82 results about "Perylene" patented technology

The invention provides a visible light photocatalytic hydrogen production material based on a D-pi-A type PTA-TFPTA imine bond COF as well as a preparation method and application of the visible light photocatalytic hydrogen production material, belongs to the technical field of functional material technologies and photocatalytic hydrogen production, and is used for solving the problem that a covalent organic framework material is generally insufficient in catalytic activity in the photocatalytic hydrogen production process. The material is prepared by mixing and reacting 2, 5, 8, 11-tetra (4-aminophenyl) perylene and an electron-deficient monomer; during application, the material is mixed with a sacrificial agent and a cocatalyst, and photocatalytic hydrogen production can be realized under visible light irradiation. The preparation process is simple and convenient, does not need complex equipment and harsh conditions, and is easy for large-scale production; the obtained material is good in crystallinity, excellent in visible light absorption performance and outstanding in photocatalytic hydrogen production activity.

Composite solid polymer electrolytes (SPE), organic cathode electrodes, and solid-state lithium batteries (SLBs) that incorporate the SPE and / or the organic cathode electrodes. The composite solid polymer electrolytes include a hybrid polymer matrix, an LiTFSI salt dispersed in the matrix polymer matrix, and an LLZTO ceramic filler dispersed in the matrix polymer matrix. The organic cathode electrodes contain perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA).

To provide an exterior laminate that can be used as an exterior component and is capable of sufficiently suppressing heat accumulation due to radiant heat such as sunlight. [Solution] An exterior laminate 10 is disclosed, having, in order from the surface side, a) a transparent film layer 1 containing an acrylic resin, c) a printed layer 2, and b) a colored film layer 3 containing a polyvinyl chloride resin, wherein the printed layer 2 of c) does not contain carbon black, the solar transmittance of the printed layer 2 of c) is 70% or more, and the solar absorptance is 20% or less. Preferably, the printed layer 2 of c) contains a perylene-based colorant and / or a phthalocyanine-based colorant.

This invention relates to the field of functional materials technology, and particularly to a floating defective g-C3N4 / PDI composite thin-film photocatalyst, its preparation method, and its application. The preparation method of the floating defective g-C3N4 / PDI composite thin-film photocatalyst provided by this invention includes the following steps: mixing defective graphene carbon nitride, N,N'-bis(3-aminopropyl)perylene-3,4,9,10-tetracarboxylic acid diimide (PDI), an organic base, and water to obtain a first suspension; mixing the first suspension with a monohaloacetic acid to undergo a protonation reaction, followed by solid-liquid separation to obtain a protonated composite material; mixing the protonated composite material with a thermoplastic resin solution to obtain a second suspension; and forming the second suspension into a film and then drying it to obtain the floating defective g-C3N4 / PDI composite thin-film photocatalyst. This photocatalyst is recyclable after use, does not cause secondary pollution to the environment, and exhibits excellent photocatalytic performance.

The invention belongs to the technical field of eutectic semiconductor materials, and discloses a D-A type acene-perylene bisimide eutectic crystal, an organic field effect transistor and a preparation method and application of the D-A type acene-perylene bisimide eutectic crystal and the organic field effect transistor. As a bipolar semiconductor material, the D-A acene-perylene bisimide eutectic crystal shows balanced bipolar with excellent performance, has an ultrahigh on-off ratio, and shows great application value in the aspect of electronic circuits.

