380 results about "Potassium persulfate" patented technology

A fireproof magnesium oxide board is prepared by mixing the following raw materials, the raw material names and weight parts are as follows: 80-100 parts of magnesium oxide; 20-30 parts of anhydrous magnesium chloride; 10-20 parts of modified expanded vermiculite foaming agent; 20-30 parts of aluminum silicate fiber; 5-10 parts of sawdust; 10-15 parts of fly ash; 8-12 parts of glass magnesium board crushed powder; 1.5-5 parts of non-woven fabric; 10-20 parts of water; wherein the modified expanded vermiculite is prepared by the following steps: (1) Vermiculite is incompletely expanded and calcined; (2) acrylic acid monomer, sodium hydroxide, acrylamide monomer, initiator potassium persulfate, crosslinking aid pentaerythritol polyglycidyl ether, incompletely expanded vermiculite, and water are taken, stirred evenly and ultrasonically dispersed to obtain a first reaction solution, which is placed in a reactor for reaction to obtain a gel material; (3) the gel material is preliminarily crushed and dried, and then further crushed in a ball mill to obtain a fire-resistant expanded vermiculite with water absorption performance.

The invention relates to an aluminum oxide CMP polishing solution for rough polishing of silicon carbide wafers and a polishing method of the aluminum oxide CMP polishing solution, and the aluminum oxide CMP polishing solution comprises the following components in percentage by weight: 2-10wt% of nano aluminum oxide abrasive; 0.2 to 2 wt.% of a dispersant; 0.001 to 0.01 wt% of a pH regulator; the concentration of the oxidizing agent is 1-5wt.%. By adopting the compound oxidant, potassium permanganate is utilized to oxidize a reduction product manganese dioxide on the surface of the silicon carbide wafer to activate potassium persulfate, so that a large amount of sulfate free radicals are generated in the polishing solution, the oxidability of the sulfate free radicals is extremely high, the polishing solution can be promoted to generate chain oxidation reaction, and the surface of the silicon carbide wafer is further oxidized; and an oxide layer with low hardness is formed on the surface of the silicon carbide and is finally removed under the mechanical action of the aluminum oxide abrasive, so that the ultra-smooth and damage-free surface of the silicon carbide wafer is formed. The surface roughness of the obtained optimal silicon carbide wafer is 0.125 nm, and the material removal rate is 3.5 [mu] m / h. Compared with an existing aluminum oxide polishing solution, the polishing solution has the advantage that the surface quality and the polishing efficiency of the silicon carbide wafer are remarkably improved.

The invention discloses a high-RAP-doping-amount cold-mixed asphalt regenerant, and particularly relates to the technical field of asphalt regenerant, the high-RAP-doping-amount cold-mixed asphalt regenerant comprises the following raw materials: hydrogenated extract oil, acetyl tributyl citrate, a low-temperature penetrant, pre-swelling SEBS master batch, a crosslinking catalyst and a microcapsule antioxidant. Molecular-level branched-chain alkyl sodium sulfonate can be wedged into aged asphalt microcracks at the temperature of 65 DEG C, lost light components are balanced and supplemented through hydrogenated extract oil, an SEBS micro-crosslinking network forms an in-situ reinforcement effect at the temperature of 90 DEG C, the triple regeneration effect of regenerated asphalt is achieved, and the service life of the regenerated asphalt is prolonged. Nano-zinc oxide is treated by a silane coupling agent and then is modified by using methyl methacrylate and potassium persulfate, so that the nano-zinc oxide is coated with polymethyl methacrylate, the compatibility of the microcapsule antioxidant and the recycled asphalt can be improved, and the anti-aging performance of the recycled asphalt is improved.

The invention provides transparent high-impact-resistance heat-resistant MBS (methyl methacrylate-butadiene-styrene) resin and a preparation method thereof, and relates to the field of high polymer material preparation methods, the transparent high-impact-resistance heat-resistant MBS resin is prepared from the following raw materials: water, ethanol, maleic anhydride, an emulsifier, MBS resin grafted latex, potassium persulfate and an antioxidant; the MBS resin grafted latex is prepared from the following raw materials: water, modified styrene-butadiene latex, sodium hydrogen sulfite, potassium persulfate, methyl methacrylate and styrene, the modified styrene-butadiene latex is prepared from the following raw materials: a pre-emulsion, glycidyl methacrylate, ammonium persulfate, divinyl benzene and potassium persulfate; the pre-emulsion is prepared from the following raw materials: water, an emulsifier, butadiene and styrene. The product is good in heat resistance and good in PVC modification effect, and the modified PVC composite material is high in light transmittance, high in cantilever beam impact strength and resistant to aging.

