1466 results about "Calcium oxide" patented technology

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention belongs to the technical field of calcium hydroxide preparation, and particularly relates to a preparation method of calcium hydroxide with high specific surface area, which comprises the following steps: S1, adding triethanolamine and diethanolisopropanolamine into water, and uniformly mixing to obtain an active agent solution; s2, mixing quick lime with an active agent solution, and carrying out digestion reaction to generate a calcium hydroxide coarse material; and S3, sieving and drying the calcium hydroxide coarse material to obtain the calcium hydroxide with the high specific surface area. The specific surface area of calcium hydroxide can be remarkably increased through the active agent solution, meanwhile, the uniformity and sufficiency of the quick lime digestion reaction are optimized, the calcium hydroxide particle aggregation phenomenon is reduced, and finally the calcium hydroxide product with the high specific surface area and the high activity is prepared.

The invention belongs to the field of hydrometallurgy, and particularly discloses a high-purity vanadium oxide electrode and a preparation method thereof. The method comprises the following steps: pre-treating the alkaline vanadium leaching solution by using an activated aluminum oxide adsorption column to obtain a pre-treated solution; adding a composite impurity removal agent taking modified lignosulfonate as a main agent into the pretreatment liquid for primary impurity removal to obtain primary impurity-removed filtrate; adding a calcium hydroxide suspension and a flocculating agent into the primary impurity-removed filtrate for secondary impurity removal to obtain secondary impurity-removed filtrate; purifying the secondary impurity-removed filtrate by using an ion exchange column to obtain a purified solution; ammonium salt is added into the purified liquid for vanadium precipitation, and ammonium metavanadate crystals are obtained; calcining the ammonium metavanadate crystal to obtain high-purity vanadium pentoxide; and preparing the high-purity vanadium oxide electrode by using the high-purity vanadium pentoxide. According to the scheme, the high-purity vanadium pentoxide is prepared by taking the alkaline vanadium leaching solution as a raw material through a multi-stage deep impurity removal process, and the high-purity vanadium oxide electrode is prepared by taking the alkaline vanadium leaching solution as the raw material.

The invention relates to the technical field of environmental protection and dust removal, and discloses a dust removal device for calcium hydroxide product production, the dust removal device comprises a box body, the lower surface of the box body is provided with two sets of dust falling hoppers, the two sides of the box body are fixedly connected with an air inlet pipe and an air outlet pipe respectively, and the inner wall of the box body is provided with a partition plate. The driving assembly drives the pulse sliding pipe and the plugging assembly to move downwards, after the pulse sliding pipe and the plugging assembly move to a certain position, the control assembly controls the plugging assembly to plug a certain section of the filter cartridge, then the pulse mechanism enables gas to pass through the pulse main pipe, the pulse fixing pipe and the pulse sliding pipe, and then the gas is blown out from the pulse head. And then the driving assembly drives the blocking assembly to continue to move downwards, pulse dust removal is carried out on the filter cartridge section by section, pulse airflow accurately covers the whole section of the filter cartridge, it is ensured that dust on all parts can be thoroughly removed, and the dust removal effect is greatly improved.

The invention discloses a method for preparing calcium hydroxide slurry with high specific surface area and high pore volume, which comprises the following steps: S1, adding an alcohol reagent into water to obtain a solution A; s2, adding an inorganic salt solution into the solution A, and uniformly mixing to obtain a solution B; s3, a reagent X is added into the solution B, ultrasonic mixing is performed to obtain a solution C, and the reagent X is a mixture of phenol or triethanolamine, ethidene diamine and ethylamine; and S4, adding calcium oxide powder into the solution C, continuously stirring, and reacting to obtain calcium hydroxide slurry. The invention provides a method for preparing calcium hydroxide slurry with high specific surface area and high pore volume, the calcium hydroxide slurry prepared by the method can form calcium hydroxide with high specific surface area and high pore volume when in use, and the method aims to solve the problems of low specific surface area and low pore volume of the existing calcium hydroxide. Therefore, the problem of desulfurization performance inactivation caused by blockage of calcium hydroxide (desulfurizer) pores by generated CaSO3 and CaSO4 in the desulfurization process is avoided.

