1410results about How to "Improve hydrophobicity" patented technology

A resist composition for immersion exposure, including a base component (A) that exhibits changed solubility in an alkali developing solution under action of acid, an acid generator component (B) that generates acid upon exposure, and a fluorine-containing compound (C) represented by a general formula (c-1) shown below that is decomposable in an alkali developing solution:

wherein R¹ represents an organic group which may contain a polymerizable group, with the proviso that said polymerizable group has a carbon-carbon multiple bond, and the carbon atoms forming the multiple bond are not directly bonded to the carbon atom within the —C(═O)— group in general formula (c-1); and R² represents an organic group having a fluorine atom.

The heat insulating composite aerogel material consists of silica aerogel, titania as infrared opacifier and reinforcing fiber in the weight ratio of 1 to 0.1-0.7 to 0.7-3. Its preparation process includes compounding sol with silanolate, surface modifier, titanolate, alcohol solvent, acid catalyst and alkaline catalyst in certain proportion; soaking fiber felt or prefabricated fiber part in the sol; and supercritical fluid drying. The material of the present invention has high blocking effect on solid heat transfer, air heat transfer and infrared radiation heat transfer, excellent hydrophobicity, simple preparation process, low cost, mechanical strength over 2 MPa, and wide application range, and may be used in strict heat protection condition in aeronautics, astronautics, military and civil uses.

The invention relates to a hydrophobic granule and a preparation method thereof, and a waterproof breathable structure and a forming method thereof. The hydrophobic granule comprises aggregate and a hydrophobic resin film coated on the aggregate, wherein the aggregate size is 6-300 meshes, and the hydrophobic resin film is made of one or a plurality of hydrophobic epoxy resin, bakelite, polyurethane resin and silicone resin, and coated on the aggregate. The preparation method of the hydrophobic granule comprises the following steps: heating the aggregate to 50-400 DEG C; adding the hydrophobic resin, evenly stirring so that a film is coated on the aggregate surface; and cooling, crushing and screening to obtain the hydrophobic granules. The hydrophobic granule can be widely used as a waterproof breathable layer in desert planting, lake bottom seepage-proofing, river course seepage-proofing, landscape water system bottom seepage-proofing, and has favorable waterproof and breathable properties.

A method for gelating a co-precursor relates to an aerogel. The invention provides a method for preparing transparent silica aerogel by normal pressure drying through a co-precursor method. The method has the advantages of low cost, simple process, short production cycle, controllable reaction course and continuous production. Tetraethyl silicate and absolute ethyl alcohol are put into a container according to a proportion and stirred, and added with methyl triethoxysilane; added with water and stirred; added with hydrochloric acid to regulate the pH of the solution; added with ammonia water to regulate the pH of the system after stirring; the silica sol is kept stand still after stirring to obtain wet gel; the obtained wet gel is put into a normal hexane solution or a normal hexane solution containing the methyl triethoxysilane with volume concentration of 10%-50% for solvent exchange and aging, after being exchanged by the solution containing the methyl triethoxysilane agent, the gel is washed by the normal hexane solution to remove the methyl triethoxysilane remained on the surface of the sample, and the transparent silica aerogel is obtained by drying.

The invention relates to a method for preparing hydrophobic silica aerogel with low cost. By means of the method, siloxane with alkyl serves as the raw material, wet gel is prepared through a sol-gel method, and then the silica aerogel is prepared through a normal-pressure drying method. By controlling content of water in the solution and pH value of the solution and adding urea solution with the temperature of 0 DEG C, hydrophobic silica aerogel products with prominent thermal insulation performance can be produced. The method for producing hydrophobic silica aerogel requires no additional surface modification processes, is simple in process and low in cost and can perform industrial production conveniently.

