632 results about "Triethoxysilane" patented technology

The invention relates to the technical field of special cables, and discloses a high and low temperature resistant composite insulating layer cable and a preparation method thereof.The cable comprises a conductor core and a composite insulating layer wrapping the conductor core, and the composite insulating layer comprises a high temperature resistant heat conduction core layer and a low temperature resistant elastic layer; the high-temperature-resistant heat-conducting core layer is prepared from the following raw material: polyamide acid; hexagonal boron nitride; alpha-phase silicon carbide; the preparation method comprises the following steps: adding gamma-amino propyl triethoxy silane; nano barium titanate; the low-temperature-resistant elastic layer is prepared from the following raw materials: vinyl terminated polydimethylsiloxane; performing hydrophobic treatment on fumed silica; a Karstedt catalyst; a hydrogen-containing silicone oil crosslinking agent; the average particle size D50 of the 1-ethynyl-1-cyclohexanol and the alpha-phase silicon carbide is 0.5 to 2 mu m. According to the invention, by adopting a microwave selective heating and interlayer heat conduction mechanism, efficient and high-quality integrated curing of the composite insulating layer is realized.

The invention discloses a modified nano hydrated calcium silicate chloride ion curing agent as well as a preparation method and application thereof, and belongs to the technical field of chemical materials. The curing agent is composed of 65-75 parts of synergistically modified nano calcium silicate hydrate, 10-20 parts of mesoporous silica with a high specific surface area, a composite dispersion stabilizer with a specific ratio, and an active activator compounded by triethanolamine and anhydrous sodium sulfate. The nano calcium silicate hydrate is synergistically modified by gamma-aminopropyltriethoxysilane and sodium dodecyl benzene sulfonate, so that the nano calcium silicate hydrate has the excellent performance that the zeta-potential absolute value is greater than or equal to 25 mV, the dispersity is high, and the chloride ion binding capacity is improved by greater than or equal to 40%. Through the synergistic effect of all the components, the technical problems that an existing chloride ion curing agent is low in adsorption capacity, poor in selectivity, prone to agglomeration in concrete and the like are solved, and the chloride ion curing agent is particularly suitable for improving the durability of the concrete in harsh chloride salt environments such as port engineering and maritime work structures.

The invention relates to aerogel with high heat insulation performance and a preparation method thereof, and belongs to the technical field of aerogel materials. The aerogel is prepared from a silicon source, nano heat insulation particles, a surface modifier, a catalyst and a solvent. The nano heat insulation particles are a compound of zirconium dioxide and hollow glass beads, and the surface modifier is a mixture of trimethylchlorosilane and gamma-aminopropyltriethoxysilane. The preparation method comprises the steps of sol preparation, modification treatment, gelation, aging and supercritical drying. Through compounding and synergistic effects of specific components, the mesoporous network structure of the aerogel is remarkably optimized, so that the aerogel has ultralow normal-temperature thermal conductivity, relatively high compression strength and excellent thermal stability, and the problem that heat insulation performance and mechanical strength of traditional aerogel are difficult to consider at the same time is solved; the method is suitable for the fields of building insulation, industrial pipelines and aerospace.

The invention relates to the technical field of ink, in particular to modified filler environment-friendly ink and a preparation method thereof. The modified filler environment-friendly printing ink is prepared from the following raw materials in parts by mass: 20 to 40 parts of waterborne acrylic emulsion, 10 to 20 parts of polyurethane acrylate prepolymer, 1 to 5 parts of bis (trimethylolpropane) tetraacrylate, 10 to 20 parts of pentaerythritol tetraacrylate, 5 to 10 parts of mica powder, 1 to 2 parts of 3-aminopropyltriethoxysilane, 0.1 to 1 part of epoxy chloropropane and 5 to 10 parts of amino-terminated polyamidoamine. The coating is prepared from the following components in parts by weight: 1-2 parts of a photoinitiator, 1-3 parts of a dispersing agent, 1-2 parts of a reactive diluent, 1-2 parts of an organic silicon defoaming agent, 0.5-1.5 parts of a mildew preventive, 0.1-1 part of a thixotropic agent, 5-15 parts of pigment, 1-5 parts of kaolin, 5-10 parts of polyethylene wax and 1-5 parts of water. The obtained ink is good in dispersion stability, good in flexibility after being cured and excellent in adhesive force.

