733 results about "Zirconate" patented technology

A boron nitride composition having its surface treated with a coating layer comprising a zirconate coupling agent. The boron nitride composition can be used as fillers in polymeric compounds at levels of up to 90 wt. %, giving thermal conductivity of up to 35 W/mK.

The present invention relates to a chrome-free passivating liquid for treating aluminum alloy and a method for using the same; the components of the passivating liquid and the weight concentration of the elements thereof consist of fluorin titanate comprising Ti (IV) between 0.05 wt percent and 0.15 wt percent, fluorin zirconate comprising Zr (IV) 0.01 wt percent and 0.05 wt percent and organic phosphate compound comprising 0.02 wt percent to saturated concentration. The use method of the passivating liquid of the invention has the following procedures: after grease on the surface of the aluminum alloy is removed, the aluminum alloy is treated by alkali cleaning, deoxidation and activation; when the temperature is between 25 DEG C and 60 DEG C and the PH value is between 3 and 3.5, the aluminum alloy is treated by impregnating or spraying for 2 min to 5 min. In the passivating liquid of the invention, organic phosphoric acid is directly added to a titanium zirconium system; the formed zirconium phosphate composite structure can obviously improve the corrosion resisting property of a passivating film and the adhesive capactiy of polymer coating (primer) on the surface of aluminum alloy.

The invention is a composition comprising a) one or more organotitanates or zirconates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure with the proviso that one of the ligands has an acidic moiety; one or more strong organic acids or a mixture thereof; b) one or more alkoxysilanes; c) optionally one or more high molecular weight resins; and d) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. Preferably, the composition comprises both an organotitanate or zirconate and a strong acid.

The present invention concerns a new ferromagnetic powder composition comprising soft magnetic iron-based core particles wherein the surface of the core particles are surrounded by an insulating inorganic coating, and a lubricating amount of a compound selected from the group consisting of silanes, titanates, aluminates, zirconates, or mixtures thereof. The invention also concerns a process for the preparation of soft magnetic composite materials using the new powder composition.

Metal oxide nanoparticles having at least some surface acid sites functionalized with an adhesion promoter and at least some surface acid sites functionalized with a coupling agent. The nanoparticles are useful in forming composites comprising photopolymerizable matrix monomers, and are primarily suitable for dental and medical restoration. In a preferred embodiment, the metal oxide comprises zirconium, and the coupling agent is a zirconate.

The present invention discloses a method for producing a silane modified polyurethane sealant by using secondary amino alpha-silane, which belongs to the technical field of production of silane modified polyurethane sealants. The method comprises the following steps: removing water from polyether polyol, preparing polyurethane prepolymer, synthesizing silane-terminated polyurethane prepolymer and preparing the modified polyurethane sealant, wherein in the step of synthesizing the silane-terminated polyurethane prepolymer, the used silane for termination is formed by mixing one or two kinds of compounds selected from a group of secondary amino alpha-silane such as anilino-methyl-triethoxy silane, amine formic acid methyl trimethoxy silane or amine formic acid methyl methyl dimethoxy silane; in the step of preparing the modified polyurethane sealant, a catalyst used in the step is formed by mixing one or two kinds of compounds selected from a group of metal zirconate titanate compounds such as tetra-tert-butyl orthotitanate, tetraisopropyl titanate, tetrabutyl titanate and zirconium n-butoxide. The termination process of the prepolymer is simple, and the silane modified polyurethane sealant produced by the method has fast curing speed.

The invention relates to niobium sodium potassium antimonate-potassium sodium bismuth zirconate leadless piezoelectric ceramic with a high piezoelectric constant and a preparation method thereof, which belong to the field of environmental coordinative piezoelectric ceramic of perovskite structures. The leadless piezoelectric ceramic with a general formula of (1-x) (K1-yNay) (Nb1-zSbz) O3 + xBi0.5 (Na1-uKu) 0.5ZrO3 is prepared by a traditional solid state sintering method, wherein in the formula, x is not smaller than 0 while not larger than 0.05, y is not smaller than 0.40 while not larger than 0.68, z is not smaller than 0.02 while not larger than 0.06, and u is not smaller than 0 while not larger than 1; the d33 of the leadless piezoelectric ceramic disclosed by the invention can be as high as 470 pC/N, kp can reach 47%, and Tc is as high as 313 DEG C. Devices prepared by the ceramic can work under high temperatures, so that the ceramic has a practical application value in high-temperature electronic equipment; since the ceramic contains no expensive tantalum element, the price of the used raw materials is low, so that the cost is saved.

