496 results about "Polytetrahydrofuran" patented technology

The invention belongs to the technical field of polyurethane elastomers, and particularly relates to a high-static-rigidity high-damping low-pressure-change polyurethane elastomer and a preparation method thereof. Comprising a polyol component and an isocyanate component, and the polyol component comprises polyol A, a chain extender, a stabilizer, a hydrolysis-resistant agent and a catalyst; the isocyanate component is prepared from isocyanate, polyhydric alcohol B and branched chain unit alcohol; the polyol A comprises amine ether polyol and polytetrahydrofuran ether polyol; the polyhydric alcohol B comprises bio-based hydrolysis-resistant polyhydric alcohol and polytetrahydrofuran ether polyhydric alcohol; the bio-based hydrolysis-resistant polyol is prepared by carrying out a reaction on sebacic acid, 1, 2-propylene glycol and 1, 4-butanediol; the branched-chain unit alcohol is prepared from tetrahydrofuran and isooctanol through a reaction. By introducing the bio-based hydrolysis-resistant polyhydric alcohol and branched chain monohydric alcohol, the damping effect is remarkably enhanced, and on this basis, through formula adjustment and raw material screening, the product toughness is greatly improved, the compression set is reduced, and the performance of the product in heavy haul railway application is effectively optimized.

The invention relates to the technical field of polyurethane coatings, in particular to a hydrophobic flame-retardant polyurethane coating and a preparation method thereof. The preparation method comprises the following steps: firstly, taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and methallyl alcohol as raw materials, and reacting to obtain hydroxyl grafted phosphaphenanthrene; taking 1, 1, 3, 3-tetramethyldisiloxane and methallyl alcohol as raw materials, and reacting according to a molar ratio of 1: 2 to obtain dihydroxy siloxane; then cyanuric chloride, hydroxyl grafted phosphaphenanthrene and dihydroxyl siloxane react according to the molar ratio of 1: 1: (1.5-1.8), and the dihydroxyl-terminated silicon-containing flame retardant is obtained. The preparation method comprises the following steps: mixing a dihydroxyl-terminated silicon-containing flame retardant with polytetrahydrofuran ether glycol to serve as a soft segment, and reacting with isocyanate to obtain a hydrophobic flame-retardant polyurethane emulsion; mixing the hydrophobic flame-retardant polyurethane emulsion, an anti-aging agent, an ultraviolet light absorber, a defoaming agent, kaolin, nano silicon dioxide and talcum powder to obtain the hydrophobic flame-retardant polyurethane coating.

The invention belongs to the technical field of conductive adhesives, and particularly relates to a salt-fog-resistant waterborne conductive adhesive and a preparation method thereof.The salt-fog-resistant waterborne conductive adhesive is mainly prepared from, by weight, 5-10 parts of salt-fog-resistant waterborne polyurethane; 5 to 10 parts of water-based tackifying resin; 30 to 50 parts of conductive silver powder; 10 to 20 parts of ethanol; 2-10 parts of an anti-hydrolysis agent; and 10-30 parts of deionized water. According to the salt-fog-resistant aqueous conductive adhesive, polyurethane resin with polytetrahydrofuran alcohol and polycaprolactone polyol as main structures is used as matrix resin, a system is endowed with excellent water resistance and salt-fog resistance, the salt-fog-resistant aqueous conductive adhesive shows outstanding hydrolysis-resistant stability after being cured, and the salt-fog-resistant aqueous conductive adhesive and the conductive silver powder have a synergistic effect, so that the anti-settling performance is effectively improved.

The invention discloses a wear-resistant vehicle body film and a preparation method thereof, and relates to the technical field of films. The wear-resistant automobile body film prepared by the invention is prepared from polytetrahydrofuran ether glycol, isophorone diisocyanate, a catalyst, dihydric alcohol quaternary ammonium salt, a functional aid, modified silicon dioxide and a chain extender. The dihydric alcohol quaternary ammonium salt is obtained by reacting N, N '-dihexyl-N, N'-dimethyl propane-1, 3-diamine with monochloroacetone and then condensing with glycerol; the functional additive is obtained by reacting 2-boric acid thiophene-4-methyl acetate with 2, 7-dibromofluorene and then carrying out bromination hydrolysis; the modified silicon dioxide is obtained by reacting pretreated silicon dioxide with melamine and then reacting with sodium hypophosphite. The wear-resistant vehicle body film prepared by the invention has good anti-aging, wear-resistant, antibacterial and flame-retardant properties.