The invention provides a novel silane coupling agent and a preparation method thereof, and belongs to the technical field of silane coupling agents, and the preparation method comprises the following steps: taking chloropropyltriethoxysilane and 2, 2-(1, 2-ethanedioxy) diethyl mercaptan as raw materials, adding a catalyst and an acid-binding agent, mixing, and heating for reaction to obtain the novel silane coupling agent. The invention provides a novel silane coupling agent and a preparation method thereof. The purposes of facilitating industrial production and obtaining high-purity and high-yield products are achieved.

The invention relates to the field of pipes, and discloses a high-flame-retardance MPP cable protection pipe and a preparation method thereof.The cable protection pipe comprises polypropylene resin, modified graphene oxide, modified maleic anhydride grafted polypropylene and auxiliaries; the modified graphene oxide is prepared by grafting a modified benzotriazole intermediate and a double-bond DOPO derivative substituted cyclotriphosphazene derivative into graphene oxide; the modified benzotriazole intermediate is prepared by grafting 2-(2, 4-dihydroxyphenyl)-2H-benzotriazole and ethyl bromoacetate, and then reacting with 2, 2, 6, 6-tetramethyl-4-piperidinol; the double-bond DOPO derivative is prepared through the reaction of DOPO-HQ and 4-vinyl benzyl chloride; the modified maleic anhydride grafted polypropylene is prepared by grafting octa-aminopropyl polyhedral oligomeric silsesquioxane prepared by a polycondensation reaction of 3-aminopropyltriethoxysilane and maleic anhydride grafted polypropylene. The pipe prepared by the invention has good mechanical properties, ultraviolet aging resistance, low-temperature toughness, heat resistance, flame retardance and wear resistance.

The invention discloses a molecular sieve catalyst for synthesizing methyl ethyl carbonate by a transesterification method and a regeneration method, and relates to the technical field of molecular sieve catalysts, the molecular sieve catalyst comprises a microporous double-active-center inner core and an amphoteric mesoporous shell; the microporous double-active-center core takes the X-type zeolite as a carrier to load potassium, cesium, lanthanum and barium; the amphoteric mesoporous shell is an MCM-41 and SBA-15 composite mesoporous silica layer coating the outer part of the inner core and has a double-mesoporous structure, amino propyl triethoxy silane and carboxyethyl triethoxy silane are grafted on the surface of the amphoteric mesoporous shell, and zirconium and titanium are co-doped. According to the invention, collaborative optimization of active centers and mass transfer channels is realized through a core-shell structure of a microporous double-active-center core and an amphoteric mesoporous shell. The activity and selectivity of catalytic transesterification are remarkably improved by the microporous core; due to the double-mesoporous structure and surface functional modification of the amphoteric mesoporous shell, the mass transfer efficiency of reactants and products is improved, and the adaptability of the catalyst to a reaction system is enhanced.

The invention relates to the technical field of cables, and provides a fireproof flame-retardant cable and a preparation method thereof. The fireproof flame-retardant cable comprises a conductor, an insulating layer and a sheath layer which are sequentially arranged from inside to outside, and the sheath layer is prepared from, by weight, 40-50 parts of high-density polyethylene, 30-40 parts of ethylene-vinyl acetate copolymer, 30-40 parts of flame retardant, 15-20 parts of filler, 8-10 parts of plasticizer, 2-4 parts of lubricant, 2-4 parts of antioxidant, 2-3 parts of stabilizer and 2-3 parts of cross-linking agent; the flame retardant is prepared from the following component raw materials in parts by weight: 30 to 40 parts of magnesium hydroxide, 10 to 15 parts of aluminum hydroxide, 4 to 5 parts of zinc borate, 3 to 4 parts of diethyl phosphoryl ethyl triethoxy silane and 1 to 1.5 parts of 2-(2-pyridyl) ethyl trimethoxy silane. According to the technical scheme, the problem of insufficient fireproof and flame-retardant performance of the cable in the prior art is solved.