The invention relates to the technology of metal material surface modification, in particular to a production method of bionic superhydrophobic surface of an aluminum alloy base, and aims to improve hydrophobicity of the aluminum alloy surface. The production method includes: pre-processing, namely washing aluminum alloy with absolute ethyl alcohol; subjecting the surface of the aluminum alloy to laser processing to obtain a plurality of micro-scale crater structures on the surface of a sample; immersing the sample in chemical etching solution to change morphology features of the surface of the sample, keep the surface to contain chemical elements different from the base, and form micro-nano double-layer hierarchical structure on the surface of the aluminum alloy; and after reaction, placing the chemically etched aluminum alloy sample in DTS-bearing (dodecyltrichlorosilane-bearing) toluene solution for modification so that a low surface energy film gradually forms on the surface. Therefore, the surface of the aluminum alloy in the micro-nano double-layer hierarchical structure has typical biological super-hydrophobicity and has typical petal-effect adhesion.

The invention discloses novel nano calcium carbonate used for a plastic film and a preparation method thereof. A Ca(OH)2 suspension and CO2 are carbonized in a reactor to generate the nano calcium carbonate, and then the obtained nano calcium carbonate is subjected to liquid phase coating treatment or is directly subjected to mixed coating by using dried nano calcium carbonate and a surfactant to obtain nano calcium carbonate powder which is highly dispersed and surface-activated. The invention has the advantages that: the process is simple, the nano calcium carbonate is effectively dispersed in a polymer and a remarkable enhancement effect can be achieved on the premise of ensuring the transparency. The nano calcium carbonate prepared by adopting the invention can remarkably improve the mechanical property of a polyolefin material; after the nano calcium carbonate is used for polyethylene plastic, the tension strength of the material is greatly improved; and after the nano calcium carbonate is used for a polyolefin film, a fish eye is free, and the high transparency of the film is maintained.

The invention discloses a fluorine silicon-modified acrylic ester emulsion and a preparation method thereof. The fluorine silicon-modified acrylic ester emulsion is a shell-core emulsion mainly prepared from a fluorine monomer, vinyl triisopropoxysilane, nano silica sol, a vinyl monomer, a long carbon chain monomer, an emulsifier, a pH buffer, an initiator, deionized water and the like. The fluorine monomer is delayed to be dripped during polymerization, so that the fluorine element is enriched on the surfaces of emulsion particles, the hydrophobic and oleophobic properties of fluorine elusion is given full play to, the use of the fluorine monomer is reduced, and the cost is reduced. The composition of inorganic silicon oxide particles and an organic polymer keeps the good film forming property of the polymer and has the weather resistance, high hardness and other characteristics of the inorganic matter, so as to improve the stain resistance of a varnish film.

A method for rendering a microstructured surface of a substrate hydrophobic comprises a first step of applying to the microstructured surface a coating composition capable of forming a hydrophobic coating having a nanoscale roughness on the microstructured surface. The composition is then cured to form a hydrophobic coating having a nanoscale roughness on the microstructured surface. The resultant surface has both nanoscale roughness and microscale roughness.

The invention relates to waterproof moisture permeation polyurethane paint used for textiles and a preparation method. The waterproof moisture permeation polyurethane paint is prepared from methyl diphenylene diisocyanate, toluene di-isocyanate, polyether glycol (with the molecular weight of 2000), linear dihydroxylated alkylsiloxane (with the molecular weight of 1000), polyester dihydric alcohol (with the molecular weight of 2000), trimethylolpropane, chain extending agents, sealing compounds, dibutyl tin laurate and solvents through the processes of pre-polymerization reaction, chain extension reaction and sealing reaction. The production process is simple, and the products have the advantages of self-crosslinking effect, soft hand feeling, good cold resistance performance, high moisture permeation performance, high water pressure resistance and little reduction after water pressure resistance washing.

Aluminophosphate compounds and compositions as can be used for substrate or composite films and coating to provide or enhance, without limitation, planarization, anti-biofouling and/or anti-microbial properties.