The invention relates to a hyaluronic acid-polyurethane composite material based on a double dynamic network and a preparation method and application thereof, and the preparation method comprises the following steps: carrying out hydrophobic modification reaction on hyaluronic acid and aminophenylboronic acid to obtain aminophenylboronic acid modified hyaluronic acid; the preparation method comprises the following steps: mixing polytetrahydrofuran ether glycol, polyethylene glycol and isophorone diisocyanate, carrying out a primary reaction, adding trimethylolpropane tri (3-mercaptopropionic acid) ester, carrying out a secondary reaction, adding tannic acid, and carrying out a third reaction to obtain tannic acid-terminated dynamic thionocarbamate polyurethane; and mixing the amino phenylboronic acid modified hyaluronic acid with the tannic acid terminated dynamic thionocarbamate polyurethane for reaction to obtain the hyaluronic acid-polyurethane composite material with the double dynamic networks. Compared with the prior art, by introducing a'thionocarbamate-borate 'double-dynamic network, high toughness, high strength, good self-repairability and repeatable processability in an extreme environment are realized, and the material is particularly suitable for manufacturing and repairing of key components in an LNG ship body and a heat insulation system thereof.

The invention relates to the technical field of polyurethane, in particular to a bio-based polyurethane buffer material. The material is prepared by foaming and curing a bio-based polyurethane prepolymer. The bio-based polyurethane prepolymer is prepared by the following steps: modifying attapulgite with branched polyol containing quaternary ammonium salt and polytetrahydrofuran ether glycol, and then reacting with raw materials such as soybean oil-based polyol, polytetrahydrofuran ether glycol, isophorone diisocyanate and the like. The bio-based polyurethane buffer material provided by the invention has high compression strength and compression modulus, the hysteresis loss rate is lower than 20%, the elastic recovery rate is higher than 99%, and the bio-based polyurethane buffer material shows excellent rebound resilience and energy absorption capacity, and has excellent adaptability and durability in the fields of high rebound resilience and lightweight design.

The invention provides a modified single-component polyurea waterproof coating as well as a preparation method and application thereof and a hydraulic concrete protective coating structure, and relates to the technical field of hydraulic concrete protection. The modified single-component polyurea waterproof coating provided by the invention is prepared from the following raw materials by mass: polytetrahydrofuran polyol, polyether triol, fluorine-containing polyether polyol, FEVE type fluorocarbon resin, organic silicon polyether glycol, a water repellent agent, isocyanate, a defoaming agent, a diluent, a dispersing agent, a catalyst, a latent curing agent, a coupling agent, a water removal agent, a pigment filler, a thixotropic agent and a plasticizer. The modified single-component polyurea waterproof coating has excellent comprehensive mechanical properties, anti-icing adhesion performance and ice pulling resistance, and the problem of freezing injury is thoroughly solved; the surface roughness is low, the hydrophobicity is high, and resistance and roughness are reduced; the water resistance is high; the coating is high in adhesive force. The modified single-component polyurea waterproof coating is applied to cold region hydraulic concrete anti-freezing damage protection engineering, and the long-term operation protection performance is good.