The invention relates to the technical field of high polymer materials, and particularly discloses a flame-retardant heat-conducting silica gel insulating coating and a preparation method thereof. The invention discloses a flame-retardant heat-conducting silica gel insulating coating. Comprising the following components: polydimethylsiloxane, aluminum hydroxide, modified nano aluminum oxide, a phosphorus-nitrogen flame retardant, silicon dioxide, methyltris (methylethylketoxime) silane, vinyltris (methylethylketoxime) silane, dibutyltin dilaurate, a diluent, amino propyl triethoxy silane, propyl trimethoxy silane and ethyl aminopropyl trimethoxy silane. And the polydimethylsiloxane is formed by compounding polydimethylsiloxane with the viscosity of 1,500 cp and polydimethylsiloxane with the viscosity of 20,000 cp. According to the invention, by finely blending the proportion of various functional components, especially the optimal combination of polydimethylsiloxane, modified nano aluminum oxide, the flame retardant and the filler, the flame retardance and thermal conductivity of the coating are effectively improved, and meanwhile, good insulativity and mechanical properties are ensured.

The invention relates to a calcium-based desulfurizer and a preparation method and application thereof, and relates to the technical field of desulfurizers, the calcium-based desulfurizer comprises a calcium-based carrier with a micropore-mesopore-macropore three-level pore structure, and a gamma-aminopropyltriethoxysilane modifier dispersed in pore channels, the molecular imprinting layer is modified by an inactive region on the inner wall of the mesoporous; the preparation method comprises the steps of calcium-based carrier pretreatment, composite pore forming, pre-roasting, hydroxyl strengthening and the like. The efficient mass transfer system is constructed through a three-stage pore structure, the modifier and the molecular imprinting layer synergistically improve the structural stability and the sulfur dioxide adsorption selectivity, the calcium base utilization rate and the desulfurization efficiency are improved, and the industrial flue gas desulfurization requirement is met.

The invention discloses a water treatment filtering material and a preparation method thereof, and relates to the technical field of water treatment. When the water treatment filtering material is prepared, alkaline lignin, epichlorohydrin and triethylenetetramine are subjected to a reaction through a reverse suspension cross-linking technology, and lignin porous microspheres are prepared; carrying out reaction on the lignin porous microspheres and picolinamide ligands to obtain modified lignin porous microspheres; 3-mercaptopropyltriethoxysilane and titanium dioxide are subjected to a reaction, and modified titanium dioxide is prepared; the preparation method comprises the following steps: reacting pyromellitic dianhydride, 1, 4-diaminobutylene and 4 ', 4-diaminodiphenyl ether to prepare functionalized polyamide; the functional polyamide, the modified lignin porous microspheres and the modified titanium dioxide are prepared into a spinning solution, and a polyamide membrane is prepared through electrostatic spinning; and carrying out liquid reaction on bromohexane on the polyamide membrane to obtain the water treatment filtering material. The prepared water treatment filtering material has excellent antibacterial property, heavy metal adsorption property, dye removal property and mechanical property.

