The invention provides a method for preparing a 
graphene-carbon 
nano tube hybrid composite and relates to a method for preparing a functional high molecular material and a device thereof. The method comprises the following steps of: carrying out the stirring and sonic oscillation treatment on 
graphene and carbon nano tubes to preform an entangled 
network structure, thoroughly mixing the entangled 
network structure and 
polymer particles, and thus obtaining an uniformly-mixed 
system in which the 
graphene-carbon 
nano tube network is coated on the surfaces of the 
polymer particles after removing the 
solvent; and putting the uniformly-mixed 
system in a mould, hot-compacting, and obtaining the graphene-carbon 
nano tube hybrid composite after cooling and demoulding. By mingling the graphene and the carbon nano tubes in advance to form the communicated 
network structure, the method realizes the 
advantage complementation of the graphene and carbon nano tube structures and enables the 
hybrid composite to have favorable electric conduction and heat conduction properties. The method can be widely used in the fields such as 
aviation, transportation and communication, 
electronic industry, civil facilities, construction, 
chemical industry and the like, can be produced in the 
industrial scale, and has the advantages of low cost and environmental friendliness.