1298 results about "Micro nano" patented technology

The present invention relates to an in-situ micro-nano impact indentation testing instrument, falling within the technical field of material micromechanical testing. The instrument comprises a nitrogen generation module, an environmental chamber, a high / low temperature loading module, an “optical-infrared” in-situ monitoring module, an “electromagnetic-piezoelectric” coupling impact module, etc. After the nitrogen is introduced into the environmental chamber and the test area is determined by microscopic imaging, the “electromagnetic-piezoelectric” coupling impact module can drive an indenter to indent a specimen. An acoustic emission sensor embedded in the high / low temperature loading module can monitor the surface crack propagation of the specimen. The “optical-infrared” in-situ monitoring module can perform real-time high-speed optical imaging and infrared imaging on the impact indentation process. The present invention can perform micro-nano impact indentation testing on the material at high or low temperatures.

The invention belongs to the technical field of micro-nano processing, and particularly relates to a preparation method and application of a metal micro-nano tube array. Comprising the following steps: preparing a metal layer on the surface of a substrate; coining glue is sprayed on the surface of the metal layer, then coining is conducted through a template, and a micro glue column array is formed after curing; a plasma etching process is adopted, the micro glue column array is used as a mask, the metal layer exposed out of the gaps in the bottom of the micro glue column array is etched, and a structure with the micro glue columns wrapped by metal is formed; and removing the rubber columns in the structure of the metal-coated micro rubber columns to obtain the metal micro-nano tube array. According to the invention, a residual-layer-free imprinting technology is adopted, the problem of glue layer residue in traditional imprinting is avoided, and the etching uniformity is improved. A plasma dynamic balance process is adopted, the side wall redeposition effect of etching by-products is utilized, and the metal micro-nano tubes are formed in a self-assembly mode. The prepared metal micro-nano tube array has high aspect ratio compatibility, and the nano tube array with the aspect ratio as high as 10: 1 can be realized.

The invention relates to the technical field of refrigeration material preparation, in particular to an efficient passive radiation refrigeration material suitable for a sub-super environment and a preparation method and application of the efficient passive radiation refrigeration material. The method comprises the following steps: uniformly mixing thermoplastic polyurethane, sunlight high-reflection inorganic particles and a phase change material in a solvent; after a chemical foaming agent is added, the obtained suspension liquid is heated and foamed in a confinement mold, and wet gel is formed; and finally, carrying out freeze drying treatment to obtain the composite porous aerogel. The prepared material has a micro-nano porous skeleton formed by TPU, and inorganic particles and PCM are uniformly dispersed in the skeleton wall. Through component cooperation and a special porous structure, the material has extremely high sunlight reflectivity and mid-infrared emissivity, self-adaptive temperature regulation and control are achieved through PCM phase change, the problem that refrigeration of a traditional material fails in the sub-environment such as the vertical surface is effectively solved, and efficient sub-super-environment heat management is achieved.

The invention discloses a system for mineralizing carbon dioxide by micro-nano bubble reinforced base solid waste and an application method.The system for mineralizing carbon dioxide by micro-nano bubble reinforced base solid waste comprises a micro-nano bubble generation and injection unit, a mineralization reaction unit and a circulating water treatment unit, the micro-nano bubble generation and injection unit comprises a micro-nano bubble generation device, a gas supply pipeline and a water supply pipeline, the mineralization reaction unit comprises a mineralization reactor, and a quartz sand filling layer and a nylon screen are arranged at the bottom of the mineralization reactor. Through the multi-unit integrated coupling design, the micro-nano bubbles are creatively utilized to strengthen the gas-liquid-solid three-phase synergistic reaction process, the column type filling structure and the sectional type reaction mechanism are combined, the carbon dioxide mass transfer efficiency and the mineralization reaction rate are effectively improved, and the system has the advantages of being high in system adaptability, stable in continuous operation, flexible in module deployment and the like; the method is suitable for efficient treatment of alkaline solid waste and carbon dioxide sequestration collaborative scenes, and has good engineering popularization prospects and resource utilization value.