The invention discloses a method for preparing calcium hydroxide with high specific surface area and high pore volume by a semi-dry method, which comprises the following steps: S1, adding an alcohol reagent into water, and uniformly mixing to obtain a solution A; s2, adding a composite cationic surfactant into the solution A, and dissolving to obtain a solution B; s3, adding an iron salt solution into the solution B, and uniformly mixing to obtain a solution C; s4, adding triethanolamine into the solution C, and performing ultrasonic dissolution to obtain a solution D; and S5, spraying the solution D into calcium oxide powder, continuously stirring, and reacting to prepare calcium hydroxide with high specific surface area and high pore volume. The calcium hydroxide prepared by the method has a high specific surface area and a rich pore structure, is powdery after reaction, and is relatively low in water content.

The utility model discloses an ammonium sulfate wastewater treatment system which comprises an ammonium sulfate wastewater storage pool used for collecting ammonium sulfate wastewater, the calcium hydroxide preparation system is used for preparing a calcium hydroxide solution, an evaporator and a first circulating heater and is used for reacting ammonium sulfate wastewater and calcium hydroxide and heating and evaporating; the first crystallizer and the second circulating heater as well as the second crystallizer and the third circulating heater are used for two times of evaporative crystallization, a final concentrated solution is filtered by the filter and then flows into the mother liquor collecting tank to facilitate wastewater treatment, and evaporated ammonia gas is absorbed by the cooling absorption tower and the condensate collecting tank to form ammonia water; and condensate water of the second heat exchanger, the first circulating heater, the second circulating heater and the third circulating heater also flows back to the condensate collecting pool. According to the wastewater treatment system, ammonium sulfate wastewater and a calcium hydroxide solution are distilled and crystallized, so that calcium sulfate and ammonia water can be recovered, and waste utilization is realized.

The invention relates to the technical field of fireproof cables, and provides an aluminum alloy core fireproof cable and a preparation process thereof. An aluminum alloy core fireproof cable comprises a conductor, an insulating layer, a filling layer, a bundling heat insulation layer, an isolation layer, a fireproof layer and a sheath layer which are sequentially arranged from inside to outside, and the sheath layer comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride, 10-15 parts of a plasticizer, 10-15 parts of an ethylene-vinyl acetate copolymer, 25-30 parts of a flame retardant, 0.5-1.5 parts of an antioxidant, 10-20 parts of a filler and 0.5-1 part of a lubricant. The preparation method of the flame retardant comprises the following steps: mixing calcium oxide, magnesium oxide and zinc oxide, carrying out solid solution annealing to obtain a solid solution, and mixing the solid solution with aluminum hydroxide, ammonium polyphosphate and a metal acetylacetonate complex to obtain the flame retardant. According to the technical scheme, the problem of insufficient flame retardant property of the fireproof cable in the prior art is solved.

The invention discloses a preparation method of a rubber waterstop material with a low compression set rate, which comprises the following steps: firstly, carrying out blending reaction on hydroxyl silicone oil and boric acid to obtain liquid polyborosiloxane; the preparation method comprises the following steps: adding liquid polyborosiloxane and natural rubber into an internal mixer according to a ratio, and carrying out internal mixing to obtain a mixture; adding zinc oxide, an anti-aging agent, stearic acid and an anti-tearing agent into the obtained mixture, and continuously mixing; continuously adding kaolin talcum powder, calcium carbonate, calcium oxide, white carbon black, N550, N330 and KH550, and internally mixing again to obtain a preform; adding a vulcanization accelerator and a vulcanizing agent into the preform, and continuously mixing to obtain a rubber material to be vulcanized; and vulcanizing and forming the rubber material to be vulcanized to prepare the rubber water-stop belt material with the low compression set rate. According to the invention, the compression set rate of the rubber material can be reduced while the tensile strength, elongation, tear resistance and other properties of the rubber are not sacrificed, so that the product performance is enhanced.

