818 results about "Calcium oxide" patented technology

The invention relates to the technical field of environmental protection and dust removal, and discloses a dust removal device for calcium hydroxide product production, the dust removal device comprises a box body, the lower surface of the box body is provided with two sets of dust falling hoppers, the two sides of the box body are fixedly connected with an air inlet pipe and an air outlet pipe respectively, and the inner wall of the box body is provided with a partition plate. The driving assembly drives the pulse sliding pipe and the plugging assembly to move downwards, after the pulse sliding pipe and the plugging assembly move to a certain position, the control assembly controls the plugging assembly to plug a certain section of the filter cartridge, then the pulse mechanism enables gas to pass through the pulse main pipe, the pulse fixing pipe and the pulse sliding pipe, and then the gas is blown out from the pulse head. And then the driving assembly drives the blocking assembly to continue to move downwards, pulse dust removal is carried out on the filter cartridge section by section, pulse airflow accurately covers the whole section of the filter cartridge, it is ensured that dust on all parts can be thoroughly removed, and the dust removal effect is greatly improved.

The invention discloses a preparation method of a rubber waterstop material with a low compression set rate, which comprises the following steps: firstly, carrying out blending reaction on hydroxyl silicone oil and boric acid to obtain liquid polyborosiloxane; the preparation method comprises the following steps: adding liquid polyborosiloxane and natural rubber into an internal mixer according to a ratio, and carrying out internal mixing to obtain a mixture; adding zinc oxide, an anti-aging agent, stearic acid and an anti-tearing agent into the obtained mixture, and continuously mixing; continuously adding kaolin talcum powder, calcium carbonate, calcium oxide, white carbon black, N550, N330 and KH550, and internally mixing again to obtain a preform; adding a vulcanization accelerator and a vulcanizing agent into the preform, and continuously mixing to obtain a rubber material to be vulcanized; and vulcanizing and forming the rubber material to be vulcanized to prepare the rubber water-stop belt material with the low compression set rate. According to the invention, the compression set rate of the rubber material can be reduced while the tensile strength, elongation, tear resistance and other properties of the rubber are not sacrificed, so that the product performance is enhanced.

The invention discloses an energy system and method for coupling calcium-based thermochemical heat storage and carbon capture. The energy system comprises a calcination unit, a carbon dioxide pretreatment storage unit, a calcium oxide heat exchange storage unit, a carbonation reaction unit and a heat utilization unit which are arranged based on a boiler. The calcining unit takes green valley electricity as energy to drive calcining reaction to realize heat storage, and generated CaO is processed by the calcium oxide heat exchange storage unit and then is stored for use in a heat release stage; generated COs are stored for standby application after passing through the carbon dioxide pretreatment storage unit; in the heat release stage, CaO and the desulfurized flue gas are subjected to heat release carbonation reaction in the carbonation reaction unit, and heat is released; caCO3 generated by the carbonation reaction can be used for the next heat storage stage; and the heat released by the carbonation reaction is conveyed to the heat utilization unit for heat exchange. Through coupling of calcium-based thermochemical heat storage and carbon capture, green electricity and off-peak electricity are fully utilized, and efficient storage and gradient utilization of energy are achieved.

The invention provides a method for decomposing and mineralizing fluorine-containing organic matter wastewater, which is applied to the technical field of treatment of fluorine-containing organic matter wastewater generated in a perfluoroether elastomer emulsion flocculation process, and comprises the following steps: S1, carrying out adsorption and desorption treatment on the fluorine-containing organic matter wastewater to obtain a concentrated solution of the fluorine-containing organic matter wastewater; s2, hydrogen peroxide and ferrous ions are added into a container containing the concentrated solution to obtain a mixed solution, the pH of the mixed solution is adjusted to be 2-4, the concentration mass ratio of the hydrogen peroxide to organic matter contained in the fluorine-containing organic matter wastewater is 1: 1-2, the molar ratio of the hydrogen peroxide to the ferrous ions is 1-6: 1, micro-nano bubbles are introduced into the mixed solution, and ultrasonic treatment is conducted; s3, calcium hydroxide is added into the treated mixed solution, calcium fluoride precipitates are obtained through centrifugal treatment, and the fluorine-containing organic matter in the wastewater can be degraded and mineralized.