The invention discloses a micro-nano air flotation coupling critical micro-flocculation phosphorus removal control method, which relates to the technical field of water treatment, and comprises the following steps: when the total phosphorus concentration is lower than a preset concentration threshold value, determining the proportion of non-target particles based on the water turbidity and particle spectrum distribution; adding a flocculating agent according to a preset critical dosage to generate target phosphorus floc, and synchronously forming a primary flocculation phase which can be distinguished from non-target particles; applying an interfacial activity regulation factor to the micro-nano bubbles based on the primary flocculation phase, and performing selective regulation; forming a bubble-phosphorus floc complex based on a selective regulation effect; the bubble-phosphorus floc complex is separated and removed in an air flotation mode, the competition intensity history of non-target particles is recorded, and a competition memory curve is formed. According to the method, interfacial activity regulation factors are applied to the surfaces of the micro-nano bubbles, so that the micro-nano bubbles can preferentially and selectively adsorb target phosphorus floc, and efficient removal of low-concentration total phosphorus is realized.

The invention relates to the technical field of bubble generation, and provides a micro-nano bubble stable generation method and a micro-nano bubble stable generation device.The method comprises the steps that a liquid-phase working medium flows through a Venturi tube, so that negative pressure is formed in the throat portion of the Venturi tube, a gas-phase working medium is sucked in, preliminary mixing is conducted, and a gas-liquid mixture is obtained; the gas-liquid mixture is tangentially guided into a rotary-cut type excitation cavity to drive a free rotating impeller in the rotary-cut type excitation cavity to rotate, and fine shearing is conducted on bubbles; the gas-liquid mixture obtained after fine shearing is guided into a diffusion and flow stabilization cavity for speed reduction and flow stabilization; the gas-liquid mixture subjected to flow stabilization flows through a nanocrystallization foam stabilizing unit, a plurality of parallel micro-channels are arranged in the nanocrystallization foam stabilizing unit, and the surface of the inner wall of each micro-channel is covered with a layer of nanofiber net-shaped structure; and carrying out final nanocrystallization and interface stabilization treatment on the gas-liquid mixture through a nanofiber net structure, and outputting stable micro-nano bubble liquid. The problems of poor stability, short service life and high energy consumption of the traditional technology are solved.

The invention relates to the field of water pollution abatement, in particular to an underwater micro-nano bubble generator and a using method thereof.The underwater micro-nano bubble generator comprises a bubble cutting pipe, a bubble cutting generating device is arranged in the middle of the bubble cutting pipe, and an erecting fixing plate is arranged at the front end of the bubble cutting pipe; a plurality of first venturi tubes are arranged on the erected fixing plate, each first venturi tube comprises a first liquid inlet section, a first compression section and a first expansion section, a water passing pipe is connected between the first expansion section and the bubble cutting tube, and an air inlet which is the same as the interior of the first venturi tube is fixedly formed in the first venturi tube; and a second Venturi tube is fixedly mounted at the rear end of the bubble cutting tube, so that the problems that a micro-nano bubble generator in the prior art is relatively high in cost, water and gas cannot be preliminarily mixed before bubble cutting, and the damage resistance is poor can be solved.

The invention discloses an alternate aeration venturi tube type micro-nano bubble generation device, which comprises a venturi jet device, a double-feedback channel fluid oscillator is communicated with the throat part of the venturi jet device, the top of the double-feedback channel fluid oscillator is an air inlet, and the bottom of the double-feedback channel fluid oscillator is a first outlet and a second outlet; a first annular porous material ring and a second annular porous material ring are installed at the positions, corresponding to a first outlet and a second outlet of the double-feedback-channel fluid oscillator, of the throat portion of the Venturi jet device respectively, the first outlet is communicated with the first annular porous material ring, and the second outlet is communicated with the second annular porous material ring. A flexible film is arranged in a divergent section of the Venturi jet device, and a rotational flow impeller is installed in a convergent section of the Venturi jet device. Interval ventilation can be achieved through the double-feedback-channel fluid oscillator, the double-feedback-channel fluid oscillator is combined with the annular porous material ring, and bubble gathering is restrained; meanwhile, under the synergistic effect of rotational flow shearing and film dynamic breaking, micro-nano bubbles are generated.

