2122 results about "Sulfonate" patented technology

The invention relates to a phosphorus-free zinc-free seawater special-purpose scale and corrosion inhibitor, which comprises, by weight, 20-25% of sulfonic acid modified polyaspartic acid, 8-12% of quaternized chitosan, 5-10% of a sulfonate copolymer, 5-10% of polyepoxysuccinic acid, 1-3% of benzotriazole or methyl benzotriazole, 0.5-1% of sodium tungstate, and the balance of deionized water. According to the formula, traditional corrosion inhibitors such as phosphorus and zinc are completely abandoned, functions are achieved through natural polymer derivatives such as sulfonic acid modified polyaspartic acid and quaternized chitosan, and the scale and corrosion inhibitor has the following environmental protection advantages that the scale and corrosion inhibitor does not contain phosphorus and zinc elements at all, and water eutrophication and heavy metal accumulation caused by a traditional phosphorus and zinc formula are avoided.

The invention provides weather-resistant anti-freezing road concrete and a preparation method thereof, and belongs to the technical field of concrete. The concrete comprises the following components: sulphoaluminate cement, Portland cement, silica fume, fly ash, modified granite gravel coarse aggregate, medium sand fine aggregate, silica fume blended fiber, silica fume blended polyacrylonitrile fiber, a composite air entraining agent, a functional modifier, a composite antifreeze agent, pre-absorbent zeolite powder and the like. The preparation method comprises the following steps: modifying granite macadam with Al (H2PO4) 3, SiO2 and methoxypolyethylene glycol triethoxysilane, and modifying with a lithium silicate aqueous solution to obtain the modified granite macadam coarse aggregate. The composite air entraining agent comprises a JRY-Q air entraining agent and sodium alpha-olefin sulfonate. The functional modifier is prepared from gas phase method spherical nano silicon dioxide and nano alpha-Al2O3. The composite antifreeze agent comprises ethylene glycol butyl ether acetate and modified calcium carbonate. The modified calcium carbonate is obtained by sequentially modifying nano calcium carbonate with calcium chloride, a KH-550 silane coupling agent and stearic acid.

The invention discloses a high-initial-efficiency fast-charge graphite composite material and a preparation method thereof, the composite material is of a core-shell structure, the core is graphite, and the shell is lithium sulfonate / lithium molybdate and an amorphous carbon coating layer thereof; the mass ratio of the shell is 5-15 wt% according to the mass ratio of the composite material being 100%. The preparation method comprises the following steps: adding a molybdenum compound into a solvent to prepare a solution, adding graphite oxide, an inorganic lithium salt and a carbon nanotube conductive solution, reacting for 2-12 hours at the temperature of 50-120 DEG C, filtering, carbonizing filter residues to obtain a lithium molybdate conductive agent coated graphite material, and depositing a lithium sulfonate derivative on the surface of the lithium molybdate conductive agent coated graphite material by an atomization method to obtain the lithium molybdate conductive agent coated graphite material. The electron and ion conductivity of the material can be improved, and the rate and the first efficiency of the material can be improved.

The invention relates to the technical field of PC transparent flame-retardant toughening modification, in particular to phenolic hydroxyl-terminated modified polysiloxane with a side chain containing phenyl and sulfonate groups and a preparation method of copolymerized PC. The modified polysiloxane is prepared by the following steps: performing ring opening polymerization on phenol-containing double end sockets and cyclotetrasiloxane to obtain modified polysiloxane containing double bonds and phenyl functional groups, and grafting sulfonate through a thiol-ene click chemical reaction. Diphenyl carbonate, bisphenol A and the modified polysiloxane are used as raw materials, a polysiloxane-PC block copolymer is formed through copolymerization, efficient flame retardance and high transparency are achieved, and meanwhile extremely high low-temperature impact strength is achieved.

