The invention discloses a high-compaction-density
ferromanganese phosphate precursor and a preparation method thereof, and belongs to the technical field of
lithium batteries, and the provided preparation method comprises the following steps: step 1, respectively dissolving a
manganese source, an
iron source and a
phosphorus source in water to form solutions; 2, adding a complexing agent into the
iron source solution to form a complexing iron
salt solution; step 3, mixing the complexing
ferric salt solution, the
manganese source solution and the
phosphorus source solution, adding an
oxidizing agent and alkali liquor, keeping the pH value of the
system to be 5.5-8, heating and stirring for reaction, and synchronously introducing
oxygen for bubbling during reaction; and 4, after the reaction is finished, carrying out
solid-liquid separation, and
drying and
roasting to obtain the
ferromanganese phosphate precursor. According to the method, under the action of the complexing agent, the homogeneity of iron-
manganese coprecipitation is improved,
oxygen is introduced for bubbling in the reaction process, and
excessive growth of crystals is inhibited while the oxidation condition is ensured, so that the
ferromanganese phosphate precursor is proper in particle size and uniform in distribution, and the positive
electrode material prepared from the precursor has high compaction density and excellent electrochemical performance.