The invention relates to the field of abrasive materials, in particular to an efficient grinding diamond abrasive material and a preparation process thereof.The efficient grinding diamond abrasive material is prepared by coating diamond micro-powder for multiple times to prepare composite diamond micro-powder, then blending the composite diamond micro-powder with electrolytic copper powder, filler, a wetting agent and modified polyvinyl alcohol to obtain slurry, and conducting freezing-unfreezing gel forming to obtain the efficient grinding diamond abrasive material. The prepared diamond grinding material is good in water resistance and efficient in grinding; the preparation method comprises the following steps: depositing a tungsten coating on the surface of diamond micro-powder, then carrying out vacuum high-temperature treatment to obtain pretreated diamond micro-powder with a tungsten carbide layer growing in situ on the surface, generating a silicon oxide layer on the pretreated diamond micro-powder by using tetraethoxysilane, and then generating praseodymium-doped cerium oxide nanoparticles on the surface of the modified diamond micro-powder by using a homogeneous precipitation method; the preparation method comprises the following steps: carrying out chain extension treatment on a prepolymer generated by polytetrahydrofuran ether glycol and 4, 4 '-dicyclohexylmethane diisocyanate by using a silicon-containing chain extender to obtain a polyurethane prepolymer, and then modifying polyvinyl alcohol by using the polyurethane prepolymer and phenolic resin.

The invention relates to the field of fabrics, in particular to a metallic yarn fabric based on a discontinuous aluminum layer and a processing technology thereof.The metallic yarn and polyester fibers are blended to serve as warps, the polyester fibers serve as wefts, the warps and the wefts are interwoven to obtain base cloth, the base cloth is subjected to discontinuous etching in the warp direction through etching liquid, and the pretreated base cloth is obtained; transferring the fabric into antibacterial finishing liquid for padding treatment to prepare the fabric. Modified waterborne polyurethane emulsion containing silicon and nitrogen elements is introduced into finishing liquid, polytetrahydrofuran glycol, hydroxyl-terminated polydimethylsiloxane and isophorone diisocyanate are used as raw materials, 2, 2-bis (hydroxymethyl) propionic acid is used as a hydrophilic chain extender, and cyanuric chloride derivative glycol based on menthol is used as a chain extender; the preparation method comprises the following steps: introducing nano zinc oxide as a finishing agent into a finishing liquid, firstly aminating the nano zinc oxide by using 3-aminopropyltriethoxysilane, then obtaining phytic acid modified nano zinc oxide by using electrostatic and hydrogen-bond interaction, and further grafting cyanuric chloride derivative diol based on menthol.

The invention discloses an antifouling waterborne polyurethane coating for ships, and relates to the technical field of waterborne polyurethane coatings, and the antifouling waterborne polyurethane coating is prepared from the following raw materials in parts by weight: 5 to 8 parts of polytetrahydrofuran, 3 to 5 parts of diphenylmethane diisocyanate, 4 to 5.2 parts of chain extender and 0.45 to 0.7 part of functional filler. According to the antifouling waterborne polyurethane coating for the ship, the chain extender I tends to be distributed on a coating-water interface through the hydrophilicity of triethanolamine in the chain extender I, meanwhile, boric acid groups are preferentially in contact with seawater and are distributed on the surface layer of a coating, the water solubility is high, boric acid ions are rapidly released at the initial stage, and the antifouling waterborne polyurethane coating is good in antifouling property. The initial adhesion of marine microorganisms is inhibited through ion repulsion; an MDI fragment in the chain extender II provides an extra-NCO reaction site, and chemical crosslinking is generated between the MDI fragment and a network formed by the chain extender I, so that the overall crosslinking density is improved, and the toughness and weather resistance of a coating film are improved.

The invention discloses a method for preparing antibacterial and antistatic polyester fibers by regenerating waste polyester, belongs to the technical field of polyester fiber processing, and is used for solving the technical problem that the antistatic performance, moisture absorption performance and antibacterial performance of polyester fibers in the prior art need to be further improved. The method specifically comprises the following steps: crushing waste polyester, performing alcoholysis to prepare an alcoholysis extract, mixing the alcoholysis extract, polytetrahydrofuran ether glycol, 1, 4-butylene glycol and a catalyst under the protection of inert gas, and performing reaction to obtain the polytetrahydrofuran ether glycol / 1, 4-butylene glycol / polytetrahydrofuran ether glycol / 1, 4-butylene glycol / polytetrahydrofuran ether glycol / 1, 4-butylene glycol composite material. According to the invention, the olefin modified silver-loaded montmorillonite and hydroxyethyl methylacrylate reinforced copolyester polyester fiber with a flexible polyether block structure is subjected to padding modification through the reinforcing modifier, so that the breaking strength and the antistatic property of the polyester fiber are effectively improved, and the moisture absorption property and the antibacterial property of the polyester fiber are also improved.

