2024 results about "Calcium oxide" patented technology

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention provides a cement paste system with high strength, elasticity and toughness and application of the cement paste system in deep coal bed gas horizontal well cementation, and the cement paste system is prepared from the following raw materials in parts by mass: 40-70 parts of oil well cement, 13-40 parts of fly ash, 15-45 parts of slag, 5.0-20.0 parts of water-based organic silicon resin, 0.1-0.5 part of ultra-high performance polyethylene fiber, 3.0-8.0 parts of calcium oxide and 2.0-5.0 parts of calcium sulfate whisker. 1.0-8.0 parts of nano silicon dioxide, 1.0-6.0 parts of a fluid loss agent, 0.5-2.0 parts of a drag reducer, 0.2-1 part of a defoaming agent and 50-80 parts of water. The cement paste system disclosed by the invention has the characteristics of remarkable low-temperature quick setting and high early strength, also has the advantages of low water loss, controllable thickening, simple preparation operation and the like, and set cement is high in compressive strength, high in breaking strength and very excellent in elastic and tough mechanical properties.

The invention belongs to the technical field of calcium hydroxide preparation, and particularly relates to a preparation method of calcium hydroxide with high specific surface area, which comprises the following steps: S1, adding triethanolamine and diethanolisopropanolamine into water, and uniformly mixing to obtain an active agent solution; s2, mixing quick lime with an active agent solution, and carrying out digestion reaction to generate a calcium hydroxide coarse material; and S3, sieving and drying the calcium hydroxide coarse material to obtain the calcium hydroxide with the high specific surface area. The specific surface area of calcium hydroxide can be remarkably increased through the active agent solution, meanwhile, the uniformity and sufficiency of the quick lime digestion reaction are optimized, the calcium hydroxide particle aggregation phenomenon is reduced, and finally the calcium hydroxide product with the high specific surface area and the high activity is prepared.

The invention provides a modified coal gangue-based large-flow-state grouting and water plugging material and a preparation method thereof. Comprising 80-90 parts of a coal gangue sample, 1-5 parts of Portland cement, 1-5 parts of sulphoaluminate cement, 0.51-3 parts of a polycarboxylic acid water reducing agent, 1-4 parts of cellulose ether with the viscosity of 200w, 0.1-5 parts of a calcium oxide expanding agent, 0.5-5 parts of a plastic expanding agent, 0.5-1 part of redispersible latex powder, 0.5-5 parts of polyacrylamide with the molecular weight of 1000 and water, and the water-material ratio is 0.4. According to the modified coal gangue-based large-flow-state grouting and water plugging material and the preparation method thereof, the cement consumption can be remarkably reduced, the cost is reduced, the utilization rate of solid wastes (such as coal gangue) is increased, and the material has good flow-state performance and adjustable setting time; the method is suitable for deep and large shaft surrounding rock water seepage treatment in coal mining and other mine engineering.

The invention discloses a special phosphorus removal agent for deep phosphorus removal and a preparation method and application thereof, and relates to the field of phosphorus removal agents and preparation methods thereof.The phosphorus removal agent is prepared from a porous precursor, an activating agent and a dispersing agent, and the porous precursor comprises at least one of aluminum oxide, iron oxide, calcium oxide and magnesium oxide; the activating agent comprises at least one of lanthanum salt, cerium salt, zircon salt, magnesium salt and ferric salt. By optimizing the composition of the porous precursor and activating treatment, the phosphorus adsorption capacity is remarkably improved, the phosphorus removal agent also plays a role in micro-flocculation in the process of mixed adsorption with sewage, a wet adding mode is adopted, the adding amount can be flexibly adjusted according to the phosphorus concentration condition of inlet water and outlet water, and the phosphorus removal efficiency is improved. The phosphorus removal agent can reduce the total phosphorus concentration in tail water of a sewage treatment plant to 0.5 mg / L or below.