This invention relates to a highly efficient functional ceramsite for purifying phosphorus-containing wastewater, its preparation method, and its application. Based on a complementary functional strategy, it uses natural clay rich in Al2O3 and SiO2 as a binder and calcium-rich industrial solid waste as the calcium-rich active component. Functional additives are also added to mitigate pH changes caused by calcium oxide reactions. The above raw materials are calcined at high temperature to obtain inexpensive, calcium-rich functional ceramsite with high mechanical strength, large adsorption capacity, and ecological safety. This effectively solves the common problems of increased water pH and poor phosphate adsorption capacity at neutral pH in calcium-based ceramsite, achieving highly efficient phosphorus purification in water. This invention uses inexpensive and readily available natural clay and calcium-rich industrial solid waste as raw materials, resulting in low cost, good effect, and effective application in the treatment of low-pollution water.

The invention relates to a waterproof sealing gasket material for a shield tunnel and a preparation method of the waterproof sealing gasket material. The preparation method comprises the following steps: plastifying raw rubber to obtain plastified raw rubber; the preparation method comprises the following steps: stirring and mixing plasticated raw rubber, carbon black N550, calcium carbonate, paraffin oil, zinc oxide, stearic acid, calcium oxide, an anti-aging agent and an organic magnesium compound, mixing in a mixing mill, and cooling to room temperature to obtain a mixture I; stirring and mixing the mixture I, modified NPE particles and an accelerant, mixing, and cooling to room temperature to obtain a mixture II; uniformly mixing the mixture II and sulfur in a mixing mill, vulcanizing at high temperature, and standing at room temperature for 24 hours to obtain the waterproof sealing gasket material. According to the waterproof sealing gasket material, the modified NPE particles of the core-shell structure are added, the compatibility of a water-swelling material and non-polar rubber is improved, the organic magnesium compound is added as a multifunctional auxiliary agent, the interface bonding, vulcanization network and flame retardant performance are synergistically improved, and the waterproof sealing gasket material has good waterproof performance. The prepared sealing gasket material has excellent mechanical properties, heat aging resistance, compression set resistance and flame retardance.

The invention relates to a method for recovering lithium and fluorine from aluminum electrolysis hazardous waste, which comprises the following steps: firstly, mixing organic polyol and alkaline hydroxide according to a molar ratio of 1: (0.5-2) to obtain a eutectic solvent; heating the eutectic solvent to 80-150 DEG C, and adding a proper amount of raw material fine powder and calcium oxide for reaction leaching; carbonating and filtering the leachate to obtain lithium carbonate; washing the leaching residues with an acetic acid solution to obtain a calcium fluoride product; the concentration of fluorine ions in the leachate is smaller than or equal to 200 ppm, and the purity of calcium fluoride is larger than or equal to 90%; the leaching rate of lithium in the method is greater than 85%; the slag feeding rate of fluorine is greater than 95%; and no hydrogen fluoride gas is generated in the method. According to the method, a non-toxic and biodegradable eutectic solvent is adopted as a leaching agent, and efficient leaching of lithium and fluorine in the aluminum electrolysis dangerous waste materials is achieved; calcium oxide is used as a precipitating agent, free fluorine is promoted to be precipitated and recycled as calcium fluoride, the whole process meets the requirement of green metallurgy, and the win-win situation of resources and the environment is achieved.

Processes and apparatuses for degrading PFAS into calcium fluoride, carbon dioxide, and water. PFAS are heated and introduced to a calcium base which will degrade the PFAS. The PFAS may be in a stream that is a PFAS enriched stream formed by desorbing the PFAS from an adsorbent which removed the PFAS from a contaminant stream. The PFAS may be desorbed in the presence of the calcium base. The calcium base may be calcium hydroxide, calcium oxide, calcium carbonate, or combinations thereof.