The invention relates to the field of new energy batteries, in particular to a negative electrode current collector and a preparation method thereof, a pole piece and a battery, and the preparation method comprises the following steps: preparing a carbon nanotube with a hydroxyl group on the surface; mixing a carbon nanotube with hydroxyl on the surface, an isocyanate raw material, diol, water and a second organic solvent, and carrying out heating reflux treatment to obtain a third product; mixing the third product, a polytetrahydrofuran raw material, a second organic solvent and a second ammonium salt, and carrying out a polymerization reaction to obtain a precipitate; carrying out drying treatment on the precipitate, so as to obtain foam polyurethane modified by the carbon nano tube; and taking the foam polyurethane modified by the carbon nano tube as a working electrode, carrying out deposition reaction on the working electrode to obtain a base material with a metal layer deposited on the surface, and washing and drying the base material with the metal layer deposited on the surface. The negative electrode current collector lithium metal battery provided by the invention has relatively large energy density, relatively small battery internal resistance, relatively strong cycle performance and relatively low safety risk.

The present invention relates to the field of polyurethane materials and particularly to a temperature-induced color-changing vehicle film and a preparation method therefor. The method of the present invention comprises: firstly, using polyurethane to wrap vanadium dioxide powder to obtain color-changing microcapsules; then using 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-allyloxy-1,2-propanediol as raw materials to synthesize an organosilicon-modified diol, and enabling trimellitic anhydride to react with toluene diisocyanate to synthesize a dicarboximide compound; enabling the organosilicon-modified diol and the dicarboximide compound to undergo an esterification reaction and a polymerization reaction to obtain an organosilicon-modified imide polyester diol; then mixing the organosilicon-modified imide polyester diol with polytetrahydrofuran ether glycol 2000, and then enabling the mixture to react with toluene diisocyanate to obtain a polyurethane elastomer; and mixing the polyurethane elastomer, the color-changing microcapsules, a silane coupling agent, a plasticizer, an antioxidant, and an ultraviolet light absorber, followed by melt extrusion and blow molding into a film, so as to obtain the temperature-induced color-changing vehicle film.

The invention discloses a preparation method and application of a wear-resistant TPE (thermoplastic elastomer) material for data lines, and the preparation method comprises the following steps: carrying out reaction on polytetrahydrofuran ether glycol and isophorone diisocyanate to form a polyurethane prepolymer, adding a reinforcing monomer and a modified filler, carrying out chain extension reaction, and finally adding ethylenediamine to prepare the wear-resistant TPE material. The TPE material is of a hyperbranched structure, the mechanical performance of the material can be improved, cross-linking points of the TPE material are increased by adding the modified filler, TPE material molecules form a stable grid shape, the wear resistance of the TPE material is further improved, a zinc organic framework is connected between the modified filler and a polyurethane prepolymer molecular chain, and the modified filler contains a six-membered ring structure, so that the wear resistance of the TPE material is improved. According to the present invention, the modified filler is added to the TPE material, such that the TPE material can well adapt to the surface contact when the TPE material is worn so as to reduce the wear, and the dynamic cross-linking of the modified filler and the TPE material molecules does not cause the substantial reduction of the toughness due to the increase of the cross-linking point so as to improve the bending resistance effect of the TPE material.

The invention discloses a high-performance polyurethane paint and a preparation method thereof, and particularly relates to the technical field of coatings. The high-performance polyurethane paint is prepared from the following components in parts by weight: 45 to 60 parts of functional polyurethane prepolymer, 4 to 7 parts of modified kaolin, 1 to 3 parts of propylene glycol methyl ether acetate, 0.1 to 0.5 part of defoaming agent, 0.2 to 0.6 part of flatting agent, 10 to 15 parts of titanium dioxide and 0.5 to 1 part of dispersing agent, the preparation method of the functional polyurethane prepolymer comprises the following steps: mixing polytetrahydrofuran glycol, diisocyanate and dibutyltin dilaurate to carry out a first reaction, and then adding a functional diol monomer to carry out a second reaction, thereby obtaining the functional polyurethane prepolymer. The coating is mildew-proof and antibacterial, and has good waterproof self-cleaning performance, mechanical property and storage stability.