The invention discloses a method for preparing a seaweed cellulose aerogel oil absorption material and relates to a method for preparing an oil absorption material. The method comprises the following steps: I, purifying seaweed cellulose; II, preparing seaweed nano cellulose microfibril in a mechanical colloid milling mode; III, preparing seaweed cellulose aerogel; and IV, performing hydrophobic modification on the seaweed cellulose aerogel. The seaweed cellulose aerogel oil absorption material prepared by using the method is natural and pollution-free and has the advantages of high oil absorption efficiency, , good strength, simple secondary treatment and the like, and is an important development direction of novel aerogel oil absorption materials.

The present application is directed to a hydrophobic membrane assembly (28) used within a gas-generating apparatus. Hydrogen is separated from the reaction solution by passing through a hydrophobic membrane assembly (28) having a hydrophobic lattice like member (36) disposed within a hydrogen output composite (32) further enhancing the ability of the hydrogen output composite's ability to separate out hydrogen gas and prolonging its useful life.

The invention discloses a method for preparing active calcium carbonate, which comprises the following steps of: adding 1 to 10 weight parts of one or a mixture of more of fatty acid and fatty acid salt and 0.05 to 5 weight parts of coupling agent into suspension containing 100 weight parts of calcium carbonate, and modifying at the temperature of between 60 and 90 DEG C for 0.5 to 5 hours to prepare the active calcium carbonate. The method has a simple preparation process and is stable in performance; and the surface of the prepared active calcium carbonate has the good hydrophobicity, is easy to disperse in rubber and resin, improves the combination property of polymers, and can be used in fields of the rubber, adhesives and the like.

The invention relates to a preparation method of antifouling flash insulator coating which is prepared by mixing fluorine-containing polysiloxane component A, linear hydroxyl-terminated polysiloxane component B, organic and inorganic silicon dioxide taken as reinforcing material component C, functional powder material component D, cross-linking agent E, catalyst component F and tackifier component G. The method prepares the single-component moisture curing antifouling flash insulator coating which is removed alcohol and oxime by adding fluorine-containing silicon material into the hydroxyl-terminated linear silicone and the reinforcing material, and has good electrical performance and aging resistance, better antifouling flash capability and excellent hydrophobicity and hydrophobicity migration performance.

The invention discloses a continuously-produced full-degradable starch-based plastic alloy and a preparation method thereof. The starch-based plastic alloy contains the following components in parts by weight: 40-90 parts of starch, 5-60 parts of poly(butylene succinate), 5-60 parts of polylactic acid, 10-40 parts of plasticizer, 0.1-10 parts of compatibilizer and 1-10 parts of processing acid. The preparation method comprises the steps of mixing starch, plasticizer and part of processing aid, and extruding to obtain thermoplastic starch particles; then, mixing the thermoplastic starch particles with poly(butylene succinate), polylactic acid, compatibilizer and the residual processing aid, and extruding to obtain the starch-based plastic alloy. The starch-based plastic alloy disclosed by the invention is favorable in hydrophobicity and strength, good in component compatibility, favorable in thermoplastic processability, capable of realizing continuous production and processing as well as simple and feasible in technical process.

The invention relates to strong-hydrophobic porous carbon nanofiber and a preparation method thereof, and belongs to the technical field of porous carbon fiber. The preparation method comprises the following steps: adding thermosetting phenol resin and high molecular weight linear polymers into organic solvent with two proportions to be mixed until the thermosetting phenol resin and the high molecular weight linear polymers are fully dissolved, performing electrostatic spinning on the solution to form phenolic resin fiber, and carrying out curing and carbonizing to obtain the hydrophobic porous carbon nanofiber. The porous carbon nanofiber and the preparation method have the advantages as follows: the diameter, the pore structure and the hydrophobicity of the fiber can be adjusted and controlled through the change of the proportions of the solvent, the prepared carbon nanofiber has good flexibility, a developed pore structure and strong hydrophobicity, and is more conductive to practical application.