The invention discloses a method for comprehensively recycling electrolytic aluminum carbon residues, and relates to the technical field of comprehensive recycling of waste materials. The method for comprehensively recycling the electrolytic aluminum carbon residues comprises the following steps of: breaking the carbon residues into 0.1-1cm particles by a hammer, carrying out wet ball milling under the condition of adding a flotation agent, and separating carbon powder on the upper layer and gray regenerated cryolite on the bottom layer of slurry through flotation equipment, wherein the fineness is 40-100 meshes, and the carbon content is less than 1%; the preparation method comprises the following steps: adding water into cryolite to prepare slurry, adding calcium oxide or calcium hydroxide, heating, stirring and reacting for 1-3 hours, and carrying out filter pressing to obtain filtrate and filter residues which are calcium fluoride and a sodium metaaluminate solution; the purity of the calcium fluoride powder is greater than 85%; and introducing hydrochloric acid into the filtrate, stirring and adjusting the pH to 7-9 to obtain aluminum hydroxide slurry, filtering and washing to obtain aluminum hydroxide, and drying to obtain the aluminum hydroxide with the purity of more than 95%.

The invention discloses artificial soil based on manganese slag, red mud and ardealite. The artificial soil is mainly prepared from a manganese slag-red mud-ardealite mixed matrix and a modifier, the weight ratio of the manganese slag to the red mud to the ardealite in the manganese slag-red mud-ardealite mixed matrix is (0.4-1.6): (0.1-0.5): (0.5-0.9); the modifier comprises calcium oxide, and further comprises rice straw, biochar, zeolite or a combination thereof, and the modifier accounts for 1-15% of the weight of the artificial soil. Accordingly, a corresponding preparation method is also established. According to the method, the three solid wastes are mixed according to the characteristics, so that specific pollutants such as ammonia nitrogen, phosphorus, fluorine and Mn < 2 + > can be fixed, the reduction of heavy metals is realized, the nutrients beneficial to plant growth are reserved, the artificial soil with rich nutrients is synchronously reconstructed, the qualitative change from waste residues to resources is realized, the process is simple, and the effect is good. The obtained artificial soil can be used for greening planting, supplementing manganese ore, aluminum ore and phosphorite surrounding soil deficiency areas, and solving the problems of no soil, ploughability and ecological restoration of mining areas.

A process produces high-purity vanadium chemicals from vanadium raw materials having high molybdenum contents. Molybdenum is selectively precipitated via vanadium from alkaline vanadate solutions using the following process steps: providing a molybdenum-containing alkaline vanadate solution, adding calcium hydroxide as a precipitant in portions while keeping the pH constant between 6 and 7 using acid, mixing the solution, solid-liquid separation of the resulting suspension, and further processing the low-molybdenum alkaline vanadate solution to produce a high-purity vanadium chemical having a molybdenum content of at most 500 ppm.

The invention discloses a method for preparing an environment-friendly magnesium aluminate spinel raw material by utilizing industrial solid wastes, and relates to the technical field of magnesium aluminate spinel raw material production. The method comprises the following steps: a, raw material synergistic purification treatment: crushing magnesium slag into coarse particles, and mixing the coarse particles with aluminum ash raw powder which is not subjected to desalting treatment according to a mass ratio of (1-3): 1 to obtain a mixture; the mixture is subjected to first heat treatment at the temperature of 450-650 DEG C in a non-oxidizing atmosphere, and heat preservation is conducted for 1-3 h; according to the method, two industrial solid wastes, namely the magnesium slag and the aluminum ash, are subjected to direct synergistic heat treatment in a non-oxidizing atmosphere, and chloride impurities in the aluminum ash are used for synchronously removing free calcium oxide on the surface of the magnesium slag and removing part of soluble salt of the aluminum ash in the volatilization and migration process, so that coupling purification of treating wastes with wastes is realized; the problem that various solid wastes need to be subjected to complex pretreatment in a traditional process is solved, the process is simplified, the impurity removal efficiency is improved, and meanwhile the risk of environmental pollution caused by solid waste stockpiling or landfill is reduced.

The invention relates to the technical field of waste asphalt regeneration, in particular to preparation of a coarse grain type regenerated asphalt mixture. The invention discloses a coarse grain type recycled asphalt mixture and a preparation method thereof, and the coarse grain type recycled asphalt mixture comprises the following components in parts by mass: 100 parts of the total mass of the mixture, the recycled asphalt pavement material comprises the following components in parts by weight: 50-70 parts of a recycled asphalt pavement material, 28-36 parts of a new aggregate, 2.5-3.2 parts of new asphalt, 0.2-0.6 part of an A-phase recycling agent formed by compounding waste vegetable oil and an antioxidant, 0.05-0.3 part of a B-phase recycling agent formed by compounding environment-friendly rubber oil and natural rock asphalt, 1.5-2.5 parts of fine-grained calcium oxide powder, 0.4-0.8 part of a dry premixing reinforcing agent and 0.8-1.5 parts of a warm mixing agent. According to the invention, the problem that the performance of the high-proportion regenerated mixture is degraded is solved, and high-performance resource utilization of the waste asphalt pavement material is realized.

