529results about How to "Reduced Diffusion Resistance" patented technology

A polarizable electrode for an electric double layer capacitor includes an activated carbon powder, and a binder material mixed with the activated carbon. The amount of water contained in the polarizable electrode is 1500 ppm or less with respect to the weight of the polarizable electrode.

An adsorption module has heat medium pipes through which a fluid flows, a porous heat transferring member, and adsorbent. The porous heat transferring member is a sintered body formed by sintering a metallic material that is in a form of one of powders, particles and fibers, and has pores for allowing an adsorbed medium to pass through. The porous heat transferring member is disposed on peripheries of the heat medium pipes and bonded to outer surfaces of the heat medium pipes by sintering. The adsorbent is disposed in the pores. The porous heat transferring member further has an adsorbed medium passage for allowing the adsorbed medium to pass through. The adsorbed medium passage is located between the heat medium pipes, and extends straight and parallel to axes of the heat medium pipes.

The invention relates to a kind of method for manufacturing propylene by catalytic cracking alkene of no less than tetra carbon, which mainly solves the short catalyst regeneration period problem and the stability problems uninvolved in previous technique. The invention uses minor crystalline grain and molecular sieve with high silicon-aluminium ratio as the catalyst for catalytic cracking with alkene that no less than tetra carbon to manufacture propylene. According to the technique scheme that described above, the invention can solve the problems mentioned above excellently, and can be used in industrial production of manufacturing propylene by catalytic cracking with alkene.

An all-solid battery is formed so that an electrode active material layer of at least one of positive and negative electrodes has a composition distribution such that a local volume ratio, expressed by a ratio of a volume of an electrode active material contained in a part of the electrode active material layer with respect to a volume of a solid electrolyte material contained in the part of the electrode active material layer, increases as the part of the electrode active material layer approaches from an interface of the solid electrolyte layer toward an interface of a current collector in a thickness direction of the electrode active material layer, and a voidage of the electrode active material layer increases as the part of the electrode active material layer approaches from the interface of the solid electrolyte layer toward the interface of the current collector in the thickness direction.

The invention provides a lithium ion battery and a lithium-rich anode sheet. The lithium-rich anode sheet comprises: a current collector; and a diaphragm, which contains an active substance and is formed on the current collector, wherein the diaphragm and the current collector form an initial anode sheet. The current collector in the initial anode sheet is a porous current collector. The initial anode sheet is rich in lithium on one side, and the lithium rich amount matches the lithium supplement capacity needed by the initial anode sheet. The lithium ion battery includes: a cathode sheet; an anode sheet; an isolation membrane disposed between the cathode sheet and the anode sheet; and an electrolyte solution. The anode sheet is a lithium-rich anode sheet. The lithium-rich anode sheet of the lithium ion battery provided by the invention not only overcomes the excess lithium supplement problem in traditional lithium-rich anode sheets, and also can effectively control the lithium supplement amount of the anode so as to realize uniform lithium supplement and enhance the first coulombic efficiency of the lithium ion battery adopting the lithium-rich anode sheet. Thus, the energy density of the lithium ion battery is greatly improved, and the lithium ion battery can be ensured with better electrochemical properties.

The invention discloses a preparation method of a soft/hard carbon modified anode material for lithium ion batteries. The method comprises the following steps: (1) carrying out mixed granulation; (2)screening and crushing; (3) mixing; (4) treating at high temperature; (5) screening; (6) modifying; (7) carrying out secondary carbonization. The method is characterized in that a soft carbon precursor and a hard carbon precursor are both used as binding agents, kneading and granulating are carried out at a certain temperature and under other conditions, small graphite particles are polymerized soas to enable the internal structure to be further densified and increase the volume density, high-temperature graphitization is then performed, and asphalt and resin are converted to pyrolytic carbon, so that a soft/hard carbon graphite composite systems is formed; the surface of the modified soft/hard carbon composite anode material is evenly coated with a layer of Ti3SiC2, having good electrical conductivity and stable chemical properties, and a conductive network, so that the improvement of the discharge capacity, discharge efficiency and cycling stability of the graphite anode material isbetter promoted.

The invention provides a process nozzle and a system for gasifying water coal slurry. The process nozzle comprises a first oxygen channel, a water coal slurry channel, a second oxygen channel, a first cooling water jacket and a cooling water coil, wherein the first oxygen channel comprises a first oxygen channel inlet and a first oxygen channel outlet; the water coal slurry channel comprises at least one water coal slurry channel inlet and a water coal slurry channel outlet; the second oxygen channel comprises a second oxygen channel inlet and a second oxygen channel outlet; the first cooling water jacket comprises a first cooling water jacket inlet and a first cooling water jacket outlet; and the cooling water coil comprises a cooling water coil inlet and a cooling water coil outlet. The process nozzle is characterized in that: the first oxygen channel is positioned at the central position of the process nozzle; the water coal slurry channel is positioned between the first oxygen channel and the second oxygen channel and surrounds the periphery of the first oxygen channel; and the second oxygen channel surrounds the periphery of the water coal slurry channel. The process nozzle reduces the length of combustion flame more effectively, reduces the ablation of flame on a refractory brick, promotes the mixing and atomization of water coal slurry and oxygen and improves gasification efficiency.