The invention relates to a process for recycling and regenerating a waste lithium iron phosphate positive electrode material by using a specific chelating agent. The method comprises the following steps: carrying out heat treatment on a waste lithium iron phosphate positive electrode material, putting separated waste lithium iron phosphate powder into a ball milling tank, adding organic acid and a chelating agent, and carrying out ball milling; after the ball milling is finished, adding hydrogen peroxide, uniformly stirring and mixing, adjusting the pH value to 2-3 by using nitric acid, and filtering to obtain a filter cake which is iron phosphate; adding saturated sodium carbonate into the filtrate, precipitating, and recovering lithium carbonate; putting the iron phosphate, the lithium carbonate, the iron source, the lithium source and the phosphorus source in the step S3 into a ball mill for ball milling, and performing high-temperature solid-phase sintering after ball milling to obtain a regenerated lithium iron phosphate material; the chelating agent disclosed by the invention is prepared from (9ci)-2-(2-propenyl)-1-cyclopentene-1-carboxylic acid, 2-mercaptobenzimidazole carboxylic acid, an ethylene boric anhydride pyridine complex and potassium persulfate. The regenerated lithium iron phosphate material prepared by the method has excellent electrochemical performance.

The invention provides a modified chitosan flocculant for slime water treatment. The modified chitosan flocculant is prepared from the following raw materials: chitosan, dimethyl diallyl ammonium chloride, acrylamide, acetic acid and potassium persulfate. The invention also provides a preparation method of the modified chitosan flocculant for slime water treatment. The preparation method comprises the following steps: dissolving chitosan in a dilute acetic acid solution with the mass concentration of 60%, and stirring; adding acrylamide and dimethyl propyl chloride cyclic amine into the mixed solution, uniformly stirring, adding a potassium persulfate solution with the mass concentration of 4%, and introducing nitrogen for 20 minutes; then carrying out microwave reaction, and cooling to room temperature after the reaction is completed; adding absolute ethyl alcohol, centrifuging for 10 minutes, taking out, and continuously soaking in absolute ethyl alcohol for 12 hours, so as to obtain a final insoluble substance which is a graft polymer CS-g-ADM; and drying the polymer in a drying box at 105 DEG C until no weight loss occurs, and then grinding and storing. The flocculating agent disclosed by the invention has relatively good flocculability.

The invention discloses a biomass-inorganic-organic ternary composite flocculant and a preparation method and application thereof, and belongs to the field of coking wastewater treatment.The preparation method comprises the steps that chitosan serves as a substrate material, glutaraldehyde serves as a cross-linking agent, and polyferric sulfate (PFS) and chitosan are subjected to chemical cross-linking to generate an intermediate product PFS and chitosan composite particles; then potassium persulfate is used as an initiator, graft copolymerization of acrylamide and methacryloyloxyethyl trimethyl ammonium chloride is initiated through hydroxyl on the surface of PFS-chitosan, a cationic branched chain is introduced, and a final product is obtained. Through multi-component cooperation and structural design, the defects that a traditional flocculating agent is not thorough in demulsification, large in sludge amount, unstable in floc combination and the like in coking wastewater treatment are overcome, and the flocculating agent is particularly suitable for treating oil pollutants in coking wastewater.

The invention provides a pharmaceutical wastewater treatment process. The pharmaceutical wastewater treatment process comprises the following steps: A1, pretreatment, A2, adsorption treatment, A3, oxidation treatment and A4, filtration treatment. In the step A2, a composite adsorbent comprising the following raw materials: attapulgite, activated carbon, carbon nanotubes, 4-carboxyphenylboronic acid, polyethyleneimine, sodium dithiocarbamate, epoxy resin E-44, deionized water and modified nano zero-valent iron is used, and self-repairing is realized through dynamic chemical bonds such as boric acid ester bonds, imine bonds and thiol-disulfide bonds; the adsorbent can be self-repaired during microscopic damage, so that the service life is prolonged, and relatively high adsorption capacity is kept. In the step A3, a gel microsphere oxidant comprising the following raw materials: hydrogen peroxide, potassium persulfate, copper-iron sulfide, nitrogen-doped carbon quantum dots, sodium alginate powder, sodium polyacrylate and a phosphate buffer solution is used, and efficient degradation is realized through a synergistic mechanism of free radical oxidation, non-free radical oxidation and photocatalysis.