The invention relates to the field of pipes, and discloses a high-strength CPVC pipe and a preparation method thereof.The pipe comprises CPVC resin, modified multi-walled carbon nanotubes, modified nano silicon dioxide and auxiliaries; the modified multi-walled carbon nanotubes are prepared by grafting phosphorus-containing cardanol derivative based benzoxazine and oxidized multi-walled carbon nanotubes; phosphorus-containing cardanol derivative benzoxazine reacts with 1, 5-naphthylenediamine to prepare an aldehyde cardanol intermediate, the aldehyde cardanol intermediate is prepared by reacting paraformaldehyde with hydrogenated cardanol, the obtained cardanol derivative and DOPO are subjected to addition, and then the obtained phosphorus-containing cardanol derivative reacts with paraformaldehyde and 3-aminopropyltriethoxysilane to prepare the flame retardant. The modified nano silicon dioxide is prepared by introducing polyethylene glycol into the surface of isocyanated nano silicon dioxide and grafting with 3, 5-bis (tert-butyl)-4-hydroxybenzene propionyl chloride, and the pipe prepared by the invention is high in tensile strength and impact strength and has good long-acting oxidation resistance, high temperature resistance and flame retardance.

The invention relates to the technical field of brass materials, in particular to a high-strength and high-toughness brass material and a preparation method thereof.The preparation method comprises the steps that a porous oxide film layer is prefabricated on the surface of brass through plasma electrolytic oxidation, and an oxide film layer doped with double-bond silver-loaded graphene oxide is constructed on the surface of the brass; the preparation method comprises the following steps: firstly, preparing modified MXene, then preparing a photocurable hole sealing coating for hole sealing treatment, introducing double-bond silver-loaded graphene oxide and the modified MXene as fillers into the photocurable hole sealing coating, firstly performing sulfhydrylation on the MXene by using 3-mercaptopropyltriethoxysilane, and then grafting a double-bond-containing bis-benzimidazole ring derivative through light click to obtain the modified MXene; vinyl-terminated polyurethane is used as a cross-linking agent, o-phenyl phenoxyethyl acrylate, butyl acrylate, glycidyl methacrylate and octadecyl acrylate are compounded to serve as an acrylic monomer, a diluent and a solvent are introduced, a complex cross-linked network is constructed, and the service life of the brass material is prolonged.

The invention discloses a low-dielectric insulation fixing adhesive and a preparation method thereof, and belongs to the technical field of fixing adhesives. The raw materials comprise, by weight, 25-40 parts of an epoxy resin matrix, 5-10 parts of a modified silane coupling agent, 15-30 parts of a low dielectric filler, 8-15 parts of a curing agent, 3-8 parts of a toughening agent, 2-5 parts of a diluent, and 0.5-2 parts of an antioxidant; the low dielectric filler is a composite filler of hollow glass beads and boron nitride, the mass ratio of the hollow glass beads to the boron nitride is (2-3): 1, and the modified silane coupling agent is a gamma-aminopropyltriethoxysilane grafted maleic anhydride modified product; according to the invention, the dielectric constant and the dielectric loss of the adhesive can be reduced, and the insulating property, the bonding strength and the compatibility with a base material can be improved at the same time.

This invention discloses an MPP pipe for power cables and its preparation method, relating to the field of polymer materials technology. The invention comprises, by weight, 80-90 parts of a toughening nucleating agent; 40-45 parts of an insulating nucleating agent obtained by in-situ composite and gradient temperature imidization treatment of a polyamic acid prepolymer prepared from hexagonal boron nitride nanosheets (prepared by surface modification with dopamine hydrochloride, followed by modification with octyltriethoxysilane) to obtain a silanized boron nitride suspension; 40-45 parts of melamine cyanurate; 2.1-2.4 parts of an antioxidant; 2.6-3 parts of a light stabilizer; 8-9 parts of a lubricant; and 1340-1500 parts of polypropylene. The introduction of the toughening nucleating agent and insulating nucleating agent in this invention effectively improves the flame retardancy, low-temperature rigidity-toughness balance, and aging resistance of the MPP pipe.