The invention discloses an energy system and method for coupling calcium-based thermochemical heat storage and carbon capture. The energy system comprises a calcination unit, a carbon dioxide pretreatment storage unit, a calcium oxide heat exchange storage unit, a carbonation reaction unit and a heat utilization unit which are arranged based on a boiler. The calcining unit takes green valley electricity as energy to drive calcining reaction to realize heat storage, and generated CaO is processed by the calcium oxide heat exchange storage unit and then is stored for use in a heat release stage; generated COs are stored for standby application after passing through the carbon dioxide pretreatment storage unit; in the heat release stage, CaO and the desulfurized flue gas are subjected to heat release carbonation reaction in the carbonation reaction unit, and heat is released; caCO3 generated by the carbonation reaction can be used for the next heat storage stage; and the heat released by the carbonation reaction is conveyed to the heat utilization unit for heat exchange. Through coupling of calcium-based thermochemical heat storage and carbon capture, green electricity and off-peak electricity are fully utilized, and efficient storage and gradient utilization of energy are achieved.

The invention provides a method for decomposing and mineralizing fluorine-containing organic matter wastewater, which is applied to the technical field of treatment of fluorine-containing organic matter wastewater generated in a perfluoroether elastomer emulsion flocculation process, and comprises the following steps: S1, carrying out adsorption and desorption treatment on the fluorine-containing organic matter wastewater to obtain a concentrated solution of the fluorine-containing organic matter wastewater; s2, hydrogen peroxide and ferrous ions are added into a container containing the concentrated solution to obtain a mixed solution, the pH of the mixed solution is adjusted to be 2-4, the concentration mass ratio of the hydrogen peroxide to organic matter contained in the fluorine-containing organic matter wastewater is 1: 1-2, the molar ratio of the hydrogen peroxide to the ferrous ions is 1-6: 1, micro-nano bubbles are introduced into the mixed solution, and ultrasonic treatment is conducted; s3, calcium hydroxide is added into the treated mixed solution, calcium fluoride precipitates are obtained through centrifugal treatment, and the fluorine-containing organic matter in the wastewater can be degraded and mineralized.

The invention belongs to the technical field of coal combustion, and particularly relates to an environment-friendly rare earth catalyst as well as a preparation method and application thereof in promoting coal combustion. The catalyst is prepared from composite rare earth oxide, calcium oxide, potassium carbonate, ferrous sulfate, kaolin, diatomite and a multi-component composite assistant component in a specific proportion through the steps of slurry ultrasonic activation, rare earth coating, assistant step-by-step doping, microwave drying, protective atmosphere roasting and the like. The catalyst is unique in structure and good in dispersity, the coal combustion efficiency can be remarkably improved, the burnout temperature and the carbon content of fly ash are reduced, emission of flue gas pollutants such as CO, NOx and SO2 is effectively reduced, and the catalyst is suitable for the fields of energy conservation, carbon reduction and environment-friendly treatment of coal-fired power plants and industrial boilers.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for improving the leaching rate and the carbon adsorption rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; a green oxygen activating agent and hydrogen peroxide are sequentially added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore, ore pulp activating liquid is formed, and the green oxygen activating agent is a mixture of calcium oxide, sodium persulfate and soluble bivalent iron salt; and adding a gold leaching agent into the ore pulp activation solution, adjusting the pH value of the ore pulp to 9-12, carrying out stirring gold leaching treatment, filtering to obtain a leaching solution, and then adding activated carbon to adsorb and extract gold. According to the method, a stronger oxidation environment is provided, meanwhile, the residual concentration of arsenate radicals in the solution is effectively reduced, the leaching rate of gold and the adsorption rate of activated carbon are greatly increased, excellent oxidation performance and environment friendliness are shown, and a more sustainable high-sulfur-arsenic gold ore pretreatment process is provided.