The invention provides a micro-nano bubble-surfactant synergistic coal seam gas seepage displacement-dust fall method, which adopts a multi-stage gas and dust comprehensive prevention and control means, adopts a pressure pump and a pumping system in a liquid injection period, and controls the pressure and the pumping flow rate, so that the gas seepage displacement and dust fall of a coal seam are realized. A micro-nano bubble-surface active liquid coupling medium is adopted for conducting seepage displacement on coal seam gas, and it is ensured that the coal seam gas is efficiently discharged or extracted. After liquid injection is finished, the micro-nano bubble-surface active liquid coupling medium is stored in the coal seam, dust falling is conducted on the coal seam, reverse wetting of the coal seam is achieved, the water content is increased, and therefore dust is reduced, and the safety of coal mining is improved.

The invention discloses a method for preparing a super-hydrophobic antibacterial fabric with a photothermal effect. The method first loads a photothermal preparation on the surface of the fabric to impart photothermal properties, and then introduces a composite coating formed by hydrophobic silica nanoparticles and a silane coupling agent with an alkane chain to reduce the surface energy of the material and construct a micro-nanoscale rough structure, thereby preparing an antibacterial fabric with excellent photothermal and super-hydrophobic properties. The super-hydrophobic antibacterial fabric prepared by the invention has a fabric surface water contact angle of 158° and a surface temperature of 120°C under near-infrared light irradiation, showing excellent photothermal cycle stability and super-hydrophobic high temperature resistance. The super-hydrophobic antibacterial fabric has an antibacterial rate of over 99.0% under the synergistic effect of passive super-hydrophobic antibacterial adhesion and active photothermal sterilization, and has a wide antibacterial range and a long antibacterial life.

This invention relates to the field of anti-icing technology and provides a hydrophobic and lubricating anti-icing coating that solves the problems of poor wear resistance and inadequate anti-icing effect of existing low-ice adhesion coatings in low-temperature and high-humidity environments. The hydrophobic and lubricating anti-icing coating comprises a surface layer formed by a hydrogel component, a lubricant component, and modified micro / nano particles. The modified micro / nano particles are interwoven within the hydrogel component to form a three-dimensional network structure. This three-dimensional network structure forms a superhydrophobic micro / nano structure on the upper surface of the surface layer. The lubricant component permeates within the three-dimensional network structure, and the hydrogel component is covalently bonded to the modified micro / nano particles.

The invention relates to the technical field of dredged sediment treatment, and discloses a dredged sediment sludge separation treatment method and system.The method comprises the following steps that S1, pretreatment is conducted, specifically, dredged mud is sequentially subjected to impurity removal and primary precipitation concentration, impurities are removed, and preliminary concentrated mud is obtained; s2, pollutant extraction and sludge separation; s3, carrying out multi-phase separation and pollutant enrichment; step S4, mud phase treatment; and step S5, residual water treatment. According to the dredged bottom mud sludge separation treatment method and system, pollutants in dredged mud are separated out by introducing a solid-phase extraction adsorption material and / or a liquid-phase extraction agent, and the pollutants are separated out through a sludge separation enhanced mass transfer unit integrating stirring, micro-nano bubble generation and pH regulation functions in the treatment process. The extraction-separation efficiency is remarkably enhanced by utilizing the synergistic effect of physical disturbance, interfacial effect and chemical conditions, and the core problems of mixed treatment of sludge, incomplete removal of pollutants and low recycling level in the traditional process are effectively solved.