The invention discloses a supported integrated catalyst for formaldehyde purification and a preparation method thereof. The supported integrated catalyst consists of a titanium dioxide nanotube array supporter and precious metal M, wherein the precious metal M is one or a mixture of at least two of Pt, Ru, Rh, Pd and Au. The titanium dioxide nanotube array supporter is soaked in a precursor solution containing the precious metal and then is roasted to obtain a precious-metal-component-supported catalyst, and the catalyst is reduced through hydrogen or a reducing solution and can be directly used for catalytically purifying formaldehyde. The catalyst is simple in composition and preparation flow, and convenient to popularize and apply. The high activity and stability of the catalyst on the formaldehyde can be kept at low temperature, the formaldehyde can be catalytically oxidized under the condition that other additional devices are not needed, and can be converted into harmless H2O and CO2, and thus the green elimination of the formaldehyde is further realized.

The invention discloses a thermal gravimetrical reactor applied to bulk specimen testing, belonging to testing equipment for performing thermo gravimetric analysis on specimens and aiming to solve the problems that small-mass and small-sized specimens are required and a sample vessel is unbeneficial to gas-solid reactions in the conventional thermo gravimetric analyzer. Through a high-temperature reactor, reaction gas is preheated fully, so that mass measuring errors caused by temperature change of the reaction atmosphere are avoided; two types of hanging baskets are specific to different specimens respectively, so that the diffusion resistance during the reactions of bulk specimens is reduced effectively, and complete reactions and measuring accuracy are ensured; the height of an electric heating furnace is adjusted through a hydraulic lifting platform, so that samples can be heated at constant temperature under a high-accuracy condition. The thermal gravimetrical reactor can be used for dynamically measuring the mass changes of bulk specimens at various heating rates or under a constant-temperature condition, and is more consistent with the requirements of scientific research production than the conventional thermal gravimetrical analyzer.

The invention discloses a mesoporous titanium-silicon molecular sieve, and a preparation method and application thereof. The titanium-silicon molecular sieve is a mesoporous nano titanium-silicon molecular sieve TS-1. The invention also discloses a novel catalyst for preparing an epoxy propane system through direct gas-phase epoxidation of propylene. Metal particles are loaded on the catalyst by taking the mesoporous nano titanium-silicon molecular sieve TS-1 provided by the invention as a supporter.

This invention relates to TiO2 photocatalysis materials preparation, particularly relates to a classification carbon-doped titanium dioxide catalyst material and preparation method. This invention is a kind of the carbon-doped titanium dioxide with mesoporous - macroporous grade pore structure, carbon 3-25%, anatase phase, the big channel pore size of 300-1000nm, mesoporous aperture 2.0-24nm, the specific surface area can be as high as 691m2/g. The described material is prepared by titanate and carbon mixture hydrolysis product of the roasting 300-600deg.C, and preparation of equipment used simple, the described materials in organic dye molecules have good catalytic properties on the photodegradation.

The invention discloses a high-safety all-solid-state lithium ion battery which comprises solid electrolyte, a positive plate and a negative plate, wherein the positive plate and the negative plate are overlapped with each other; the solid electrolyte is arranged between the positive plate and the negative plate adjacent to each other; the solid electrolyte is formed by mixing Li1+aAaSibO4 (A is one of Al, Mn, Ni and Ti, a is more than 1 and less than 2, and b is less than or equal to 2), an adhesive and a solvent according to a ratio of t:h:(1-t-h), wherein t is 30-55 percent, and h is 5-17 percent. The original combustible electrolyte and diaphragm are replaced by the noncombustible solid electrolyte, so that the risk that the battery is on fire is effectively reduced. When the solid electrolyte is in a slurry state, the battery is assembled, good contact between the solid electrolyte and a pole piece can be guaranteed, and ion diffusion impedance is reduced. The invention also discloses a method for producing the high-safety all-solid-state lithium ion battery.