The invention provides a thermal response self-ceramization fireproof coating and a preparation method thereof. The thermal response self-ceramization fireproof coating is prepared from the following raw materials in parts by mass: 3 to 10 parts of acrylic monomer, 3 to 10 parts of organic sulfonate, 1 to 4 parts of silane coupling agent, 0.5 to 3 parts of silicate ester, 4 to 6 parts of ceramic precursor, 3 to 6 parts of fluxing agent and 0.05 to 0.4 part of initiator. The fluxing agent comprises a component A and a component B, the component A is one of boric oxide, zinc borate or low-melting-point glass powder, and the component B is one of phosphorus pentoxide and ammonium polyphosphate. The silane coupling agent can be copolymerized with an acrylic monomer to construct a C-C main chain, the C-C main chain and silicate ester are subjected to hydrolytic condensation to form a Si-O-Si three-dimensional network, a chemical cross-linked skeleton is formed, and the chemical cross-linked skeleton can generate silicon dioxide at high temperature to participate in a ceramization reaction; the ceramic precursor and silicate ester can form a strong physical cross-linking effect, so that the fireproof coating with a chemical and physical double-cross-linked network can be formed, and the fireproof coating has excellent mechanical property and machinability at normal temperature.

The invention provides a low-temperature-impact-resistant food packaging material and a preparation method and application thereof.The low-temperature-impact-resistant food packaging material is prepared from, by mass, 100 parts of polylactic acid, 1-10 parts of modified layered double hydroxide and 5-40 parts of hyperbranched polyester; wherein the modified layered double hydroxide is obtained by treating layered double hydroxide with a composite anionic surfactant and then treating the treated layered double hydroxide with an organic cationic compound with a long alkyl chain; the composite anionic surfactant comprises a first anionic surfactant and a second anionic surfactant; wherein the first anionic surfactant comprises sodium dodecyl sulfate; the second anionic surfactant comprises a sulfonate anionic surfactant containing an amido bond and a catechol structure. Through the formula design, the impact toughness of the material at low temperature can be improved while the mechanical property of polylactic acid is maintained, and the material can be suitable for the field of food packaging.

The invention discloses high-performance anti-wear engine lubricating oil as well as a preparation method and application thereof. The high-performance anti-wear engine lubricating oil is prepared from the following raw materials: self-developed lubricating oil base oil, poly-alpha-olefin, zinc dialkyl dithiophosphate, calcium sulfonate, polyisobutylene succinimide, an antioxidant, polymethacrylate, an organic molybdenum complex, a de-foaming agent and a pour point depressant. The preparation method comprises the following steps: 1) synthesizing 9, 10-bis (2-tert-butyl-4-methylphenoxy) trimethylolethane stearate as base oil of the lubricating oil; and 2) mixing the base oil with other assistants to obtain the high-performance anti-wear engine lubricating oil. According to the preparation method, novel-like synthetic ester oil is firstly prepared, a phenol group and a large steric hindrance substituent group are introduced into a polymer, the anti-oxidation function is directly built in base oil molecules, meanwhile, super-strong heat resistance is achieved, and finally the high-performance anti-wear engine lubricating oil is obtained and can be applied to high-end application scenes such as aero-engines or gas turbines.

The invention relates to the technical field of waterproof coiled materials, and provides a macromolecule waterproof coiled material with a hook-and-loop fastener and a preparation method thereof.The macromolecule waterproof coiled material with the hook-and-loop fastener sequentially comprises the hook-and-loop fastener, a macromolecule sheet layer, a blocking layer, an upper gluing waterproof layer, a film-based macromolecule layer, a lower gluing waterproof layer and an anti-sticking layer from top to bottom; the upper adhesive waterproof layer and the lower adhesive waterproof layer are both modified self-adhesive asphalt sizing materials, and the modified self-adhesive asphalt sizing materials comprise asphalt, softening agents, styrene-butadiene-styrene block copolymers, butadiene styrene rubber, butyl rubber, tackifying resin, desulfurized rubber powder, filler and compatilizers. The filler is prepared from the following raw materials: carbon black, silicon dioxide, a silane coupling agent and 5-methylphenol-2-calcium sulfonate; the hook-and-loop fastener is a hook-and-loop fastener, the hook-and-loop fastener comprises a hook-and-loop fastener hook surface layer and a hook-and-loop fastener loop surface layer, and by means of the technical scheme, the problem that in the prior art, the high polymer waterproof roll is low in peel strength is solved.