The invention discloses a preparation method of graphene-coated silicon dioxide nanoparticles. Graphite powder is taken as a raw material, graphene oxide with oxygen-containing functional groups is prepared with an improved Hummers method, the silicon dioxide nanoparticles are prepared with a hydrothermal method, a proper quantity of silane coupling agents are added to a solution containing silicon dioxide and uniformly stirred, the silane coupling agents are attached to the surfaces of silicon dioxide particles, and surface-modified silicon dioxide particles are obtained; graphene oxide is added to the modified silicon dioxide solution, and surfaces of the silicon dioxide particles are completely coated with graphene oxide under the interaction of functional groups. Finally, a reducing agent is added to the solution, graphene is formed by further removing the oxygen-containing functional groups of graphene oxide, and a composite with graphene completely coating silicon dioxide is prepared. The method has the advantages that a process is simple, the reaction time is short, regulation is easy and the like. The prepared composite has the characteristics of regular structure, high porosity, low density, good hydrophobicity and the like.

The invention discloses a silicon wafer chemical and mechanical polishing composition with high stability, belonging to the technical field of polishing compositions for roughlly polishing a semiconductor silicon substrate material. The polishing composition comprises the following components in percentage by weight: 0.5-50 percent of silicon dioxide abrasive particles, 0.01-10 percent of silicon-containing stabilizer, 0.01-20 percent of organic alkali corrosive, 0.01 -10 percent of organic acid chelating agent, 0.01-5.0 percent of other functional auxiliaries and the balance of deionized water. The polishing solution has a stabilization period of over 2 years, can perform repeated polishing or cyclic polishing, and has stable pH value and removal speed, wherein the number of cyclic polishing times can be up to 10. Meanwhile, the polishing composition has high silicon wafer removal rate up to over 1.0 mum/min, and the cyclic polishing removal rate in multiple times can be stable. The polishing solution is convenient to prepare and easy to use, has low cost, and is suitable for the rough polishing of silicon wafers of various types and sizes in the semiconductor industry.

The invention provides a modification method of a ceramic membrane and a modified ceramic membrane. The modification method of the ceramic membrane comprises the following steps: performing surface treatment on the ceramic membrane to obtain a fresh ceramic membrane; coating the surface of the ceramic membrane with a silane compound through an impregnation method or a sedimentation method; performing thermal treatment on the coated ceramic membrane under a protective atmosphere, naturally cooling to obtain the modified ceramic membrane after the modification. The modification method of the ceramic membrane provided by the invention has advantages that the modification process is simple, the raw material cost is low, and secondary pollution on the environment can be avoided in the modification process; compared with the common organic modification material, the modified ceramic membrane prepared through modification has the features of high long-term stability, strong acid-base resistance, and strong hydrophobic property; and the modified ceramic membrane can be extensively applied to sea water desalinization, oil-water separation, wastewater treatment and other fields.

A water-repellent structure and a method for fabricating the same are provided. The method adopts an atmospheric pressure plasma deposition (APPD) technique to form a hardened coating having a rough surface on a substrate, and form a water-repellent coating on the rough surface. Because the water-repellent structure includes the hardened coating and the water-repellent coating, hardness, abrasion-resistance, transparency and hydrophobicity of the water-repellent structure are improved. The hard water-repellent structure protects the substrate from friction. Moreover, because the present invention adopts the APPD technique to form the water-repellent structure, the cost of production is reduced dramatically. Thus, the present invention can solve drawbacks of prior art.

The invention discloses a preparation method of a flexible high-solid-content hydroxyl waterborne polyurethane resin. The method comprises the following steps: polyester diol, hydroxyl-terminated sulfonate polyester diol, micromolecule diol, polyol and hydrophilic monomers are added in a reaction container for mixing and dehydrating; diisocyanate is slowly added at 60-65 DEG C for 1 hour, and is kept at the temperature for 1 hour; a catalyst is added for heating to 65-70 DEG C, and is kept at the temperature for reacting; when the content of isocyanate is less than or equal to 0.1 wt%, the heating is stopped; the temperature is decreased to 40-50 DEG C; acetone is used for regulating viscosity, and organic amine is used for neutralizing to 7-8; de-ionized water is added under high-speed stirring at 35-40 DEG C for dispersing 30 minutes; the acetone is removed by relieving pressure to obtain the hydroxyl waterborne polyurethane resin in milky white color accompanied with blue light. Bi-component paint prepared by using the high-solid-content hydroxyl waterborne polyurethane resin has good appearance, good soft flexibility and excellent scrape, wear and chemicals resistance.