A bond is created between a gypsum matrix and titanium or zirconium based coupling coating applied onto a glass fiber during gypsum board cure. The commercially available titanium or zirconium based coupling has a generic formula of the type [RO-}-nTi—[—OXR′Y]4-n or [RO-}-nZr—[—OXR′Y]4-n. These coupling compositions chemically bond to glass fibers by replacing the —OH groups present on the glass fibers in aqueous solutions with Ti—O or Zr—O bonds. In order to bond with calcium ions in hydrated gypsum crystals, the X functionality is selected to be a phosphate or pyrophosphato group. The bond between the glass fiber and the titanium or zirconium based coupling composition is due to the formation of a monolayer, while the bond between the hydrated gypsum crystal and the coupling composition is intermittent due the acicular structure of gypsum crystals. The titanium or zirconium based coupling composition coating on glass fibers bonded to the gypsum matrix results in load transfer between the gypsum matrix and the glass fibers, resulting in improved flexure strength and nail pullout resistance. The Titanate/Zirconate can also be used as a board mechanical properties enhancing agent without addition of glass fiber.

A RE zirconate coating material for preparing high-temp heat barrier layer has a chemical formula: A2B2O7, where A is chosen from La, Nd, Sm, Gd, Dy, Er and Yb and B is Zr. It is prepared through ball grinding of raw materials, baking, die pressing, and reaction in air at 1550-1650 deg.C. It has low heat conductivity and high high-temp stability.

Disclosed are a nano-rare earth zirconate ceramic powder material for high-temperature thermal barrier coatings, and the preparation method, relating to a nano-rare earth zirconate ceramic powder material for high-temperature thermal barrier coatings, and the preparation method. The invention solves the problems that the existing ceramic materials for high-temperature thermal barrier coatings are of phase change failure, serious sintering, and too high thermal conductivity and mismatch with the matrix thermal expansion. The chemical formula of the nano-rare earth zirconate ceramic powder material for high-temperature thermal barrier coatings is Ln2Zr2O7, wherein, Ln is the combination of one or more rare earth elements among Gd, Sm, Nd or Yb. The preparation method is that rare earth oxide or soluble salt and zirconium salt containing rare earth oxides are used to respectively prepare the solution containing Ln3 + and the solution containing Zr4 +; the two solutions are mixed and added with surfactant under the ongoing mixing conditions; the mixed solution is dropped into precipitator to get sediment; after repeated washing, the sediment is dried, grinded and calcined. The invention can effectively protect high temperature alloy.

The invention relates to an anti-CMAS-corrosion ultrahigh-temperature-resistant long-service-life thermal barrier coating and a preparation method thereof. The thermal barrier coating is sequentially provided with a binding layer, a first ceramic layer and a second ceramic layer on a matrix from bottom to top, the binding layer is made of an MCrAlX alloy, M refers to Ni, or Co or a composition of Ni and Co, X refers to one of or a composition of two of Y, Hf, Si and Pt, the first ceramic layer is made of YSZ, and the second ceramic layer is rare earth zirconate with Sc2O3. The preparation method includes that an electron beam physical vapor deposition method or an atmosphere plasma spraying method are adopted. Sc2O3 is doped in a rare earth zirconate coating, so that heat conductivity of the coating can be further lowered, toughness of the coating is improved, anti-CMAS-corrosion capability of the coating is improved, thermal cycling life of the coating can be prolonged, and high-temperature stability of the coating under CMAS coupling action can be improved.

CO₂ sorptive pellets and/or granules and their use for removing CO₂ from CO₂-containing gases and for producing hydrogen. CO₂ sorptive pellets are suitable for use in fixed bed reactors and the like due to sufficient crush strength. CO₂ sorptive granules are suitable for moving, ebullated, expanded and fluidized beds. The CO₂ sorptive pellets and/or granules comprise calcium oxide and/or magnesium oxide and at least one binding agent such as calcium titanate, calcium aluminate, calcium zirconate, magnesium titanate, magnesium aluminate, and magnesium zirconate. A method for making the CO₂-sorptive pellets is described. The CO₂ sorptive pellets optionally comprise at Ni, Pd, Pt, and/or Rh.

The invention provides a preparation method of lead zirconate-titante ceramic fiber, which relates to a ceramic fiber. The fiber obtained with the diameter less than 30Mum and the length about 1cm has a single perovskite phase and comparatively high consistency and the invention can be a preparation method of lead zirconate-titante ceramic fiber of ceramic fiber for 1-3 piezoelectric composites. The preparation of lead zirconate-titante precursor solution is : lead acetate trihydrate is added into n-Butyl alcohol, complexing agent glacial acetic acid is added then; the mixture is heated, dissolved and cooled to obtain solution A; zirconium butoxide and titanium butoxide are poured into the n-Butyl alcohol in sequence to obtain the binary mixed solution of zirconium and titanium, and then acetyl acetone is added into the binary mixed solution and solution B is obtained after backflowing; the solution A and the solution B are mixed and the lead zirconate-titante precursor solution is obtained after backflowing. The preparation of lead zirconate-titante precursor sol is: the lead zirconate-titante precursor solution is steamed, concentrated and stirred, rod winding is carried out and the lead zirconate-titante precursor sol is obtained after concentration; lead zirconate-titante gel fiber is obtained through fiber drawing; after aging, the lead zirconate-titante gel fiber is dried and carried out by heat treatment.