The invention provides a preparation method and application of low-bath-ratio and high-viscosity hydroxypropyl carboxymethyl composite starch ether, and relates to the technical field of starch deep processing. The method comprises the following steps: S1, premixing corn starch with a compound base catalyst and magnesium stearate, and spraying an ethanol water solution for alkalization; s2, adding epoxypropane to carry out first-stage etherification, and then adding sodium chloroacetate to carry out second-stage etherification; and S3, after the reaction is finished, performing vacuum drying, crushing and sieving to obtain the high-viscosity hydroxypropyl carboxymethyl composite starch ether. Wherein the composite alkali catalyst comprises sodium hydroxide, sodium carbonate and calcium oxide. The starch ether obtained by the method has the advantages of high substitution degree, high viscosity, low solvent consumption and low energy consumption, and overcomes the defects of the traditional semi-dry method.

The invention relates to the technical field of lithium battery materials, in particular to a method for preparing battery-grade lithium carbonate from waste lithium batteries. The method comprises the following steps: disassembling, crushing and sieving a recycled lithium iron phosphate battery to obtain a crushed lithium battery material; a choline chloride-citric acid mixed solution is adopted to conduct leaching treatment on the crushed materials, and sulfuric acid is added to inhibit leaching of iron and phosphorus ions; filtering to obtain a first filtrate and a first filter residue; adding calcium hydroxide into the first filtrate, and filtering to obtain second filtrate and second filter residues; adsorbing the second filtrate with activated carbon to remove impurities, and filtering to obtain a third filtrate and a third filter residue; adding hydrochloric acid into the third filtrate to obtain a lithium chloride solution; carbonizing and converting the lithium chloride solution into a lithium carbonate solution; and carrying out gradient crystallization treatment on the lithium carbonate solution, pulping with pure water, and drying to obtain the high-purity lithium carbonate finished product. The method overcomes the problems of low lithium recovery rate, complex process, low lithium carbonate purity, large crystal particle size, more impurities and the like of the existing lithium iron phosphate battery.

This invention relates to a highly efficient functional ceramsite for purifying phosphorus-containing wastewater, its preparation method, and its application. Based on a complementary functional strategy, it uses natural clay rich in Al2O3 and SiO2 as a binder and calcium-rich industrial solid waste as the calcium-rich active component. Functional additives are also added to mitigate pH changes caused by calcium oxide reactions. The above raw materials are calcined at high temperature to obtain inexpensive, calcium-rich functional ceramsite with high mechanical strength, large adsorption capacity, and ecological safety. This effectively solves the common problems of increased water pH and poor phosphate adsorption capacity at neutral pH in calcium-based ceramsite, achieving highly efficient phosphorus purification in water. This invention uses inexpensive and readily available natural clay and calcium-rich industrial solid waste as raw materials, resulting in low cost, good effect, and effective application in the treatment of low-pollution water.

The invention relates to a waterproof sealing gasket material for a shield tunnel and a preparation method of the waterproof sealing gasket material. The preparation method comprises the following steps: plastifying raw rubber to obtain plastified raw rubber; the preparation method comprises the following steps: stirring and mixing plasticated raw rubber, carbon black N550, calcium carbonate, paraffin oil, zinc oxide, stearic acid, calcium oxide, an anti-aging agent and an organic magnesium compound, mixing in a mixing mill, and cooling to room temperature to obtain a mixture I; stirring and mixing the mixture I, modified NPE particles and an accelerant, mixing, and cooling to room temperature to obtain a mixture II; uniformly mixing the mixture II and sulfur in a mixing mill, vulcanizing at high temperature, and standing at room temperature for 24 hours to obtain the waterproof sealing gasket material. According to the waterproof sealing gasket material, the modified NPE particles of the core-shell structure are added, the compatibility of a water-swelling material and non-polar rubber is improved, the organic magnesium compound is added as a multifunctional auxiliary agent, the interface bonding, vulcanization network and flame retardant performance are synergistically improved, and the waterproof sealing gasket material has good waterproof performance. The prepared sealing gasket material has excellent mechanical properties, heat aging resistance, compression set resistance and flame retardance.