The invention discloses high-resistance self-extinction waterborne polyurethane resin as well as a preparation method and application thereof, the preparation method comprises the following steps: S1, uniformly mixing polymeric polyol, a catalyst, a carboxylate hydrophilic chain extender and a micromolecule chain extender to obtain a mixed system; s2, diisocyanate is added into the mixed system in the step S1 for a reaction, and an addition product is obtained; s3, after the addition product obtained in the step S2 is cooled to the room temperature, adding an organic solvent, and then adding a neutralizer for neutralization to obtain a waterborne polyurethane prepolymer; s4, a sulfonate chain extender is added into the waterborne polyurethane prepolymer prepared in the step S3 for reaction, water is added for emulsification, and waterborne polyurethane emulsion is obtained; and S5, dispersing an amine chain extender with water, adding the dispersed amine chain extender into the waterborne polyurethane emulsion obtained in the step S4, and carrying out a reaction so as to obtain the high-resistance self-extinction waterborne polyurethane resin. According to the preparation method, function integration is realized, the production process is simplified, and the production efficiency is improved.

The invention discloses a lignin-inorganic oxide composite binder, preparation thereof and application of the lignin-inorganic oxide composite binder in a hard carbon negative electrode. The preparation method comprises the following steps: firstly, carrying out quaternization modification on lignosulfonate to obtain quaternized lignosulfonate, and then utilizing the action of quaternary ammonium and sulfonate of the quaternized lignosulfonate, hydroxyl and inorganic oxyacid radicals of inorganic nano oxide and carboxyl and hydroxyl of sodium carboxymethyl cellulose to prepare the modified lignosulfonate. The lignin-inorganic oxide composite binder with the interpenetrating network structure is formed. According to the binder, sodium carboxymethyl cellulose serves as a hard phase to enhance the mechanical rigidity, quaternized lignosulfonate rich in flexible long chains serves as a soft phase to bear part of loads, and inorganic nano oxide rich in hydroxyl serves as a crosslinking point or physical filler to enhance the structural stability of the binder. Besides, a multi-network structure formed by hydrogen bond crosslinking not only endows the binder with an excellent ion transmission rate, but also helps to enhance the interfacial compatibility of the binder with an ester electrolyte, thereby significantly improving the rate capability and cycle performance of the hard carbon negative electrode.

The invention relates to the technical field of electrolytic copper foil processing, and particularly provides a method for reducing the rough surface roughness of an HVLP copper foil by using a composite additive, which comprises the following steps: step (1): enabling the composite additive to flow into a high-level tank through an additive flow pump, uniformly mixing the composite additive with a copper sulfate electrolyte, and enabling the mixture to flow into a crude foil machine; step (2), then adjusting process parameters of a crude foil machine, including current and line speed of a cathode roller; (3) foil generation and foil drawing are carried out; the composite additive comprises one or two of gelatin and collagen. One or more composite additives composed of gelatin, collagen, sodium dithiodipropane sulfonate, N, N-dimethyl-dithioformamide sodium propanesulfonate, 3-sulfydryl-1-sodium propane sulfonate, hydroxyethyl cellulose and polyethylene glycol are added into the raw foil electrolyte, so that the copper electrodeposition reaction potential can be effectively changed; and uniform and compact copper crystallization peaks are obtained, the rough surface roughness of the raw foil is reduced, and the uniformity of a plating layer is improved.

The invention relates to the technical field of degradable materials, and discloses a water-soluble degradable fiber and a preparation method thereof. The water-soluble degradable fiber disclosed by the invention is prepared by taking polylactic acid as a main matrix, adding modified sodium lignin sulfonate, polyvinyl alcohol and polyethylene wax, blending, carrying out melt extrusion, and carrying out melt spinning. The fiber has water solubility, degradability, sand carrying performance and salt resistance, and has a good application prospect in a fracturing fluid used in a well drilling fracturing process based on the advantages of water solubility, degradability, sand carrying performance and salt resistance.

The embodiment of the invention discloses a preparation method of trifluoromethyl sulfinate. The preparation method comprises the following steps: reacting a trifluoromethyl sulfinyl reagent with an amino compound containing hydroxyl to obtain a trifluoromethyl sulfinate intermediate; and reacting the trifluoromethyl sulfinate intermediate with alkali metal salt in an organic solvent to obtain the trifluoromethyl sulfinate. According to the embodiment of the invention, firstly, the trifluoromethyl sulfinyl reagent reacts with the amino compound containing the hydroxyl group to obtain the trifluoromethyl sulfinate intermediate, and then the trifluoromethyl sulfinate and the alkali metal salt react in the organic solvent, so that the high-purity trifluoromethyl sulfinate can be prepared with high yield under mild conditions. The yield and the purity of the target product are effectively improved, and meanwhile, the production condition requirement and the environmental pollution degree are reduced, so that large-scale production and application are facilitated.