The invention discloses high-strength concrete and a preparation method thereof in the field of concrete. The high-strength concrete is prepared from the following raw materials in parts by weight: superfine sulphoaluminate cement; coarse aggregate; quartz sand; silica fume; coal ash; nano metakaolin; silicon carbide whiskers; a graphene oxide; a pH responsive microcapsule; coating the steel fibers with liquid metal; a carbon nanotube; and a polycarboxylic acid water reducer. Release of the repairing agent is accurately regulated and controlled by adopting the pH response microcapsule, the interface performance is enhanced by combining with the liquid metal coating steel fiber, and the composite dispersion process of the nano material is optimized. Wherein the environment response efficiency of the microcapsule is remarkably improved through the collaborative design of a calcium oxide-slow release agent system and a methyl methacrylate / acrylic acid copolymerization shell layer; according to the gallium-based liquid metal coating, metallurgical bonding of fibers and a matrix is achieved through the low-melting-point characteristic, and traditional physical bonding limitation is broken through.

The invention discloses a coal gasification slag-based backfill material for replacing flow-state solidified soil, a preparation method and an application, utilizes a synergistic gelling effect among three raw materials, breaks through a material strength forming mechanism of traditional flow-state solidified soil, solves the problems of multiple components and high cost of a flow-state solidified soil material in the prior art, and has the advantages of low raw material cost, low raw material cost, low raw material cost, low raw material cost and the like. And the product popularization is facilitated. The specific scheme is as follows: the coal gasification slag-based backfill material for replacing the fluidized stabilized soil comprises coal gasification slag, carbide slag and titanium gypsum, the ratio of the coal gasification slag to the carbide slag to the titanium gypsum is 6-8: 1.5-3.5: 0.5-1.5, and an alkaline activator is also added; the coal gasification slag is a slag block with a set particle size formed after slag at the bottom of a gasification furnace is cooled, the carbide slag is waste slag which takes calcium oxide as a main component after acetylene gas is obtained by hydrolyzing calcium carbide, and under the action of an exciting agent, the coal gasification slag and the carbide slag are fully activated to release polyhedrons; part of the polyhedrons form a gelling product so as to improve the early strength of the coal gasification slag-based backfill material.

The invention belongs to the field of hydrometallurgy, and particularly discloses a high-purity vanadium oxide electrode and a preparation method thereof. The method comprises the following steps: pre-treating the alkaline vanadium leaching solution by using an activated aluminum oxide adsorption column to obtain a pre-treated solution; adding a composite impurity removal agent taking modified lignosulfonate as a main agent into the pretreatment liquid for primary impurity removal to obtain primary impurity-removed filtrate; adding a calcium hydroxide suspension and a flocculating agent into the primary impurity-removed filtrate for secondary impurity removal to obtain secondary impurity-removed filtrate; purifying the secondary impurity-removed filtrate by using an ion exchange column to obtain a purified solution; ammonium salt is added into the purified liquid for vanadium precipitation, and ammonium metavanadate crystals are obtained; calcining the ammonium metavanadate crystal to obtain high-purity vanadium pentoxide; and preparing the high-purity vanadium oxide electrode by using the high-purity vanadium pentoxide. According to the scheme, the high-purity vanadium pentoxide is prepared by taking the alkaline vanadium leaching solution as a raw material through a multi-stage deep impurity removal process, and the high-purity vanadium oxide electrode is prepared by taking the alkaline vanadium leaching solution as the raw material.

The invention relates to the technical field of ceramic substrates, and provides a bending-resistant aluminum oxide multilayer ceramic substrate and a preparation method thereof. The bending-resistant aluminum oxide multilayer ceramic substrate comprises the following raw material components in parts by weight: 95-110 parts of aluminum oxide, 3-8 parts of a plasticizer, 6-12 parts of an auxiliary agent, 4-7 parts of a binder, 3-6 parts of a dispersant and 60-70 parts of a solvent, the preparation method of the additive comprises the following steps: A1, adding calcium oxide into ethanol, adding glucose, stirring until the materials are uniformly mixed, and concentrating to obtain a glucose coated material; a2, carrying out annealing treatment on the glucose coated material to obtain a carbon coated material; and A3, uniformly mixing the carbon-coated material with magnesium oxide and titanium dioxide, and carrying out ball milling to obtain the auxiliary agent. According to the technical scheme, the problem of low mechanical property of the aluminum oxide ceramic substrate in the prior art is solved.

