The invention relates to a
phosphorus chemical
wastewater treatment method, and belongs to the field of
phosphorus chemical
wastewater treatment.The method comprises the steps that
wastewater is introduced into an electrochemical
reaction zone, OH <-> is generated through
cathode electrolysis to form a local high-pH micro-zone, and
calcium and
magnesium ions and
phosphate radicals are induced to generate nanoscale
crystal seeds in situ; a
seed crystal-containing
mixed solution enters a
fluidized bed crystallization area at the flow speed of 20-60 m / h, and hydraulic classification and
crystal growth are realized through dynamic matching of the flow speed and the particle
settling speed; a seed-rich concentrated solution obtained after
solid-liquid separation returns to the
system according to the
reflux ratio of 20%-50%; through linkage of online monitoring and an
intelligent control unit, the
current density and the
reflux ratio are adjusted in real time, and a subarea self-stabilizing environment with the pH value of a
cathode near area being 9.5-11.0, the pH value of a main
body solution being 7.5-8.5 and the pH value of an
anode near area being 6.5-7.5 is formed in the reactor; and the particles at the bottom are automatically discharged when growing to 0.5-2.0 mm. According to the invention, the
total phosphorus in the
effluent is stably lower than 0.5 mg / L, the purity of the recovered
phosphate particles is greater than or equal to 85%, the
sludge yield is reduced by more than 80%, the operation cost is reduced by 50%, the
system has self-adaptive
impact resistance, and efficient removal and recycling of
phosphorus are realized.