The invention discloses a coherent interference-based coaxial transceiving line scanning three-dimensional profile measurement system and method. The system comprises a low-coherence light source; the beam splitter is used for collimating light emitted by the low-coherence light source and then dividing the light into two paths; the measuring light is focused into a linear light beam through the cylindrical lens and is emitted to the surface of the to-be-measured sample, and the measuring light reflected by the surface of the to-be-measured sample returns to the beam splitter along the original path; the reference light is emitted to a reference mirror with a certain inclination angle and is reflected back to the beam splitter through the reference mirror; the measuring light reflected by the surface of the sample to be measured and the reference light reflected by the reference mirror are subjected to beam combination interference through a beam splitter and are imaged to enter a camera for interference pattern acquisition; the signal processing system is used for processing the interference patterns to obtain height distribution of the to-be-measured sample on a line field, and three-dimensional profile measurement of the to-be-measured sample is realized by transversely moving or transversely scanning the to-be-measured sample and overlapping the interference patterns measured at different positions. Therefore, high-efficiency measurement can be realized while the micro-nano precision is kept.

The invention discloses a method for preparing micro-nano fibers through needle-free electrostatic spinning equipment assisted by an ion blower gun, and belongs to the technical field of spinning. The method specifically comprises the following steps: S1, dissolving a high-molecular polymer in a proper solvent to prepare a spinning precursor solution; and S2, preparing the micro-nano fiber from the spinning solution on a suitable collection surface by using an ion blower gun assisted needleless electrostatic spinning device. Through the synergistic effect of directional airflow generated by the ion blower gun and a controllable electric field, fiber surface charges are effectively neutralized, the jet instability is inhibited, and the controllability of a fiber flight path is improved. Meanwhile, the ionic wind assists in enhancing interface attachment between the fiber and the collector, uniform deposition is promoted, and the compactness and adhesive force of the fiber membrane are remarkably improved. According to the method, chemical modification does not need to be carried out on a material system, the intrinsic performance of the fiber is kept, universality and expandability are achieved, and a new path is provided for continuous preparation of the high-performance micro-nano fiber.

The invention belongs to the technical field of super-hydrophobic coatings, and particularly relates to a thermochromic photo-thermal super-hydrophobic coating and a preparation method and application thereof. The thermochromic photo-thermal super-hydrophobic coating sequentially comprises a photo-thermal epoxy bottom layer, a thermochromic epoxy middle layer and a super-hydrophobic surface layer from bottom to top in the thickness direction. Wherein phase change microcapsules for packaging phase change materials are distributed in the photo-thermal epoxy bottom layer, and the surfaces of the phase change microcapsules are modified with polydopamine layers and MXene layers in a layer-by-layer self-assembly mode; thermochromic microcapsules are distributed in the thermochromic epoxy middle layer; the super-hydrophobic surface layer is of a micro / nano structure formed by a silane derivative. Through the multifunctional design of integrating photothermal conversion, phase change and thermochromism mechanisms, all-weather ice resistance / ice removal is achieved, the energy utilization efficiency is optimized through an intelligent temperature control mechanism, and a sustainable solution is provided for surface ice prevention in an extreme environment.

The invention provides a multi-scale super-amphiphobic anti-wax coating and a preparation method thereof.The preparation method comprises the following steps that S1, cellulose nanofibers are added into an ethyl alcohol-water mixed solution, after ultrasonic treatment and uniform stirring are conducted, sodium methyl silicate is added for stirring reaction, then fluorosilane and tetraethoxysilane are added for hydrolytic condensation reaction, and a mixed solution is obtained; centrifuging and drying to obtain multi-scale fluorinated micro-nano particles; and S2, mixing the multi-scale fluorinated micro-nano particles, an adhesive and a diluent in proportion, performing ultrasonic stirring, spraying the mixture on a base material, and curing to obtain the multi-scale amphiphobic paraffin-proof coating. Hydrophobic modification is carried out on cellulose nanofibers by using fluorosilane, sodium methyl silicate and tetraethoxysilane to form a multi-scale micro-nano multilevel structure, and the structure can effectively capture air and is combined with ground surface energy, so that the coating has excellent super-amphiphobic performance.