The invention relates to a bioelectrode formed by a three-dimensional ordered porous oxide modified conductive film and a preparation method of the bioelectrode. The bioelectrode comprises a conductive film electrode which is formed on an insulation substrate, wherein the film electrode is formed on the insulation substrate in a deposition manner through a physical vapor deposition process; a three-dimensional ordered porous oxide layer containing redox proteins is prepared in situ on the surface of the film electrode; the redox proteins are fixed in pores of the three-dimensional ordered porous oxide layer by adopting an adsorption way, a crosslink way or a covalent bonding way. The pores in the three-dimensional ordered porous oxide layer of the bioelectrode are communicated with one another, so that the dispersion of analyte in an ordered porous material modified layer on the surface of the conductive film can be favored, the dispersion capacity of the analyte can be improved, a mesoporous structure which can be matched with different enzyme molecules can be obtained by utilizing different mesoporous structure guiding agents, and the fixation of the enzyme molecules can be favored. The bioelectrode has good biological compatibility, the fixing effect of the redox proteins is good, the dispersion resistance of the analyte is small, and the electron transmission efficiency is high, so that a biological sensor with high sensitivity can be provided.

The invention discloses a regeneration treatment method for a modified zeolite molecular sieve amination catalyst. The regeneration method comprises the following steps of: regenerating soluble coke by inorganic acid or organic acid; smelting most coking materials and non-framework aluminum formed by hydrothermal dealumination; and performing charking regeneration on the smelted zeolite molecular sieve amination catalyst by N2 and O2 mixed gas to completely remove non-smelted coke, so that the performance of the modified zeolite molecular sieve amination catalyst is recovered. By the regeneration treatment method, the problem of activity loss caused by the hydrothermal dealumination is solved; and the service life of the modified zeolite molecular sieve amination catalyst is prolonged. The regeneration treatment method is mainly applied to a regeneration treatment process of the modified zeolite molecular sieve amination catalyst under the ethanol amine and the ammonia condensation and amination reaction.

The invention discloses a method for preparing the molecular engram solid phase micro-extraction coat, which comprises following steps: alkali cleaning, acid cleaning, activating and silanizing quartz fiber; assembling the template molecular and functional nomomer; adding crosslinking agnet and initiator, inserting silanized quartz molecular and thermally initiating the polymerization; extracting out the fiber to be aged; repeating aforementioned steps to reach needed thickness of coat; washing and removing the template molecular. Compared with commercial coat, the Prometryne molecular engram solid phase micro-extraction coat prepared by said method has better molecular recognition function on the triazine herbicide, while said coat is in porous structure without broken in long service. And its thickness can be adjusted via the plating times with better repeating ability. The extracting head can be used with the liquid chromatography, to separated and collect the triazine herbicide in the complex base as environment sample and food.

The invention discloses a perforated positive plate of a lithium ion battery. The perforated positive plate comprises a current collector coated with a lithium-iron oxide layer, and active substance layers arranged on upper and lower surfaces of the current collector, wherein uniform diffusion through holes are formed on the active substance layers and the current collector. The preparation methodcomprises the following steps: firstly coating a layer of Li5FeO4 on the aluminum foil surface to provide redundant lithium source for the battery, thereby retarding the lithium ion with the negativepole first effect to form irreversible SEI film consumption and enhancing long circulation performance; secondly, increasing the energy density of the battery by using the positive electrode with high compaction and high surface density; and finally forming a perforated pole plate, wherein the electrolyte can sufficiently enter the internal of the active substance to increase the infiltration ofthe electrolyte and retarding the expansion of the active substance, and the perforated positive plate can be applied in the battery industrialization in large scale. The conventional perforated aluminum foil is obtained by coating after perforating, and the perforated positive plate is obtained by perforating after coating, so that the surface density of the active substance is higher, and the energy density of the battery is 30% higher in relative to the conventional perforated pole plate.

The invention discloses a device for producing coarse titanium tetrachloride by low-temperature fluidizing chlorination. The device comprises a furnace top, a furnace body and a furnace bottom, wherein the furnace bottom is provided with a gas distributor which is communicated with a gas inlet pipe and comprises a chassis and a plurality of gas nozzles uniformly distributed on the chassis; a gas outlet of each gas nozzle is upward; the furnace body is in a straight cylinder shape; the side wall of the furnace body is provided with a charging opening and a slag discharging opening; the charging opening is positioned at the bottom of the furnace body and is arranged opposite to the slag discharging opening; the arrangement position of the slag discharging opening is higher than that of the charging opening; and the vertical distance of the slag discharging opening to the charging opening is 1.2-2.2m. With the adoption of the device, production large scale is easily realized, static pressure and diffusion resistance in the furnace are reduced, the vibration strength of the furnace body is reduced; reverse backmixing of the gas is inhibited, the mass transfer and heat transfer rate are improved, the contact time and contact surface of carbide slag and chlorine are ensured, the transformation rate of TiC is improved; and the device is beneficial to continuous operation of a chlorination furnace and is convenient in manufacturing, transformation and maintenance compared with the traditional chlorination furnace.