The invention belongs to the technical field of photothermal conversion materials, and discloses a preparation method and application of an inorganic-organic hybrid polyoxotungstate photothermal material with wide spectrum absorption. The structural formula of the photo-thermal material is Per4W10O32, the crystal structure belongs to a triclinic system, the space group is P-1, and the photo-thermal material has specific unit cell parameters. The preparation method comprises the following steps: oxidizing perylene molecules through constant current electrolysis in a mixed solvent system containing perylene molecules and a decatungstate precursor in an electrochemical oxidation manner, and assembling the oxidized perylene molecules with decatungstate anions to form bulk crystals; the photo-thermal material has continuous strong absorption in a region from ultraviolet light to short wave infrared, the photo-thermal conversion efficiency is as high as 98.24%, when the photo-thermal material is applied to the fields of solar driven interface photo-thermal evaporation and water treatment, the evaporation rate of a two-dimensional system is 1.89 kg.m <-2 >. H <-1 >, the evaporation rate of a three-dimensional hydrogel system is increased to 3.02 kg.m <-2 >. H <-1 >, salt deposition can be inhibited in long-term seawater desalination operation, and the photo-thermal material has a good application prospect. Fresh water quality meets drinking water standards.

The invention discloses a heterojunction-based bipolar synapse transistor and a preparation method thereof, and the heterojunction-based bipolar synapse transistor comprises a gate layer, a gate insulating layer located on the surface of the gate layer, a charge storage layer located on the surface of the gate insulating layer, and a semiconductor layer located on the surface of the charge storage layer. The drain electrode and the source electrode are located on the surface of the semiconductor layer. The charge storage layer is prepared from n-type N, N '-dioctyl-3, 4, 9, 10-perylene dicarboximide through vacuum evaporation; and the semiconductor layer is prepared by vacuum evaporation of p-type pentacene. According to the transistor prepared by the invention, a balanced bipolar behavior is combined with an effective charge capture mechanism, the functions of a memory and a photoelectric synapse transistor can be realized at the same time, and the transistor has huge application potential in the aspect of constructing a brain-like computing system.

The invention relates to a cyclic bisazo initiator for preparing EVOH as well as a preparation method and application of the cyclic bisazo initiator, the initiator is a cyclic bisazo compound, an aromatic ring is used as an intermediate structure of the compound, tetrahydropyridazine is coupled to an adjacent position of the aromatic ring, and the aromatic ring is selected from any one of naphthalene, anthracene, pyrene and perylene. Compared with the prior art, the initiator provided by the invention has a ring rigid structure and two azo groups, can be rapidly initiated to generate free radicals with a certain concentration, is high in polymerization efficiency, and effectively improves the performance of an EVOH product.

The present application relates to fluorescent nanoparticles based on fluorinated zwitterionic random copolymer and its preparation method and application, the fluorescent nanoparticles include the single chain nanoparticles formed by poly trifluoroethyl methacrylate-co-methacryloyloxyethyl sulfobetaine, the molecular chain end of the poly trifluoroethyl methacrylate-co-methacryloyloxyethyl sulfobetaine is connected with ACQ type group selected from anthryl, perylene imide group and pyrene base or AIE type group selected from tetraphenyl ethylene base, carbazole base and cyanine-containing triphenyl ethylene group.The fluorescent nanoparticles based on the poly trifluoroethyl methacrylate-co-methacryloyloxyethyl sulfobetaine of the present application that terminal fluorescent group is terminated, has excellent controllable fluorescent luminescence performance.It is considered that the single chain nanoparticles have isolation effect, avoid the fluorescence quenching effect of ACQ type group, and can provide limited microenvironment for AIE type group, ensure the fluorescent luminescence performance of nanoparticles.

An electrochemical sensor for the detection of a selected analyte and methods of detecting the selected analyte. The sensor comprises an active layer containing a sensing material dispersed in a semiconducting and / or conducting polymer. The conductance of the active layer is responsive to the presence / amount of selected analyte in the active layer. The sensing material comprises a pi-conjugated moiety and at least one chemical functional group bonded to the pi- conjugated moiety, interaction of the sensing material with the selected analyte induces charge transfer into the active layer to change the conductance of the active layer. Example selected analytes are volatile bases, particularly ammonia, volatile amines, diamine or polyamines. Example sensing material is the N-Annulated perylene diamine NPDI-NH.