The invention relates to a preparation method and application of a composite piezoelectric catalytic material NaNbO3-coated BiFeO3 for rapidly degrading antibiotics, NaNbO3 is flaky crystal grains with [001] crystallographic orientation prepared by a two-step molten salt method, and BiFeO3 is micro-nano particles prepared by a coprecipitation method. Composite micro-nano BiFeO3 powder and [001] oriented NaNbO3 flaky grains form a heterojunction, conversion of mechanical energy and electric energy of the material is achieved under the ultrasonic vibration condition, inductive charges are generated on the surface of the material, and photon-generated carriers move reversely under driving of a built-in electric field. According to the invention, the piezoelectric catalytic degradation capability of the BiFeO3 and NaNbO3 composite piezoelectric catalytic materials with different proportions on four antibiotics, namely oxytetracycline, levofloxacin, carbamazepine and paracetamol in different time periods is researched. When the mass ratio of the BiFeO3 to the NaNbO3 composite material is 1: 3, the oxytetracycline degradation rate within 30 min can reach 78.2%, the oxytetracycline degradation rate within 120 min can reach 91.8%, and the piezoelectric electro-catalysis characteristic is rapid and efficient. The method disclosed by the invention has important significance in developing a high-efficiency piezoelectric catalyst for degrading antibiotics.

The invention discloses a powder coating imitation copper wire drawing coating based on a gradient composite structure and a preparation method of the powder coating imitation copper wire drawing coating, and relates to the technical field of novel printing ink. The invention relates to a gradient composite structure-based powder coating copper-wire-drawing-imitating coating, which is characterized by comprising a bottom layer, a middle layer and a surface layer, wherein the bottom layer is an epoxy resin-based powder coating layer containing nano silicon dioxide; the middle layer is a copper-imitating ink wiredrawing layer containing micro-nano copper powder in directional arrangement; the surface layer is a water-based gloss oil layer containing a self-repairing flatting agent; wherein the bottom layer is formed by electrostatic spraying. Through the gradient composite structure design of the bottom layer, the middle layer and the surface layer, the coating provided by the invention shows remarkable advantages in the aspects of hardness (4H), salt fog resistance (more than 1000 hours), self-repairing property and the like, and overcomes the limitation that the traditional coating is insufficient in adhesive force and hard to consider both hardness and wear resistance.

The present invention provides a micro-nano impact indentation testing device and method based on cyclic refrigeration, and relates to the technical field of material property testing. The testing device comprises a pressure rod and a stage for low-temperature micro-nano impact indentation testing, and a refrigeration device for refrigerating and cooling the pressure rod and the stage, wherein the refrigeration device refrigerates the pressure rod and the stage by adopting an embedded channel, a cold conduction wire connected to the pressure rod and the stage and a refrigeration balancer in contact with the cold conduction wire are arranged between the pressure rod and the stage, and the temperature of the pressure rod and the temperature of the stage are stabilized at a common temperature point by the cold conduction wire and the refrigeration balancer together.

The invention belongs to the technical field of ceramic materials, and particularly relates to a composite ceramic material and a preparation method and application thereof. The eutectic ceramic is prepared by taking aluminum oxide and yttrium oxide stabilized tetragonal phase zirconium oxide powder as raw materials and adopting a laser suspension zone melting directional solidification method, the drawing speed of the laser suspension zone melting directional solidification is greater than or equal to 100 mu m / s, and the laser power is greater than or equal to 300W; the eutectic ceramic is sequentially subjected to crushing, smashing and wet screening, eutectic ceramic powder is obtained, and the particle size of the eutectic ceramic powder is 20-100 microns; mixing the eutectic ceramic powder, silicon carbide whiskers and a sintering aid to obtain mixed powder; the mixed powder is subjected to hot pressing sintering, the composite ceramic material is obtained, and the hot pressing sintering temperature is smaller than or equal to 1550 DEG C. The composite ceramic material obtained by the preparation method provided by the invention has both a large size and a fine structure and has a micro-nano eutectic structure, and the mechanical properties of the material are remarkably improved.