The invention provides an anti-stain inducer as well as a preparation method and a use method thereof. According to the anti-waterlogging inducer, 0.01-0.02 g of potassium persulfate is mixed with a corresponding dosage of a synergistic compound agent in 1 L of an earthworm enzyme solution, a proper amount of ROS is induced in plants by spraying of potassium persulfate, ROS is used as a stress resistance signal, a crop plant defense reaction is activated, a stress memory is formed, and the anti-waterlogging inducer has a good anti-waterlogging effect. Therefore, the stress response of the plant can be quickly activated in a subsequent stress environment, and the stress resistance of the plant is improved. The anti-stain inducer provided by the invention is low in cost and easy for large-scale production. When the wheat waterlogging stress occurs, the wheat waterlogging resistance can be effectively improved by spraying the wheat waterlogging stress resisting agent before the wheat is subjected to waterlogging stress in a simple and convenient use mode easy for farmers to operate, so that the yield and the quality of the wheat are remarkably improved. The inducer provided by the invention avoids the problem that the existing remedial conditioning agent is difficult to apply in time under the condition of heavy rainfall, and provides a new solution for agricultural disaster resistance and reduction.

The invention discloses a high-performance additive and a steel-slag-doped cementing material applied to the high-performance additive, and relates to the technical field of cementing materials. The high-performance additive is prepared from the following components in parts by weight: 0.5 to 1 part of calcium citrate, 1.5 to 2 parts of modified sodium alginate, 4 to 6 parts of modified diatomite and 0.01 to 0.03 part of potassium persulfate. The modified sodium alginate is prepared from the following raw materials: oxidized sodium alginate, 4-hydroxycinnamamide, aminated graphene and sodium sulfanilate. The raw materials of the modified diatomite comprise alkali lignin and aminated diatomite. The invention provides the high-performance additive which is applied to the binding material doped with the steel slag, so that the problems of low activity of the steel slag and single function of the traditional additive are solved, the comprehensive improvement of the performance of the binding material is also realized, and the binding material has environmental protection property and economic benefit.

The invention relates to the technical field of waste drilling fluid treatment, and discloses a modifier for treating water-based drilling waste and a preparation method thereof.The modifier is prepared from, by weight, 30-40 parts of potassium persulfate, 10-25 parts of ferric trichloride, 20-40 parts of quaternary ammonium cationic polymer and 10-20 parts of magnetized modified attapulgite clay. According to the modifier for treating the water-based drilling waste, through the synergistic effect of all the components, an oxidation-catalysis-flocculation-magnetic separation four-stage synergistic treatment process is formed, the problem that gel breaking is not thorough in the water-based drilling waste treatment process is solved, the content of metal ions in a liquid phase after solid-liquid separation is reduced, and the water-based drilling waste treatment effect is improved. The water distribution requirement of the drilling fluid can be met under the condition that the liquid phase does not need to be further treated, the treatment process is simplified, and the cost is reduced.

The invention discloses a super absorbent material and side leakage prevention paper diapers, and belongs to the field of hygienic product materials. Comprising the following steps: cooling acrylic acid in an ice-water bath, and partially neutralizing the acrylic acid by using a sodium hydroxide solution; mixing potato starch with deionized water, and gelatinizing at high temperature to obtain gelatinized starch; mixing gelatinized starch, neutralized acrylic acid, potassium persulfate and deionized water; uniformly stirring under the protection of nitrogen, heating and carrying out graft copolymerization reaction to obtain a copolymer; adding modified silicon dioxide into the copolymer, and uniformly dispersing; then adding an oxetane compound, and carrying out a cross-linking reaction at a high temperature to obtain a super absorbent material; wherein the modified silicon dioxide has a porous structure, and nano-silver particles are loaded in pore walls. The super absorbent material disclosed by the invention effectively breaks through the gel blocking effect of the traditional high-molecular water-absorbent resin, has ultrahigh liquid absorption capacity and water locking capacity, and realizes slow-release long-acting bacteriostasis at the same time.