The application discloses a zinc extraction process from secondary zinc oxide, and belongs to the technical field of zinc oxide preparation. In the rotary kiln roasting, composite porous flaky reducing carbon with waste paper, rice husk and wooden chips as main raw materials is used as a reducing agent. Compared with the commercially available anthracite, the composite porous flaky reducing carbon has low cost, realizes resource recycling, and has a large specific surface area and porous properties. A multi-level structure of flaky layers and pores is constructed, so that the contact sites of the composite porous flaky reducing carbon and the secondary zinc oxide are increased. The porous structure can avoid the caking of the material layer caused by the stacking and agglomeration of the flaky layers, and avoid the obstruction of gas flow, so that the pain points of the traditional reducing agent, such as local agglomeration and insufficient contact, are solved. The surface of the composite porous flaky reducing carbon is deposited with calcium oxide. The presence of the calcium oxide can react with a small amount of sulfur elements generated in the rotary kiln roasting process of the composite porous flaky reducing carbon, so as to generate calcium sulfate and reduce the content of sulfur dioxide.

The invention provides a composite hydrogen transfer catalyst based on an MOFs material as well as a preparation method and application of the composite hydrogen transfer catalyst. The composite hydrogen transfer catalyst comprises the MOFs material loaded with an active metal component and solid alkali, the active metal component is selected from at least one of palladium, platinum, ruthenium, rhodium and nickel; the active metal component accounts for 0.5-5% of the mass of the catalyst; the MOFs material is selected from at least one of ZIF-8, MIL-101, UiO-66, HKUST-1 and MOF-5 (Metal Organic Frameworks); the solid alkali is selected from at least one of magnesium oxide, calcium oxide, hydroxyapatite and barium oxide. The catalyst provided by the invention has the advantages of high catalytic activity, good selectivity, strong stability, reusability and the like, can efficiently catalyze fatty alcohol to perform hydrogen transfer reaction under a lower-temperature reaction condition to prepare Guerbet alcohol, remarkably improves the yield and purity of a product, and reduces the reaction energy consumption and cost.

The invention discloses a cement clinker f-CaO content prediction method and system based on transfer learning, and belongs to the field of cement industry intelligent manufacturing and soft measurement. According to the method, process variable data of three sub-systems in a cement production line are collected, a CNN-Transform prediction model is constructed, local time sequence features of the sub-systems are extracted through three independent one-dimensional convolutional neural networks, a cross-variable cross attention mechanism is introduced to capture a dynamic coupling relationship among the different sub-systems, and the dynamic coupling relationship among the sub-systems is determined. A Transform encoder is used for learning global time sequence dependence, and an f-CaO content prediction value is output; according to the method, a transfer learning strategy is adopted, a model is pre-trained on source domain large sample data, and a specific layer freezing and fine tuning strategy is adopted on target domain small sample data for adaptation, so that the prediction precision of the f-CaO content and the generalization ability across production lines are remarkably improved, and effective support is provided for real-time optimization control in the cement production process.

This invention provides a method and equipment for preparing compound fertilizer using lepidolite slag as raw material. The method includes the following steps: S1, pretreatment: lepidolite slag is taken, crushed, and screened to obtain lepidolite slag particles with a particle size of 40 to 400 mesh; S2, activation: lepidolite slag is thoroughly mixed with an activator and a flux, and then ground to obtain powder with a particle size less than 80 mesh, wherein the activator is sodium hydroxide and anhydrous sodium carbonate, and the flux is calcium oxide; S3, sintering: the activated and ground powder is sintered at a temperature of 650℃-1000℃ for 0.5 h-5 h; S4, compounding: trace elements are added to the sintered fertilizer, mixed evenly, and ground into powder. The method for preparing compound fertilizer using lepidolite slag as raw material provided by this invention can effectively utilize lepidolite slag to prepare compound fertilizer, solving the environmental problem of large-scale accumulation of lepidolite slag and realizing the resource utilization of waste.

