1119 results about "Butyl methacrylate" patented technology

A coating composition for use in coating implantable medical devices to improve their ability to release bioactive agents in vivo. The coating composition is particularly adapted for use with devices that undergo significant flexion and/or expansion in the course of their delivery and/or use, such as stents and catheters. The composition includes the bioactive agent in combination with a mixture of a first polymer component such as poly(butyl methacrylate) and a second polymer component such as poly(ethylene-co-vinyl acetate).

A coated coronary stent, comprising: a stainless steel sent framework coated with a primer layer of Parylene C; and a rapamycin-polymer coating having substantially uniform thickness disposed on the stent framework, wherein the rapamycin-polymer coating comprises polybutyl methacrylate (PBMA), polyethylene-co-vinyl acetate (PEVA) and rapamycin, wherein substantially all of the rapamycin in the coating is in amorphous form and substantially uniformly dispersed within the rapamycin-polymer coating.

The invention relates to a process for producing a coated drug form or a drug form in the form of an active ingredient matrix, by processing a copolymer, an active pharmaceutical ingredient, a core if present and/or pharmaceutically customary excipients in a conventional manner by melting, injection molding, extrusion, wet granulation, casting, dipping, spreading, spraying or compression to form a coated drug form and/or to form an active ingredient matrix, characterized in that a copolymer is used which is composed of 20 to 33% by weight methacrylic acid, 5 to 30% by weight methyl acrylate, 20 to 40% by weight ethyl acrylate and more than 10 to 30% by weight butyl methacrylate and, if desired, 0 to 10% by weight further vinylically copolymerizable monomers, with the proviso that the glass transition temperature of the copolymer in accordance with ISO 11357-2, section 3.3.3, is 55 to 70° C. The invention further relates to the drug form produced in accordance with the invention, to the copolymer, and to the use thereof.

Coating compositions containing bioactive agents, and medical devices coated with compositions containing bioactive agents are described. In certain embodiments the coating compositions comprise a first layer, said first layer containing a bioactive agent and a polymeric material derived from poly[vinylpyrrolidone]; and a second layer outside said first layer, said second layer comprising poly(butylmethacrylate) and poly(ethylene-co-vinyl acetate). In some example embodiments the coating composition further comprises a third layer outside said first layer, said third layer comprising poly(butylmethacrylate).

The invention relates to a preparation method of a foamed porous graphene/polypyrrole composite oil absorption material, belonging to the technical fields of environmental protection and composite materials. The method is characterized by comprising the following steps: carrying out KH570 functionalization on graphite oxide prepared from graphite; carrying out ultrasonic treatment on the functionalized graphite oxide product to obtain a graphene oxide aqueous solution with a certain concentration, adding certain amounts of pyrrole, styrene or butyl methacrylate or lauryl methacrylate and an initiator (ammonium persulfate or potassium persulfate); carrying out thermostatic reaction in a hydrothermal reaction kettle for 10 hours, thereby obtaining a black solid; and carrying out freeze-drying on the black solid to obtain the foamed porous graphene/polypyrrole composite oil absorption material in a three-dimensional structure. The graphene/polypyrrole composite oil absorption material ina three-dimensional structure is prepared by a chemical process, so the material has hydrophobicity and large specific area of the graphene, can contain abundant oil molecules, and has high oil adsorbability. The preparation method is simple to operate, and has the advantage of mild reaction conditions.

The present invention is directed to a water-based acrylic emulsion dispersant to be used as a grind resin to incorporate inorganic pigment into a pigment dispersion for a coating composition. The acrylic emulsion dispersant is the reaction product of butyl methacrylate, butyl acrylate, styrene, methyl ether polyethylene glycol methacrylate, polyethylene glycol methacrylate, and polyphosphoric acid. The present invention is also directed to a method of preparing the acrylic emulsion dispersant. In this method, the butyl methacrylate, butyl acrylate, and styrene are combined with water to establish a first reaction blend. Similarly, the methyl ether polyethylene glycol methacrylate and the polyethylene glycol methacrylate are combined with water to establish a second reaction blend. Next, the first and second reaction blends are polymerized to form an intermediate emulsion polymer containing a hydroxyl group from the functionality of the polyethylene glycol methacrylate. Finally, the hydroxyl group from the polyethylene glycol methacrylate is reacted with polyphosphoric acid to form the acrylic emulsion dispersant which is utilized for efficient wetting and grinding of the pigment.