The invention provides anti-erosion hydraulic concrete and a preparation method thereof, and belongs to the technical field of concrete. The concrete comprises the following components: composite cement, high-activity nano-modified metakaolin, blast furnace slag powder, low-calcium fly ash, coarse aggregate, natural river sand fine aggregate, granite machine-made sand fine aggregate, an erosion inhibitor, a functional additive, an early-strength polycarboxylic high-performance water reducer, a composite air entraining agent and the like. The composite cement comprises sulphoaluminate cement, Portland cement and polymer waterproof mortar. The high-activity nano modified metakaolin is obtained by modifying metakaolin with an organic silicon-ZnO composite emulsion and then drying. The erosion inhibitor comprises organic carboxylate, a hydrophobic-crystallization complexing agent and a pH buffer type corrosion inhibitor. The functional auxiliary agent comprises an itaconic acid and acrylic acid copolymer, a JRY-F concrete waterproof agent and polyethylene glycol-400 dilaurate. The composite air entraining agent comprises liquid sodium abietate and sodium alpha-olefin sulfonate. Through component synergism, modification and grading, an anti-erosion barrier is constructed.

The invention provides a sulfonated modified COF-based hydrogel based on a TPAD skeleton, and a preparation method and application thereof, and belongs to the field of water treatment. The preparation method comprises the following steps: S1, synthesizing a TPAD-NHBoc amino monomer by using reagents such as 1, 4, 5, 8-tetrachloroanthraquinone and the like; s2, sequentially adding a TPAD-NHBoc amino monomer, a Dha aldehyde monomer, dioxane and trifluoroacetic acid into a glass tube according to a certain proportion, carrying out ultrasonic treatment, stirring, putting into a reaction kettle, and reacting at 115-125 DEG C for 96-120 hours; s3, after the reaction is finished and cooling is performed, carefully taking out the blocky gel from the glass tube, respectively immersing the blocky gel into dioxane and DMF, and repeatedly replacing the solvent for washing; s4, washing the gel, soaking the washed gel in a DMF solution containing 1, 3-propane sultone, and carrying out a reaction at 75-85 DEG C for 16-20 h to obtain sulfonated modified gel; s5, the obtained sulfonated modified COF-based gel is soaked in DMF, acetone, methanol and water for multiple times of soaking and washing, and the hydrogel is obtained. The sulfonated modified hydrogel based on the TPAD skeleton has excellent solar photo-thermal water evaporation performance.

The invention belongs to the technical field of high polymer materials, and particularly relates to a lightweight high-strength expandable polystyrene material and a preparation method thereof. The high-temperature-resistant foaming material is prepared from the following components in parts by weight: 90 to 100 parts of styrene, 200 to 250 parts of deionized water, 0.3 to 0.6 part of a dispersing agent, 1.5 to 2.5 parts of a nucleating agent, 0.2 to 0.6 part of an initiator, 0.2 to 0.5 part of a particle size regulator, 4 to 7 parts of a foaming agent and 3 to 6 parts of composite filler, the composite filler is prepared by mixing modified graphene and modified silicon dioxide; the modified graphene is maleic anhydride copolymer sulfonate modified graphene, and the modified silicon dioxide is polydopamine / carboxymethyl cellulose modified silicon dioxide; the water dispersibility and interfacial compatibility of the composite filler are remarkably improved in a physical and chemical grafting manner, and the mechanical property, thermal stability and flame retardance of the polystyrene material are synchronously optimized by utilizing a multi-component synergistic effect.

The invention provides a sulfinate organic positive alkali metal ion supplement for a secondary battery, and relates to the technical field of secondary batteries. The organic positive electrode alkali metal ion supplement has a structure as shown in the following general formula: [R-SO2]-M < + >, wherein M < + > is a metal cation and is selected from at least one of Li < + >, Na < + > and K < + >; [R-SO2]-is a sulfinate anion, and wherein R is an organic group. The supplement compensates irreversible capacity loss by efficiently releasing active ions, so that the energy density of the battery is improved; the oxidation potential is proper, the environmental stability is excellent, and the catalyst is not needed to decompose and easy to process; decomposition products are harmless, an electrode interface can be optimized, and the cycle life of the battery is remarkably prolonged.