The invention discloses a chitin-silicon-calcium-based modified material for rammed earth wall repair and a weather resistance evaluation method thereof, and belongs to the technical field of rammed earth wall repair, the chitin-silicon-calcium-based modified material comprises metakaolin, calcium oxide, quartz and chitin; the ratio of chitin to metakaolin to calcium oxide to quartz is 1: 1: 2: 4; the method comprises the following steps: pre-treating at the earlier stage of a test, evaluating freeze-thaw cycle performance, evaluating dry-wet cycle performance, evaluating salt corrosion resistance, analyzing association between a microstructure and a strength performance, and finally, revealing a material degradation rule and mechanism by combining scanning electron microscope observation, unconfined compressive strength test and crack rate analysis. When the freezing and thawing cycle number N is less than or equal to 5, the dry and wet cycle number I is less than or equal to 9, and the salt solution concentration c is less than or equal to 0.3 mol / L, the characteristics of freezing and thawing resistance, dry and wet resistance, salt erosion resistance and the like of the modified material are obviously improved; after the modified material is added, internal pores of plain soil can be filled, unconfined compressive strength of a soil body is enhanced, and long-term durability of the soil body is improved.

The application provides a quartz sand acid washing waste liquid resource treatment method, and belongs to the field of industrial waste water treatment, and comprises the following steps: adding magnetic composite seeds to the quartz sand acid washing waste liquid, and performing magnetic separation after stirring treatment; adding soluble potassium salt to the treated waste liquid to recover potassium fluosilicate; treating the filtrate through diffusion dialysis to obtain recovered acid and dialysis residual liquid; the diffusion dialysis treatment adopts an asymmetric membrane, the asymmetric membrane has a physical gradient of one side being a dense structure and the other side being a loose structure, and the dense structure side is in contact with the waste liquid; and adding calcium oxide or calcium hydroxide to the dialysis residual liquid for deep treatment and calcium recovery. The application provides a quartz sand acid washing waste liquid resource treatment method which is low in treatment cost, high in resource recovery rate and friendly to the environment, and realizes the differentiated resource recovery of the quartz sand acid washing waste liquid.

The embodiment of the invention discloses a hafnium oxide-based ferroelectric film doped in a calcium gap position and a preparation method. The method comprises the following steps: preparing a target material: mixing hafnium oxide and calcium oxide according to a set ratio, and grinding to obtain mixed raw material powder; calcining the mixed raw material powder for the first time; grinding the mixed raw material powder calcined for the first time, and performing compression molding to obtain a target material biscuit; calcining the target material biscuit for the second time to obtain the hafnium oxide-based ceramic target material doped in the calcium gap position; a commercial bottom electrode La0. 7Sr0. 3MnO3 target material is used as a first sputtering target, sputtering is carried out under a first set condition, and an LSMO bottom electrode thin film is obtained; taking the calcium gap position doped hafnium oxide-based ceramic target material as a second sputtering target, sputtering under a second set condition, and epitaxially growing on the LSMO bottom electrode film to form a calcium gap position doped hafnium oxide-based ferroelectric film; the chemical composition of the hafnium oxide-based ferroelectric film doped in the calcium gap position is CaxHf (1-x) O (2-x), x is 0.01-0.05, and calcium ions occupy the gap position of a hafnium oxide crystal lattice.

The utility model discloses a calcium hydroxide particle size accurate regulation and control device which comprises a workbench and a particle size regulation and control assembly used for accurately regulating and controlling the particle size of calcium hydroxide particles, a collecting hole is formed in one end of the upper surface of the workbench, and a fixing cylinder is fixedly installed at one end of the edge of the upper surface of the collecting hole. The particle size regulation and control assembly is detachably installed on one side of the fixing cylinder, an installation rod is fixedly installed at the other end of the upper surface of the workbench, an empty groove is formed in one side of the workbench, a vibration motor is arranged in the empty groove, and a linkage cylinder is fixedly installed at one end of the outer surface of the fixing cylinder. The whole structure has high regulation and control capacity on calcium hydroxide particles, accurate regulation and control can be carried out, the condition of mixing caused by large particle size span is avoided, particle size distribution is uniform, and application scenes with high particle size uniformity requirements can be effectively met.