The invention relates to the technical field of lime manufacturing, and provides a process and a system for manufacturing high-purity lime. The process comprises the steps of raw material pretreatment, plasma surface pretreatment, segmented atmosphere calcination, sound wave reinforced mass transfer, heat energy comprehensive utilization and intelligent control, rapid cooling, flue gas treatment and finished product packaging. The system comprises a raw material pretreatment unit, a plasma surface pretreatment unit, a multi-section gradient atmosphere calcining kiln, a sound wave reinforced mass transfer system, a heat energy comprehensive utilization and intelligent control system, a carbon dioxide capturing and recycling unit and a finished product cooling and packaging unit. Through raw material deep purification, surface activation treatment, gradient calcination and atmosphere accurate control, sound wave mass transfer reinforcement, intelligent optimization regulation and control, rapid cooling and flue gas purification and resource recovery, the purity and the reaction activity of a calcium oxide product are synergistically improved, and the production energy consumption and pollutant emission are remarkably reduced; and high-efficiency, clean and resource production of the high-purity lime is realized.

The invention relates to a method for recovering lithium and fluorine from aluminum electrolysis hazardous waste, which comprises the following steps: firstly, mixing organic polyol and alkaline hydroxide according to a molar ratio of 1: (0.5-2) to obtain a eutectic solvent; heating the eutectic solvent to 80-150 DEG C, and adding a proper amount of raw material fine powder and calcium oxide for reaction leaching; carbonating and filtering the leachate to obtain lithium carbonate; washing the leaching residues with an acetic acid solution to obtain a calcium fluoride product; the concentration of fluorine ions in the leachate is smaller than or equal to 200 ppm, and the purity of calcium fluoride is larger than or equal to 90%; the leaching rate of lithium in the method is greater than 85%; the slag feeding rate of fluorine is greater than 95%; and no hydrogen fluoride gas is generated in the method. According to the method, a non-toxic and biodegradable eutectic solvent is adopted as a leaching agent, and efficient leaching of lithium and fluorine in the aluminum electrolysis dangerous waste materials is achieved; calcium oxide is used as a precipitating agent, free fluorine is promoted to be precipitated and recycled as calcium fluoride, the whole process meets the requirement of green metallurgy, and the win-win situation of resources and the environment is achieved.

Processes and apparatuses for degrading PFAS into calcium fluoride, carbon dioxide, and water. PFAS are heated and introduced to a calcium base which will degrade the PFAS. The PFAS may be in a stream that is a PFAS enriched stream formed by desorbing the PFAS from an adsorbent which removed the PFAS from a contaminant stream. The PFAS may be desorbed in the presence of the calcium base. The calcium base may be calcium hydroxide, calcium oxide, calcium carbonate, or combinations thereof.

The invention discloses a method for comprehensively recycling electrolytic aluminum carbon residues, and relates to the technical field of comprehensive recycling of waste materials. The method for comprehensively recycling the electrolytic aluminum carbon residues comprises the following steps of: breaking the carbon residues into 0.1-1cm particles by a hammer, carrying out wet ball milling under the condition of adding a flotation agent, and separating carbon powder on the upper layer and gray regenerated cryolite on the bottom layer of slurry through flotation equipment, wherein the fineness is 40-100 meshes, and the carbon content is less than 1%; the preparation method comprises the following steps: adding water into cryolite to prepare slurry, adding calcium oxide or calcium hydroxide, heating, stirring and reacting for 1-3 hours, and carrying out filter pressing to obtain filtrate and filter residues which are calcium fluoride and a sodium metaaluminate solution; the purity of the calcium fluoride powder is greater than 85%; and introducing hydrochloric acid into the filtrate, stirring and adjusting the pH to 7-9 to obtain aluminum hydroxide slurry, filtering and washing to obtain aluminum hydroxide, and drying to obtain the aluminum hydroxide with the purity of more than 95%.