The invention relates to the technical field of high polymer materials, and discloses a wear-resistant and anti-slip plastic tray and a manufacturing method thereof. Comprising the following steps: S1, adding polytetrahydrofuran glycol and dihydroxyl-terminated polysiloxane into acetone, uniformly stirring, heating to 65-70 DEG C, adding isophorone diisocyanate and a tin catalyst, and stirring for 2-3 hours to obtain an isocyanato-terminated polyurethane prepolymer; adding a branching agent, reacting for 2-3 hours at the temperature of 60-70 DEG C, adding hydroxyethyl methylacrylate, stirring and reacting until the content of isocyanate groups in the system is not changed any more, and carrying out rotary evaporation to remove the solvent, so as to obtain modified polyurethane acrylate; s2, taking urethane acrylate, a photoinitiator, modified urethane acrylate, modified silicon dioxide and a diluent, and uniformly stirring to obtain a wear-resistant antiskid coating; and S3, the outer surface of the tray base body is coated with the wear-resistant and anti-skid coating, curing is conducted, and the wear-resistant and anti-skid plastic tray is obtained.

The invention discloses a preparation method and application of a reproducible self-healing polyurethane elastomer with synergism of dynamic silicon oxygen bonds and multiple hydrogen bonds. The method comprises the following steps: (1) carrying out a pre-polymerization chain extension reaction on polytetrahydrofuran, isophorone diisocyanate and a catalyst; (2) adding a 3, 13-dihydroxy propyl octaphenyl double-layer silsesquioxane monomer to carry out a chain extension reaction, and then adding carbohydrazide to carry out a reaction; and (3) adding glycerol and camphorsulfonic acid, uniformly stirring, pouring into a mold, curing and drying, thereby obtaining the reproducible self-healing polyurethane elastomer with synergistic dynamic silicon-oxygen bonds and multiple hydrogen bonds. According to the invention, a common fabric is soaked in a dispersion liquid formed by uniformly mixing diluted polyurethane and hydrophobically modified MXene to obtain the multifunctional composite material with the functions of self-cleaning, self-repairing, photo-thermal conversion and human body sensing.

The invention relates to the technical field of preparation of functional polymer materials, in particular to organic-inorganic hybrid self-repairing polyurethane and a preparation method thereof, and the organic-inorganic hybrid self-repairing polyurethane comprises the following components in parts by weight: 20-40 parts of polytetrahydrofuran glycol; 10 to 20 parts of modified polytetrahydrofuran glycol; 1-5 parts of a hydrophilic chain extender; 20 to 45 parts of isophorone diisocyanate; 1-10 parts of a chain extender I; 2-10 parts of a chain extender II and the like. An organic-inorganic hybridization method is adopted, a polysiloxane structure is introduced into a polyurethane cross-linked network, a polysiloxane area and polyurethane polyol macromolecules are connected through covalent bonds through interface modification, and phase separation is effectively avoided; besides, a chain extender with polyfunctional groups is adopted to prepare waterborne polyurethane which has a cross-linked structure and contains dynamic covalent bonds and dynamic non-covalent bonds, the hybrid polyurethane material is finally cured to form an organic-inorganic hybrid cross-linked structure, and the organic-inorganic hybrid polyurethane material has the characteristics of high strength and high self-repairing performance; wide application prospects are realized.

