The invention relates to a super hydrophobic silicon-fluorine polymer/nanometer silica hybridization nanometer material and a preparation method thereof, relating to a super hydrophobic nanometer material and a preparation method thereof. The invention provides the super hydrophobic silicon-fluorine polymer/nanometer silica hybridization nanometer material with mild reaction condition, definite reaction product structure as well as simple and convenient operation and the preparation method thereof. The preparation method comprises the following steps of: firstly, preparing nanometer silica modified by a silane coupling agent; secondly, preparing a nanometer silica atom transfer radical surface initiator; thirdly, preparing a SiO2-poly-Methacryloxypropyltrimethoxysilane macromolecule initiator; and finally preparing the silicon-fluorine polymer/nanometer silica hybridization nanometer material. The silicon-fluorine polymer/nanometer silica hybridization nanometer material has excellent high temperature resistance, ultraviolet resistance, infrared radiation resistance, oxidative degradation resistance, chemicals resistance and contamination resistance. Polymethyl 2-propenoic acid, 2,2,3,3,4,4,4-heptafluorobutyl ester has very low surface energy and very good hydrophobicity, wherein the surface energy can be as low as 0.5-1.5mN/m, and the hydrophobic angle can be over 150 degrees.