The invention discloses an
ozone-assisted method for
catalytic decomposition of volatile organic pollutants in high-temperature
flue gas. According to the invention,
ozone gas is introduced into a
fixed bed reactor of a catalytic reaction. According to the catalyst in the
fixed bed reactor, carbon nano-tubes,
activated carbon,
titanium dioxide, silica, or a composition thereof is adopted as a carrier; and Mn2O3, MnO2, CeO2, CuO, Cu2O, V2O5, Fe2O3, FeO, or a composition thereof is adopted as an
active component. The
active component accounts for 1-50% of total
mass of the catalyst. The concentration of the introduced
ozone gas is in a range of 0.1-50mg / L. According to the invention, a strong oxidant ozone is introduced in a
catalytic decomposition process, such that
active oxygen in the
system is increased,
catalytic decomposition of
pollutant molecules is promoted, catalytic
decomposition efficiency of the catalyst upon the volatile organic pollutants is substantially improved, and
carbon dioxide selectivity is greatly improved. Therefore, an optimal effect of volatile organic
pollutant low-temperature catalytic
decomposition is achieved.