The invention relates to an organic-inorganic composite oil-absorbing material formed by compounding an acrylic ester monomer with attapulgite, and a preparation method thereof. The oil-absorbing material takes the following components as raw materials in parts by weight: 50-60 parts of acrylic ester, 35-50 parts of styrene, 0.5-2 parts of initiator, 0.2-1 part of cross-linking agent, 1-5 parts of dispersant and 1-10 parts of the attapulgite. The preparation method comprises the following steps of: based on a polyvinyl alcohol water solution as a reaction system, adding a mixed solution formed by uniformly mixing butyl methacrylate, styrene, the initiator, the cross-linking agent, and attapulgite under the protection of inert gas to react; and then washing to obtain the product. Compared with the traditional oil-absorbing material, the organic-inorganic composite oil-absorbing material has the advantages of high oil-absorbing multiplying power, oil retention rate and repeated oil-absorbing times, and has a potential application prospect on the aspect of environmental protection.

The invention relates to a moisture-absorbing and perspiring anti-bacterial fabric and a preparation technology thereof. The moisture-absorbing and perspiring anti-bacterial fabric is blended and weaved by the following raw materials in parts by weight: 40 to 80 parts of bamboo fibers, 40 to 80 parts of long staple, 10 to 30 parts of ramie, 10 to 30 parts of coolmax fibers, 10 to 20 parts of corn fibers, 10 to 20 parts of Delight fibers, and 5 to 20 parts of Tancel, and then is treated by anti-bacterial finishing liquid; the anti-bacterial finishing liquid comprises 5 to 10 parts of chitosan, 5 to 10 parts of silk fibroin, 0.5 to 3 parts of butyl ricinoleate sodium sulfate, 0.5 to 3 parts of lemon acid, 0.5 to 2 parts of butyl methacrylate, 5 to 8 parts of dodecyl diphenyl ether sodium disulfonate, 5 to 10 parts of hydroxypropyl methyl cellulose, 5 to 10 parts of polyhexamethylene biguanidine, 5 to 15 parts of organosilicon quaternary ammonium salt, 3 to 8 parts of dodecyl trimethyl ammonium chloride, and 5 to 10 parts of water-based polyurethane. The moisture-absorbing and perspiring anti-bacterial fabric has the advantages that the anti-bacterial property is higher, the moisture-absorbing, perspiring, anti-pilling and air-ventilation properties are realized, the softness is realized, and the abrasion is resisted; the moisture-absorbing and perspiring anti-bacterial fabric is particularly suitable for being applied to the fields of underwear, overwear, sportswear and bedding articles.

The invention discloses a coloring agent for a textile fabric. The coloring agent consists of the following ingredients in parts by weight: 1 to 2 parts of polypropylene glycol, 2 to 3 parts of tetracarboxydiphthalic ether dianhydride (ODPA), 1 to 2 parts of zinc stearate, 4 to 5 parts of trimethylolpropane, 4 to 5 parts of mica powder, 5 to 6 parts of butyl methacrylate, 4 to 5 parts of dibutyltin dilaurate, 3 to 4 parts of polyurethane, 6 to 7 parts of iron oxide red, 1 to 2 parts of dibutyl phthalate, 3 to 4 parts of ethyl acetate, 3 to 4 parts of an initiator, 5 to 6 parts of closed blocked isocyanate, 5 to 6 parts of water and 2 to 3 parts of polyvinylpyrrolidone. The coloring agent for the textile fabric is easy for coloring and unlikely to fade.

The invention provides a water-based room temperature crosslinking acrylic acid emulsion and a preparation method thereof, wherein, the water-based room temperature crosslinking acrylic acid emulsion comprises the following components by weight percent: 10-40% of methylmethacrylate, 0-40% of styrene, 0-3% of methacrylic acid, 0.5-1.5% of acrylic acid, 0.5-2% of N-hydroxylacrylamide, 1-3% of ethylmethacrylate, 1-23% of butyl methacrylate, 1-3% of emulsifier, 0.3-1% of initiator, 0.1-0.5% of sodium bicarbonate, 3-9% of neutralizer, 30-60% of water, 0.1-1% of inhibition stabilizer and 0.05-2% of crosslinking agent. In the process of polymerization, the crosslinking monomers (modified monomers) like acrylic acid, methacrylic acid and N-hydroxylacrylamide are introduced to perform carboxyl crosslinking, hydroxyl crosslinking and amido crosslinking with copolymer so that the cohesive strength, heat resistance and ageing resistance of emulsion are obviously increased and the stability of emulsion is increased; the inhibition stabilizer is used so as to prolong the service life.