The invention discloses a preparation method and application of a polymer lithium-conducting glue solution and a solid-state lithium battery, and the preparation method comprises the following steps: adding a lithium salt and a polymer monomer into a solvent according to a mass ratio of (5-10): (3-5) to form a mixed solution; adding an initiator, uniformly stirring to obtain a mixture glue solution, and carrying out heat treatment to obtain a polymer lithium-conducting glue solution; the initiator is selected from one or a mixture of two or more of azodiisobutyronitrile, benzoyl peroxide, potassium persulfate and ammonium persulfate in any proportion; the interface material which is formed in situ in the battery and has excellent mechanical property and lithium conducting capacity is used for reducing the operation pressure of the solid-state battery and improving the electrochemical performance of the solid-state battery.

The invention discloses a core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule, the microstructure is of a spherical structure, the core-shell structure is adopted, the core structure is hexadecane, the shell structure is a methyl methacrylate (MMA) and N, N-methylene bisacrylamide (MBA) copolymer, the emulsifier is lauryl sodium sulfate (SDS), the initiator is potassium persulfate, and the pH value of the core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule is 7-8. And the coating efficiency is 70-75%. The preparation method comprises the following steps: 1, preparing an oil phase and a water phase; and 2, polymerization reaction of the microcapsule. A phase change cement material based on a core-shell structure P (MMA-MBA) copolymer heat storage phase change microcapsule is prepared by compounding the P (MMA-MBA) copolymer heat storage phase change microcapsule and a cement matrix, and has hydrophobicity; obvious weightlessness exists in two times.

The invention relates to high-strength degradable self-healing hydrogel and a preparation method thereof, and belongs to the technical field of high polymer materials. The hydrogel is prepared from the following components in percentage by mass: 15 to 20 percent of carboxymethyl cellulose, 10 to 14 percent of acrylic acid, 15 to 20 percent of N-isopropylacrylamide, 4 to 8 percent of tannic acid, 2 to 4 percent of borax, 0.06 to 0.1 percent of laccase, 0.5 to 1 percent of N, N-methylene bisacrylamide, 0.4 to 0.6 percent of potassium persulfate and the balance of phosphate buffer solution. According to the hydrogel disclosed by the invention, through dual-network structure design, dynamic covalent bond crosslinking and enzyme catalysis green synthesis, collaborative optimization of high strength, high self-healing property, degradability and multi-responsiveness is realized, and the problems of poor mechanical property, low repairing efficiency, environmental unfriendliness and the like of traditional hydrogel are solved; the method has wide application potential in the fields of biomedicine, flexible electronics, intelligent packaging and the like.

The invention discloses a high-load monatomic catalyst as well as a preparation method and application thereof. The monatomic catalyst is an iron monatomic catalyst, and is characterized in that the mass loading proportion of Fe can be regulated and controlled within the range of 5.16-41.31 wt%, which exceeds all Fe monatomic catalysts reported at present, and overcomes the bottleneck of few metal active sites of the monatomic catalyst. The method has the advantages that a cascade anchoring strategy is adopted, and Fe < 3 + > is assembled into a macromolecular organic framework through the multifunctional effect of a chelating agent. And calcining the obtained precursor in N2 atmosphere at 550 DEG C for 4 hours to obtain the high-quality loaded iron monatomic catalyst. The preparation method is simple, low-cost and environment-friendly. The prepared monatomic catalyst with the high iron loading capacity has more active sites, the activation performance of potassium hydrogen persulfate is remarkably improved, the degradation kinetics of sulfamethoxazole (SMX) is improved, the SMX removal rate of 90% or above can still be kept after the catalyst is repeatedly used for five times, and it is indicated that the catalyst has good activity and durability.

The invention discloses a preparation method of thermochromic HPC / PEG hydrogel, which comprises the following steps: preparing an aqueous solution of hydroxy propyl cellulose (HPC), and slowly adding potassium persulfate (KPS) and a BIS initiator under a stirring condition to obtain HPC hydrogel; adding PEG (Polyethylene Glycol) into the HPC hydrogel, and carrying out ultrasonic mixing to obtain thermochromic HPC / PEG hydrogel; the molecular weight of the PEG is 400 to 20000; the mass percent of the PEG in the HPC / PEG hydrogel is 0 to 50 percent by weight; the thermochromic intelligent window is obtained by injecting the thermochromic HPC / PEG hydrogel between two pieces of quartz glass, then sealing the periphery and standing. By adding PEG with proper content and molecular weight, dual regulation and control of LCST and optical performance of the HPC hydrogel are realized, the problem that low response temperature and high solar modulation capability of the hydrogel cannot be achieved at the same time is solved, and the obtained HPC / PEG hydrogel has the characteristics of high transmittance, high solar modulation efficiency, low critical transition temperature and long cycle life.