The invention discloses an electromagnetic shielding cable for a radio altimeter and a preparation method thereof, and relates to the technical field of cables. The preparation method comprises the following steps: treating ethylene-tetrafluoroethylene copolymer particles, a mixed compatilizer, a chemical foaming agent and a nano nucleating agent by using mixed gas low-temperature plasma containing acrylic acid, performing melt blending by using a double-screw extruder, injecting supercritical carbon dioxide, and performing slow cooling and shock cooling to obtain a three-dimensional porous matrix containing micro-nano cells; the preparation method comprises the following steps: synthesizing ferroferric oxide particles by a solvothermal method, coating a silicon dioxide dielectric layer, and then chemically silvering to prepare ternary core-shell composite particles; modifying the particles with aminopropyltriethoxysilane and a block copolymer to obtain modified composite particles; melting, mixing and granulating the porous matrix and the modified composite particles to obtain the electromagnetic shielding composite material. And performing extrusion molding on a conductor to form an insulation shielding layer, thereby obtaining the cable. The cable has an excellent electromagnetic shielding effect.

The invention belongs to the technical field of composite materials and radomes, and particularly relates to a layer structure of a radome body and a manufacturing method. The skin comprises a first skin layer, an interlayer, a second skin layer and a polyvinyl fluoride film layer which are sequentially arranged from top to bottom. Through collaborative design of a micro-nano composite structure and a low-surface-energy material, a self-cleaning surface skin layer with super-hydrophobicity, high wave transmission and weather resistance is constructed. Compared with a traditional fluorocarbon coating, the wave transmission rate is 60-70% and is improved by more than 25%, the signal transmission loss is remarkably reduced, and the harsh requirement for the wave transmission performance of the antenna housing is met. The cleaning cost of a traditional antenna housing can be saved by more than 80%, especially for high-altitude and complex-structure antenna housings, high-altitude operation or special equipment is not needed, and the maintenance safety risk is reduced. The replacement frequency of the radome caused by aging and abrasion of the coating can be reduced, and the overall life cycle cost of equipment is reduced.

The invention discloses a preparation method of a PVA / chitin porous nanosheet layered film for salinity gradient power generation, and belongs to the technical field of bio-based material functionalization. The preparation method comprises the following operation steps: firstly, preparing a chitin porous nanosheet by utilizing an acid steam combined ultrasonic strategy; modifying the surface of the chitin porous nanosheet with rich positive charges through quaternization reaction, and performing suction filtration and drying to obtain a porous nanosheet layered film; and finally, circularly freezing, thawing and packaging the porous nanosheet layered film by using polyvinyl alcohol hydrogel to prepare the PVA / chitin porous nanosheet layered film. According to the PVA / chitin porous nanosheet layered film, by means of combination of chitin nanosheet layer gap channels and micro-nano pore channels in nanosheet surfaces, ion transmission paths are increased, ion transmission resistance is reduced, the microstructure of the layered film is effectively stabilized jointly by means of the interlayer weak force effect and the hydrogen bond bonding effect between polyvinyl alcohol molecules, and therefore the film has the advantages of being capable of being used for preparing the composite film. And the optimal salinity gradient power generation output power density reaches 7.33 W / m < 2 >.

The invention discloses a dispersion distribution method for a micro-nano multi-scale mixed SiC particle reinforced phase in an aluminum-based composite material and the composite material, and relates to the technical field of metal-based composite material preparation. The method comprises the following steps: firstly, carrying out ultrasonic cleaning, ultrasonication and two-stage high-temperature oxidation treatment on SiC particles, and generating an oxidation film on the surfaces of the particles; ball-milling and mixing the treated micron and nano SiC particles and micron pure magnesium particles according to a specific proportion, and pressing into a precast block; then preparing an aluminum alloy melt, cooling to a solid-liquid two-phase region, carrying out semi-solid stirring, and adding the preheated precast block; and finally, raising the temperature to be above a liquidus, rewarming, stirring and molding by casting. Through the synergistic effect of ultrasonic physical dispersion, high-temperature oxidation surface modification and magnesium-induced semi-solid stirring, the problems that micro-nano particles are prone to agglomeration, wettability is poor and interface reaction is difficult to control are effectively solved, multi-scale uniform dispersion distribution of a reinforced phase in an aluminum matrix is achieved, and the comprehensive performance of the composite material is remarkably improved.