The invention discloses artificial soil based on manganese slag, red mud and ardealite. The artificial soil is mainly prepared from a manganese slag-red mud-ardealite mixed matrix and a modifier, the weight ratio of the manganese slag to the red mud to the ardealite in the manganese slag-red mud-ardealite mixed matrix is (0.4-1.6): (0.1-0.5): (0.5-0.9); the modifier comprises calcium oxide, and further comprises rice straw, biochar, zeolite or a combination thereof, and the modifier accounts for 1-15% of the weight of the artificial soil. Accordingly, a corresponding preparation method is also established. According to the method, the three solid wastes are mixed according to the characteristics, so that specific pollutants such as ammonia nitrogen, phosphorus, fluorine and Mn < 2 + > can be fixed, the reduction of heavy metals is realized, the nutrients beneficial to plant growth are reserved, the artificial soil with rich nutrients is synchronously reconstructed, the qualitative change from waste residues to resources is realized, the process is simple, and the effect is good. The obtained artificial soil can be used for greening planting, supplementing manganese ore, aluminum ore and phosphorite surrounding soil deficiency areas, and solving the problems of no soil, ploughability and ecological restoration of mining areas.

The invention discloses a method for preparing calcium hydroxide with a high specific surface area by digesting calcium oxide, and relates to the technical field of preparation of calcium hydroxide with a high specific surface area. The method is characterized in that diethylene glycol / triethanolamine / magnesium chloride is adopted as a compound digestion aid through two processes of wet digestion and dry digestion; and calcium hydroxide with high specific surface area can be controllably prepared. The specific surface area of the calcium hydroxide prepared through wet digestion can reach 70 m < 2 >. G <-1 > or above, the specific surface area of the calcium hydroxide prepared through dry digestion is 45 m < 2 >. G <-1 > or above, the reaction activity of the calcium hydroxide is effectively improved, and the novel controllable method for preparing the calcium hydroxide with the high specific surface area is provided.

The invention discloses a CO2 mineralized solid waste-based cementing material for a refractory material, the CO2 mineralized solid waste-based cementing material comprises aluminate cement and a solid waste material subjected to CO2 mineralization treatment, and the solid waste material contains components capable of being subjected to mineralization reaction with carbon dioxide. According to the invention, the mineralizable solid waste material is mineralized by using carbon dioxide, and then the mineralized solid waste material is mixed with aluminate cement to obtain the cementing material, so that components such as free calcium oxide in the solid waste material are effectively stabilized, and unstable factors in the solid waste material are solved; in addition, the solid waste material subjected to CO2 mineralization treatment can promote generation of C2ASH8, so that crystal phase transformation of CAH10 and C2AH8 in the aluminate cement is inhibited, the problem that the later strength of the aluminate cement is reduced can be effectively solved, and the performance of the cement can be improved.

The invention discloses a molybdenum-vanadium-aluminum intermediate alloy and a low-cost preparation method thereof. The molybdenum-vanadium-aluminum intermediate alloy comprises the following chemical components in percentage by mass: 39-41% of Mo, 39-41% of V and the balance of Al. The method comprises the following steps: uniformly mixing vanadium oxide (tablets replace powder), molybdenum trioxide, metal aluminum, calcium fluoride, calcium oxide and a cold material according to a mass ratio of (28-32): (24-26): (32-35): (10-13): (1.5-4): (5-10); then putting the mixture into a graphite crucible for tamping treatment; and finally, the metal powder is directly ignited for a reduction reaction, and the molybdenum-vanadium-aluminum intermediate alloy can be obtained. According to the method, the recovery rates of the molybdenum and the vanadium are increased by adjusting the components and the ratio of the raw materials and the auxiliary materials and adopting a one-step aluminothermic reduction method, and the recovery rates of the molybdenum and the vanadium can reach 95 wt% or above and 96 wt% or above respectively.