Provided is dental glass having sufficient antibacterial properties through the inclusion of zinc. This dental glass contains 41-52 mass% of ZnO, 47-51 mass% of P2O5, 7 mass% or less of MgO, and 9 mass% or less of CaO. The fluorine content in the dental glass is preferably 3 mass% or less. The dental glass can be easily produced through a mixing step for mixing a starting material solution containing a zinc salt solution, a phosphate solution, an optional magnesium salt solution, and an optional calcium salt solution to form aggregates in the starting material solution, and a drying step for drying the aggregates to obtain a powder.

The present disclosure proposes a soluble ceramic shell / core and a preparation method and an application, and belongs to the technical field related to rapid casting. The preparation method includes the following steps: step S1: performing ball milling and drying on a raw material containing calcium oxide and a modifying solution to obtain a modified calcium oxide powder; step S2: printing the modified calcium oxide powder into a ceramic shell / core primary blank, and performing heat curing, infiltration and drying to obtain a ceramic shell / core blank; and step S3: sintering the ceramic shell / core blank to obtain the soluble ceramic shell / core. The present disclosure prepares the ceramic shell / core by a 3DP molding process, which is simple in procedure and short in production cycle, and does not need support, wherein solubility of the calcium oxide, after casting, makes it easier for a casting to be de-shelled. In addition, the raw material during a sintering process cannot be decomposed, which reduces shrinkage during the sintering process and can meet requirements for molding a large and complex structural ceramic shell / core.

The invention belongs to the technical field of concrete, and provides ecological concrete and a preparation method thereof, the ecological concrete comprises 25-35 parts of steel slag, 10-20 parts of slag powder, 5-10 parts of desulfurized gypsum, 30-35 parts of recycled aggregate, 5-8 parts of charcoal, 1-2 parts of fiber, 1-1.5 parts of a water reducing agent, 0.5-1 part of an air entraining agent, 1-2 parts of an antifreezing agent, and 15-20 parts of water. The steel slag serving as an early strength and alkaline component of the concrete not only provides strength, but also can release calcium hydroxide in the hydration process due to the calcium oxide active component contained in the steel slag, so that an alkaline environment is provided for the system; the superfine slag powder is rich in active silicon dioxide, aluminum oxide and other components and can be subjected to a pozzolanic reaction with calcium hydroxide in an alkaline environment, so that the later strength of the ecological concrete is remarkably enhanced, and the defect that the later strength of the steel slag is slowly increased is overcome; according to the invention, volcanic ash reaction is taken as a core mechanism, and the strength and durability are improved by recycling wastes.

The invention discloses a magnetic geopolymer as well as a preparation method and application thereof, and relates to the technical field of solid waste resource utilization and wastewater treatment. The preparation method comprises the following steps: drying nickel slag, crushing and grinding, adding calcium oxide to adjust alkalinity, and heating and melting to obtain a nickel slag melt; the nickel slag melt is subjected to water quenching, and magnetic slag micro powder is obtained through drying, crushing and screening; and mixing the magnetic slag micro powder with an alkaline activator, injecting the mixture into a mold, performing constant-temperature maintenance, demolding, and crushing to obtain the magnetic geopolymer. The magnetic geopolymer prepared by the invention has high adsorption capacity and rapid adsorption kinetics for multiple heavy metal ions in water, and has excellent magnetic separation performance.

The utility model discloses a kind of calcium hydroxide efficient centrifugal fan, including bottom plate, the top of bottom plate is equipped with two fixed frame, two fixed frame are slidably fitted with moving frame, one fan body is rotatably fitted between two moving frames, one side of one moving frame is equipped with support plate, the top of support plate is equipped with motor, the side of fan body is rotatably fitted with fan shaft, coupling is provided between motor output end and fan shaft;The side of fan body is provided with air inlet, air outlet is provided on fan body, filter screen is installed on the side of air inlet, lifting mechanism is provided between fixed frame and moving frame.The utility model is equipped with moving frame, can mobilize lifting mechanism to adjust the height of moving frame and fan body, make fan body rotation adjustment the orientation of air outlet, so that it can be adjusted according to need, it is convenient to install when different orientation and height of air outlet change.