The present invention relates to liquid aqueous detergent compositions comprising a surfactant system comprising a primary surfactant being anionic surfactant and a secondary surfactant being amphoteric surfactant whilst the surfactant system is free of alkylbenzene sulphonates and derivatives thereof. The invention further relates to a method of cleaning a stainless-steel hard surface using the composition of the invention, as well as the use thereof.

The invention discloses a preparation method of a lignosulfonate controlled-release drug-loaded capsule. The invention constructs a pH controlled release type lignin-based drug-loaded capsule around a three-stage delivery strategy of emulsion construction-electrostatic self-assembly-metal chelation. The preparation method specifically comprises the following steps: dissolving pesticide active ingredients and an emulsifier in an organic solvent to serve as an oil phase; dissolving lignosulfonate and a dispersing agent in water to serve as a water phase; mixing the oil phase and the water phase under stirring and homogenizing conditions to form O / W type emulsion; cationic monomers are added into the O / W type emulsion, a prototype of a shell layer is formed by means of electrostatic acting force, then the shell layer is cured by means of chelation of metal ions, and the lignosulfonate-based drug-loaded capsule loaded with pesticide is formed. The drug-loaded capsule prepared by the invention can shield ultraviolet light through the lignosulfonate metal complexing layer, has sensitive acid-base response performance, can realize the response controlled release process of encapsulated drugs, and effectively reduces the dosage of pesticides.

The invention provides high-grinding-efficiency color paste, a preparation method thereof and dispersed ink, and belongs to the technical field of dispersed ink, and the high-grinding-efficiency color paste comprises the following components in percentage by weight: 15%-30% of disperse dye toner, 15%-25% of a dispersing agent, 5%-15% of resin ammonium salt, 10%-20% of a dissolution promoting mixture, 0.5%-2% of a wetting agent and the balance of water; the dispersing agent comprises a hyperbranched polymer and a sodium naphthalene sulfonate improved polymer; the hyperbranched polymer takes a benzene ring as a center, hydrophobic groups and hydrophilic groups on a branched chain are randomly distributed, the hydrophilic groups of the branched chain comprise carboxylate and sulfonate, and the hydrophobic groups of the branched chain comprise alkane, ester and aryl. According to the invention, the hyperbranched polymer and the sodium naphthalene sulfonate improved polymer are mixed with the dispersing agent, so that the problem of abrupt change of ink viscosity can be avoided when the content of ink toner is relatively high, thereby obtaining the color paste with strong dispersion and high stability, and further obtaining the dispersed ink with good stability.

The invention relates to the technical field of PC alloys, in particular to an impact-resistant flame-retardant PC alloy with melt flowability and a preparation method of the impact-resistant flame-retardant PC alloy with melt flowability, and the impact-resistant flame-retardant PC alloy with melt flowability comprises the following components in parts by mass: 60-70 parts of PC resin; 30 to 40 parts of ABS resin; 6-10 parts of a core-shell flame retardant; 5-8 parts of a toughening agent; 0.5 to 1.0 part of a compatilizer; 0.3 to 0.5 part of an antioxidant; 1.0 to 1.5 parts of other auxiliary agents; the core-shell flame retardant comprises nano SiO2 loaded with sulfonate, low-molecular-weight PC (polycarbonate) and epoxy polysiloxane in sequence from inside to outside, wherein the weight-average molecular weight of the low-molecular-weight PC is 5000-8000; the toughening agent is prepared by mixing an organic silicon toughening agent, MBS and hydrogenated SBS; the serious negative influence of the existing flame retardant on the mechanical property and the processability of the PC / ABS alloy is overcome, so that the material meets the UL94 V0 level, and meanwhile, the balance optimization among the properties is realized.