Sanitary articles such as sanitary napkins including several layers, wherein an ink is applied on at least one of the layers. The ink application area is situated at least partially above the core and extends outwardly across at least a portion of the periphery of the core, but does not entirely cover the core. The ink is visible in the finished article. The ink provides improved resistance to re-wet of the topsheet and side leakage of the core.

The invention relates to a high oil absorption polyurethane foam which comprises the following components in parts by weight: 20 to 40 parts of isocyanate, 35 to 60 parts of polyol, 0.5 to 3 parts of catalyst, 0.5 to 3 parts of foam stabilizer, 5 to 10 parts of foaming agent, 2 to 10 parts of opening agent,5 to 20 parts of flame retardant, 5 to 15 parts of silicon rubber spherical micro powder and 0.5 to 2 parts of coupling agent. The preparation method comprises the following technology steps of weighing, prepolymerization, dispersing, polymerization foaming reaction, curing and peeling at room temperature and cutting. The high oil absorption polyurethane foam can be used for the absorption and recycle of various oil products (crude oil, engine oil, diesel fuel, gasoline, kerosene and the like) on water surfaces, ground or surfaces of other objects, and various oil soluble organic compounds (benzene, methylbenzene, dimethylbenzene, chloroform, nitrobenzene, chlorobenzene and the like). The invention has the advantages of simple technology and low cost, obviously improves the dispersing effect of the silicon rubber spherical micro powder in a polymerization system by using ultrasonic technique, and greatly increase the oil absorption quantity and oil absorption rate of the polyurethane foam by adding the silicon rubber spherical micro powder.

The invention relates to an inorganic composite heat insulation material, which is prepared from the following raw materials in part by weight: 100 parts of common silicate cement, 10 to 30 parts of quick hardening sulfate aluminum cement, 10 to 30 parts of gypsum powder, 10 to 40 parts of admixture, 20 to 40 parts of mineral fiber, 150 to 200 parts of vitrified micro bubbles, 4 to 8 parts of re-dispersible latex powder, 2 to 4 parts of cellulose ether, 0.1 to 0.3 part of starch ether, 0.2 to 1.0 part of water reducing agent, 0.2 to 0.6 part of retarder, 1 to 3 parts of early strength agent, 0.5 to 3 parts of water repellent, and 0.02 to 0.06 part of air entraining agent. The raw materials are mixed uniformly to prepare dry powder, and the dry powder and water are mixed in a weight ratio of 1: (0.8-1.2) and stirred to form slurry for use. The inorganic composite heat insulation material has good workability, quick strength development, high construction efficiency, good adhesive property, low drying shrinkage, heat insulation, hydrophobic property, fire resistance and durability.

The invention discloses a preparation method of a rock wool thermal-insulation material and a rock wool, belonging to the field of manufacturing of thermal-insulation materials. The method comprises the following steps: (1) raw material processing; (2) material fiberization: centrifugating the molten solution in the step (1) to form fibers while spraying 35-55kg of phenol aldehyde resin to every ton of fibers; (3) wool collection: collecting the fibers formed by centrifugation in the step (2); (4) superposition: converting the fibers collected in the step (3) into sheet-shaped fiber ribbons; (5) curing: curing the superposed fiber ribbons in the step (4); (6) compression: compressing the superposed fiber ribbons while curing to obtain a rock wool thermal-insulation board; and (7) cutting and packaging. The rock wool has the advantage of low content of slag balls (with the particle size of greater than 0.25mm), favorable thermal-insulation effect and better performance indexes than the prior art.