This invention discloses a Janus particle crosslinking agent, a two-step preparation method, and its applications, belonging to the field of functional coating technology. The Janus particle crosslinking agent comprises SiO2 particles, one end of which is modified with a hydrophilic isocyanate group, and the other end with a low surface energy material, hydrogen-containing silicone oil. The Janus particle crosslinking agent with the hydrogen-containing silicone oil as the hydrophobic side can achieve directional arrangement, thereby imparting excellent hydrophobic properties to the coating. Utilizing the isocyanate group of the Janus particle crosslinking agent, it can not only exert its crosslinking effect in the coating but also stabilize the toluene / water Pickering emulsion. The two-step preparation method involves using hydrogen-containing silicone oil as a modifier to prepare J(SiO2·PMHS) particles via the Pickering emulsion interface method; then, using isocyanate propyltriethoxysilane as a modifier, a one-pot method is used to prepare the Janus particle crosslinking agent with the isocyanate group as the hydrophilic end and the hydrogen-containing silicone oil as the hydrophobic end. The isocyanate groups in the crosslinking agent are directly modified on one side of the Janus particles, thereby enabling them to play their crosslinking role in the coating and improving the wear resistance of the coating.

The application discloses an electronic skin-oriented conductive silver paste and a preparation method and application thereof, and relates to the technical field of flexible printed electronic materials.The raw materials of the electronic skin-oriented conductive silver paste include flaky silver powder, silver nanoparticles, thermoplastic polyurethane elastomer, acrylic elastomer, PEDOT:PSS microgel dispersion, (3-glycidylpropoxy)trimethoxysilane, polydiallyldimethylammonium chloride, hexanedial modified dopamine copolymer, (3-aminopropyl)triethoxysilane, methacryloyloxypropyltrimethoxysilane, cellulose acetate, modified polyurea thixotropic agent, hydrogenated castor oil, ethylene glycol ether acetate, dibasic acid ester, leveling agent and water.The electronic skin-oriented conductive silver paste has the advantages of good electrical performance, good mechanical-electrical stability, good anti-electromigration and sweat corrosion resistance, and can still maintain dendrite-free and low drift under long-term coupling of sweat and bias, and is suitable for electronic skin.

The invention relates to the technical field of non-ferrous metal beneficiation, in particular to a flotation reagent composition for recycling micro-fine particle copper sulfide from copper oxide acid leaching residues and a beneficiation method of the flotation reagent composition. The flotation reagent composition for recovering copper sulfide from copper oxide acid leaching residues is characterized by comprising a collecting agent, a hydrophobic agglomeration agent and a foaming agent, and the collecting agent is ethyl thioacetate; the hydrophobic agglomeration agent is prepared from octadecyl triethoxy silane and kerosene; and the foaming agent is selected from terpilenol, methyl isobutyl carbinol or sec-octanol. The ethyl thioacetate serving as a collecting agent is stable in chemical property in an acid environment, weak in gangue mineral collecting capacity and good in selectivity in the copper sulfide mineral flotation process, and therefore the grade and the recovery rate of obtained copper sulfide concentrate are higher.

This invention relates to the field of functional textile materials technology, and discloses a fluorine-free waterproof fabric and its preparation process. The fluorine-free waterproof fabric is composed of a host-guest inclusion crosslinking type organosilicon synergistic film-forming agent, an organic small molecule film-forming component, a crosslinking promoter, a dispersant stabilizer, a softening agent, and a solvent. The host-guest inclusion crosslinking type organosilicon synergistic film-forming agent is prepared by forming a host-guest inclusion structure with β-cyclodextrin and adamantane carboxylic acid, followed by reactive modification with 3-isocyanate propyltriethoxysilane. The organic small molecule film-forming component is norbornene-2-carboxylic acid. Through host-guest inclusion, crosslinking, and organic small molecule synergistic film formation, a stable and dense fluorine-free waterproof functional layer is formed on the fabric surface. This invention significantly improves waterproof performance and its washability and abrasion resistance without using fluorine-containing compounds, while also maintaining the soft hand feel of the fabric, demonstrating good environmental friendliness and application prospects.

