3results about How to "Increased diffusion resistance" patented technology

The application discloses a lithium-free high-heat-resistant ceramic mud and a preparation method thereof, and relates to the technical field of ceramic materials. In the preparation of the lithium-free high-heat-resistant ceramic mud, alumina is reacted with 3-(2,3-epoxypropoxy) propyl trimethoxysilane to obtain pre-modified alumina; the pre-modified alumina is reacted with starch to obtain modified alumina; ethyl acetoacetate, isopropyl alcohol, zirconium oxychloride, aluminum sec-butoxide, polyvinylpyrrolidone and N-N dimethylformamide are mixed to form a spinning solution, the spinning solution is electrospun, and then immersed in yttrium oxide sol to obtain alumina-zirconia-yttria composite fibers; the modified alumina, talc, alumina-zirconia-yttria fibers, hydroxypropyl methyl cellulose, glycerol, oleic acid, polyethylene glycol and water are stirred and mixed, and vacuum pugging is carried out to obtain the lithium-free high-heat-resistant ceramic mud. The lithium-free high-heat-resistant ceramic mud prepared by the application has good thermal shock resistance and bending strength after sintering.

This invention discloses an electrochromic smart dimming film and its roll-to-roll preparation method. The dimming film employs an innovative four-layer structure, consisting of a first transparent conductive substrate, an electrochromic composite layer, a composite electrolyte layer with both ion conduction and storage functions, and a second transparent conductive substrate. By integrating the ion storage function into the electrolyte layer, the ion migration path is significantly shortened, thereby achieving an ultrafast response of less than or equal to 0.5 seconds and an ultra-long cycle life of ≥100,000 cycles. Its preparation utilizes a fully wet roll-to-roll coating process, including steps such as electrochromic layer coating and curing, electrolyte layer slot coating, roll lamination, and low-temperature curing. The product of this invention features a simplified structure, superior performance, low cost, and suitability for mass production, and can be widely applied in the automotive, consumer electronics, and building energy conservation fields.

A lithium-mediated electrochemical method for ammonia synthesis, relating to the field of ammonia synthesis technology, solves the technical problems of severe side reactions, limited nitrogen mass transfer, and poor interfacial stability in existing lithium-mediated ammonia synthesis systems. Tetra(4-formylphenyl)porphyrin iron and an amino-containing multifunctional organic ligand are added to a mixed solvent of n-butanol and o-dichlorobenzene. An acid catalyst is added, and after stirring until homogeneous, the mixture is degassed and sealed for reaction. The solid product is collected by centrifugation, washed, and dried to obtain COF powder. This powder is then added to an ethanol-water solution, followed by ultrasonic dispersion with Nafion solution. The powder is then drop-coated / sprayed onto the surface of a carbon paper current collector and dried. This powder is used as the working electrode, with a platinum mesh as the counter electrode, a platinum wire as the quasi-reference electrode, and a LiBF4 tetrahydrofuran solution as the electrolyte. Ethanol is used as the proton donor, and electrolysis is performed under a nitrogen atmosphere using a constant current. This invention can be applied to the field of ammonia synthesis technology.