The invention discloses a resin binding agent for a resin diamond wire, the resin diamond wire and a preparation method of the resin binding agent, and belongs to the technical field of binding agents for resin diamond wires. Two brand-new modified compounds are designed and synthesized, boron-containing and nitrogen-containing compounds are introduced to form a covalent bond enhanced polyurethane derivative; and the other one is a double-functional-group siloxane oligomer containing an epoxy group and a carboxyl group, which is prepared by carrying out hydrolytic condensation on raw materials such as methyltrimethoxysilane and the like, neutralizing and purifying. The resin binder takes epoxy-phenolic hybrid resin as a main body and is compounded with the two modified compounds, a curing agent, a coupling agent and other components. The resin diamond wire is prepared through wire core pretreatment, glue solution preparation, coating, multi-stage curing and post-treatment. The heat resistance, the bonding strength with diamond and the impact toughness of the bonding agent are remarkably improved, and the bonding agent is suitable for high-precision cutting of hard and brittle materials such as photovoltaic silicon wafers and the like.

The invention discloses an anti-ultraviolet automobile window film and a preparation method thereof, and relates to the field of high polymer materials. When the anti-ultraviolet automobile window film is prepared, methylcyclotetrasiloxane, octamethylcyclotetrasiloxane, 3-glycidyl propyl (dimethoxy) methylsilane and 1, 3-bis (3-aminopropyl)-1, 1, 3, 3-tetramethyldisiloxane are subjected to a reaction, and modified polysiloxane is prepared; the preparation method comprises the following steps: reacting benzo [1, 2-d: 5, 4-d '] bis (oxazole)-2, 6-dithiol with 4-aminobenzoyl chloride to prepare a modified ultraviolet absorbent; isophorone diisocyanate, polytetrahydrofuran ether glycol, the modified polypyrrole particles, the modified polysiloxane and the modified ultraviolet absorbent are subjected to a reaction, and the reaction product is spread in a mold. The anti-ultraviolet automobile window film prepared by the invention has good anti-ultraviolet, heat-insulating, flame-retardant and anti-aging properties and good mechanical properties.

The invention relates to the technical field of layered materials, in particular to an antibacterial layered composite elastic fabric and a preparation method thereof. The defects that an existing layered fabric is poor in antibacterial property and elasticity are overcome. The preparation method comprises the following steps: preparing modified spandex fiber yarns by taking polytetrahydrofuran ether glycol, diphenylmethane diisocyanate and modified microcrystalline cellulose as raw materials; preparing modified polyester fiber yarns by taking terephthalic acid, ethylene glycol, 1, 4-butanediol, isophthalic acid and nano silicon dioxide as raw materials; plying the modified polyester fiber yarns and the modified spandex fiber yarns, and weaving to obtain an outer-layer fabric; performing pretreatment, dipping and heat treatment on the outer layer fabric to obtain an outer layer finished fabric; performing dipping and heat treatment on the inner-layer fabric to obtain an inner-layer finished fabric; the antibacterial layered composite elastic fabric obtained by laminating and compounding the outer-layer finishing fabric and the inner-layer finishing fabric has strong antibacterial property and strong elasticity, and is suitable for manufacturing outdoor textiles.

The invention relates to the technical field of anti-seepage protective materials, in particular to a high-toughness high-molecular flexible auxiliary anti-seepage protective material and a preparation method thereof, and the high-toughness high-molecular flexible auxiliary anti-seepage protective material comprises a component A and a component B, the component A at least comprises the following preparation raw materials: first polyol, a chain extender, diisocyanate and an anti-aging agent, the mass ratio of the diisocyanate in the component A is 22-35%, and the mass ratio of the anti-aging agent in the component A is 0.1-1%; the first polyhydric alcohol is prepared from poly (neopentyl glycol adipate)-1, 6-hexanediol ester glycol, hydrogenated castor oil polyether polyol, polytetrahydrofuran glycol and polyfunctional polyether polyol, and the second polyhydric alcohol is prepared from poly (neopentyl glycol adipate)-1, 6-hexanediol ester glycol, hydrogenated castor oil polyether polyol, polytetrahydrofuran glycol and polyfunctional polyether polyol; the chain extender is prepared from dipropylene glycol and methyl propylene glycol; the component B is prepared from the following raw materials: second polyol, a plasticizer, a filler and an amine catalyst, and is subsequently coated on the surfaces of base materials such as asphalt concrete and concrete to isolate a bottom structure from the external environment, so that the effects of isolation, seepage prevention, protection, insulation, flame retardance and the like are achieved.

