composite material, an
electrode and a
lithium battery.The method comprises the following steps: placing a
lithium dopant and a MOF material in a first
organic solvent, adding a template agent and a catalyst, reacting, filtering, freeze-
drying and obtaining a gel composite; in an
inert atmosphere, the gel composite is heated to a first preset temperature,
carbon dioxide is introduced at a preset flow rate, the temperature is lowered, the gel composite is soaked in mixed acid,
pickling is performed,
vacuum drying is performed, and a
porous carbon composite material is obtained; liquid
silane, a
phosphine derivative, a dispersing agent, the
porous carbon composite material and a
silane coupling agent are added to a second
organic solvent,
spray drying is performed, primary
carbonization is performed, and a
silicon-carbon precursor material is obtained; resin is dissolved in a third
organic solvent, a
fast ion conductor and the
silicon-carbon precursor material are added, secondary
carbonization is performed, the temperature is lowered to a second preset temperature, a reducing gas is introduced, and a double-coated silicon-carbon composite material is obtained; the
conductivity is improved, the interface stability is improved, and the full charge swelling is reduced.