The invention relates to the technical field of functional materials, in particular to a floating type defect g-C3N4 / PDI composite film photocatalyst as well as a preparation method and application thereof. The preparation method of the floating type defect g-C3N4 / PDI composite film photocatalyst provided by the invention comprises the following steps: mixing defect type graphene carbon nitride, N, N '-bis (3-aminopropyl) perylene-3, 4, 9, 10-tetracarboxylic diimide (PDI), organic alkali and water to obtain a first suspension; mixing the first suspension with halogenated acetic acid, carrying out protonation reaction, and then carrying out solid-liquid separation to obtain a protonated composite material; and mixing the protonated composite material with a thermoplastic resin solution to obtain a second suspension, forming a film from the second suspension, and drying to obtain the floating type defect g-C3N4 / PDI composite film photocatalyst. The photocatalyst can be recycled after being used, does not cause secondary pollution to the environment, and has excellent photocatalytic performance.

The invention relates to an organic compound, a polymer and a light-emitting device. The organic compound has a structural formula as shown in a formula (1). According to the invention, a condensed ring structure with perylene groups is formed in the organic compound, so that blue light can be effectively absorbed; when the organic compound is used for forming a color conversion layer and used in a light-emitting device, the light-emitting efficiency and the light-emitting effect of the light-emitting device can be improved.

The invention discloses a perylene bisimide flame-retardant pigment as well as a preparation method and application thereof, and relates to the technical field of high polymer material additives, and the perylene bisimide flame-retardant pigment comprises a compound as shown in a formula I. According to the perylene bisimide flame-retardant pigment provided by the invention, the design thought of an organic functional pigment is broadened, the blank of synergistic application of a flame retardant and a pigment in the prior art is filled up, a novel structure considering flame-retardant and coloring requirements in a single molecule is realized, the adjustability of color and performance of a material is endowed through substituent group engineering, and the flame-retardant perylene bisimide pigment is suitable for industrial production. The method has important significance in the fields of textile fibers, engineering plastics, electrical and electronic components and the like which need to consider attractiveness and safety. Formula I.

The invention relates to the technical field of textile fiber preparation, in particular to a preparation method of colorful chitosan-based fluorescent anti-counterfeiting nanofibers. The method comprises the following steps: (1) preparing a spiropyrane (SP) labeled red fluorescent chitosan (CS) solid material SP-CS; (2) preparing a perylene (Perylene) labeled green fluorescent chitosan solid material Perylene-CS (Chlorine Sulfonate); (3) preparing a tetraphenylethylene (TPE) labeled blue fluorescent chitosan (CS) solid material TPE-CS; (4) blending the SP-CS dilute acetic acid solution, the Perylene-CS dilute acetic acid solution, the TPE-CS dilute acetic acid solution and the polyvinyl alcohol (PVA) solution according to different proportions to prepare a spinning solution; and (5) preparing the colorful chitosan-based fluorescent anti-counterfeiting nanofiber through electrostatic spinning. The series of chitosan-based anti-counterfeiting nanofibers prepared by the invention can emit fluorescence in various colors such as orange, yellow, cyan and purple under the excitation of ultraviolet light, the diameter distribution of the fibers is uniform, the surface is smooth, and the average diameter is within the range of 110-150nm.

The utility model relates to the technical field of photoelectric equipment, in particular to an organic photoelectric detector and equipment comprising the organic photoelectric detector, and the organic photoelectric detector comprises an anode and a cathode; one end, far away from the cathode, of the anode is arranged on the transparent glass substrate; a hole transport layer is arranged at one end, far away from the transparent glass substrate, of the anode; an electron transport layer is arranged at one end, close to the anode, of the cathode; an active layer is arranged between the hole transport layer and the electron transport layer; the active layer is composed of at least two aggregation layers, and each aggregation layer comprises a graphene-azo sub-layer, a graphene-perylene sub-layer and a graphene-phthalocyanine sub-layer which are sequentially arranged in the longitudinal direction. Through collaborative design of a graphene grid thin layer structure and various photosensitive pigments, the generation, separation and migration efficiency of photon-generated carriers is remarkably improved.