The invention relates to the technical field of environmental protection and dust removal, and discloses a dust removal device for calcium hydroxide product production, the dust removal device comprises a box body, the lower surface of the box body is provided with two sets of dust falling hoppers, the two sides of the box body are fixedly connected with an air inlet pipe and an air outlet pipe respectively, and the inner wall of the box body is provided with a partition plate. The driving assembly drives the pulse sliding pipe and the plugging assembly to move downwards, after the pulse sliding pipe and the plugging assembly move to a certain position, the control assembly controls the plugging assembly to plug a certain section of the filter cartridge, then the pulse mechanism enables gas to pass through the pulse main pipe, the pulse fixing pipe and the pulse sliding pipe, and then the gas is blown out from the pulse head. And then the driving assembly drives the blocking assembly to continue to move downwards, pulse dust removal is carried out on the filter cartridge section by section, pulse airflow accurately covers the whole section of the filter cartridge, it is ensured that dust on all parts can be thoroughly removed, and the dust removal effect is greatly improved.

The invention discloses a method for preparing calcium hydroxide slurry with high specific surface area and high pore volume, which comprises the following steps: S1, adding an alcohol reagent into water to obtain a solution A; s2, adding an inorganic salt solution into the solution A, and uniformly mixing to obtain a solution B; s3, a reagent X is added into the solution B, ultrasonic mixing is performed to obtain a solution C, and the reagent X is a mixture of phenol or triethanolamine, ethidene diamine and ethylamine; and S4, adding calcium oxide powder into the solution C, continuously stirring, and reacting to obtain calcium hydroxide slurry. The invention provides a method for preparing calcium hydroxide slurry with high specific surface area and high pore volume, the calcium hydroxide slurry prepared by the method can form calcium hydroxide with high specific surface area and high pore volume when in use, and the method aims to solve the problems of low specific surface area and low pore volume of the existing calcium hydroxide. Therefore, the problem of desulfurization performance inactivation caused by blockage of calcium hydroxide (desulfurizer) pores by generated CaSO3 and CaSO4 in the desulfurization process is avoided.

The utility model relates to the technical field of limestone calcination, in particular to a limestone calcination device which comprises a rotary kiln and a preheater, a coarse material bin, a first preheating area, a second preheating area and a discharging chute are distributed in the preheater from top to bottom, and a coarse material inlet is formed in the top of the coarse material bin. The coarse material bin is communicated with the first preheating area through a plurality of blanking pipes, a preheating table used for receiving blanking materials is arranged in the second preheating area, the preheater is provided with a material pushing mechanism used for pushing the materials on the preheating table into the discharging chute, and a fine material inlet is formed in the side wall of the preheater in the second preheating area. And the fine material inlet is externally connected with a fine material feeding mechanism. By using the device, the preheating effect of coarse material particles and fine material particles is improved, the coarse material particles and the fine material particles can be decomposed more completely after entering the rotary kiln, the quality of calcium oxide is improved, in the whole production process, the energy loss is reduced, the utilization rate of raw materials and resources and the overall production efficiency are improved, and the production cost is greatly saved.

The invention discloses a perfluorohexanone fire extinguishing agent and a preparation method and application thereof.The perfluorohexanone fire extinguishing agent is prepared from, by mass, 60-70 parts of perfluorohexanone microcapsules, 10-20 parts of aluminum hydroxide, 6-10 parts of graphite, 5-10 parts of titanium dioxide, 4-8 parts of ultraviolet absorbent, 2-6 parts of ammonium polyphosphate, 3-6 parts of calcium oxide, 1-3 parts of fumed silica, 1-3 parts of nano-silica and 1-3 parts of trimethyl phosphate. According to the formula and process of the fire extinguishing agent, through triple technical innovation of shell layer modification, nano compounding and supercritical deposition, the breakthrough of efficient explosion suppression, long-acting anti-after-combustion, low toxicity and environment friendliness of the fire extinguishing agent is achieved, and the industrial popularization potential is achieved.