The invention provides a fluorine-silicon composite modified waterborne polyurethane acrylate anti-ultraviolet coating and a preparation method thereof, and belongs to the technical field of waterborne polyurethane preparation. The preparation method comprises the following steps: stirring isophorone diisocyanate, polytetrahydrofuran ether glycol and dimethylolpropionic acid, adding a catalyst, and stirring for reaction to obtain a polyurethane prepolymer; adding a chain extender into the polyurethane prepolymer, and stirring; cooling the reaction system after chain extension, adding an end-capping reagent for stirring reaction, and adding a neutralizer for stirring reaction after the system is cooled; adding low-temperature deionized water into the reaction system, and stirring to emulsify polyurethane to obtain a polyurethane emulsion; acrylic ester, fluorine-containing acrylic ester and silicon-containing acrylic ester are added into the polyurethane emulsion, azobis (isobutylamidine hydrochloride) dissolved in water is slowly and dropwise added after stirring, a heat preservation reaction is conducted, and fluorine-silicon composite modified waterborne polyurethane acrylate emulsion is obtained; and coating and drying the emulsion to obtain the fluorine-silicon composite modified waterborne polyurethane acrylate film.

The invention belongs to the field of photovoltaic materials, provides a preparation method and application of reinforced polyurethane resin for a photovoltaic frame, and solves the problem that the existing polyurethane resin for the photovoltaic frame cannot have excellent flame retardant property, water resistance, aging resistance and mechanical property at the same time. Comprising the following steps: carrying out a reaction on polytetrahydrofuran ether glycol and polyisocyanate to obtain a polyurethane prepolymer, and chemically grafting a phosphorus-containing compound onto a polyurethane main chain by using prepared 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, so as to obtain the flame-retardant polyurethane. Hydroxyl-terminated polydimethylsiloxane and polyhydric alcohol are used as part of flexible chain segments to be embedded into a polyurethane main chain, 2-(2-hydroxy-4-acryloyl)-2H-benzotriazole is added to serve as an anti-ultraviolet agent, and final polyurethane resin is obtained through reaction. And injecting the polyurethane resin and the glass fiber into a mold, and preparing the photovoltaic frame profile through a pultrusion process.

The invention discloses a transparent polyurethane elastomer and a preparation method thereof, and relates to the technical field of polyurethane elastomers, the preparation method comprises the following steps: carrying out vacuum dehydration on polytetrahydrofuran ether glycol-2000 and polytetrahydrofuran ether glycol-1000 for later use; the preparation method comprises the following steps: preheating a reaction container, adding isophorone diisocyanate and benzoyl chloride, uniformly stirring, adding polytetrahydrofuran ether glycol-2000 and polytetrahydrofuran ether glycol-1000, and carrying out heat preservation reaction to obtain a polyurethane prepolymer; uniformly stirring polyether polyol N330, a chain extender, dibutyltin dilaurate, silicone oil, a defoaming agent, an antioxidant and an ultraviolet light absorber, carrying out vacuum degassing, adding into the polyurethane prepolymer, uniformly stirring, pouring into a mold, curing, molding and demolding to obtain the transparent polyurethane elastomer.

The invention relates to the technical field of polyurethane materials, in particular to a non-MOCA type fitness equipment rubber coating material and a preparation method thereof. The preparation method comprises the following steps: adding polytetrahydrofuran, isophorone diisocyanate, 1, 4-butanediol, a 2, 2-dimethylolpropionic acid solution, a hydroxyl chain extender, triethylamine, deionized water and a flame-retardant filler to obtain a polyurethane emulsion; and coating the polyurethane emulsion to form a film, and drying to obtain the polyurethane adhesive film. Adding the flame-retardant filler into ethanol, and ultrasonically dispersing uniformly to obtain dispersion liquid; spraying the dispersion liquid onto the surface of a polyurethane adhesive film to obtain a pretreated polyurethane adhesive film; and carrying out layer-by-layer self-assembly on the surface of the pretreated polyurethane adhesive film for 5-6 times to obtain a finished product. The finished product prepared by the invention has excellent flame retardant property, antibacterial property and mechanical property, thereby having wide application prospect in the technical field of polyurethane materials.