The invention belongs to the field of polymer electrolyte. Polyurethane (PU) which is high in strength, good in elasticity, convenient to form and capable of being self-repaired is selected as a substrate of the solid electrolyte. A deep eutectic solvent (DES) which can be copolymerized with the lithium salt is selected to enhance the polarity of the system and promote dissociation of the lithium salt, so that the conductivity of the solid electrolyte is improved. The invention provides a preparation method of a DES copolymerization modified self-repairing polyurethane-based solid electrolyte. The preparation method comprises the following steps: preparing a long-chain polyurethane prepolymer; preparing a self-repairing prepolymer; performing double-bond modification on the self-repairing prepolymer; preparing DES containing lithium salt and double bonds; uniformly mixing the self-repairing polyurethane prepolymer with the end capped by double bonds and DES (diethylbenzene sulfonate); pouring into a mold and curing to obtain the DES / polyurethane-based solid electrolyte membrane; and preparing the solid-state lithium battery. The solid electrolyte disclosed by the invention is free from slag falling and liquid leakage, capable of self-repairing, high in ion mobility, simple in preparation process, low in cost and outstanding in performance, and has a wide market application prospect.

The invention belongs to the technical field of oilfield chemistry, and particularly relates to application of a hyperbranched zwitterionic polymer in high-temperature and high-salinity drilling fluid. The hyperbranched zwitterionic polymer is prepared by carrying out Michael addition reaction on polyethyleneimine and a monomer which is neutralized by alkali and contains double bonds and sulfonic acid groups; the polymer has a hyperbranched structure, and the amphoteric ion characteristic that an amino group from polyethyleneimine on a molecular chain and a sulfonic acid group from a monomer form an inner salt structure; the hyperbranched zwitterionic polymer is used as an inhibitor and a viscosity reducer of the drilling fluid. According to the hyperbranched zwitterionic polymer provided by the invention, the salt tolerance and high-temperature stability of the polymer are enhanced by introducing a sulfonate group; the polymer is endowed with low viscosity and high adsorption capacity through a hyperbranched structure, the viscosity of the drilling fluid can be effectively reduced, and clay hydration is inhibited; clay particles are stabilized through electrostatic interaction by zwitterionic characteristics, and the rheological property of the drilling fluid is optimized.

The invention relates to a composition with functions of protecting gingiva and repairing enamel and a preparation method of the composition, and belongs to the technical field of oral care. The composition contains a functional additive, a plant compound fermentation extract and the like, the functional additive is a mixture of corn starch, calcium phosphosilicate, hydroxyapatite, ubiquinone, sodium guaiazulene sulfonate, menthol and vitamin E, and the plant compound fermentation extract is obtained by fermenting and purifying honeysuckle flowers, radix polygonati officinalis and dandelions according to a specific proportion. Through the synergistic effect of the fermentation extract and the functional components, the problems that an existing toothpaste body is hardened, the storage stability is poor, the gingival protecting effect is short, and the enamel repairing persistence is insufficient are solved, the gingival protecting effect can be enhanced, the enamel repairing effect can be improved, the stability of the toothpaste body can be optimized, the antibacterial property and the oral mucosa relieving effect are achieved, and the oral cavity repairing effect is achieved. And the preparation process is scientific and reasonable, and is suitable for daily oral care.

The invention discloses an electrolyte for water system energy storage and a preparation method and application thereof, and belongs to the technical field of electrochemical energy storage, the electrolyte for water system energy storage comprises a mixed salt and a mixed solvent, the mixed salt comprises a metal salt and an organic salt; the mixed solvent comprises water and an aprotic organic solvent; the organic salt is trifluoromethanesulfonate containing imidazole cations. Through the ion-solvent synergistic effect, an anion-rich and water-poor double-electrode-layer structure is formed on an electrode interface, dendritic crystal growth and side reaction are remarkably inhibited, and meanwhile high ionic conductivity is kept. The aqueous battery prepared from the electrolyte has good cycling stability and excellent practical performance under the conditions of low N / P ratio and low current density.

The invention belongs to the technical field of fine chemical organic synthesis, and discloses a synthesis method of 1, 3-propane sultone without generation of three wastes. The synthesis method comprises the following steps: by taking allyl alcohol, sulfite and hydrosulfite as raw materials, generating 3-hydroxy propanesulfonate; then removing part of water, adding a solvent A to separate out sulfite, filtering, and adding sulfuric acid into filtrate for acidification; and adding a solvent B to separate out sulfate, filtering and separating out the sulfate, and adding a dehydrating agent to carry out dehydration cyclization reaction to prepare the 1, 3-propane sultone. According to the synthesis method provided by the invention, a 1, 3-propane sultone product with the yield not lower than 95% and the purity reaching 99.9% or above and a sulfate byproduct with the purity reaching 99.6% or above can be obtained; no waste gas, waste solid or waste water is generated in the reaction process, the catalyst sulfite can be repeatedly used, and the used solvent is easy to recover and can be repeatedly used.