The invention discloses a preparation method and application of an amphipathic long-side-chain polycarboxylate dispersing agent, and the preparation method comprises the following steps: taking one or more of maleic anhydride, methyl allyl polyoxyethylene ether (TPEG) or allyl polyoxyethylene ether (HPEG), sodium p-styrenesulfonate or sodium allysulfonate or acrylamide or styrene or hydroxyethyl acrylate as a raw material; and potassium persulfate or an ammonium persulfate initiator is used as raw materials, and a free radical polymerization method is adopted to synthesize the long-side-chain polycarboxylate dispersant with an anchoring effect on the end group. Compared with an existing preparation method of a low-content unsaturated polyether monomer, 70-78 wt% of methyl allyl polyoxyethylene ether or allyl polyoxyethylene ether is adopted, the prepared dispersing agent is more suitable for dispersion of organic pigment phthalocyanine blue, and color paste obtained through dispersion is good in stability.

The invention belongs to the technical field of electrochemical luminescence analysis and detection, and relates to an electrochemical luminescence sensor of a defective iron metal organic framework enhanced pyrenyl self-assembled hydrogen bond organic framework, and a preparation method and application thereof. Comprising the following steps: dispensing a PSA-HOF / Pca-MIL-88B (Fe) dispersion liquid on a GCE electrode, drying, dropwise adding a perfluorooctanoic acid aptamer, reacting at room temperature to finally obtain an aptamer modified PSA-HOF / Pca-MIL-88B (Fe) electrode as a working electrode, Ag / AgCl as a reference electrode and a Pt electrode as a counter electrode, and introducing the aptamer modified PSA-HOF / Pca-MIL-88B (Fe) electrode, Ag / AgCl as a reference electrode and a Pt electrode as a counter electrode into a PBS phosphate buffer solution containing potassium persulfate for detecting perfluorooctanoic acid. The prepared PSA-HOF / Pca-MIL-88B (Fe) system electrochemical luminescence sensor has the characteristics of simplicity, convenience and flexibility in operation, wide detection range, low detection limit, low detection cost and the like.

The application discloses a preparation method of urolithin A. The method uses urolithin B as a raw material, adopts potassium persulfate to perform Elbs oxidation under alkaline conditions, and obtains urolithin A. A reaction route is as follows: wherein, formula I is a chemical structural formula of urolithin B, and formula II is a chemical structural formula of urolithin A. The preparation method of urolithin A provided by the application effectively reduces a synthesis cost, avoids use of dangerous and toxic reagents, effectively reduces generation of industrial three wastes, and is simple in process, convenient in operation, low in raw material cost, high in yield, and beneficial to large-scale industrial production.

The invention provides high-temperature-resistant textured paper and a preparation process thereof, and belongs to the technical field of textured paper. The preparation process comprises the following steps: preparing the raw paper; preparing a gum dipping solution; and impregnating the raw paper. The preparation method comprises the following steps: by taking p-vinylbenzoic acid and 2-vinylpyridine as functional monomers, mixing the p-vinylbenzoic acid and 2-vinylpyridine with styrene, butadiene and tert-dodecanethiol, adding the mixture into an emulsifier solution, emulsifying to prepare a pre-emulsion, then carrying out copolymerization under the initiation of potassium persulfate to prepare modified styrene-butadiene latex, and introducing carboxyl to form a strong hydrogen bond, so as to obtain the modified styrene-butadiene latex. According to the modified styrene-butadiene latex, the action force between molecular chains is remarkably enhanced, polar nitrogen atoms of pyridine rings and polar groups in adjacent molecular chains can form dipole interaction, the binding force between molecules is enhanced, and then the thermal stability of the styrene-butadiene latex is improved. The high temperature resistance of the prepared masking paper can be effectively improved.

