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137 results about "Naphthalene Compound" patented technology

A class of compounds with the basic naphthalene structure, an aromatic hydrocarbon compound, consisting of two fused benzene rings.

Axially-chiral indole-naphthalene compounds and preparation method thereof

The invention discloses axially-chiral indole-naphthalene compounds and a preparation method thereof. The axially-chiral indole-naphthalene compounds have a chemical structure represented by a formula9 shown in the description; and the method comprises the following steps: a compound represented by a formula 7 and a compound represented by a formula 8 are used as reaction raw materials, a mixed solution of 1,1,2,2-tetrachloroethane and p-xylene is used as a solvent, a molecular sieve is added, a reaction is performed under stirring under the action of a chiral phosphoric acid catalyst, the reaction is tracked by TLC until the reaction is completed, filtration is performed, concentration is performed, purification is performed, and therefore one compound is obtained. The method for preparing the axially-chiral indole-naphthalene compounds provided by the invention is an asymmetric addition reaction under catalysis of organic small molecules, starts from the racemic raw material to construct the axially-chiral indole-naphthalene structure in one step, and has the advantages of simple and convenient operation, mild reaction conditions and economical easily-available raw materials, and the prepared axially-chiral indole-naphthalene compounds have high optical purity; and the axially-chiral indole-naphthalene compounds prepared by the method are expected to be widely used in the field of asymmetric catalysis.
Owner:XUZHOU NORMAL UNIVERSITY

Intermediate-phase asphalt stock with superior spinning performance and preparation method

The invention relates to an intermediate-phase asphalt stock with superior spinning performance and a preparation method. The method comprises the following steps: performing a polymerization reaction on a naphthalene compound serving as a raw material in the presence of hydrogen fluoride and boron trifluoride serving as catalysts, wherein the using amount of the hydrogen fluoride is 0.5-15 times the mole number of the raw material, the using amount of the boron trifluoride is 0.2-1.0 time the mole number of the raw material, and the polymerization reaction temperature is 250-300 DEG C; after the polymerization reaction ends, removing HF-BF3 serving as a catalyst; distilling an obtained product under reduced pressure under the condition that the temperature is 400 DEG C and the pressure intensity is below 1KPa; and separating a low-boiling-point product out to obtain an intermediate-phase asphalt stock product. Compared with the prior art, intermediate-phase asphalt has the characteristics of superior spinning performance and small quantity of low molecular volatile matters in a spinning process. The preparation method contributes to long-term stable performance of spinning operation, is suitable for industrial production, and meanwhile contributes to the preparation of high-performance asphalt-based carbon fibers.
Owner:SHANGHAI JIAO TONG UNIV

4-bromo-1,2-dihydrocyclobuteneo[alpha]naphthalene compound and preparation method thereof

The invention discloses a novel method for synthesizing 4-bromo-1,2-dihydrocyclobuteneo[alpha]naphthalene. The method comprises the following steps: (1) adding 1,2-dihydrocyclobuteneo[alpha]naphthalene, glacial acetic acid and methanol into a low-temperature reactor, stirring, and reducing the temperature to be 10 DEG C below zero to 0 DEG C; (2) dissolving bromine in glacial acetic acid at the temperature of 10 DEG C below zero to 0 DEG C, dripping reaction liquid, preserving the temperature after the dripping operation of the reaction liquid is finished, keeping the reaction liquid in dark place, putting the reaction liquid in a low-temperature cabinet freezer, reacting at the temperature of 30 DEG C below zero to 15 DEG C below zero, and standing the reaction liquid at room temperature; (3) adding the reaction liquid into dichloromethane, extracting an organic phase, adding an aqueous solution of sodium metabisulfite into the organic phase, stirring, standing, layering, washing by using deionized water, separating out the organic phase, and drying; and (4) concentrating the dried organic phase into thick solid, and recrystallizing, thereby obtaining 4-bromo-1,2-dihydrocyclobuteneo[alpha]naphthalene. According to the method disclosed by the invention, 1,2-dihydrocyclobuteneo[alpha]naphthalene synthesized by self research and development serves as a raw material, and 4-bromo-1,2-dihydrocyclobuteneo[alpha]naphthalene with excellent performance and low price is synthesized. The reaction conditions are mild, the operation is simple, and the yield is high.
Owner:MIANYANG DAGAOTE NEW MATERIAL

Intermediate phase asphalt raw material for producing carbon fibers and preparation method thereof