The invention discloses a preparation method of nano SiO2/ACR composite particles and application thereof. The method comprises the following steps: adopting ultrasonic to assisting in pre-emulsifying a monomer, and taking an anionic/nonionic compound emulsifier as the emulsifier; taking ethyl acrylate as the monomer to prepare seed latex; taking butyl methacrylate and the ethyl acrylate as the monomers and a compound crossinking agent consisting of N,N'-methylene bisacrylamide (BIS) and a compound CH2=CHRCH2COOR' to prepare an inner core; taking the methyl methacrylate and the butyl methacrylate as the monomers and the compound crosslinking agent consists of the BIS and the CH2=CHRCH2COOR' to prepare a shell; adding nano SiO2 emulsion which is modified by soft water and a siloxane coupling agent while preparing the shell so that SiO2 produces a grafting reaction at the shell of core-shell polyacrylate (ACR); and finally obtaining the nano SiO2/ACR composite particles with excellent impact resistance and the like. The prepared composite particles are applied to preparing PVC as an impact modifier, and have excellent impact resistance, good dispersivity and good mechanical properties.

The invention relates to a polymer-type water glass curing agent with easily-controlled curing time and high toughness. The curing agent is mainly formed by polymerizing and copolymerizing double bonds-containing acids such as crylic acid, methacrylic acid and the like and double bonds-containing esters such as butyl methacrylate, vinyl acetate, hydroxy-ethyl methacrylate and the like by latex. The polymer-type water glass curing agent of the invention is a novel water-soluble water glass curing agent, which can control the curing time of the water-soluble grouting materials by controlling the content of carboxyl and ester group in a polymer. By using the curing agent, a water glass consolidating body has vey high compressive strength and toughness, synthetically overcomes the shortages of too fast curing time, high corrosiveness, low consolidating body strength and the like of an acid curing agent which is commonly used in the water glass grouting materials and the shortages of poor water solubility, slow curing time and the like of an organic ester curing agent, and can be widely applied in the field of anti-seepage stoppage engineering.

The invention discloses a modification method for ground calcium carbonate powder (referred to as coarse whiting powder, the same below). The modifying agent of the coarse whiting powder is the composite compatilizer which comprises the components of polymer maleic anhydride-acrylamide-n-butyl methacrylate and stearic acid. Two-time modification is performed, the first modification adopts a wet method about in-situ polymerization with the modifying agent of polymer maleic anhydride-acrylamide-n-butyl methacrylate, and the second modification adopts a dry method with the modifying agent of stearic acid; the brief method comprises the steps as follows: fully mixing the coarse whiting powder, the polymer maleic anhydride-acrylamide-n-butyl methacrylate and the stearic acid, and dissolving the mixture into the mixed liquor formed by liquid paraffin and swill-cooked dirty oil, wherein the total organic matters account for 1 to 3 percent of the coarse whiting powder (mass fraction); the volume ratio of liquid paraffin to swill-cooked dirty oil is 1:1, and mass ratio of the polymer maleic anhydride-acrylamide-n-butyl methacrylate to the stearic acid is 2:1. According to the invention, the active coarse whiting powder can be used as filler of chlorinated polyvinyl chloride, polyvinyl chloride and polyethylene. The active coarse whiting powder is good in dispersion uniformity in the resin, and low in cost, and oriented towards industrialized production.

The invention discloses a CBN (cubic boron nitride) resin grinding wheel and a preparation method of the CBN resin grinding wheel. The CBN resin grinding wheel is prepared from the following components in parts by weight, 50-60 parts of CBN grinding material, 5-10 parts of white corundum grinding material, 5-10 parts of silicon carbide powder, 5-15 parts of phenolic resin powder, 2-6 parts of phenolic resin liquid, 1-2 parts of n-butyl methacrylate, 5-10 parts of nano dolomite dust, 5-10 parts of nano quartz sand powder, 2-5 parts of micro polyamide wax mist and 2-5 parts of steel scrap powder. According to the CBN resin grinding wheel and the preparation method of the CBN resin grinding wheel, as a ceramic material is added into padding, the adhesive property is good, the grinding materials hardly fall off, the heat resistance and hardness of the resin grinding wheel are improved, and cracks formed by rigid grinding are reduced, thereby the use efficiency and service life of the resin grinding wheel are improved further; and in addition, as steel power is added, fast heat dissipation effect is achieved, a great deal of heat generated in a cutting process of the grinding wheel can be dissipated quickly, and the effect of lowering cutting temperature is achieved.