Iodized micellar casein is produced by adding, to an aqueous solution of micellar casein, crystalline potassium iodide at a ratio of 1:7-1:9; holding the mixture for 5-10 minutes; adding to the mixture crystalline potassium persulphate at a ratio of 1:8-1:12 crystalline potassium persulphate to micellar casein mass; holding the mixture for 4-8 hours at a temperature of 18-25°С and a pH of 6.5-8.9 while constantly monitoring the molecular iodine content of the solution and periodically adding portions of crystalline potassium persulphate at a ratio of 1:12-1:24 crystalline potassium persulphate to micellar casein mass to continue the iodination reaction; removing residual inorganic salts from the resulting aqueous solution by microfiltration and diafiltration, followed by sterilizing microfiltration and freeze drying or spray drying. The method makes it possible to produce iodized micellar casein that is suitable for creating products for preventing iodine deficiency and optimizing iodine metabolism and for preventing and protecting against radiation poisoning.

The invention discloses a silicon carbide substrate rough polishing composition and a preparation method and application thereof, and belongs to the technical field of semiconductor device processing. The rough polishing composition for the silicon carbide substrate is a polishing composition obtained by adjusting the pH value of a basic system to 3-4 by using a pH regulator; the basic system comprises the following components in percentage by mass: 2-10% of an abrasive, 2-6% of a first oxidant, 2-10% of a second oxidant and 0.5-2% of a dispersing agent besides water; the first oxidant is potassium permanganate; the second oxidizing agent is potassium persulfate or ferric persulfate. According to the method, the combination of potassium permanganate and persulfate is used as an oxidizing agent, and the rough polishing efficiency and uniformity of silicon carbide are remarkably improved through oxidation potential complementation, acidic environment synergy, free radical catalysis chain reaction and surface wettability optimization.

The invention relates to the field of industrial waste gas treatment, and discloses a technology for removing NOx and SOs in industrial flue gas through an ultrasonic atomization wet method. The technology comprises the steps that S1, the industrial flue gas is cooled and dedusted; s2, performing oxidation washing on NO by using a first washing solution and a second washing solution respectively; s3, absorbing NOx and SOs generated by oxidation of the industrial flue gas by using an absorption liquid subjected to ultrasonic atomization; s4, carrying out demisting treatment on the industrial flue gas; a first washing solution in the step S2 is a 0.5-1.5 wt% potassium persulfate aqueous solution, and a second washing solution is composed of 1-2wt% of ferrous sulfate, 0.5-1wt% of EDTA and the balance of water; the absorption liquid in the step S3 is prepared from basic hydroxide, carbonate, an interface modifier and water. According to the ultrasonic atomization wet process, the solid precipitation amount of the absorption liquid is small, the NOx and SOabsorptivity is high, and equipment cannot be corroded after long-term use.

The invention discloses a regenerated carbon aggregation medium as well as a preparation method and application thereof, and belongs to the technical field of organic matter recovery. The preparation method comprises the following steps: by taking a carbon aggregation medium enriched with organic matters as a matrix and hydrochloric acid or a hydroxide modifier, carrying out hydrothermal reaction in a stirring state, filtering, drying and grinding to obtain hydrothermal regenerated carbon; and adding water into the hydrothermal regenerated carbon, adjusting the pH value to 2-7, heating to 50-70 DEG C, adding potassium persulfate and a methacryloyloxyethyl trimethyl ammonium chloride solution in a protective atmosphere, and carrying out graft copolymerization reaction on the hydrothermal regenerated carbon and methacryloyloxyethyl trimethyl ammonium chloride under the initiation action of potassium persulfate to obtain the regenerated carbon aggregation medium. The grafting rate, grafting efficiency and charge density of the prepared regenerated carbon aggregation medium can reach 7.76%, 7.96% and 1.132 mmol / g respectively, and the removal rates of COD (Chemical Oxygen Demand) and turbidity are 62.81% and 88.87% respectively.

