The invention relates to a preparation method of modified cation waterborne
polyurethane emulsion containing hydrophilic and hydrophobic side long chains and a product thereof. The method comprises the following steps that raw materials are prepared;
polyester glycol dehydration pretreatment is carried out;
polyester glycol obtained after
dehydration pretreatment is subjected to a prepolymerization reaction with an end
alkyl polysiloxane linear body, a nonionic chain
extender, a functionality chain
extender and diisocyanate under catalyzing of a
polymerization catalyst so that a
prepolymer can be obtained; the
prepolymer reacts with a nonionic chain
extender and a part
diluent to prepare an intermediate; the intermediate reacts with a
silane coupling agent, and is emulsified to prepare the modified cation waterborne
polyurethane emulsion. The product is a
polyester type cation waterborne
polyurethane high-
polymer material containing hydrophilic and hydrophobic side long chains, wherein polysiloxane is embedded into a main chain of the material, a
side chain is grafted with long-chain polyether and long-chain
alkyl, and the
silane coupling agent is connected into the
tail end of the material; the film-forming ability is high, and serving as a film, the
emulsion has obvious water-repellent, antifouling and easy
dirt-removing abilities, is excellent in compatibility with a cation
softening agent, and has an excellent low-temperature soft feature; the product is safe,
environmentally friendly and convenient to use.