A method for hydraulically fracturing a subterranean formation comprises introducing into the formation a cross-linking composition which comprises (a) an aqueous liquid, (b) a pH buffer, (c) a cross-linkable organic polymer, (d) a cross-linking agent which comprises an organic titanate, an organic zirconate, or combinations thereof, and (e) a delay agent which is a hydroxyalkylaminocarboxylic acid. The method can be used over a wide range of pH conditions.

The invention relates to a preparation method of a carbon fiber-reinforced ultra high-temperature ceramic-base composite material capable of being repeatedly ablated for use. Vacuum pressure is adopted to soak and combine reaction melt, the reaction melt is permeated in the conventional carbon fiber-reinforced ultra high-temperature ceramic-base composite material, and rear-earth metal elements such as La, Y, Yb, Sc, and the like are added to achieve effects of reducing volatilization of SiO2 at a high temperature, stabilizing a ZrO2/HfO2 crystal form and generating rare-earth zirconate or rear-earth hafnate. After ablation, glass-state SiO2 is formed on the material surface and filled between ZrO2 and HfO2; and a compaction layer of the rare-earth zirconate/the rear-earth hafnate is mixed to protect the material very well, so that repeatable ablation of the ultra high-temperature ceramic-base composite material is possible.

The invention relates to a composite coating use for a smelting metal high-temperature vessel and a preparation method thereof, belonging to the technical field of smelting and preparing noble metal or rare metal. The method comprises the following steps: the surface of the smelting metal high-temperature vessel is provided with one or more metal tungsten, metal molybdenum, metal tantalum or metal niobium transition layers; the transition layer is provided with one or more yttrium oxide, calcium zirconate or magnesium zirconate coatings; or more than three layers of ladder coatings consisting of the metal tungsten, the metal molybdenum, the metal tantalum or the metal niobium and a ceramic surface material are formed on the surface of the smelting metal high-temperature vessel, with the compositions from more to less or from less to more. The composite coating solves the problem that smelting metal at high temperature reacts with the high-temperature vessel, and can be applied to the field of high-temperature smelting.

The invention provides an YSZ-rare earth zirconate thermal barrier coating of a gradient structure and a preparation method thereof. The coating material comprises an adhesive layer, an 8YSZ-rare earth zirconate gradient layer and a surface layer. The 8YSZ-rare earth zirconate material has relatively low conductivity, high-temperature sintering resistance and excellent resistance to heat shocks, and also can prevent oxygen from entering the adhesive layer on active service to alleviate oxidization of the adhesive layer to form TGO. The heat mismatching stress of the material can be reduced bymeans of an optimized design of the gradient structure, so that the heat stability of the whole material member is improved; the surface layer is a CMAS corrosion layer, so that the problem that an existing YSZ coating is corroded by CMAS can be alleviated. As Pd or a oxide ceramic layer is adopted, CMAS molten at a high temperature is not wet in the surface layer, and the rolling angle is small,and CMAS is hardly attached to the surface of the coating, so that CMAS corrosion is avoided.

The invention relates to a barium zirconate proton conductor designed by complex phase structure with a high electric conductivity and its manufacturing method. The invention is coating a layer of NaOH or sulfate around the crystal grain of the barium zirconate. The manufacturing method is: taking the BaCO3, ZrO2 and Y2O3 as raw material, water as medium, ball milling mixing for 4-10 hours, calcining for 4-12 hours in 1200-1400 DEG C; then adding 1-10% molar ZnO, ball milling mixing for 4-10 hours, adding 5-50% mol NaOH or K2SO4 or Na2SO4 or Li2SO4 in a way of hand lapping to make the mixture uniform; putting the mixing material into the die and dry pressing molding under a pressure of 50-120 MPa, and then isopressing under 200-350 MPa; sintering in the air of 1200-1500 DEG C with a heating rate of 2-10 DEG C/minute and keeping warm for 2-10 hours, then cooling to the room temperature to produce the barium zirconate proton conductor material with a high electric conductivity. The invention adopts the new designing thought of complex phase structure to establish a foundation for exploiting hydrogen gas and vapor sensor, hydrogen pump and concentration cell electrolyte material.