InactiveCN104151531AExcellent pre-oxidation performanceFast oxidation reactionFibre chemical featuresFiberCarbon fibers
The present invention relates to an intermediate phase asphalt raw material for producing carbon fibers and a preparation method thereof, wherein the intermediate phase asphalt raw material intermediate phase content determined through the polarizing microscope method is 100%, S1/S2 in the infrared absorption spectrogram of the intermediate phase asphalt is more than 1.7, S1 is the area of the absorption peak at the wavelength of 2800-2990 cm<-1>, S2 is the area of the absorption peak at the wavelength of 2990-3150 cm<-1>, S3/S4 in the <13>C nuclear magnetic resonance spectrogram of the intermediate phase asphalt is less than 19, S3 is the area of the absorption peak with the chemical shift of 23.8-58.0 ppm, and S4 is the area of the absorption peak with the chemical shift of 8.0-23.8 ppm. According to the present invention, methylnaphthalene and other naphthalene compounds are adopted as raw materials, hydrogen fluoride-boron trifluoride is adopted as a catalyst, and the polymerization conditions are controlled to prepare the intermediate phase asphalt. Compared with the intermediate phase asphalt in the prior art, the intermediate phase asphalt of the present invention has characteristics of excellent spinnability, excellent pre-oxidation property and simple preparation process control, and can be adopted as the industrial production raw material of the high strength and high modulus asphalt-base carbon fibers.
Owner:SHANGHAI JIAO TONG UNIV

Novel method for preparing naphthalene sodium sulfonate formaldehyde condensation compound through continuous flows

The invention discloses a novel method for preparing a naphthalene sodium sulfonate formaldehyde condensation compound through continuous flows. The method comprises the following steps: putting a naphthalene compound into a stirring kettle A at a kettle temperature of 40-90 DEG C; putting concentrated sulfuric acid into a stirring kettle B; injecting into an internal spiral tube type reactor at the same time, and controlling the temperature to 140-150 DEG C to carry out a reaction so as to obtain a sulfonation liquid; putting the sulfonation liquid into a stirring kettle C, adjusting the acidity to 15-20%, putting a formaldehyde solution into a stirring kettle D, injecting into the internal spiral tube type reactor at the same time, and controlling the temperature to 105-120 DEG C to carry out a reaction so as to obtain a condensation liquid; putting the condensation liquid into a stirring kettle E, and keeping the temperature at 100 DEG C; putting a sodium hydroxide solution into a stirring kettle F, and injecting into the internal spiral tube type reactor at the same time, and controlling the temperature to 70-90 DEG C to carry out a reaction so as to obtain a neutralization product; drying the neutralization product, and evaporating off moisture, thereby obtaining a brown-yellow solid product. The novel method is safe, simple and efficient in process, and the synthesized naphthalene sodium sulfonate formaldehyde condensation compound is low in content of sodium sulfate, and good in thermal resistance stability.
Owner:江苏精禾界面科技有限公司

105% acid sulfonation manufacturing technique of 2-naphthalenol

The present invention relates to a 105 percent acidic sulfonation production process of 2-naphthol, and belongs to the technical field of chemical production. In the process, molten refined naphthalene is added into a reaction still and is heated to be at the temperature between 135 DEG C and 140 DEG C, sulfuric acid of 105 percent is added within 30 minutes according to a mass ratio of 1.28 to 1, the temperature in the reaction still is raised to be 160 DEG C and maintained for 135 minutes, the sulphonation product with an acidity of 24 to 27 percent is prepared, and the next procedure is performed. The present invention solves the problems in the traditional process with sulphonation of sulphuric acid of 100 percent that water is generated in the process of substituting hydrogen on a double benzene nucleus with sulfonic group and has dilution effects on sulphuric acid, the substitution reaction is impeded, water becomes water vapor at the temperature of 160 DEG C which has hydrolysis effects on 1-naphthalene sulfonic acid and 2-naphthalene sulfonic acid, and the total yield rate of the sulfonation reaction is not high. And the present invention has the advantages that sulfuric acid of 105 percent is added, the sulfonation conversion and the product yield rate are improved, the generated naphthalene compounds and other byproducts are reduced, and the yield rate is improved by 1.1 percent.
Owner:湖北鑫慧化工有限公司

Synthesis of novel chiral polyester containing binaphthyl and application thereof to molecular recognition

The invention discloses synthesis for chiral polyester containing binaphthyl. A binaphthyl compound is a common atropisomer compound with a C3 chiral axis. The axis of a binaphthyl structure is in an asymmetrical, multifunctional and stable chiral form, so that molecules and copolymers constructed by binaphthyl have superior structures and properties and wide application prospects in the field of materials. The patent is developed mainly around the synthesis of novel chiral polyester containing binaphthyl. A method for preparing the chiral polyester comprises the following steps of: synthesizing binaphthol or dinaphthyline by taking 2-naphthol or 2-naphthylamine as a raw material, and splitting to obtain chiral binaphthol or dinaphthyline; making dinaphthyline react with halohydrinare to obtain diol containing dinaphthalene radial, and react with the diacid to obtain chiral polyester; and making naphthidine react with chloride acyl chloride, hydrolyzing to obtain diol containing binaphthyl, and reacting with diacid to obtain chiral polyester containing binaphthyl. In the preparation of the chiral polyester, diol or diacid containing binaphthyl is prepared firstly, and then the chiral polyester is prepared by reacting. At last, the prepared chiral polyester is applied to molecular recognition.
Owner:QIQIHAR UNIVERSITY
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