Super hydrophobic/ super oleophylic oil-water separation net has meshes 300-1500 covered thin perfluoroalkyl siloxane copolymer membrane with thickness 20~50nm, which can be metal fiber fabric of stainless steel or cupper, or fabric or terylene and nylon. Its preparation method is: 1. degrease, clean with acid and bath to the fabric net and dry; 2. for the weight share, mix the liquid with perfluoroalkyl siloxane 0.1-5%, water 1-10%, hydrochloric acid or 1N 0.1-2% and other is alcohol for 30-120 minutes, form gel-sol; 3. dip the net into gel-sol for 3-30 seconds, take out, dry naturally, repeat for 2-8 times; 4. take hot curing for the fabric net at 80-250Deg for 10-120 minutes, obtain the membrane and oil-water separation net.

The invention relates to a polyfunctional castor oil-based photo-cured resin as well as a preparation method and application thereof. The preparation method comprises the following steps: with isocyanate and hydroxyl acrylate as raw materials, adding a polymerization inhibitor and a catalyst, introducing nitrogen for protection, and reacting for a certain period of time, so as to obtain an intermediate isocyanate semi-blocked prepolymer; adding castor oil into the prepared isocyanate semi-blocked prepolymer, so as to obtain castor oil-based urethane acrylate resin; and mixing the castor oil-based urethane acrylate resin with a photoinitiator and a diluent, and carrying out ultraviolet light radiation, so as to obtain UV castor oil-based resin with excellent performance. The photo-cured resin synthesized by virtue of the preparation method has relatively high molecular weight and viscosity, so that the interaction among resin molecules is enhanced, and the photo-crosslinking reaction efficiency of the resin is improved; the photo-cured resin contains more terminal double bonds, can be rapidly photo-cured and is suitable for being used as UV cured coatings, 3D printing materials and the like; and the prepared photo-cured resin has the beneficial effects that the water absorption rate and volume shrinkage rate of a cured film are substantially increased, meanwhile, the cost is low, the process is simple and controllable, and a product is relatively environment-friendly.

The invention discloses a method for coating and modifying surface of inorganic paper making fiber calcium sulfate whisker, which comprises the following steps: 1) mixing the calcium sulfate whisker with a dispersant relative to 1-10% of mass fraction of calcium sulfate whisker, dispersing the calcium sulfate whisker; filtering and drying after treating to obtain the calcium sulfate whisker with high dispersion; 2) measuring water, ethanol, ammoniacal liquor and organosilicon source with set volume ratio, placing the water, ethanol and ammoniacal liquor in a three-mouth flask, performing magnetic stirring, adding a proper amount of surfactant, uniformly mixing for standby; 3) adding the prepared calcium sulfate whisker with high dispersion in the three-mouth flask filled with a mixed solution, uniformly mixing, slowly adding the measured organosilicon source by batches; and 4) stirring and modifying the prepared mixed solution at the temperature of below than 25 DEG C, subsiding for 8-10 hours, filtering, and drying under the temperature of 95% to prepare the modified calcium sulfate whisker.

The invention discloses a glaze and preparation of an embossment phantom glazed brick. The glaze comprises a ground glaze, a surface glaze and an embossment phantom printing glaze, wherein the ground glaze is prepared from a frit b, zirconium silicate, kaolin, calcined kaolin, potassium feldspar powder, fired talc, aluminum oxide powder, quartz powder, carboxymethyl cellulose, sodium tripolyphosphate and water; the surface glaze is prepared from a frit, the frit b, a frit c, kaolin, carboxymethyl cellulose, sodium tripolyphosphate and water; the embossment phantom printing glaze is prepared from parent glaze powder, zinc oxide, tin oxide, cerium oxide and ceramic adhesive roll-printing oil; the parent glaze powder is prepared from the frit c, kaolin, carboxymethyl cellulose, sodium tripolyphosphate and water. The preparation method comprises the following steps: sequentially applying the ground glaze and the surface glaze on a green brick, then printing the embossment phantom printing glaze, performing inkjet printing, and finally firing to obtain the embossment phantom glazed brick. The product disclosed by the invention has unique decorative effect and visual aesthetic feeling; moreover, each indicator can reach the standard requirements, so that the product has relatively strong universality, and is easily popularized in the industry.