The invention relates to mirror back paint resin and curtain flow coating. Its features are that the resin solid component includes 50-70% medium oil length alkyd resin, 20-40% multi-hydroxy acrylic acid resin, and 10-20% polyurethane resin; middle resin is formed by medium oil length alkyd resin, acrylamide, ethoxyl methacrylate, and butyl methacrylate monomer; the mirror back paint resin is formed by the middle resin and toluene diisocynate. Its viscosity is 100-300s; acid value is under 5mgKOH/g. The coating is formed by the resin, proper cross-linking resin, pigment, extender pigment, auxiliary agent, and solvent has low curing temperature, high-speed, high hardness of paint film, good flexibility, adhesive force, and chemical resistance. It can be applied to our country silver mirror production line to ensure the product quality.

The invention discloses attapulgite-modified polyvinyl chloride (PVC) synthetic leather. The attapulgite-modified PVC synthetic leather comprises a surface layer, a foamed layer, a bonding layer and a brushing fabric, and is characterized in that the surface layer is prepared by mixing the following raw materials in parts by weight to form slurry: 70 to 80 parts of SG-2 type PVC resin, 30 to 40 parts of SG-5 type PVC resin, 10 to 15 parts of triethyl citrate, 30 to 35 parts of epoxy butyl oleate, 20 to 25 parts of n-butyl methacrylate, 5 to 6 parts of PVC color paste, 1 to 2 parts of dibasic lead phosphate, 1 to 2 parts of tribasic lead sulfate and 5 to 10 parts of modified diatomite. Through the improvements of the formula and the process, the flexibility of the synthetic leather is improved, and the synthetic leather has a natural comfortable hand feeling similar to that of natural leather and is difficult to damage or tear after being used for 3 to 5 years.

The invention discloses acoustic wool with high impact resistance. The acoustic wool is prepared from, by weight, 1-2 parts of barium stearate, 0.5-1 part of sodium xylene sulfonate, 5-10 parts of zircon powder, 3-5 parts of silicon carbide, 1-2 parts of ethylene bis stearamide, 80-100 parts of polypropylene, 2-4 parts of styrene, 1-2 parts of epoxy rice bran oleic acid butyl ester, 3-5 parts of butyl methacrylate, 1-2 parts of polyethylene glycol, 0.05-0.1 part of azodiisobutyronitrile, 0.5-1 part of castor oil and 3-5 parts of functional powder. The acoustic wool is good in sound absorption effect and mechanical performance, high in durability, high in impact resistance, less prone to deformation, good in processing performance, capable of absorbing harmful substances in air, effectively purifying the air and protecting human health, high in comprehensive value and high in practicality.

The present invention relates to an environmentally friendly shell powder functional coating, a preparation method therefor and uses thereof. The coating comprises: bisphenol A-epon, modified shell powder, vegetable extract, propyl silicone emulsion, a nano additive, a modified organic micro powder agent, a surfactant, dioctylphthalate, 3, 3'-(4-trifluoromethyl methyl)-bi-4-hydroxy coumarin, 2,2,4-amino trimethyl-1,3-isoprene glycol mono iso-butyl methacrylate, butyl acetate, ethanol, trimethylol propane triacrylate, N-ammonia amino ethyl piperazine, polydimethylsiloxane and deionized water. In the present invention, by modification of a variety of components and materials, selection and collocation of specific components and a specific preparation method, the variety of components exert a synergistic effect, so as to make the prepared coating have significant antimicrobial, environmental-cleaning and wear-resisting properties. The coating has a huge application potential and extensive value in industrial production.

The invention pertains to the technology field of micro total analysis, relating to a three-dimensional micro-flow control chip which includes an in-situ polybutyl methacrylate pretreatment integral pole. The polymer butyl methacrylate pretreatment integral pole is prepared by ultraviolet-radiated in-situ polymerization in the micro-channel on the micro-flow control chip; the substrate of the micro-flow chip can adopt glass, silicon, polymethyl methacrylate (PMMA) or poly(dimethylsiloxane) (PDMS), and the like as base materials, and etched with micro-channel networks for fluid mixing and reaction; the cover plate adopts PDMS integral casting method to fabricate the micro-channels of the solid-phase extracting and processing unit, a fluid lead-in/lead-out hole is arranged at the position corresponding to each micro-channel opening of the substrate, and is directly bounded with the substrate, and integration of the sample pretreatment integral pole and the micro-flow control chip micro-pipeline network is realized. The chip has the advantages of easy fabrication, low cost, small sampling quantity, rapid compartment analysis, and is applicable to pretreatment, analysis and test of sophisticated biochemical samples.