The invention discloses an organic long-afterglow material for afterglow emission of a polycyclic aromatic hydrocarbon compound and a preparation method and colorful display application of the organic long-afterglow material for afterglow emission of the polycyclic aromatic hydrocarbon compound. The organic long-afterglow material for afterglow emission of the polycyclic aromatic hydrocarbon compound comprises cholic acid and the polycyclic aromatic hydrocarbon compound uniformly distributed in the cholic acid, the polycyclic aromatic hydrocarbon compound is one or a mixture of benzo [a] anthracene, benzo [c] phenanthrene, pyrene, benzo [ghi] perylene and naphthalene [2, 3-a] pyrene. The organic long-afterglow material shows a good color-changing long-afterglow property under excitation of an ultraviolet lamp, and overcomes the defects that most of existing long-afterglow materials are single in color and have a static afterglow effect. The dynamic color-changing long-afterglow material can display colored afterglow for a long time after optical excitation is stopped, and shows a dynamic and differentiated luminous effect. Meanwhile, the organic long-afterglow material is suitable for various polycyclic aromatic hydrocarbon compounds and is high in universality.

The invention belongs to the technical field of polymer composite heat conduction materials, and particularly relates to a hot adhesive for a composite material and a preparation method thereof. The method aims at solving the problem that current thermal conductivity improvement generally depends on a sacrifice process and adhesion. A three-dimensional heat conduction network is constructed through surface modification and magnetic field induced orientation of the perylene modifier on graphene, the perylene modifier is firmly adsorbed on the surface of the graphene through pi-pi accumulation and forms a dynamic covalent and chemical bonding interface with a hyperbranched polysiloxane matrix, and meanwhile, the surface of the modified graphene is loaded with nano-scale magnetic particles, so that the surface of the modified graphene is subjected to surface modification and magnetic field induced orientation. Under the action of a magnetic field, orientation is performed to form a three-dimensional heat-conducting chain structure, so that good flowability and adhesive force are still realized under relatively high filler loading, and the heat conductivity coefficient is improved.

The invention relates to a stomach adhesion type double-network hydrogel sensor capable of realizing long-time gastric acid imaging and application of the stomach adhesion type double-network hydrogel sensor. The RHO-PDI probe takes perylene bisimide as a framework and rhodamine B as an acid response unit, pKa is approximately equal to 1.97, and 500-650 nm fluorescence is emitted in gastric acid. The double-network hydrogel is formed by crosslinking sodium polyalginate-calcium ions and polyethylene glycol dithiol-four-arm maleimide, has excellent mechanical strength and gastric wall adhesiveness, and realizes long-term, stable and non-invasive dynamic monitoring of gastric acid and circadian rhythm hormone change tracking.

The invention discloses a double-terminal fluorescence labeled polymer as well as a preparation method and application thereof. The structural formula of the double-terminal fluorescence labeled polymer is shown as a formula V. In the formula V, n is 30-300, and x is 1-10. The preparation method comprises the following steps: carrying out ATRP (Atom Transfer Radical Polymerization) active polymerization reaction on a monomer by taking 2-bromo-2-methyl propionate 2-hydroxyethyl ester with hydroxyl at the tail end as an initiator to obtain a compound of which the tail end is terminated by hydroxyl and bromo; a hydroxyl terminal in the compound reacts with a perylene fluorescent dye shown in a formula II, a bromine terminal is subjected to an azidation reaction and then is subjected to a click chemical reaction with an ATTO647N dye, and the double-terminal fluorescence labeled polymer shown in a formula V is obtained. The double-fluorescent-molecule end-capped polymer disclosed by the invention has an FRET effect; the double-fluorescent-molecule-terminated polymer can realize single-molecule fluorescence microscopic imaging, and has important significance on basic researches such as micro-nano structure evolution of characterization and analysis materials and the like.