The invention provides a preparation method of a high-wear-resistance alloy lining plate, and relates to the technical field of wear-resistance alloys, carbon steel and pig iron are mixed, heated and melted, high-carbon ferromanganese, medium-carbon ferrochrome and ferrosilicon are added, heating refining is carried out, aluminum powder is added, the mixture is put into a mold, cooling and demolding are carried out, heating homogenization, quenching and cooling are carried out, and a mother plate is prepared; mixing bismaleimide, the composite powder and sepiolite fibers, heating and stirring, coating a mother board with the mixture, firstly applying negative pressure, then applying positive pressure, heating and cooling to obtain a substrate layer; and placing the mother board in magnetron sputtering equipment, sputtering on the substrate layer to obtain a chromium nitride functional layer, and cooling to obtain the high-wear-resistance alloy lining board. The composite powder is prepared by mixing and heating chromium carbide powder and a hydrogen peroxide solution, filtering, mixing with an ethanol solution and gamma-aminopropyltriethoxysilane, heating, condensing and refluxing, washing and drying, and mixing and heating with amine-terminated polyether and N, N-dimethylformamide. The wear-resistant stability of the alloy lining plate can be improved.

This invention relates to the field of casting technology for sand cores and sand shells, and particularly to a method for preparing high-precision casting sand cores and sand shell components based on a coated sand process. The method includes the following steps: rinsing quartz sand and reacting it with a sodium silicate solution to obtain coated quartz sand; adding 3-aminopropyltriethoxysilane and water to the coated quartz sand in a high-speed mixer; sequentially adding modified benzoxazine resin, calcium citrate, magnesium chloride, hyperbranched polyamide, and polycaprolactone-grafted starch to obtain finished coated sand; plasma-treated chromium-12 molybdenum-vanadium mold steel to obtain an amino-modified mold; sand-jetting the finished coated sand into left / right half-shells; shaping and pre-embedding chromite sand cores with chills to obtain left / right half-shell green blanks; milling the surfaces of the left / right half-shell green blanks, coating them with resin, butt-jointing, curing, and deburring to obtain the casting sand core and sand shell. This method solves the problems of poor mechanical strength, poor high-temperature stability, low production efficiency, and poor environmental performance in high-precision casting sand cores and sand shells.

The invention relates to the technical field of battery diaphragms, in particular to a wood fiber composite diaphragm and a preparation method thereof. According to the diaphragm, renewable softwood pulp is used as a basic raw material, after aldehyde groups are introduced through sodium periodate oxidation, tannic acid, zinc acetate and cystamine are utilized to synergistically construct a zinc coordination network functional layer; then, molecular crosslinking with methoxypolyethylene glycol, polyethylene glycol, hexamethylene diisocyanate, gamma-aminopropyltriethoxysilane and nano silicon dioxide is realized under the action of a catalyst; and finally, the paper-making and hot-pressing processes are performed to prepare and mold. The diaphragm is particularly suitable for being applied to high-safety and high-performance aqueous metal zinc batteries, and an innovative technical path is provided for industrialization and green upgrading of zinc ion battery diaphragm materials.

The invention discloses a liquid-liquid coalescence filter element material for oil dehydration, which takes glass fiber paper as a substrate and is coated with the following modified materials in percentage by mass: 1 to 5 percent of nano silicon dioxide, 2 to 10 percent of gamma-aminopropyltriethoxysilane, 2 to 10 percent of octadecyltriethoxysilane and the balance of absolute ethyl alcohol. The water contact angle of the liquid-liquid coalescence filter element material is larger than 150 degrees, and the oil contact angle is smaller than 10 degrees; the invention also discloses a preparation method which comprises the following steps: uniformly mixing the raw materials to form a modified solution, spraying the modified solution on the surface of the cured glass fiber paper, and drying to obtain the liquid-liquid coalescence filter element material. According to the invention, the nano silicon dioxide is modified by gamma-aminopropyltriethoxysilane and octadecyltriethoxysilane, so that the super-hydrophobicity and super-lipophilicity of the glass fiber paper are improved; the prepared liquid-liquid coalescence filter element material is uniform and firm in coating adhesion and suitable for the fields of oil product production, storage, transportation and the like.

