The invention discloses a method for preparing a
lithium-doped
silicon-based
luminescent material through
atomic layer deposition and a structure thereof, and the method comprises the steps: introducing
tris (dimethylamino)
silane pulse steam into a reaction cavity of
atomic layer deposition equipment, enabling the
tris (dimethylamino)
silane pulse steam to react with uniformly distributed active sites formed on the surface of a substrate, and generating Si-N bonds; the
plasma hydrogen reacts with the Si-N bonds to generate Si dangling bonds and Si atoms, so that a Si thin film is obtained through adsorption and deposition on the surface of the substrate, and finally a Si layer is obtained; (2, 2, 6, 6-tetramethyl-3, 5-heptadione)
lithium pulse steam is introduced into a reaction cavity of the
atomic layer deposition equipment so that the (2, 2, 6, 6-tetramethyl-3, 5-heptadione)
lithium pulse steam can be adsorbed with Si dangling bonds on the surface of the Si layer to form an unstable Si-O-Li intermediate, the Si-O-Li intermediate can be adsorbed to the surface of the Si layer,
plasma hydrogen reacts with the Si-O-Li intermediate on the surface of the Si layer, and a stable lithium-
silicon layer is formed; and completing the
doping process of the lithium-doped
silicon-based
luminescent material to form the lithium-doped silicon-based
luminescent material. According to the invention, the precise
doping of the lithium element in the silicon at the nanoscale can be realized, and the uniformity of the
doping concentration is ensured.