The application relates to a sensor for synchronously detecting enniatin and roquefortine based on a double-potential electrochemiluminescence immunoassay technology as well as a preparation method and a detection method thereof. The sensor comprises a base electrode, a sensing interface composed of a nanocomposite is modified on the surface of the base electrode, mixed coated antigens including ENNs-BSA and AOH-BSA fixed on the sensing interface, mixed probes including a cathode probe and an anode probe, the cathode probe is Zr-Por-MOF-ENNs Ab which is obtained by marking ENNs antibodies with a porphyrin zirconium metal organic framework, the anode probe is Ce-In-MOF@ABEI-AOH Ab which is obtained by marking AOH antibodies with ABEI loaded on a cerium-doped indium metal organic framework, and a detection solution containing a single co-reactant potassium persulfate. The application can realize one-time sample adding, double-potential scanning and synchronous quantification for two kinds of mycotoxins of enniatin and roquefortine.

The application discloses an ECL biosensor for detecting microcystin. Under the excitation of a photomultiplier tube, AuNC and a co-reactant, potassium persulfate (K2S2O8), directly react to generate AuNC •+ and SO4 •‑ , SO4 •‑ is reduced to SO4 •+ by AuNC 2‑ , and AuNC * is generated simultaneously, wherein AuNC * is an excited state of AuNC, and the excited state is transitioned to a ground state to release light intensity, which is captured by an ECL instrument to generate an ECL signal. With the increase of the content of MC-LR, the ECL signal is stronger, so that quantitative detection of the content of MC-LR is realized. The biosensor platform has a wide detection range from 0.1 pM to 1 nM, and the detection limit is as low as 62.3 fM. The application can realize rapid detection of low-concentration target microcystin MC-LR, and can be applied to detection in various samples, such as food, medicine, milk, beverage, water and the like.

This invention relates to a method for preparing a broadband absorption hydrogel. The method comprises the following steps: S1, mixing solvent A (N,N-dimethylformamide or acetonitrile) with deionized water to obtain a mixed solvent; S2, adding polyethylene glycol methyl ether acrylate-480 and acryloylmorpholine to the solvent in S1 and dissolving them to obtain a mixed solution; S3, removing dissolved oxygen from the mixed solution in S2, sealing the container, and stirring under ice bath conditions; S4, adding potassium persulfate and N,N,N',N'-tetramethylethylenediamine to the mixed solution after stirring in S3, and sealing the container again; S5, completing the polymerization reaction in the container at 60 °C to obtain the hydrogel. Compared with the prior art, the hydrogel material provided by this invention has improved reflection loss intensity and effective absorption bandwidth performance, thus providing a new perspective for developing highly flexible and efficient electromagnetic wave absorbers.

The invention belongs to the technical field of packaging materials. The invention relates to an adhesive, in particular to a PVA adhesive tape adhesive and a preparation method thereof. The preparation method comprises the following specific preparation steps: mixing guar gum and water according to a mass ratio of 1: (15-20) for swelling, adding endo-beta-glucanase accounting for 0.3-0.5% of the mass of the guar gum, carrying out ultrasonic enzymolysis reaction for 30-45 minutes under the conditions that the pH is 5.0-5.2, the temperature is 48-52 DEG C and the ultrasonic frequency is 50-60 kHz, heating for enzyme deactivation, and cooling to obtain an activated vegetable gum solution; uniformly stirring and mixing a PVA (Polyvinyl Alcohol) solution and the activated vegetable glue solution, adding a thickening agent solution, continuously stirring and mixing uniformly, adding a composite modifier and potassium persulfate, carrying out heat preservation curing reaction for 2-4 hours at the temperature of 40-45 DEG C, aging for 24-36 hours, and discharging to obtain a mixed glue solution; and coating the mixed adhesive solution, and drying to obtain the PVA adhesive tape adhesive.

Embodiments herein relate to recycling of used lithium battery materials. In some aspects, a method may include suspending a lithium source in a solvent containing an oxidizing agent to extract lithium, forming an extracted lithium solution, separating the extracted lithium solution from residual solids of the lithium source, purifying the extracted lithium solution by precipitating and filtering impurities, and precipitating lithium in the purified lithium solution to produce lithium carbonate (Li2CO3). In some embodiments, the method may also include pre-treating the lithium source to improve the kinetics of the lithium extraction. In some embodiments, the pretreatment may include a cutting or comminution step to reduce the size of the lithium source. In some embodiments, the lithium source may include lithium ion battery waste. In some embodiments, the oxidizing agent may include sodium persulfate (Na2S2O8), potassium persulfate ((NH4) 2S2O8), ammonium persulfate (NH4) 2S2O8, hydrogen peroxide (H2O2), ozone (O3), and / or nitrous oxide (N2O).