The application discloses a method for preparing hydrogen peroxide by photocatalysis without a sacrifice agent based on naphthalene imide / perylene imide polymer. The naphthalene imide / perylene imide polymer photocatalyst is synthesized by a hydrothermal method, and the catalyst can catalyze the reaction of oxygen and water to prepare hydrogen peroxide by photocatalysis without adding a sacrifice agent. The naphthalene imide / perylene imide polymer synthesized by the application is a photocatalyst with a donor / acceptor electron transport interface, and the structure greatly improves the electron-hole transport rate, thereby promoting the generation of hydrogen peroxide and inhibiting the decomposition of hydrogen peroxide. The application first applies the naphthalene imide / perylene imide polymer catalyst to the field of photocatalytic preparation of hydrogen peroxide. Compared with the industrial anthraquinone method and the method for preparing hydrogen peroxide by electric and thermal catalysis, the application is safe and environmentally friendly, simple to operate and low in cost.

The application discloses a perylene imide compound and a preparation method and application thereof, and belongs to the technical field of photoacid generators. The perylene imide compound is shown as formula I, and acid and CBI molecules can be generated under excitation of visible light (530-605 nm). On one hand, the acid generating property of the perylene imide compound can be utilized to provide a remote and non-invasive controllable pH adjusting method, which can be used for polymerization of thioctic acid ester and the like; on the other hand, the structure of CBI generated by the perylene imide compound can be used as a photosensitizer to generate active oxygen under light conditions for inhibiting bacterial activity. The perylene imide compound has wide application prospects.

The application discloses a high-efficiency heat-dissipation bus, and belongs to the technical field of buses.The high-efficiency heat-dissipation bus comprises a copper-clad aluminum pipe layer, a shielding layer and an insulating layer, the heat-dissipation effect is realized by modifying the insulating layer, and the insulating layer comprises, in weight parts, 100-200 parts of silicone rubber, 20-30 parts of fumed white carbon black, 20-30 parts of boron nitride, 10-25 parts of four-needle-shaped zinc oxide whiskers, 15-30 parts of an interfacial agent and 1-5 parts of a silane coupling agent; wherein the interfacial agent is acryloyl perylene and N-acryloyl piperidine modified polysiloxane.The composite filler of sheet boron nitride and four-needle-shaped zinc oxide whiskers is blended with the interfacial agent, three-dimensional heat-conducting channels can be formed in the silicone rubber substrate, the interfacial thermal resistance is reduced, the interfacial structure is optimized, the heat-conducting performance and heat-resistant performance of the insulating layer material are greatly improved, and the mechanical performance and insulating performance are not negatively affected.

The application belongs to the technical field of analytical chemistry, and particularly relates to a preparation method and application of a dual-mode sensor based on ZnIn2S4 / Ag4V2O7 / PTCA heterojunction and CuFe2O4-AuNPs nanosensor. The preparation steps of the sensor are as follows: (1) ITO substrate pretreatment; (2) heterojunction modification layer construction; (3) antibody immobilization interface engineering; (4) biological recognition interface optimization; (5) antigen-antibody specific reaction; (6) signal probe assembly; (7) detection process. The CEA antigen solution is a standard or an actual biological sample.

The invention belongs to the technical field of high polymer materials, and relates to a black transparent PC material capable of transmitting white LED light and a preparation method thereof. The invention relates to a black transparent PC material capable of transmitting white LED light, which comprises the following components in parts by weight: 99-100 parts of PC resin and 0.5-1 part of compound toner, the compound toner is formed by compounding perylene red toner, anthraquinone blue toner and azo yellow toner according to the weight ratio of 1: (0.7-0.9): (0.8-1.2), and the azo yellow toner is azo yellow toner K1700 or azo yellow toner Ranbar P3860. The preparation method comprises the following steps: uniformly mixing the PC resin and the toner in proportion, extruding and granulating. According to the black transparent PC material, the appearance of a PC part can be black, white LED light can penetrate through the PC part, the visible light transmittance is 3.0%-4.0%, and the black transparent PC material has important application value in the field of lighting devices.