The invention relates to the technical field of packaging materials, in particular to a manufacturing method of an industrial byproduct semi-hydrated gypsum hollow plastic plate. The plastic plate is prepared from the following components in parts by weight: 60 to 70 parts of superfine modified semi-hydrated phosphogypsum powder, 28 to 35 parts of polypropylene resin, 0.5 to 1.5 parts of slipping agent, 0.5 to 1.5 parts of dispersing agent, 0.5 to 1.5 parts of antistatic agent, 0.3 to 0.8 part of antioxidant, 5 to 10 parts of calcium oxide and 3 to 6 parts of polyolefin elastomer. The gypsum powder subjected to purification, calcination and quaternary ammonium / stearic acid surface treatment has oleophylic and hydrophobic properties, and 65% high-proportion filling can be realized; the light moisture-proof plate with the density of 0.75-0.95 g / cm < 3 > and the thickness of 3-6 mm is obtained by matching with a double-screw granulation process and a single-screw hollow plate extrusion process, the use amount of resin is reduced, the mechanical property and the heat resistance are obviously superior to those of a single surface modifier, and high-value utilization of ardealite resources is realized.

The invention provides a bridge anti-disturbance concrete material and a preparation method thereof, and belongs to the technical field of building materials, the bridge anti-disturbance concrete material comprises a gel material, a reinforcing material and a functional additive; the reinforcing material comprises fibers, modified styrene butadiene rubber particles and self-repairing capsules; the self-repairing capsule comprises a water phase and an oil phase, the water phase contains nano calcium oxide, and the oil phase contains an HDI-ethylenediamine copolymer. The invention provides a bridge anti-disturbance concrete material and a preparation method thereof. The adaptability of concrete to high-frequency vibration and extremely low-temperature environments is improved.

A process produces high-purity vanadium chemicals from vanadium raw materials having high molybdenum contents. Molybdenum is selectively precipitated via vanadium from alkaline vanadate solutions using the following process steps: providing a molybdenum-containing alkaline vanadate solution, adding calcium hydroxide as a precipitant in portions while keeping the pH constant between 6 and 7 using acid, mixing the solution, solid-liquid separation of the resulting suspension, and further processing the low-molybdenum alkaline vanadate solution to produce a high-purity vanadium chemical having a molybdenum content of at most 500 ppm.

The present invention provides a calcium-based thermochemical heat storage material modified with high-entropy fluorite oxide and a preparation method thereof. The material comprises a calcium-based material and a high-entropy fluorite oxide, with the calcium-based material accounting for 70-85% by mass. The calcium-based material is calcium oxide, and the high-entropy fluorite oxide is a fluorite-structured oxide formed by zirconium, cerium, lanthanum, neodymium, and ytterbium, with a molar ratio of 1:1:1:1:1 for the oxides of zirconium, cerium, lanthanum, neodymium, and ytterbium. The invention utilizes the high-entropy fluorite oxide as an anti-sintering component to disperse calcium oxide and prevent its sintering, while simultaneously promoting the adsorption, dissociation, and migration of CO2 on the surface of the material, thereby enhancing the cycling stability and energy density of the heat storage material.

The invention discloses a method for preparing an environment-friendly magnesium aluminate spinel raw material by utilizing industrial solid wastes, and relates to the technical field of magnesium aluminate spinel raw material production. The method comprises the following steps: a, raw material synergistic purification treatment: crushing magnesium slag into coarse particles, and mixing the coarse particles with aluminum ash raw powder which is not subjected to desalting treatment according to a mass ratio of (1-3): 1 to obtain a mixture; the mixture is subjected to first heat treatment at the temperature of 450-650 DEG C in a non-oxidizing atmosphere, and heat preservation is conducted for 1-3 h; according to the method, two industrial solid wastes, namely the magnesium slag and the aluminum ash, are subjected to direct synergistic heat treatment in a non-oxidizing atmosphere, and chloride impurities in the aluminum ash are used for synchronously removing free calcium oxide on the surface of the magnesium slag and removing part of soluble salt of the aluminum ash in the volatilization and migration process, so that coupling purification of treating wastes with wastes is realized; the problem that various solid wastes need to be subjected to complex pretreatment in a traditional process is solved, the process is simplified, the impurity removal efficiency is improved, and meanwhile the risk of environmental pollution caused by solid waste stockpiling or landfill is reduced.