The invention discloses a deicing material with a low-interface-toughness coating coupled with a mixed phase change material and a preparation method of the deicing material, and belongs to the technical field of anti-icing and deicing materials. The preparation method comprises the following steps: spraying a product solution obtained by grafting micron-sized hydrophilic silicon dioxide, nano-sized aluminum oxide and a silane coupling agent on the surface of a substrate, drying and curing to obtain a micro-nano porous structure bottom layer, and uniformly coating the micro-nano porous structure bottom layer with a Graphene-coated PEG400 mixed phase change material to form a phase change heating / photo-thermal layer. And finally, spraying a low-interface toughness coating prepared by reacting polydimethylsiloxane with a cross-linking agent and a polymerization increasing agent on the phase change heating / photo-thermal layer to obtain the deicing material. According to the invention, the weak binding force of the low-interface toughness coating is utilized to greatly reduce the adhesive force between the ice layer and the substrate, and the heating effect of the phase change heating / photo-thermal layer is utilized to realize low-energy-consumption intelligent deicing, so that the safety and economical efficiency of equipment are remarkably improved.

The present invention discloses a stain-resistant, long-lasting anti-slip agent and a preparation method thereof. The anti-slip agent comprises, by weight, 10-15 parts of an organic acid, 5-10 parts of a fluoride salt, 0.5-2 parts of a surfactant, 0.5-1 parts of zirconium phosphate, 5-10 parts of a silane coupling agent, 0.2-0.5 parts of a defoaming agent, and 30-60 parts of water. The surfactant is a mixture of sodium dodecylbenzenesulfonate and dodecylethoxysulfobetaine in a mass ratio of 1:2-3. The formula of the present invention is gentle and can form uniform micro-nanoscale pores on the surface of floor tiles without compromising the glossiness of the tiles. Zirconium phosphate, as a filling material, can be distributed in the micro-nanoscale pores formed by the floor tiles where the anti-slip agent is applied, forming new friction points to increase friction. At the same time, zirconium phosphate and dodecylethoxysulfobetaine can also impart certain antibacterial properties to the floor tiles, enhancing their stain resistance.

The invention discloses a preparation method of plasma activated water based on a micro-nano bubble synergistic effect, and mainly solves the technical problems that the generation efficiency of liquid-phase active particles in the plasma activated water prepared by the existing method is low, the chemical activity of the plasma activated water is difficult to maintain and the like. The preparation method comprises the following steps: introducing micro-nano bubbles into pure water until the pure water is saturated to obtain micro-nano bubble water; then performing plasma activation treatment on the micro-nano bubble water within 3 minutes to obtain plasma activated water based on the micro-nano bubble synergistic effect; the gas adopted by the micro-nano bubbles is one of air, oxygen, nitrogen or helium. The chemical activity of the plasma activated water is enhanced, the maintenance time of the activity of the activated water is greatly prolonged, efficient production and long-acting storage of the plasma activated water are facilitated, and the method has great significance in biomedical application of the plasma activated water.

The invention provides a polyurethane composite aerogel sheet material as well as a preparation method and application thereof, and belongs to the technical field of building waterproof heat insulation materials. The polyurethane composite aerogel sheet material has a structure with a dense surface and a porous interior; the polyurethane composite aerogel sheet material is prepared from the following components in parts by weight: 100 parts of polyurethane, 5 to 15 parts of flaky micro-nano particles and 10 to 20 parts of spherical micro-nano particles. The polyurethane composite aerogel sheet material is prepared by the following steps: dissolving raw materials, carrying out solvent exchange in a poor solvent, and then drying. The polyurethane composite aerogel sheet provided by the invention has good capabilities of reflecting sunlight and emitting heat radiation through synergistic cooperation of materials and structures, improves the surface hydrophobicity, can achieve the effect of'energy-consumption-free refrigeration ', does not obviously affect the waterproof effect due to slight damage of the surface, also has a self-cleaning function, and is convenient to use. The material can be used as a building waterproof heat-insulating material.