The present invention addresses the problem of providing a positive photosensitive pigment composition which does not leave any residue in a pattern opening and which is capable of forming a pixel division layer and a spacer layer having high light-blocking properties at the same time. The present invention is a positive photosensitive pigment composition containing a pigment (a), an alkali-soluble resin (b), a compound (c) having a phenolic hydroxyl group and a molecular weight of 1000 or less, a photoacid generator (d) and a solvent (e), the pigment (a) being a dioxazine-based pigment and / or a perylene-based pigment having a benzimidazole skeleton, and the compound (c) containing a compound (c1) having an alkyl group having 5-20 carbon atoms.

The present invention aims to provide a compound having high fluorescence intensity as a fluorescent dye, and a colored curable resin composition capable of forming a color filter having excellent fluorescence intensity. The present invention relates to a colored curable resin composition containing a colorant, a resin, a polymerizable compound, and a polymerization initiator, the colorant comprising a benzo perylene compound.

The application provides a lipid peroxidation detection probe based on a perylene imide-triphenyl phosphine structure and a preparation method and application thereof, and belongs to the technical field of design and synthesis of lipid peroxidation fluorescent probes and visual imaging technology.The structural formula of the lipid peroxidation detection probe is: the lipid peroxidation detection probe is based on structure optimization of a perylene imide-triphenyl phosphine compound Liperfluo, and the stability of the lipid peroxidation detection probe is greatly improved.The lipid peroxidation detection probe has good sensitivity and selectivity to the iron death marker lipid hydroperoxide, and the pretreatment of a test sample is simple.The lipid peroxidation detection probe can be used for detecting endogenous and exogenous iron death in fibrosarcoma cells, and can be used for studying specific regulation mechanisms and biological functions of iron death related metabolic diseases.The lipid peroxidation detection probe is a solid powder, is convenient to store and use, and has a simple synthesis method, high yield, low cost and good market application prospect.

This invention provides a ferrocene-perylene imide composite small molecule compound, its preparation method, and its application, belonging to the field of organic solar cell technology. The compound provided by this invention has the structure shown in Formula I, combining the high electron mobility and high electrical conductivity of perylene imide and ferrocene units. Simultaneously, the presence of ester groups in the molecular structure ensures good film-forming properties when used as an electron transport layer material, while also endowing it with thickness insensitivity, which is beneficial for its commercial application.

The invention discloses a tertiary amine or quaternary ammonium salt substituted perylene bisimide dimer compound as well as a preparation method and application thereof, and belongs to the technical field of organic photoelectric materials. The structure is shown in the specification. The preparation method comprises the following steps: carrying out condensation reaction on a perylene dimer connected by a single bond or different modules and different amines; a tertiary amine and quaternary ammonium salt substituted perylene bisimide monomer is subjected to coupling reaction with the perylene bisimide monomer or different modules, and the tertiary amine substituted perylene bisimide dimer compound is prepared in one step. The quaternary ammonium salt substituted perylene bisimide dimer compound can be obtained by reacting a tertiary amine substituted perylene bisimide dimer compound with halogenated alkane or oxidizing the tertiary amine substituted perylene bisimide dimer compound with hydrogen peroxide. The compound can be used as an electron transport layer to be applied to the fields of organic solar cells, perovskite solar cells, organic light-emitting diodes and the like.

This invention discloses a covalent organic framework composite material, its preparation method, and its application in the preparation of antibacterial products. It belongs to the field of functional materials technology. This invention uses crystalline covalent organic frameworks synthesized from triporphyrin, perylene imide, or nitrogen-containing heterocyclic building blocks and chitosan to prepare a covalent organic framework composite material. It is a composite material with efficient, long-lasting, and broad-spectrum antibacterial properties. This composite material can overcome the defect that COF powder is difficult to apply directly and expand the antibacterial spectrum and efficacy of chitosan materials.