The invention discloses a multi-component nano inhibitor for flotation separation of high-argillaceous copper sulphide ore and application, the nano inhibitor is a nano calcium carbonate-calcium oxide-sodium humate coating body, the nano inhibitor is applied to flotation separation of the high-argillaceous copper sulphide ore, collaborative optimization of slime inhibition and copper ore selective collection is achieved, and the flotation separation efficiency of the high-argillaceous copper sulphide ore is improved. And high-quality copper sulfide concentrate and sulfur concentrate are obtained. According to the method, the high specific surface area and the surface activity of the nano particles are utilized, under the weak alkaline environment without desliming, through the simple, convenient, economical and efficient mineral processing technology and reagent combination, efficient recovery of copper, gold and sulfur in the high-argillaceous ore is achieved, the use amount of lime is greatly reduced, and the technical problem of tailing sedimentation is solved.

The present invention discloses a kind of preparation method and use method of anti-abrasion concrete admixture under freeze-thaw-solution environment, the admixture includes the components of following parts by weight:50~60 parts of STG powder, 5~8 parts of polyimide fibers, 1~3 parts of hydroxypropyl methyl (HPMC) cellulose, 10~13 parts of polycarboxylate water-reducing agent, 10~15 parts of antifreeze, 10~13 parts of expansion agent, wherein STG powder includes modified silica fume-glass powder, silicon carbide titanium, graphene oxide. Anti-abrasion concrete admixture under freeze-thaw-solution environment of the present invention can effectively suppress the decomposition of calcium hydroxide, and can refine pore structure, make hydraulic concrete more compact, while improving the ability of hydraulic concrete to resist dissolution, enhance its anti-abrasion performance, the admixture has good low temperature resistance, can be applicable to cold low temperature environment, for the anti-abrasion strength under low temperature conditions there is obvious improvement.

The invention discloses a waste incineration fly ash coupling sodium-based waste salt harmless treatment resource utilization method, which comprises the following steps: preparing household waste incineration fly ash and sodium-based waste salt according to a dry basis molar content ratio of (1-1.05): 1, uniformly mixing, and carrying out heat treatment at 450-500 DEG C to obtain an ash-salt mixture; washing with water to remove chlorine salt and heavy metal to obtain a chlorine salt solution and a mud cake; treating the chlorine salt solution to obtain industrial regenerated salt sodium chloride and potassium chloride; pulping the mud cake, adding a flotation agent for flotation to obtain flotation residues and industrial dihydrate gypsum, and preparing alpha gypsum from the industrial dihydrate gypsum by using a dry method; and after flotation, feeding residues into a grinding unit for grinding to obtain the desulfurizer. According to the method, the fly ash and the sodium-based waste salt are subjected to coupling treatment in one set of equipment, potassium chloride, sodium chloride, gypsum, calcium carbonate, calcium hydroxide and the like in the waste incineration fly ash and the sodium-based waste salt are effectively and respectively treated into products for all purposes, recycling of all valuable components is achieved, and the resource utilization value is high.

The invention discloses a method for preparing calcium hydroxide with high specific surface area and high pore volume by a semi-dry method, which comprises the following steps: S1, adding an alcohol reagent into water, and uniformly mixing to obtain a solution A; s2, adding a composite cationic surfactant into the solution A, and dissolving to obtain a solution B; s3, adding an iron salt solution into the solution B, and uniformly mixing to obtain a solution C; s4, adding triethanolamine into the solution C, and performing ultrasonic dissolution to obtain a solution D; and S5, spraying the solution D into calcium oxide powder, continuously stirring, and reacting to prepare calcium hydroxide with high specific surface area and high pore volume. The calcium hydroxide prepared by the method has a high specific surface area and a rich pore structure, is powdery after reaction, and is relatively low in water content.

The present application pertains to processes for making calcium oxide and / or sulfuric acid from calcium sulfate. In some embodiments the processes comprise reacting a component comprising calcium sulfate with a second component comprising magnesium sulfite under conditions to form a solid comprising calcium sulfite and a solution comprising magnesium sulfate. Next, at least a portion of the solid comprising calcium sulfite is decomposed to form a second solid comprising calcium oxide, or calcium hydroxide, or cement, or clinker, or any combination thereof.