The application discloses a beneficiation method for complexly-embedded high-sulfur-content lead-zinc sulfide ore, which comprises one-stage rough separation, three-stage cleaning and three-stage scavenging; a zinc flotation operation comprises one-stage rough separation, three-stage cleaning and three-stage scavenging; a sulfur flotation operation comprises one-stage rough separation, one-stage cleaning and one-stage scavenging; a sulfur concentrate dezincing operation comprises one-stage rough separation, one-stage cleaning and one-stage scavenging, calcium oxide is added in the one-stage cleaning process, a zinc collecting agent is added in the one-stage scavenging process, and tailings after the one-stage cleaning and concentrate after the one-stage scavenging are returned to the one-stage rough separation of the sulfur concentrate dezincing operation. The column machine is combined to improve the recovery rate of useful minerals, the flotation column is used for scavenging to improve the recovery rate of fine particles, the sulfur concentrate is subjected to the dezincing operation, and the dezincing product is returned to the zinc rough separation operation, so that the recovery rate of zinc minerals is improved, and through the column machine combined with the middling regrinding mode, the recovery rates of lead and zinc in the complexly-embedded high-sulfur-content lead-zinc sulfide ore are improved.

This invention discloses an in-situ three-dimensional bioremediation method for slightly polluted water bodies. The method involves collecting a mud-water mixture from the water body to be treated, enriching and culturing it, and collecting the settled sludge. Culture medium II is added to the settled sludge for acclimatization and cultivation to prepare a biological agent. This biological agent is then added to a mixed solution of polyvinyl alcohol-hydrated calcium silicate-fulvic acid (PVA-CSH-FA) or PVA-modified zeolite-FA to prepare an immobilized biological carrier that can slowly release or adsorb calcium ions from the water. Calcium peroxide packing is also prepared to provide oxygen. The immobilized biological carrier packing and calcium peroxide packing are respectively fixed in the upper and lower layers of an ecological sedimentation bed, which is then placed in the slightly polluted water body to achieve in-situ three-dimensional bioremediation. The calcium-precipitating bacterial biological agent obtained through enrichment and acclimatization in this invention, when immobilized and mixed with the carrier material, efficiently and simultaneously removes pollutants such as nitrogen, phosphorus, organic matter, and heavy metals from slightly polluted water bodies.

This invention belongs to the field of roadbed solidification technology and relates to an additive for solidifying slag and its preparation method. Calculated by weight, it includes the following components: 15-25 parts mineral admixture, 5-10 parts modified diatomaceous earth, 1-1.5 parts activator, and the balance cement, with a total mass of 100 parts. This application uses an activator and steel slag and blast furnace slag powder to prepare a solidification material. The combined effect of these two components can simultaneously improve the early and late strength of the solidified soil. Simultaneously, by modifying the diatomaceous earth, the dispersibility of diatomaceous earth and carbonaceous powder in the cementitious material is improved, enhancing the bonding performance of cement. Utilizing the property that diatomaceous earth and sodium polyacrylate aggregate in the aqueous environment and calcium oxide in cement to form water-insoluble crystalline substances, the strength and water erosion resistance of the solidified soil are improved.

The invention discloses a treatment process and a treatment system for crystallization of photovoltaic wastewater calcium fluoride sludge, limestone particles and photovoltaic sludge are mixed according to a mass ratio of 3%-5% to obtain a homogeneous mixed material, the homogeneous mixed material is pre-dried and then fed into a rotary kiln, sintering is carried out at 1200-1500 DEG C for 1.5-3 hours, and the sintered material is cooled to room temperature. Calcium fluoride is attached to the surface of the silicate framework, sulfur trioxide and calcium oxide are released at the same time, after sintering is finished, the material is subjected to annealing treatment in a rotary kiln, calcium fluoride seed crystals accounting for 0.1%-1.0% of the total mass of the material are added, calcium fluoride crystals are induced to grow directionally and be repaired, and the calcium fluoride is obtained. According to the method, the purity of calcium fluoride is increased to 75%-85%, the sulfur content in the product can be controlled to be 0.1% or below, and the cold compressive strength of the pellets prepared from the product reaches 2.5 MPa or above.