The invention belongs to the technical field of waterborne polyurethane dispersions, and particularly discloses a bio-based waterborne polyurethane printing adhesive and a preparation method thereof. The bio-based waterborne polyurethane printing adhesive is prepared from the following raw materials in parts by mass: # imgabs0. The bio-based waterborne polyurethane printing adhesive is prepared from bio-based polymer polyols, such as polytetrahydrofuran ether glycol and polypropylene glycol with 100% bio-based content, polycarbonate diol with 50-70% bio-based content, polyethylene glycol with 50-70% bio-based content, polyethylene glycol with 50-70% bio-based content and polyethylene glycol with 50-70% bio-based content, wherein the bio-based polymer polyols are similar to or completely identical to a petroleum-based structure; the characteristics of the traditional petroleum-based waterborne polyurethane printing adhesive are maintained; the prepared bio-based waterborne polyurethane printing adhesive has high bio-based content and is unique in the field of waterborne printing.

The invention relates to the technical field of coatings, in particular to a bio-based polyurethane waterproof coating and a preparation method thereof. The coating is prepared from organic fluorine-silicon cross-linked castor oil, dibutyltin dilaurate, an HDI tripolymer, polytetrahydrofuran ether glycol, 1, 4-butanediol, a filler, a plasticizer and an ultraviolet light absorber, and the organic fluorine-silicon cross-linked castor oil is obtained by silanization modification of methyl ricinoleate and hydrolysis cross-linking of fluorine-containing silane. The preparation method is simple, and the material has excellent performance, is suitable for the fields of building waterproofing, weather-resistant coatings and the like, and has wide application potential and market value.

The invention provides bio-based MS base resin, bio-based MS glue and a preparation method of the bio-based MS base resin and the bio-based MS glue, and belongs to the technical field of high polymer materials. The MS base resin is isocyanate group silane terminated bio-based polyether polyol or polyether polyol subjected to chain extension. The polyether polyol is selected from one or more of bio-based polyethylene glycol, bio-based polypropylene glycol, bio-based poly (trimethylene ether glycol) and bio-based polytetrahydrofuran ether glycol. And mixing the bio-based MS base resin, the plasticizer, the filler, the catalyst III, the coupling agent and the auxiliary agent, and stirring under a vacuum condition to obtain the bio-based MS adhesive. The bio-based MS adhesive prepared by the invention is high in bio-based material content, uncomplicated in preparation process and low in energy consumption, and meanwhile, an adhesive body is good in mechanical property, high in stability and good in high temperature resistance and humidity and heat resistance.

The technology of the present disclosure generally relates to the field of power storage devices, and more specifically to a solid electrolyte, an electrode, a solid-state battery, and a method for producing the same. An aspect of the present disclosure relates to a process for producing a solid electrolyte, comprising the steps of: - contacting, in the presence of a catalyst: - a polymer precursor compound comprising polyethylene glycol (PEG) and / or polytetrahydrofuran (PTHF), wherein the polymer precursor compound comprises on average per polymer precursor molecule, -at least 2.0 alkoxysilyl functional groups, with a functionality of at least 2.0, preferably at least 2.5, preferably at least 3.0; and / or -at least 1.0 alkoxysilyl functional groups, with a functionality of at least 3.0; - optionally, an organo-tri-alkoxy silane, an organo-tetra-alkoxy silane, and / or a mixture thereof comprising a metal ion (M+) chelating moiety being a cyanurate, a crown ether, an aza-crown ether, a thia-crown ether, a cryptand, a carbamate, a cyano group, a thiocyanate group, or a metallacrown,, - a metal (M+) salt, preferably does the metal salt comprises Li+, Na+, Mg+, Ca+, Al+, and / or a combination thereof, preferably lithium (Li+); - a solvent, preferably an organic solvent; and, - optionally, an ionically conductive compound; thereby obtaining a solid electrolyte; - optionally, drying the obtained solid electrolyte.