The utility model discloses an ammonium sulfate wastewater treatment system which comprises an ammonium sulfate wastewater storage pool used for collecting ammonium sulfate wastewater, the calcium hydroxide preparation system is used for preparing a calcium hydroxide solution, an evaporator and a first circulating heater and is used for reacting ammonium sulfate wastewater and calcium hydroxide and heating and evaporating; the first crystallizer and the second circulating heater as well as the second crystallizer and the third circulating heater are used for two times of evaporative crystallization, a final concentrated solution is filtered by the filter and then flows into the mother liquor collecting tank to facilitate wastewater treatment, and evaporated ammonia gas is absorbed by the cooling absorption tower and the condensate collecting tank to form ammonia water; and condensate water of the second heat exchanger, the first circulating heater, the second circulating heater and the third circulating heater also flows back to the condensate collecting pool. According to the wastewater treatment system, ammonium sulfate wastewater and a calcium hydroxide solution are distilled and crystallized, so that calcium sulfate and ammonia water can be recovered, and waste utilization is realized.

The invention relates to the technical field of fireproof cables, and provides an aluminum alloy core fireproof cable and a preparation process thereof. An aluminum alloy core fireproof cable comprises a conductor, an insulating layer, a filling layer, a bundling heat insulation layer, an isolation layer, a fireproof layer and a sheath layer which are sequentially arranged from inside to outside, and the sheath layer comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride, 10-15 parts of a plasticizer, 10-15 parts of an ethylene-vinyl acetate copolymer, 25-30 parts of a flame retardant, 0.5-1.5 parts of an antioxidant, 10-20 parts of a filler and 0.5-1 part of a lubricant. The preparation method of the flame retardant comprises the following steps: mixing calcium oxide, magnesium oxide and zinc oxide, carrying out solid solution annealing to obtain a solid solution, and mixing the solid solution with aluminum hydroxide, ammonium polyphosphate and a metal acetylacetonate complex to obtain the flame retardant. According to the technical scheme, the problem of insufficient flame retardant property of the fireproof cable in the prior art is solved.

The invention discloses a preparation method of a rubber waterstop material with a low compression set rate, which comprises the following steps: firstly, carrying out blending reaction on hydroxyl silicone oil and boric acid to obtain liquid polyborosiloxane; the preparation method comprises the following steps: adding liquid polyborosiloxane and natural rubber into an internal mixer according to a ratio, and carrying out internal mixing to obtain a mixture; adding zinc oxide, an anti-aging agent, stearic acid and an anti-tearing agent into the obtained mixture, and continuously mixing; continuously adding kaolin talcum powder, calcium carbonate, calcium oxide, white carbon black, N550, N330 and KH550, and internally mixing again to obtain a preform; adding a vulcanization accelerator and a vulcanizing agent into the preform, and continuously mixing to obtain a rubber material to be vulcanized; and vulcanizing and forming the rubber material to be vulcanized to prepare the rubber water-stop belt material with the low compression set rate. According to the invention, the compression set rate of the rubber material can be reduced while the tensile strength, elongation, tear resistance and other properties of the rubber are not sacrificed, so that the product performance is enhanced.

The invention discloses an energy system and method for coupling calcium-based thermochemical heat storage and carbon capture. The energy system comprises a calcination unit, a carbon dioxide pretreatment storage unit, a calcium oxide heat exchange storage unit, a carbonation reaction unit and a heat utilization unit which are arranged based on a boiler. The calcining unit takes green valley electricity as energy to drive calcining reaction to realize heat storage, and generated CaO is processed by the calcium oxide heat exchange storage unit and then is stored for use in a heat release stage; generated COs are stored for standby application after passing through the carbon dioxide pretreatment storage unit; in the heat release stage, CaO and the desulfurized flue gas are subjected to heat release carbonation reaction in the carbonation reaction unit, and heat is released; caCO3 generated by the carbonation reaction can be used for the next heat storage stage; and the heat released by the carbonation reaction is conveyed to the heat utilization unit for heat exchange. Through coupling of calcium-based thermochemical heat storage and carbon capture, green electricity and off-peak electricity are fully utilized, and efficient storage and gradient utilization of energy are achieved.