The invention discloses a preparation method and application of a super-hydrophobic antifouling coating with a self-repairing function, and belongs to the technical field of modification of self-repairing super-hydrophobic coatings of textiles. The method comprises the following steps: mixing boric acid, ethanol and n-octadecyltriethoxysilane, heating and stirring to completely dissolve the boric acid to obtain a mixed solution; and dropwise adding water into the mixed solution while heating and stirring, and then standing and reacting to form a B-O-Si covalent bond, thereby obtaining the super-hydrophobic antifouling coating material. After the fabric is subjected to immersion treatment by the super-hydrophobic antifouling coating material, a good dynamic hydrophobic effect is shown, the original air permeability and moisture permeability of the fabric are hardly influenced, and compared with the original fabric, the air permeability is reduced by 1.9-6.6%, and the moisture permeability is reduced by 3.2-4.8%; after the super-hydrophobic antifouling coating fabric is worn and damaged by washing, the super-hydrophobic performance can be recovered under the condition of standing for 180 minutes or heating at 110 DEG C for 30 minutes.

The application provides a preparation method of a hydrophobic photocatalyst H-g-C3N4 and belongs to the technical field of new materials and photocatalytic wastewater treatment. ‑1 The method comprises the following steps: base material preparation: under an inert or air atmosphere, melamine is heated at a rate of 3-8°C·min ‑1 to 520-580°C and kept for 2-5 h, and after cooling, g-C3N4 powder is obtained by grinding; surface hydrophobic modification: g-C3N4 is dispersed in an inert organic solvent containing 3-aminopropyl triethoxysilane and a fluorine-containing olefin monomer to obtain a dispersion liquid; in the presence of a free radical initiator, amine-olefin Michael addition reaction is carried out, and after filtration, washing and drying, the hydrophobic photocatalyst H-g-C3N4 covalently grafted with organosilane-fluorine-containing olefin is obtained. The method has the advantages of simple preparation, low cost of raw materials and mild conditions, and the obtained material has high hydrophobicity, high stain resistance and high activity, and has a wide application prospect in photocatalytic treatment of wastewater containing antibiotic refractory organic matter, and in particular, has high efficiency and interference resistance in degradation of SMX under visible light.

The invention discloses a SiO2 layer coated Li (Ni < x > Co < 1-2x > Mn < x >) O < 2 > positive electrode material as well as a preparation method and application thereof, and belongs to the technical field of lithium ion battery positive electrode materials. The positive electrode material comprises a matrix Li (Ni < x > Co < 1-2x > Mn < x >) O < 2 > and a coating layer located on the surface of the matrix, 0 < x < 0.5, and the coating layer is a SiO2 layer. According to the invention, hydrolysis of 3-aminopropyltriethoxysilane (APTES) and tetraethyl orthosilicate (TEOS) is utilized, and the surface of the Li (Ni < 1 / 3 > Co < 1 / 3 > Mn < 1 / 3 >) O < 2 > nano material is covered with a SiO2 layer. The reversible capacity, the rate capability and the cycling stability of the Li (NixCo1-2xMnx) O2 positive electrode material are remarkably improved through SiO2 coating, the preparation process is simple, the raw materials are non-toxic and safe, the yield is high, and the method is suitable for industrial large-scale production and has a wide application prospect in the field of lithium ion batteries.