The invention is applicable to the technical field of polymer biomedical hydrogel materials, and provides a preparation method and application of multifunctional agarose-based particle composite hydrogel based on liquid-liquid phase separation, and the agarose-based particle composite hydrogel is a product formed by introducing microsphere particles into an agarose hydrogel body matrix; the microsphere particles are formed by a prepolymer and sodium lignin sulfonate through phase separation mediated by a composite behavior based on non-covalent interaction; the prepolymer is obtained by carrying out amine-epoxy reaction on an amino compound and an epoxy compound in water. According to the prepared agarose-based particle composite hydrogel, a microsphere particle structure is formed on the surface of an agarose matrix while positively charged amino groups and sodium lignin sulfonate are introduced, so that the multifunctional agarose-based particle composite hydrogel is prepared.

The invention provides a low-temperature electrolyte, a preparation method thereof and a lithium battery, and relates to the technical field of lithium batteries. The method provided by the invention comprises the following steps: adding a lithium salt and an electrolyte additive into an organic solvent, stirring and dissolving to obtain a low-temperature electrolyte; and the electrolyte additive comprises at least one of lithium nonafluoro-1-butane sulfonate, potassium bis (nonafluoro-1-butane sulfonimide) and potassium perfluorobutanesulfonate. The low-temperature electrolyte can effectively improve the ionic conductivity of the lithium battery, optimizes an SEI film and a CEI film on the surface of an electrode to inhibit the growth of lithium dendrites and the decomposition of the electrolyte, and reduces the energy barrier of lithium ions in the desolvation process during transmission to improve the capacity retention ratio of the lithium battery at low temperature.

The invention discloses a hydrogenation device scale inhibitor for heavy high-sulfur raw oil and a preparation method of the hydrogenation device scale inhibitor, and relates to the technical field of scale inhibitors. The scale inhibitor is prepared from a polyisobutylene succinimide dispersing agent, a high-temperature-resistant scale inhibition dispersing agent, an anti-rust agent, an imidazoline corrosion inhibitor, an antioxidant, a sulfide chelating agent, a clearing agent, cup carbazole alkylbenzene sulfonate and a solvent in specific parts by weight. The preparation method comprises the following steps: heating the solvent to 80-100 DEG C, sequentially adding the other components, and stirring for 30-40 minutes. Aiming at the characteristics of heavy high-sulfur raw oil, the scale inhibitor realizes high scale inhibition rate, excellent high-temperature stability and strong sulfur corrosion resistance through a multi-component synergistic effect, effectively solves the problems of scaling and corrosion of a hydrogenation device, prolongs the operation cycle of the device, and is suitable for a hydrogenation process of high-sulfur and high-asphaltene raw oil.

The invention relates to the technical field of paint removers, and particularly discloses a paint removal composition, a paint stain cleaning agent and application of the paint stain cleaning agent. The paint stain cleaning agent provided by the invention is prepared from the following components in parts by weight: 30 to 40 parts of EDTA-2Na (Ethylene Diamine Tetraacetic Acid), 200 to 300 parts of caustic soda flakes, 140 to 170 parts of sodium alcohol ether sulphate, 160 to 180 parts of sodium xylene sulfonate, 400 to 450 parts of monoethanolamine, 1100 to 1300 parts of diethylene glycol monobutyl ether, 250 to 300 parts of limonene, 40 to 100 parts of saponin extract and 3700 to 3900 parts of water, the saponin extract is selected from one or more of soapnut saponin, fenugreek saponin and aescin; the invention further provides a paint stain cleaning agent prepared from the paint removal composition and application of the paint stain cleaning agent to cleaning of protective clothing. The paint stain cleaning agent provided by the invention can quickly permeate into paint and the contact surface of the paint and protective clothing, so that the paint on the surface of the protective clothing is dissolved and effectively stripped.