The invention provides a method for decomposing and mineralizing fluorine-containing organic matter wastewater, which is applied to the technical field of treatment of fluorine-containing organic matter wastewater generated in a perfluoroether elastomer emulsion flocculation process, and comprises the following steps: S1, carrying out adsorption and desorption treatment on the fluorine-containing organic matter wastewater to obtain a concentrated solution of the fluorine-containing organic matter wastewater; s2, hydrogen peroxide and ferrous ions are added into a container containing the concentrated solution to obtain a mixed solution, the pH of the mixed solution is adjusted to be 2-4, the concentration mass ratio of the hydrogen peroxide to organic matter contained in the fluorine-containing organic matter wastewater is 1: 1-2, the molar ratio of the hydrogen peroxide to the ferrous ions is 1-6: 1, micro-nano bubbles are introduced into the mixed solution, and ultrasonic treatment is conducted; s3, calcium hydroxide is added into the treated mixed solution, calcium fluoride precipitates are obtained through centrifugal treatment, and the fluorine-containing organic matter in the wastewater can be degraded and mineralized.

The invention belongs to the technical field of coal combustion, and particularly relates to an environment-friendly rare earth catalyst as well as a preparation method and application thereof in promoting coal combustion. The catalyst is prepared from composite rare earth oxide, calcium oxide, potassium carbonate, ferrous sulfate, kaolin, diatomite and a multi-component composite assistant component in a specific proportion through the steps of slurry ultrasonic activation, rare earth coating, assistant step-by-step doping, microwave drying, protective atmosphere roasting and the like. The catalyst is unique in structure and good in dispersity, the coal combustion efficiency can be remarkably improved, the burnout temperature and the carbon content of fly ash are reduced, emission of flue gas pollutants such as CO, NOx and SO2 is effectively reduced, and the catalyst is suitable for the fields of energy conservation, carbon reduction and environment-friendly treatment of coal-fired power plants and industrial boilers.

The embodiment of the invention discloses a fluorine removal agent and a fluorine removal process for rare earth feed liquid. The fluorine removal agent comprises a first fluorine removal agent and a second fluorine removal agent, the first fluorine removal agent is polycrystal system composite calcium, the polycrystal system composite calcium is composed of calcium oxide / calcium hydroxide and calcium carbonate according to the mass ratio of (0.1-1): (0.1-1), and the second fluorine removal agent is composed of polycrystal system composite calcium and an inorganic flocculant according to the mass ratio of (0.01-1): (0.01-1). According to the method, fluorine is removed under the condition that the pH value is 4.6-5.8, fluoride composite salt precipitation is formed, fluorine in the rare earth solution can be efficiently removed, rare earth carbonate precipitated from subsequent oxalic acid or carbonate (sodium carbonate, sodium bicarbonate, ammonium bicarbonate and the like) or high-concentration rare earth feed liquid can be recycled, and the quality of the rare earth is improved. The requirements (the F content in the mixed rare earth oxide is less than 0.3%, and the F content in the high-concentration rare earth feed liquid (the concentration is greater than 100g / L) is less than 100mg / L) are met. The method is simple in process and high in operability, and has a relatively good application prospect.

The invention relates to the technical field of lost foam casting, in particular to a lost foam composite coating, the lost foam composite coating takes a refractory material of an investment casting regenerated shell membrane as a refractory aggregate, the refractory aggregate comprises mullite and a mixture containing an inorganic preservative A and a sintering stripping material B, and one or more of quartz powder and graphite are selected. In the invention, an efficient anti-corrosion additive with sintering stripping is researched and developed as a refractory material auxiliary additive, and meanwhile, low-price refractory materials such as regenerated mullite and recycled quartz powder are utilized to form the lost foam coating aggregate, so that the selection of traditional refractory aggregate is broken through, and the reutilization of waste resources is realized; the environment pollution is reduced while the raw material cost is reduced, meanwhile, the aggregate performance is optimized by adding the raw materials such as calcium oxide and iron oxide red, and the comprehensive performance such as air permeability, suspension stability, high-temperature strength and toughness of the coating is remarkably improved through reasonable matching of the composite binder.