The invention discloses a preparation method of cellulose-based degradable hydrophobic seedling-raising mulching film paper and application of the cellulose-based degradable hydrophobic seedling-raising mulching film paper in agricultural product planting, the produced mulching film paper has the characteristics of high hydrophobicity, soil moisture conservation, heat preservation, high strength and the like, and the cellulose-based degradable hydrophobic seedling-raising mulching film paper belongs to the field of green agricultural materials. According to the technical scheme, cellulose paper serves as a substrate and is coated with cationic etherified starch and 3-aminopropyltriethoxysilane through a coating cross-linking process, and a sandwich structure is formed through glyoxal-mediated electrostatic-hydrogen bond-covalent bond triple cross-linking, so that the membrane is more compact. The method has the advantages of low energy consumption, simple process flow, easiness in batch and large-area production, good product batch repeatability, effective reduction of the water molecule permeability, enhancement of the water resistance, strength, toughness and the like of the mulching film paper, no inhibition of normal germination of seeds, and hopeful wide application in the field of agricultural mulching films.

The invention discloses a preparation process of graphene oxide liquid phase coated nano silicon. The preparation process comprises the following steps: S1, preparing modified nano silicon; s2, preparing a graphene oxide dispersion liquid; step S3: construction of a pre-coating system; s4, carrying out dynamic liquid phase coating reaction; step S5, post-treatment and purification; nano silicon is modified before coating, amino active groups are introduced to the surface of the nano silicon through gamma-aminopropyltriethoxysilane and can interact with carboxyl and hydroxyl on the surface of graphene oxide, the interfacial compatibility of the nano silicon and the graphene oxide is remarkably improved, and the binding force between a coating layer and the nano silicon is enhanced; the falling of the coating layer in the charging and discharging process is effectively inhibited; according to the preparation method, the graphene oxide is prepared by adopting an improved Hummers method, the dispersing agent is added, a stirring-ultrasonic dispersion process is combined, and meanwhile, the temperature in the ultrasonic process is controlled, so that the dispersity of the graphene oxide is effectively improved, agglomeration of the graphene oxide is avoided, and a foundation is laid for subsequent uniform coating.

The application discloses a modified hard carbon material and a preparation method and a battery thereof, and relates to the technical field of battery negative materials. The hard carbon layer is formed by using grafted silica as a template, then the soft carbon layer is coated outside the hard carbon layer, and then the silica is coated outside the soft carbon layer to limit carbonization and remove the template to obtain the target material; wherein the grafted silica contains a heteroatom S, and the hard carbon layer contains a heteroatom P; in the preparation, the silica template grafted with 3-mercaptopropyl triethoxysilane is prepared by a reverse micelle method, the phenol formaldehyde resin precursor is coated to form the hard carbon layer, P is introduced by modification of the trisglycidyl phosphate, and then the pitch-based soft carbon layer is carbonized, and then the silica is removed to obtain the target material. The material increases the active sites and the interlayer spacing by accurate doping of S and P, cooperatively relieves the volume expansion by the hard and soft carbons, and strengthens the ion adsorption by the oxygen groups, and exhibits high capacity and excellent cycle stability in the secondary batteries such as potassium ion batteries, and is suitable for the field of new energy storage batteries.

This invention discloses a method for preparing high-purity Si-75, comprising: S1, adding sodium sulfide, sulfur, and deionized water in a molar ratio of 1:(1.0~1.1):(5~8) to a reaction vessel, adding a buffer, and reacting at 80~90℃ for 1~2h; S2, adding a phase transfer catalyst and a hydrolysis inhibitor to the system, adding γ-chloropropyltriethoxysilane dropwise, and reacting at 85~95℃ for 3~5h, allowing the mixture to stand and separate into layers after the reaction, to obtain an organic phase; S3, subjecting the organic phase to short-path distillation and then filtering to obtain high-purity Si-75. Compared with existing technologies, this invention uses a phosphorus-free buffer system, which simplifies waste treatment. It uses water as the reaction medium and does not use large amounts of organic solvents, making it suitable for continuous industrial production. By adding hydrolysis inhibitors, hydrolysis can be effectively prevented during the reaction, increasing safety. The short-path distillation method provides high purification efficiency and can quickly remove impurities. The product has a disulfide content of ≥98.5% and a color of 0 (Gardner color number), which is of great significance to the light-colored rubber industry.