The invention discloses a sludge, bagasse and calcium oxide co-pyrolysis biochar as a soil additive, and a preparation method and application thereof, and belongs to the technical field of environmental restoration. Sludge biochar synergistically modified by bagasse and calcium oxide is used as a soil additive, calcium oxide is introduced for catalytic co-pyrolysis through the synergistic effect of bagasse and calcium oxide, and sludge-bagasse-calcium oxide biochar is prepared; the optimization effect of the sludge-bagasse-calcium oxide biochar in heavy metal contaminated soil remediation is evaluated through heavy metal occurrence form analysis, ecological risk assessment and soil remediation effect experiments. According to the sludge-bagasse-calcium oxide biochar prepared by the method, the fixing capacity of the biochar on heavy metals and the fixing efficiency of the heavy metals in soil are improved, and the physicochemical properties and fertility characteristics of the heavy metal contaminated soil are improved; the characteristics of the sludge-bagasse-calcium oxide biochar for well fixing heavy metals and improving soil properties are exerted, the ecological risk is reduced, the physicochemical properties and fertility characteristics of the soil are improved, and the application of a heavy metal contaminated soil remediation process is optimized.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for improving the leaching rate and the carbon adsorption rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; a green oxygen activating agent and hydrogen peroxide are sequentially added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore, ore pulp activating liquid is formed, and the green oxygen activating agent is a mixture of calcium oxide, sodium persulfate and soluble bivalent iron salt; and adding a gold leaching agent into the ore pulp activation solution, adjusting the pH value of the ore pulp to 9-12, carrying out stirring gold leaching treatment, filtering to obtain a leaching solution, and then adding activated carbon to adsorb and extract gold. According to the method, a stronger oxidation environment is provided, meanwhile, the residual concentration of arsenate radicals in the solution is effectively reduced, the leaching rate of gold and the adsorption rate of activated carbon are greatly increased, excellent oxidation performance and environment friendliness are shown, and a more sustainable high-sulfur-arsenic gold ore pretreatment process is provided.

The present invention relates to a method for co - processing and resource utilization of overhaul slag, fly ash, and desulfurized gypsum. The method comprises the following steps: Step 1) dehydrate and then dry the desulfurized gypsum, add calcium carbonate to the dried desulfurized gypsum, and collect SO3 gas; Step 2) carry out an autoclave reaction on the SO3 gas obtained in Step 1, water, and fly ash. After solid - liquid separation, silicon dioxide and an aluminum sulfate solution are obtained; Step 3) crush and ball - mill the overhaul slag, and carry out first - stage roasting with a peroxide at high temperature to obtain clinker 1; leach out sodium fluoride from clinker 1 by water immersion, and then add it to the aluminum sulfate for second - stage roasting to obtain clinker 2; Step 4) mix clinker 2 with water for leaching to obtain a filtrate and a filter residue; Step 5) calcine calcium oxide and the filter residue to obtain calcium aluminate. The beneficial effect of the present invention aims to synergistically utilize the sodium, aluminum, fluorine, and lithium elements, the aluminum and silicon elements of fly ash, and the calcium element in desulfurized gypsum to achieve the purpose of resource conversion.

The invention provides a preparation method and application of low-bath-ratio and high-viscosity hydroxypropyl carboxymethyl composite starch ether, and relates to the technical field of starch deep processing. The method comprises the following steps: S1, premixing corn starch with a compound base catalyst and magnesium stearate, and spraying an ethanol water solution for alkalization; s2, adding epoxypropane to carry out first-stage etherification, and then adding sodium chloroacetate to carry out second-stage etherification; and S3, after the reaction is finished, performing vacuum drying, crushing and sieving to obtain the high-viscosity hydroxypropyl carboxymethyl composite starch ether. Wherein the composite alkali catalyst comprises sodium hydroxide, sodium carbonate and calcium oxide. The starch ether obtained by the method has the advantages of high substitution degree, high viscosity, low solvent consumption and low energy consumption, and overcomes the defects of the traditional semi-dry method.